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1

Brenn, U., W. Schwieger, and K. Wuttig. "Rearrangement of cationic surfactants in magadiite." Colloid & Polymer Science 277, no. 4 (1999): 394–99. http://dx.doi.org/10.1007/s003960050398.

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2

Klumpp, Douglas A. "Molecular rearrangements of superelectrophiles." Beilstein Journal of Organic Chemistry 7 (March 23, 2011): 346–63. http://dx.doi.org/10.3762/bjoc.7.45.

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Superelectrophiles are multiply charged cationic species (dications, trications, etc.) which are characterized by their reactions with weak nucleophiles. These reactive intermediates may also undergo a wide variety of rearrangement-type reactions. Superelectrophilic rearrangements are often driven by charge–charge repulsive effects, as these densely charged ions react so as to maximize the distances between charge centers. These rearrangements involve reaction steps similar to monocationic rearrangements, such as alkyl group shifts, Wagner–Meerwein shifts, hydride shifts, ring opening reaction
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3

Nakamura, Itaru, Mao Owada, Takeru Jo, and Masahiro Terada. "Cationic cobalt-catalyzed [1,3]-rearrangement of N-alkoxycarbonyloxyanilines." Beilstein Journal of Organic Chemistry 14 (July 31, 2018): 1972–79. http://dx.doi.org/10.3762/bjoc.14.172.

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A cationic cobalt catalyst efficiently promoted the reaction of N-alkoxycarbonyloxyanilines at 30 °C, affording the corresponding ortho-aminophenols in good to high yields. As reported previously, our mechanistic studies including oxygen-18 labelling experiments indicate that the rearrangement of the alkoxycarbonyloxy group proceeds in [1,3]-manner. In this article, we discuss the overall picture of the cobalt-catalysed [1,3]-rearrangement reaction including details of the reaction conditions and substrate scope.
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4

Jankowski, Christopher K., Antoun Bou Laouz, Denis Lesage, and Eduardo Diaz T. "Unusual Rearrangement of Dihalocyclopropanes." Spectroscopy 17, no. 4 (2003): 735–45. http://dx.doi.org/10.1155/2003/209713.

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Dihalocyclopropanation of the double bond of some olefins, leading to dihalocyclopropanes, offered an opportunity to perform their rearrangement to dihalomethylvinyl with Hiyama type reagents, in presence of cationic system such as Cr2+/Cr3+. The chain elongation of alkenes via the gem‒dihalocyclopropanes producedα,β–unsaturated aldehydes and acids.
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5

Jacobsen, E. Jon, Jeremy Levin, and Larry E. Overman. "Synthesis applications of cationic aza-Cope rearrangements. Part 18. Scope and mechanism of tandem cationic aza-Cope rearrangement-Mannich cyclization reactions." Journal of the American Chemical Society 110, no. 13 (1988): 4329–36. http://dx.doi.org/10.1021/ja00221a037.

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6

Sedenkova, Kseniya N., Elena B. Averina, Yuri K. Grishin, Victor B. Rybakov, Tamara S. Kuznetzova, and Nikolay S. Zefirov. "Cationic Carbenoid Rearrangement of 2-Phenyl Substituted gem-Dihalogenospiropentanes." European Journal of Organic Chemistry 2010, no. 21 (2010): 4145–50. http://dx.doi.org/10.1002/ejoc.201000427.

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7

Li, Man-Rong, Maria Retuerto, Peter W. Stephens, et al. "Low-Temperature Cationic Rearrangement in a Bulk Metal Oxide." Angewandte Chemie 128, no. 34 (2016): 10016–21. http://dx.doi.org/10.1002/ange.201511360.

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8

Li, Man-Rong, Maria Retuerto, Peter W. Stephens, et al. "Low-Temperature Cationic Rearrangement in a Bulk Metal Oxide." Angewandte Chemie International Edition 55, no. 34 (2016): 9862–67. http://dx.doi.org/10.1002/anie.201511360.

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9

Clarke, DB, and RT Weavers. "The Chemistry of Laurenene. XVI. Investigation of the Mechanism of a Cationic Rearrangement." Australian Journal of Chemistry 46, no. 8 (1993): 1163. http://dx.doi.org/10.1071/ch9931163.

