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1

De Wever, Pieter, Rodrigo de Oliveira-Silva, João Marreiros, Rob Ameloot, Dimitrios Sakellariou, and Pedro Fardim. "Topochemical Engineering of Cellulose—Carboxymethyl Cellulose Beads: A Low-Field NMR Relaxometry Study." Molecules 26, no. 1 (2020): 14. http://dx.doi.org/10.3390/molecules26010014.

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The demand for more ecological, highly engineered hydrogel beads is driven by a multitude of applications such as enzyme immobilization, tissue engineering and superabsorbent materials. Despite great interest in hydrogel fabrication and utilization, the interaction of hydrogels with water is not fully understood. In this work, NMR relaxometry experiments were performed to study bead–water interactions, by probing the changes in bead morphology and surface energy resulting from the incorporation of carboxymethyl cellulose (CMC) into a cellulose matrix. The results show that CMC improves the swe
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2

Chami Khazraji, Ali, and Sylvain Robert. "Interaction Effects between Cellulose and Water in Nanocrystalline and Amorphous Regions: A Novel Approach Using Molecular Modeling." Journal of Nanomaterials 2013 (2013): 1–10. http://dx.doi.org/10.1155/2013/409676.

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The hydrophilic/hydrophobic nature of cellulose is based on its structural anisotropy. Cellulose chains are arranged in a parallel manner and are organized in sheets stabilized by interchain OH–O hydrogen bonds, whereas the stacking of sheets is stabilized by both van der Waals (vdW) dispersion forces and weak CH–O hydrogen bonds. Cellulose has a strong affinity to itself and materials containing hydroxyls, especially water. Based on the preponderance of hydroxyl functional groups, cellulose polymer is very reactive with water. Water molecular smallness promotes the reaction with the cellulose
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3

Stenqvist, Björn, Erik Wernersson, and Mikael Lund. "Cellulose-Water Interactions: Effect of electronic polarizability." Nordic Pulp & Paper Research Journal 30, no. 1 (2015): 26–31. http://dx.doi.org/10.3183/npprj-2015-30-01-p026-031.

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4

Voronova, M. I., T. N. Lebedeva, M. V. Radugin, O. V. Surov, A. N. Prusov, and A. G. Zakharov. "Interactions of water–DMSO mixtures with cellulose." Journal of Molecular Liquids 126, no. 1-3 (2006): 124–29. http://dx.doi.org/10.1016/j.molliq.2005.12.001.

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5

Masas, Daria S., Maria S. Ivanova, Gocha Sh Gogelashvili, Alexander S. Maslennikov, Yury B. Grunin, and Tatiana Yu Grunina. "Analysis of water state adsorbed by cellulose fibers." Butlerov Communications 58, no. 5 (2019): 24–31. http://dx.doi.org/10.37952/roi-jbc-01/19-58-5-24.

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Modernized model of microfibril cellulose layered structure is proposed. This model considers presence of slit-shaped micropores in space between elementary fibrils and cellulose microfibrils. It’s discussed the nature of donor-acceptor hydrogen bonds formation: intra-, intermolecular, and interlayer bonds inherent in each glucopyranous cellulose link. It’s described the mechanism of water molecules specific adsorption interactions in a monolayer with active centers located on the hydrophilic surfaces of elementary fibrils. Dipole-dipole energy transition into energy of hydrogen bond is discus
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6

Pontoh, Raynardthan, Vania Edita Rarisavitri, Christine Charen Yang, Maximilliam Febriand Putra, and Daru Seto Bagus Anugrah. "Density Functional Theory Study of Intermolecular Interactions between Amylum and Cellulose." Indonesian Journal of Chemistry 22, no. 1 (2022): 253. http://dx.doi.org/10.22146/ijc.69241.

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Amylum is one of the polysaccharides developed into biodegradable plastic bags. However, amylum-based plastics are easily damaged due to their low mechanical strength and hydrophilic properties. Cellulose is used as a support material in amylum-based plastics to increase strength and reduce water damage. This study investigated the molecular interactions between amylum and cellulose computationally. The minimum interaction energy of amylum and cellulose was calculated using in silico modeling using the Density Functional Theory (DFT) method. The B3LYP function and the basis set 6-31++g** were
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7

Chami Khazraji, Ali, and Sylvain Robert. "Self-Assembly and Intermolecular Forces When Cellulose and Water Interact Using Molecular Modeling." Journal of Nanomaterials 2013 (2013): 1–12. http://dx.doi.org/10.1155/2013/745979.

