Journal articles on the topic 'Cationic 2-Aza- Cope rearrangement'
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Jacobsen, E. Jon, Jeremy Levin, and Larry E. Overman. "Synthesis applications of cationic aza-Cope rearrangements. Part 18. Scope and mechanism of tandem cationic aza-Cope rearrangement-Mannich cyclization reactions." Journal of the American Chemical Society 110, no. 13 (1988): 4329–36. http://dx.doi.org/10.1021/ja00221a037.
Full textStas, Sara, Kourosch Abbaspour Tehrani, and Georges Laus. "Carbon–carbon bond formation via a tandem cationic 2-aza-Cope rearrangement–Lewis acid promoted Petasis reaction." Tetrahedron 64, no. 16 (2008): 3457–63. http://dx.doi.org/10.1016/j.tet.2008.02.025.
Full textAron, Zachary D., and Larry E. Overman. "Stereocontrolled Synthesis of Angularly Substituted 1-Azabicyclic Rings by Cationic 2-Aza-Cope Rearrangements." Organic Letters 7, no. 5 (2005): 913–16. http://dx.doi.org/10.1021/ol047330z.
Full textBrummond, Kay M., and Sang-phyo Hong. "A Formal Total Synthesis of (−)-FR901483, Using a Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclization Approach." Journal of Organic Chemistry 70, no. 3 (2005): 907–16. http://dx.doi.org/10.1021/jo0483567.
Full textCooke, Andrew, Jonathan Bennett, and Emma McDaid. "A facile synthesis of N -benzyl-4-acetylproline via a tandem cationic aza-Cope rearrangement-Mannich reaction." Tetrahedron Letters 43, no. 5 (2002): 903–5. http://dx.doi.org/10.1016/s0040-4039(01)02287-0.
Full textOverman, Larry E., and Soji Sugai. "Total Synthesis of (?)-Crinine. Use of Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclizations for the Synthesis of Enantiomerically PureAmaryllidaceae Alkaloids." Helvetica Chimica Acta 68, no. 3 (1985): 745–49. http://dx.doi.org/10.1002/hlca.19850680324.
Full textOVERMAN, L. E., and J. SHIM. "ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangement. Part 24. First Total Synthesis of Amaryllidaceae Alkaloids of the 5,11- Methanomorphanthridine Type. An Efficient Total Synthesis of (.+-.)- Pancracine (I)." ChemInform 23, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.199203253.
Full textWu, Pei Lin, and Frank W. Fowler. "The 1-aza-Cope rearrangement. 2." Journal of Organic Chemistry 53, no. 26 (1988): 5998–6005. http://dx.doi.org/10.1021/jo00261a003.
Full textKobayashi, S., M. Sugiura, and C. Mori. "Synthesis of Homoallylic Amines via 2-Aza-Cope Rearrangement." Synfacts 2006, no. 10 (2006): 1061. http://dx.doi.org/10.1055/s-2006-949377.
Full textAgami, Claude, François Couty, Jing Lin, Axelle Mikaeloff та Michel Poursoulis. "Asymmetric synthesis of α-amino acids via cationic aza-cope rearrangements". Tetrahedron 49, № 33 (1993): 7239–50. http://dx.doi.org/10.1016/s0040-4020(01)87201-x.
Full textMerino, Pedro, Tomás Tejero, and Vanni Mannucci. "Experimental and theoretical evidences of 2-aza-Cope rearrangement of nitrones." Tetrahedron Letters 48, no. 19 (2007): 3385–88. http://dx.doi.org/10.1016/j.tetlet.2007.03.071.
Full textKnight, Steven D., Larry E. Overman, and Garry Pairaudeau. "Synthesis applications of cationic aza-Cope rearrangements. 26. Enantioselective total synthesis of (-)-strychnine." Journal of the American Chemical Society 115, no. 20 (1993): 9293–94. http://dx.doi.org/10.1021/ja00073a057.
Full textAGAMI, C., F. COUTY, J. LIN, A. MIKAELOFF та M. POURSOULIS. "ChemInform Abstract: Asymmetric Synthesis of α-Amino Acids via Cationic Aza-Cope Rearrangements." ChemInform 24, № 50 (2010): no. http://dx.doi.org/10.1002/chin.199350286.
Full textOverman, Larry E., Graeme M. Robertson, and Albert J. Robichaud. "Synthesis applications of cationic aza-Cope rearrangements. 20. Total synthesis of (.+-.)-meloscine and (.+-.)-epimeloscine." Journal of Organic Chemistry 54, no. 6 (1989): 1236–38. http://dx.doi.org/10.1021/jo00267a003.