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Some aspects of the mechanism of the acid-induced rearrangement of laurenan-2β-ol have been deduced from deuterium- labelling studies. A key intermediate arises from two pathways, one involving a 1,4- and one a 1,5-hydride shift. Formation of this intermediate is partially suppressed by substitution of the migrating hydrogen by a deuterium. A proposed pathway which involves a 1,3-methyl migration has been disproved, and scrambling and loss of deuterium label has been accounted for in terms of equilibria involving lauren-1-ene and another previously reported rearrangement product. The rearrange
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10

Saunders, James, Chris Adamson, Yumeela Ganga-Sah, Andrew R. Lewis, and Andrew J. Bennet. "Rearrangement and nucleophilic trapping of bicyclo[4.1.0]hept-2-yl derived nonclassical bicyclobutenium ions." Canadian Journal of Chemistry 96, no. 2 (2018): 235–40. http://dx.doi.org/10.1139/cjc-2017-0569.

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Here we describe the synthesis of two specifically labelled 13C isotopologues of cis-2-(4-nitrophenoxy)bicyclo[4.1.0]heptane and their solvolysis reactions in trifluoroethanol. By using one- and two-dimensional 1H- and 13C-NMR spectroscopy, we characterized the pathways for the rearrangement of these isotopologues to give 13C-labelled 4-(2,2,2-trifluoroethoxy)cycloheptene. We show that the initially formed cationic intermediate undergoes a degenerate rearrangement, which does not reach equilibrium before nucleophilic capture of the cation. Moreover, we show that the nonclassical carbocation, c
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11

Tsuda, Masato, Taiki Morita, Shintaro Fukuhara, and Hiroyuki Nakamura. "Synthesis of 4-amino-5-allenylisoxazoles via gold(i)-catalysed propargyl aza-Claisen rearrangement." Organic & Biomolecular Chemistry 19, no. 6 (2021): 1358–64. http://dx.doi.org/10.1039/d0ob02544e.

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12

Ihmels, Heiko, та Jia Luo. "Synthesis of cationic dibenzosemibullvalene-based phase-transfer catalysts by di-π-methane rearrangements of pyrrolinium-annelated dibenzobarrelene derivatives". Beilstein Journal of Organic Chemistry 7 (26 січня 2011): 119–26. http://dx.doi.org/10.3762/bjoc.7.17.

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Dibenzobarrelene derivatives, that are annelated with a pyrrolinium unit [N,N-dialkyl-3,4-(9',10'-dihydro-9',10'-anthraceno-3-pyrrolinium) derivatives], undergo a photo-induced di-π-methane rearrangement upon triplet sensitization to give the corresponding cationic dibenzosemibullvalene derivatives [N,N-dialkyl-3,4-{8c,8e-(4b,8b-dihydrodibenzo[a,f]cyclopropa[cd]pentaleno)}pyrrolidinium derivatives]. Whereas the covalent attachment of a benzophenone functionality to the pyrrolinium nitrogen atom did not result in an internal triplet sensitization, the introduction of a benzophenone unit as part
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13

Doyle, Timothy J., Martin Hendrix, and John Haseltine. "A novel case of cationic rearrangement involving a phenonium ion." Tetrahedron Letters 35, no. 45 (1994): 8295–98. http://dx.doi.org/10.1016/s0040-4039(00)74390-5.

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14

Klei, Steven R., T. Don Tilley, and Robert G. Bergman. "An Observable Silene/Silylene Rearrangement in a Cationic Iridium Complex." Organometallics 20, no. 15 (2001): 3220–22. http://dx.doi.org/10.1021/om010435a.

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15

Tanino, Keiji, Yasuo Hatanaka, and Isao Kuwajima. "Directing Effects of a Silyl Group on Cationic Rearrangement Reactions." Chemistry Letters 16, no. 2 (1987): 385–88. http://dx.doi.org/10.1246/cl.1987.385.

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16

Su, Xiang, Yihua Sun, Jiannian Yao, Hui Chen, and Chao Chen. "Acid-promoted bicyclization of arylacetylenes to benzobicyclo[3.2.1]octanes through cationic rearrangements." Chemical Communications 52, no. 24 (2016): 4537–40. http://dx.doi.org/10.1039/c6cc00452k.