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Cellulose chains are linear and aggregation occurs via both intra- and intermolecular hydrogen bonds. Cellulose has a strong affinity to itself and toward materials containing hydroxyls groups. Based on the preponderance of hydroxyl functional groups, cellulose is very reactive with water. At room temperature, cellulose chains will have at least a monomolecular layer of water associated to it. The formation of hydrogen bonds at the cellulose/water interface is shown to depend essentially on the adsorption site, for example, the equatorial hydroxyls or OH moieties pointing outward from the cell
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8

Lee, Hye Ji, Younghyun Cho, and Sang Wook Kang. "Formation of Nanochannels Using Polypropylene and Acetylcellulose for Stable Separators." Membranes 12, no. 8 (2022): 764. http://dx.doi.org/10.3390/membranes12080764.

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In this study, a polymer separator with enhanced thermal stability is prepared to solve the problem of thermal durability of lithium-ion battery separators. This separator is manufactured by coating a solution of acetyl cellulose and glycerin on polypropylene. The added glycerin reacts with the acetyl cellulose chains, helping the chains become flexible, and promotes the formation of many pores in the acetyl cellulose. To improve the thermal stability of the separator, a mixed solution of acetyl cellulose and glycerin was coated twice on the PP membrane film. Water pressure is applied using a
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9

Tammelin, Tekla, Ramarao Abburi, Marie Gestranius, Christiane Laine, Harri Setälä, and Monika Österberg. "Correlation between cellulose thin film supramolecular structures and interactions with water." Soft Matter 11, no. 21 (2015): 4273–82. http://dx.doi.org/10.1039/c5sm00374a.

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10

Wang, Huai Fang, Hai Ning Lv, Jing Feng, and Zhi Kai Wang. "Novel Blend Films Prepared from Solution of Collagen and Cellulose in 1-Allyl-3-methylimidazolium Chloride Ionic Liquid." Advanced Materials Research 418-420 (December 2011): 30–33. http://dx.doi.org/10.4028/www.scientific.net/amr.418-420.30.

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Collagen/cellulose films were made by the blend solutions of collagen, cellulose in this paper. To begin with, collagen and cellulose was dissolved in 1-allyl-3-methylimidazolium chloride ([Amim]Cl). The structure of the blend films was characterized by FTIR and XRD. The effects of weight ratio between the two polymers on light transmittance, tensile strength, elongation at break and water absorption of the film were studied. The results showed that there were strong interactions and good compatibility between collagen and cellulose in the film and the polymers have strongest interactions at t
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11

Peydecastaing, J., C. Vaca-Garcia, and E. Borredon. "Interactions with water of mixed acetic-fatty cellulose esters." Cellulose 18, no. 4 (2011): 1023–31. http://dx.doi.org/10.1007/s10570-011-9530-2.

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12

Bering, Eivind, Jonathan Ø. Torstensen, Anders Lervik, and Astrid S. de Wijn. "Computational study of the dissolution of cellulose into single chains: the role of the solvent and agitation." Cellulose 29, no. 3 (2022): 1365–80. http://dx.doi.org/10.1007/s10570-021-04382-9.

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Abstract We investigate the dissolution mechanism of cellulose using molecular dynamics simulations in both water and a mixture solvent consisting of water with Na$$^+$$ + , OH$$^-$$ - and urea. As a first computational study of its kind, we apply periodic external forces that mimic agitation of the suspension. Without the agitation, the bundles do not dissolve, neither in water nor solvent. In the solvent mixture the bundle swells with significant amounts of urea entering the bundle, as well as more water than in the bundles subjected to pure water. We also find that the mixture solution stab
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13

Yang, Fan, Pengfei Zhu, Haiqing Zheng, et al. "Interactions between cellulose and lignin during hydrolysis in subcritical water." Journal of Supercritical Fluids 199 (August 2023): 105943. http://dx.doi.org/10.1016/j.supflu.2023.105943.