Full textKawashima, Takayuki, Tsutomu Kihara, and Naoki Inamoto. "The Azaphospha-Cope Rearrangement of 2-Aza-3-phospha-1,5-hexadiene Derivatives." Chemistry Letters 17, no. 4 (1988): 577–80. http://dx.doi.org/10.1246/cl.1988.577.
Full textZahedi, Ehsan, Safa Ali-Asgari, and Vahid Keley. "NBO and NICS analysis of the allylic rearrangements (the Cope and 3-aza-Cope rearrangements) of hexa-1,5-diene and N-vinylprop-2-en-1-amine: A DFT study." Open Chemistry 8, no. 5 (2010): 1097–104. http://dx.doi.org/10.2478/s11532-010-0084-1.
Full textGadde, Karthik, Jonas Daelemans, Bert U. W. Maes та Kourosch Abbaspour Tehrani. "Lewis acidic FeCl3 promoted 2-aza-Cope rearrangement to afford α-substituted homoallylamines in dimethyl carbonate". RSC Advances 9, № 31 (2019): 18013–17. http://dx.doi.org/10.1039/c9ra03277k.
Full textGadde, Karthik, Bert U. W. Maes та Kourosch Abbaspour Tehrani. "HFIP-mediated 2-aza-Cope rearrangement: metal-free synthesis of α-substituted homoallylamines at ambient temperature". Organic & Biomolecular Chemistry 19, № 18 (2021): 4067–75. http://dx.doi.org/10.1039/d1ob00404b.
Full textHastings, Courtney J., Dorothea Fiedler, Robert G. Bergman, and Kenneth N. Raymond. "Aza Cope Rearrangement of Propargyl Enammonium Cations Catalyzed By a Self-Assembled “Nanozyme”." Journal of the American Chemical Society 130, no. 33 (2008): 10977–83. http://dx.doi.org/10.1021/ja8013055.
Full textSun, Xi-Shang, Xing-Heng Wang, Hai-Yan Tao, Liang Wei та Chun-Jiang Wang. "Catalytic asymmetric synthesis of quaternary trifluoromethyl α- to ε-amino acid derivatives via umpolung allylation/2-aza-Cope rearrangement". Chemical Science 11, № 40 (2020): 10984–90. http://dx.doi.org/10.1039/d0sc04685j.
Full textSugiura, Masaharu, Chieko Mori, Keiichi Hirano та Shū Kobayashi. "Direct synthesis of unprotected α-amino acids via allylation of hydroxyglycine". Canadian Journal of Chemistry 83, № 6-7 (2005): 937–42. http://dx.doi.org/10.1139/v05-096.
Full textKNIGHT, S. D., L. E. OVERMAN, and G. PAIRAUDEAU. "ChemInform Abstract: Applications of Cationic Aza-Cope Rearrangements. Part 26. Enantioselective Total Synthesis of (-)-Strychnine." ChemInform 25, no. 4 (2010): no. http://dx.doi.org/10.1002/chin.199404253.
Full textGoodman, C. Guy, та Jeffrey S. Johnson. "Asymmetric Synthesis of β-Amino Amides by Catalytic Enantioconvergent 2-Aza-Cope Rearrangement". Journal of the American Chemical Society 137, № 46 (2015): 14574–77. http://dx.doi.org/10.1021/jacs.5b09593.
Full textKATRITZKY, A. R., D. FENG, M. QI, H. LANG, and P. J. STEEL. "ChemInform Abstract: Synthesis of 3-Alkylideneindolin-2-ones via 3-Aza-Cope Rearrangement." ChemInform 29, no. 11 (2010): no. http://dx.doi.org/10.1002/chin.199811131.
Full textAngle, Steven R., John M. Fevig, Steven D. Knight, Robert W. Marquis, and Larry E. Overman. "Synthesis applications of cationic aza-Cope rearrangements. 24. The aza-Cope-Mannich approach to Strychnos alkaloids. Short stereocontrolled total syntheses of (.+-.)-dehydrotubifoline and (.+-.)-akuammicine." Journal of the American Chemical Society 115, no. 10 (1993): 3966–76. http://dx.doi.org/10.1021/ja00063a016.
Full textDoedens, Robert J., Guy P. Meier, and Larry E. Overman. "Synthesis applications of cationic aza-Cope rearrangements. Part 17. Transition-state geometry of [3,3]-sigmatropic rearrangements of iminium ions." Journal of Organic Chemistry 53, no. 3 (1988): 685–90. http://dx.doi.org/10.1021/jo00238a039.