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Acid-promoted site- and stereo-selective bicyclization of alkynes to benzobicyclo[3.2.1]octanes was realized with atom- and step-economy. The reaction proceeded through two C–C bonds formed on remote alkyl C–H bonds via twice long-distance cationic rearrangement.
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17

Sworin, Michael, and William L. Neumann. "Cyclopentanoid synthesis via directed cationic cyclizations. Efficient generation and rearrangement of the intermediate cyclohexyl cation." Journal of Organic Chemistry 53, no. 20 (1988): 4894–96. http://dx.doi.org/10.1021/jo00255a052.

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18

Lee, Choi Chuck, and Dave Wanigasekera. "Solvolytic rearrangement studies with (E)- and (Z)-2-anisyl-1,2-ditolyl[2-13C]vinyl bromides." Canadian Journal of Chemistry 65, no. 5 (1987): 933–40. http://dx.doi.org/10.1139/v87-158.

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Reaction of (E,Z)-or (E)-2-anisyl-1,2-ditolyl[2-13C]vinyl bromides ((E,Z)- or (E)-6-Br-2-13C) with HOAc–AgOAc gave a 1:1 mixture of (E)- and (Z)-2-anisyl-1,2-ditolyl[1,2-13C]vinyl acetates ((E,Z)-6-OAc-1,2-13C), with about 37.4% scrambling of the label from C-2 to C-1 arising from degenerate 1,2-anisyl shifts in the 2-anisyl-1,2-ditolyl[2-13C]vinyl cation (6-2-13C). No detectable amount of 1-anisyl-2,2-ditolylvinyl acetate was formed, indicating no nondegenerate 1,2-tolyl shift in cation 6 to give the more stable 1 -anisyl-2,2-ditolylvinyl cation (10) in the reaction with HOAc–AgOAc. Reaction
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19

Creary, Xavier. "The cyclopropylcarbinyl route to γ-silyl carbocations". Beilstein Journal of Organic Chemistry 15 (24 липня 2019): 1769–80. http://dx.doi.org/10.3762/bjoc.15.170.

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The mesylate derivative of cis-1-hydroxymethyl-2-trimethylsilylcyclopropane has been prepared, along with a number of related mesylates and triflates with substituents on the 1-position. These substrates all solvolyze in CD3CO2D to give products derived from cyclopropylcarbinyl cations that undergo further rearrangement to give 3-trimethylsilylcyclobutyl cations. These 3-trimethylsilylcyclobutyl cations are stabilized by a long-range rear lobe interaction with the γ-trimethylsilyl group. When the substituent is electron-withdrawing (CF3, CN, or CO2CH3), significant amounts of bicyclobutane pro
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20

Takano, Hideaki, Sari Okazaki, Shun Nishibe, et al. "Gold-catalyzed dual C–C bond cleavage of biphenylenes bearing a pendant alkyne at ambient temperature." Organic & Biomolecular Chemistry 18, no. 30 (2020): 5826–31. http://dx.doi.org/10.1039/d0ob01211d.

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We report a catalytic skeletal rearrangement of biphenylenes with a pendant alkyne moiety at room temperature by a cationic gold catalyst, which involves the cleavage of two bonds: the C–C bond of biphenylene and the C(sp)–C(sp<sup>2</sup> or sp<sup>3</sup>) bond.
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21

Bujdák, J., N. Iyi, and T. Fujita. "The aggregation of methylene blue in montmorillonite dispersions." Clay Minerals 37, no. 1 (2002): 121–33. http://dx.doi.org/10.1180/0009855023710022.

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AbstractTheories concerning the optical properties of cationic dyes adsorbed on clay surfaces are analysed in detail. An investigation of the aggregation of methylene blue (MB) in montmorillonite dispersions is conducted using visible (VIS) spectroscopy. The effects of the dye/ clay ratio and of the swelling properties of the montmorillonite substrate on dye aggregation are compared in terms of the effect of clay layer charge. The observed influence on dye aggregation was almost negligible for both swelling and dye loading. The layer charge of the silicate determines the extent and the type of
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22

Nakamura, Itaru, Takeru Jo, Yasuhiro Ishida, Hiroki Tashiro, and Masahiro Terada. "Cationic N-Heterocyclic Carbene Copper-Catalyzed [1,3]-Alkoxy Rearrangement of N-Alkoxyanilines." Organic Letters 19, no. 12 (2017): 3059–62. http://dx.doi.org/10.1021/acs.orglett.7b01110.