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14

Mudedla, Sathish Kumar, Maisa Vuorte, Elias Veijola, et al. "Effect of oxidation on cellulose and water structure: a molecular dynamics simulation study." Cellulose 28, no. 7 (2021): 3917–33. http://dx.doi.org/10.1007/s10570-021-03751-8.

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AbstractEnzymatic cleavage of glycocidic bonds is an important, green and biocompatible means to refine lignocellulosic biomass. Here, the effect of the resulting oxidation point defects on the structural and water interactions of crystalline cellulose {100} surface are explored using classical molecular dynamics simulations. We show that even single oxidations reduce the connections within cellulose crystal significantly, mostly via local interactions between the chains along the surface plane but also via the oxidation defects changing the structure of the crystal in direction perpendicular
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15

Freitas, Pedro A. V., Paula Alonso Collado, Chelo González-Martínez, and Amparo Chiralt. "Producing Aerogels from Rice Straw Cellulose Obtained by a Green Method and Its Starch Blending." Polymers 17, no. 8 (2025): 1103. https://doi.org/10.3390/polym17081103.

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Cellulose and starch–cellulose composite aerogels were obtained using green cellulose from rice straw (RS) purified with a more environmentally friendly process. Pure starch aerogels were also obtained for comparison purposes. The effect of the aerogel cross-linking with polyamideamine-epichlorohydrin (PAE) was also analysed. The properties of the cellulose aerogels were in the range of those reported using other RS cellulose fibres with similar compositions. Blending with starch implied a decrease in the liquid water absorption capacity but an increase in the mechanical strength, flexibility,
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16

Lombardo, Salvatore, and Wim Thielemans. "Thermodynamics of the interactions of positively charged cellulose nanocrystals with molecules bearing different amounts of carboxylate anions." Physical Chemistry Chemical Physics 20, no. 26 (2018): 17637–47. http://dx.doi.org/10.1039/c8cp01532e.

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17

Gomes, Andresa, Lais Brito Cangussu, Rosiane Lopes Cunha, Leandro Soares de Oliveira, Adriana Silva Franca, and Ana Letícia Rodrigues Costa. "Investigating the Impact of Chlorogenic Acid Content and Cellulose Nanoparticles on Sunflower Protein-Based Emulsions and Films." Foods 14, no. 5 (2025): 824. https://doi.org/10.3390/foods14050824.

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This study explores how varying chlorogenic acid levels (low—yellowish, Y; high—greenish, G) in sunflower proteins (SFs) affect the properties of eugenol-loaded oil-in-water emulsions and the resulting films, while examining the interaction of cellulose nanoparticles (from commercial (CNC) and banana peel sources (CNF)) with the film-forming matrix. This research fills gaps in literature by demonstrating how interactions among proteins, lipids, phenolic compounds, and cellulose nanoparticles influence film properties. The high chlorogenic acid content in SF reduced electrostatic repulsion betw
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18

M., Hasan, Deepu Gopakumar, Vishnu Arumughan, et al. "Robust Superhydrophobic Cellulose Nanofiber Aerogel for Multifunctional Environmental Applications." Polymers 11, no. 3 (2019): 495. http://dx.doi.org/10.3390/polym11030495.

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The fabrication of superadsorbent for dye adsorption is a hot research area at present. However, the development of low-cost and highly efficient superadsorbents against toxic textile dyes is still a big challenge. Here, we fabricated hydrophobic cellulose nanofiber aerogels from cellulose nanofibers through an eco-friendly silanization reaction in liquid phase, which is an extremely efficient, rapid, cheap, and environmentally friendly procedure. Moreover, the demonstrated eco-friendly silanization technique is easy to commercialize at the industrial level. Most of the works that have reporte
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19

Gurina, Darya, Oleg Surov, Marina Voronova, and Anatoly Zakharov. "Molecular Dynamics Simulation of Polyacrylamide Adsorption on Cellulose Nanocrystals." Nanomaterials 10, no. 7 (2020): 1256. http://dx.doi.org/10.3390/nano10071256.