Full textTsuda, Masato, Taiki Morita, Shintaro Fukuhara, and Hiroyuki Nakamura. "Synthesis of 4-amino-5-allenylisoxazoles via gold(i)-catalysed propargyl aza-Claisen rearrangement." Organic & Biomolecular Chemistry 19, no. 6 (2021): 1358–64. http://dx.doi.org/10.1039/d0ob02544e.
Full textOverman, Larry E., Mark E. Okazaki, and E. Jon Jacobsen. "Synthesis applications of cationic aza-Cope rearrangements. 16. Stereocontrolled synthesis of substituted cis-cyclopenta[b]pyrrolidines." Journal of Organic Chemistry 50, no. 13 (1985): 2403–5. http://dx.doi.org/10.1021/jo00213a049.
Full textOverman, Larry E., and Steven R. Angle. "Synthesis applications of cationic aza-Cope rearrangements. Stereocontrolled synthesis of hexahydro-1H-pyrrolo[2,3-d]carbazoles." Journal of Organic Chemistry 50, no. 21 (1985): 4021–28. http://dx.doi.org/10.1021/jo00221a012.
Full textANGLE, S. R., J. M. FEVIG, S. D. KNIGHT, R. W. JUN MARQUIS, and L. E. OVERMAN. "ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 24. Aza-Cope-Mannich Approach to Strychnos Alkaloids. Short Stereocontrolled Total Syntheses of (.+-.)-Dehydrotubifoline and (.+-.) -Akuammicine." ChemInform 24, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199340279.
Full textLukowski, Mark, Kathryn Jacobs, Powen Hsueh, Harriet A. Lindsay, and M. C. Milletti. "Thermodynamic and kinetic factors in the aza-Cope rearrangement of a series of iminium cations." Tetrahedron 65, no. 50 (2009): 10311–16. http://dx.doi.org/10.1016/j.tet.2009.10.010.
Full textDenmark, Scott, and Hyung Chi. "Synthesis of 2-Alkenyl-Tethered Anilines." Synthesis 49, no. 13 (2017): 2873–88. http://dx.doi.org/10.1055/s-0036-1589002.
Full textMerino, Pedro, Maria Chiacchio, Laura Legnani та Tomás Tejero. "BET & ELF Quantum Topological Analysis of Neutral 2-Aza-Cope Rearrangement of γ-Alkenyl Nitrones". Molecules 22, № 8 (2017): 1371. http://dx.doi.org/10.3390/molecules22081371.
Full textWang, Ruo‐Qing, Chong Shen, Xiang Cheng, et al. "Sequential Ir‐Catalyzed Allylation/ 2‐aza‐Cope Rearrangement Strategy for the Construction of Chiral Homoallylic Amines †." Chinese Journal of Chemistry 38, no. 8 (2020): 807–11. http://dx.doi.org/10.1002/cjoc.202000065.
Full textShen, Chong, Ruo-Qing Wang, Liang Wei, Zuo-Fei Wang, Hai-Yan Tao та Chun-Jiang Wang. "Catalytic Asymmetric Umpolung Allylation/2-Aza-Cope Rearrangement for the Construction of α-Tetrasubstituted α-Trifluoromethyl Homoallylic Amines". Organic Letters 21, № 17 (2019): 6940–45. http://dx.doi.org/10.1021/acs.orglett.9b02543.
Full textLee, Hyun Seung, Sangku Lee, Se Hee Kim, and Jae Nyoung Kim. "Direct one-pot introduction of 2-methylpyridines to Baylis–Hillman adducts via base-mediated 3-aza-Cope rearrangement." Tetrahedron Letters 52, no. 39 (2011): 5039–42. http://dx.doi.org/10.1016/j.tetlet.2011.07.101.
Full textFEVIG, J. M., R. W. JUN MARQUIS, and L. E. OVERMAN. "ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 22. New Approach to Strychnos Alkaloids. Stereocontrolled Total Synthesis of (.+-.)-Dehydrotubifoline." ChemInform 22, no. 41 (2010): no. http://dx.doi.org/10.1002/chin.199141239.
Full textShi, Li-Min, Xi-Shang Sun, Chong Shen, Zuo-Fei Wang, Hai-Yan Tao та Chun-Jiang Wang. "Catalytic Asymmetric Synthesis of α-Trifluoromethyl Homoallylic Amines via Umpolung Allylation/2-Aza-Cope Rearrangement: Stereoselectivity and Mechanistic Insight". Organic Letters 21, № 12 (2019): 4842–48. http://dx.doi.org/10.1021/acs.orglett.9b01738.