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23

DOYLE, T. J., M. HENDRIX, and J. HASELTINE. "ChemInform Abstract: A Novel Case of Cationic Rearrangement Involving a Phenonium Ion." ChemInform 26, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199515269.

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24

Nakamura, Itaru, Mao Owada, Takeru Jo, and Masahiro Terada. "Concerted [1,3]-Rearrangement in Cationic Cobalt-Catalyzed Reaction of O-(Alkoxycarbonyl)-N-arylhydroxylamines." Organic Letters 19, no. 8 (2017): 2194–96. http://dx.doi.org/10.1021/acs.orglett.7b00700.

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25

Besora, Maria, Sergei F. Vyboishchikov, Agustí Lledós, Feliu Maseras, Ernesto Carmona, and Manuel L. Poveda. "Mechanism for Hydride-Assisted Rearrangement from Ethylidene to Ethylene in Iridium Cationic Complexes." Organometallics 29, no. 9 (2010): 2040–45. http://dx.doi.org/10.1021/om1000315.

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26

Freed, John D., David J. Hart, and Nabi A. Magomedov. "Trapping of the Putative Cationic Intermediate in the Morin Rearrangement with Carbon Nucleophiles†." Journal of Organic Chemistry 66, no. 3 (2001): 839–52. http://dx.doi.org/10.1021/jo0013406.

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27

Engström, J., A. M. Jimenez, and E. Malmström. "Nanoparticle rearrangement under stress in networks of cellulose nanofibrils using in situ SAXS during tensile testing." Nanoscale 12, no. 11 (2020): 6462–71. http://dx.doi.org/10.1039/c9nr10964a.

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This study aims to describe and evaluate the mechanism for increased strain-at-break of composites made of cellulose nanofibrils (CNFs) reinforced with nanoscopic latex particles (&lt;200 nm) stabilized by a cationic polyelectrolyte as corona.
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28

Baek, Jun Won, Young Bin Hyun, Hyun Ju Lee та ін. "Selective Trimerization of α-Olefins with Immobilized Chromium Catalyst for Lubricant Base Oils". Catalysts 10, № 9 (2020): 990. http://dx.doi.org/10.3390/catal10090990.

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The demand for poly(α-olefin)s (PAOs), which are high-performance group IV lubricant base oils, is increasingly high. PAOs are generally produced via the cationic oligomerization of 1-decene, wherein skeleton rearrangement inevitably occurs in the products. Hence, a transition-metal-based catalytic process that avoids rearrangement would be a valuable alternative for cationic oligomerization. In particular, transition-metal-catalyzed selective trimerization of α-olefins has the potential for success. In this study, (N,N′,N″-tridodecyltriazacyclohexane)CrCl3 complex was reacted with MAO-silica
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29

Nhu, Duong, Lesley Larsen, Nigel B. Perry, David S. Larsen, and Bill C. Hawkins. "Sweet Poisons: Synthetic Strategies towards Tutin Glycosides." Australian Journal of Chemistry 70, no. 3 (2017): 301. http://dx.doi.org/10.1071/ch16429.

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The polycyclic, polyoxygenated picrotoxane tutin was subjected to various glycosylation reaction conditions in an effort to synthesise β-linked tutin glycosides, recently found in toxic honeys. Cationic palladium-mediated glycosylation of tutin was successful; however, the α-linked tutin tetrabenzyl glucoside was obtained as the major product (5 : 1, α : β). Hydrogenolysis of the benzyl ether protecting groups resulted in concomitant tutin double-bond migration. Epoxide opening and rearrangement were observed upon acetylation of the tutin glucoside.
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30

Uozumi, Yasuhiro, Kazuhiko Kato, and Tamio Hayashi. "Asymmetric aza-Claisen rearrangement of allyl imidates catalyzed by homochiral cationic palladium(II) complexes." Tetrahedron: Asymmetry 9, no. 6 (1998): 1065–72. http://dx.doi.org/10.1016/s0957-4166(98)00059-7.

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31

Elkin, Masha, Anthony C. Scruse, Aneta Turlik, and Timothy R. Newhouse. "Computational and Synthetic Investigation of Cationic Rearrangement in the Putative Biosynthesis of Justicane Triterpenoids." Angewandte Chemie 131, no. 4 (2018): 1037–41. http://dx.doi.org/10.1002/ange.201810566.

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32

Elkin, Masha, Anthony C. Scruse, Aneta Turlik, and Timothy R. Newhouse. "Computational and Synthetic Investigation of Cationic Rearrangement in the Putative Biosynthesis of Justicane Triterpenoids." Angewandte Chemie International Edition 58, no. 4 (2019): 1025–29. http://dx.doi.org/10.1002/anie.201810566.

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33

Tanaka, Ken, Eri Okazaki, and Yu Shibata. "Cationic Rhodium(I)−dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade." Journal of the American Chemical Society 131, no. 31 (2009): 10822–23. http://dx.doi.org/10.1021/ja9038449.

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34

Tong, Jiaqi, Ting Hu, Anjun Qin, Jing Zhi Sun, and Ben Zhong Tang. "Deciphering the binding behaviours of BSA using ionic AIE-active fluorescent probes." Faraday Discussions 196 (2017): 285–303. http://dx.doi.org/10.1039/c6fd00165c.

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The binding behaviours of a transport protein, bovine serum albumin (BSA), in its native, unfolding and refolding states have been probed by monitoring the emission changes of two exogenous AIE-active fluorescent probes, M2 and M3, which are designed to be anionic and cationic, respectively. Due to their AIE properties, both M2 and M3 display emission enhancement when bound to the hydrophobic cavity of BSA. The binding site of M2 and M3 is found to be subdomain IIA. Then, the BSA + M2 and BSA + M3 systems are utilized to fluorescently signal the conformation changes of BSA caused by various ex
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35

Mai, Duy, Dmitriy Uchenik, and Christopher Vanderwal. "Efforts Toward a Synthesis of Crotogoudin and Crotobarin." Synlett 28, no. 14 (2017): 1758–62. http://dx.doi.org/10.1055/s-0036-1588560.

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Two synthesis designs for the diterpenoid crotogoudin are discussed, and efforts to achieve each are described. First, a Cope rearrangement/intramolecular Diels–Alder cascade reaction was investigated. Second, a bioinspired sequence of cationic bicyclization and A-ring oxidative fragmentation set-up for a lactonization induced by a phenolic oxidation, ultimately providing a tricyclic intermediate that required only installation of the bridging ring of the salient bicyclo[2.2.2]octane system. This last endeavor was fraught with difficulty, but did lead to the development of conditions for cycli
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36

De, Sriman, Eti Mahal, Md Ashraful Haque, Chandan K. Jana, and Debasis Koley. "Computational Investigation of Multifaceted Cationic Rearrangement and Stereo- and Regioselectivity in the Formation of Dysideanone’s Analogues." Journal of Organic Chemistry 86, no. 1 (2020): 1133–40. http://dx.doi.org/10.1021/acs.joc.0c02609.

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37

Brummond, Kay M., and Sang-phyo Hong. "A Formal Total Synthesis of (−)-FR901483, Using a Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclization Approach." Journal of Organic Chemistry 70, no. 3 (2005): 907–16. http://dx.doi.org/10.1021/jo0483567.

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38

Tadano-Aritomi, Keiko, Toshiyuki Hikita, Masayuki Kubota, et al. "Internal residue loss produced by rearrangement of a novel cationic glycosphingolipid, glyceroplasmalopsychosine, in collision-induced dissociation." Journal of Mass Spectrometry 38, no. 7 (2003): 715–22. http://dx.doi.org/10.1002/jms.485.

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39

Liu, Lu, and Junliang Zhang. "Selectivity Control in Lewis Acid Catalyzed Regiodivergent Tandem Cationic Cyclization/Ring Expansion Terminated by Pinacol Rearrangement." Angewandte Chemie International Edition 48, no. 33 (2009): 6093–96. http://dx.doi.org/10.1002/anie.200901628.

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40

Liu, Lu, and Junliang Zhang. "Selectivity Control in Lewis Acid Catalyzed Regiodivergent Tandem Cationic Cyclization/Ring Expansion Terminated by Pinacol Rearrangement." Angewandte Chemie 121, no. 33 (2009): 6209–12. http://dx.doi.org/10.1002/ange.200901628.