Full textLee, Hyun Seung, Sangku Lee, Se Hee Kim, and Jae Nyoung Kim. "ChemInform Abstract: Direct One-Pot Introduction of 2-Methylpyridines to Baylis-Hillman Adducts via Base-Mediated 3-Aza-Cope Rearrangement." ChemInform 43, no. 2 (2011): no. http://dx.doi.org/10.1002/chin.201202156.
Full textObrecht, Daniel, Cornelia Zumbrunn та Klaus Müller. "Formal [3 + 2] Cycloaddition Reaction of [1,4]Oxazin-2-ones and α-Alkynyl Ketones via a Tandem Mukaiyama-Aldol Addition/Aza-Cope Rearrangement". Journal of Organic Chemistry 64, № 18 (1999): 6891–95. http://dx.doi.org/10.1021/jo9902695.
Full textJin, Ming, Shi-fu Yin та Shang-Dong Yang. "Bismuth(III)-Catalyzed Sequential Enamine–Imine Tautomerism/2-Aza-Cope Rearrangement of Stable β-Enaminophosphonates: One-Pot Synthesis of β-Aminophosphonates". Organic Letters 22, № 7 (2020): 2811–15. http://dx.doi.org/10.1021/acs.orglett.0c00796.
Full textNiu, Dawen, Liqiang Wan, Lan Tian, and Jie Liu. "Iridium-Catalyzed Asymmetric Umpolung Allylation of N-Fluorenyl Imines to Prepare 1,4-Disubstituted Homoallylic Amines." Synlett 28, no. 16 (2017): 2051–56. http://dx.doi.org/10.1055/s-0036-1588514.
Full textKNIGHT, S. D., L. E. OVERMAN, and G. PAIRAUDEAU. "ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 28. Asymmetric Total Syntheses of (-)- and (+)-Strychnine (IX) and the Wieland-Gumlich Aldehyde (VII)." ChemInform 26, no. 38 (2010): no. http://dx.doi.org/10.1002/chin.199538266.
Full textKuang, Jinqiang, Shaista Parveen, and Bernhard Breit. "Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Access to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines." Angewandte Chemie International Edition 56, no. 29 (2017): 8422–25. http://dx.doi.org/10.1002/anie.201704022.
Full textWei, Liang, Lu Xiao, Zuo‐Fei Wang, Hai‐Yan Tao, and Chun‐Jiang Wang. "Ir/Phase‐Transfer‐Catalysis Cooperatively Catalyzed Asymmetric Cascade Allylation/2‐aza‐Cope Rearrangement: An Efficient Route to Homoallylic Amines from Aldimine Esters †." Chinese Journal of Chemistry 38, no. 1 (2019): 82–86. http://dx.doi.org/10.1002/cjoc.201900391.
Full textKuang, Jinqiang, Shaista Parveen, and Bernhard Breit. "Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Access to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines." Angewandte Chemie 129, no. 29 (2017): 8542–45. http://dx.doi.org/10.1002/ange.201704022.
Full textObrecht, Daniel, Cornelia Zumbrunn та Klaus Mueller. "ChemInform Abstract: Formal [3 + 2] Cycloaddition Reaction of [1,4]Oxazin-2-ones and α-Alkynyl Ketones via a Tandem Mukaiyama-Aldol Addition/ Aza-Cope Rearrangement." ChemInform 31, № 3 (2010): no. http://dx.doi.org/10.1002/chin.200003156.
Full textChen, Xiaobei, Huaqiang Fan, Shilei Zhang, Chenguang Yu, and Wei Wang. "Facile Installation of 2-Reverse Prenyl Functionality into Indoles by a Tandem N-Alkylation-Aza-Cope Rearrangement Reaction and Its Application in Synthesis." Chemistry - A European Journal 22, no. 2 (2015): 716–23. http://dx.doi.org/10.1002/chem.201503355.
Full textOverman, Larry E., and Jaechul Shim. "Synthesis applications of cationic aza-Cope rearrangements. Part 25. Total synthesis of Amaryllidaceae alkaloids of the 5,11-methanomorphanthridine type. Efficient total syntheses of (-)-pancracine and (.+-.)-pancracine." Journal of Organic Chemistry 58, no. 17 (1993): 4662–72. http://dx.doi.org/10.1021/jo00069a032.
Full textOverman, Larry E., and Jaechul Shim. "Synthesis applications of cationic aza-Cope rearrangements. 23. First total synthesis of amaryllidaceae alkaloids of the 5,11-methano morphanthridine type. An efficient total synthesis of (.+-.)-pancracine." Journal of Organic Chemistry 56, no. 17 (1991): 5005–7. http://dx.doi.org/10.1021/jo00017a002.
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