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41

CLARKE, D. B., and R. T. WEAVERS. "ChemInform Abstract: The Chemistry of Laurenene. Part 16. Investigation of the Mechanism of a Cationic Rearrangement." ChemInform 24, no. 48 (2010): no. http://dx.doi.org/10.1002/chin.199348227.

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42

Biju, P. John, Krishna Kaliappan, M. S. Laxmisha, and G. S. R. Subba Rao. "Synthesis based on cyclohexadienes. Part 34. A tandem cationic rearrangement–ene cyclisation route to 2-pupukeanone." Journal of the Chemical Society, Perkin Transactions 1, no. 22 (2000): 3714–18. http://dx.doi.org/10.1039/b003409f.

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43

Fleming, Ian, and Sunil K. Ghosh. "Stereospecific 1,2-silyl shift in a cationic rearrangement with retention of configuration at the migration origin." Journal of the Chemical Society, Chemical Communications, no. 24 (1992): 1777. http://dx.doi.org/10.1039/c39920001777.

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44

Bly, Robert S., Ruilian Wu, and Ruta K. Bly. "Regio- and diastereoselectivity in the rearrangement of cationic iron(II) .eta.1-1-(1-methylcycloalkyl)methylidenes." Organometallics 9, no. 4 (1990): 936–43. http://dx.doi.org/10.1021/om00118a007.

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45

Fisher, Nathan, Lynne Shetron-Rama, Amy Herring-Palmer, Brian Heffernan, Nicholas Bergman, and Philip Hanna. "The dltABCD Operon of Bacillus anthracis Sterne Is Required for Virulence and Resistance to Peptide, Enzymatic, and Cellular Mediators of Innate Immunity." Journal of Bacteriology 188, no. 4 (2006): 1301–9. http://dx.doi.org/10.1128/jb.188.4.1301-1309.2006.

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ABSTRACT In the environment, the gram-positive bacterium Bacillus anthracis persists as a metabolically dormant endospore. Upon inoculation into the host the endospores germinate and outgrow into vegetative bacilli able to cause disease. The dramatic morphogenic changes to the bacterium during germination and outgrowth are numerous and include major rearrangement of and modifications to the bacterial surface. Such modifications occur during a time in the B. anthracis infectious cycle when the bacterium must guard against a multitude of innate immune mediators. The dltABCD locus of B. anthracis
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46

Lolkema, Lucie D. M., Henk Hiemstra, Hendrik H. Mooiweer, and W. Nico Speckamp. "Synthesis of oxacyclic carboxylic esters by way of methoxycarbonyloxonium ions; Evidence for a cationic oxa-cope rearrangement." Tetrahedron Letters 29, no. 48 (1988): 6365–68. http://dx.doi.org/10.1016/s0040-4039(00)82348-5.

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47

Cooke, Andrew, Jonathan Bennett, and Emma McDaid. "A facile synthesis of N -benzyl-4-acetylproline via a tandem cationic aza-Cope rearrangement-Mannich reaction." Tetrahedron Letters 43, no. 5 (2002): 903–5. http://dx.doi.org/10.1016/s0040-4039(01)02287-0.

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48

Stas, Sara, Kourosch Abbaspour Tehrani, and Georges Laus. "Carbon–carbon bond formation via a tandem cationic 2-aza-Cope rearrangement–Lewis acid promoted Petasis reaction." Tetrahedron 64, no. 16 (2008): 3457–63. http://dx.doi.org/10.1016/j.tet.2008.02.025.

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49

Sharma, Mukesh K., Martin G. Banwell та Anthony C. Willis. "Generation of (+)-Prezizanol, (+)-Prezizaene, and theent-β-Isopipitzol Framework via Cationic Rearrangement of Khusiol and Related Compounds". Asian Journal of Organic Chemistry 3, № 5 (2014): 632–37. http://dx.doi.org/10.1002/ajoc.201400019.

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50

Wand, M. D., and J. A. Thompson. "Cytochrome P-450-catalyzed rearrangement of a peroxyquinol derived from butylated hydroxytoluene. Involvement of radical and cationic intermediates." Journal of Biological Chemistry 261, no. 30 (1986): 14049–56. http://dx.doi.org/10.1016/s0021-9258(18)66979-0.

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