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Classical molecular dynamics simulations of polyacrylamide (PAM) adsorption on cellulose nanocrystals (CNC) in a vacuum and a water environment are carried out to interpret the mechanism of the polymer interactions with CNC. The structural behavior of PAM is studied in terms of the radius of gyration, atom–atom radial distribution functions, and number of hydrogen bonds. The structural and dynamical characteristics of the polymer adsorption are investigated. It is established that in water the polymer macromolecules are mainly adsorbed in the form of a coil onto the CNC facets. It is found out
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20

Sadeghifar, Hasan, Richard Venditti, Joel J. Pawlak, and Jesse Jur. "Cellulose transparent and flexible films prepared from DMAc/LiCl solutions." BioResources 14, no. 4 (2019): 9021–32. http://dx.doi.org/10.15376/biores.14.4.9021-9032.

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Cellulose transparent and flexible film was prepared by dissolving micro-crystalline cellulose powder in Dimethylacetamide/Lithium Chloride (DMAc/LiCl) followed by regeneration in acetone and subsequent washing with water. The solution was cast on a glass plate. The interactions of water molecules and the swollen cellulose in the gel were examined by differential scanning calorimetry, DSC. An increased melting point of water in the gel indicated the presence of stronger bonding between water and cellulose than in the non-modified cellulose. The prepared dried films had 63 g/m2 weight and 0.06
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21

Dammström, Sofia, Lennart Salmén, and Paul Gatenholm. "On the interactions between cellulose and xylan, a biomimetic simulation of the hardwood cell wall." BioResources 4, no. 1 (2008): 3–14. http://dx.doi.org/10.15376/biores.4.1.3-14.

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The plant cell wall exhibits a hierarchical structure, in which the organization of the constituents on different levels strongly affects the mechanical properties and the performance of the material. In this work, the interactions between cellulose and xylan in a model system consisting of a bacterial cellulose/glucuronoxylan (extracted from aspen, Populus tremula) have been studied and compared to that of a delignified aspen fiber material. The properties of the materials were analyzed using Dynamical Mechanical Analysis (DMA) with moisture scans together with dynamic Infra Red -spectroscopy
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22

Ju, Zhaoyang, Yihang Yu, Shaokeng Feng, et al. "Theoretical Mechanism on the Cellulose Regeneration from a Cellulose/EmimOAc Mixture in Anti-Solvents." Materials 15, no. 3 (2022): 1158. http://dx.doi.org/10.3390/ma15031158.

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The experiments on cellulose dissolution/regeneration have made some achievements to some extent, but the mechanism of cellulose regeneration in ionic liquids (ILs) and anti-solvent mixtures remains elusive. In this work, the cellulose regeneration mechanism in different anti-solvents, and at different temperatures and concentrations, has been studied with molecular dynamics (MD) simulations. The IL considered is 1-ethyl-3-methylimidazolium acetate (EmimOAc). In addition, to investigate the microcosmic effects of ILs and anti-solvents, EmimOAc-nH2O (n = 0–6) clusters have been optimized by Den
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23

Hussin, Hazira, Seng Neon Gan, Sharifah Mohamad, and Sook Wai Phang. "Synthesis of Water-soluble Polyaniline by Using Different Types of Cellulose Derivatives." Polymers and Polymer Composites 25, no. 7 (2017): 515–20. http://dx.doi.org/10.1177/096739111702500702.

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Pure polyaniline (PAni) is insoluble in water. Water-soluble complexes of PAni with different of cellulose derivatives were successfully synthesized by using chemical oxidation polymerization of aniline in aqueous solution of cellulose derivatives. In this study, cellulose derivatives such as methylcellulose (MC), hydroxypropyl cellulose (HPC), and hydroxypropyl methylcellulose (HPMC) had been used as a steric stabilizer, aniline (Ani) as a monomer with hydrogen chloride (HCl) as an acidic dopant, and ammonium persulfate (APS) as an initiator. The chemical structure of PAni complexes were conf
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24

Camarena-Bononad, Paula, Pedro A. V. Freitas, Amparo Chiralt, and Maria Vargas. "Use of Cellulose Fibres from Posidonia oceanica to Obtain Chitosan Biocomposites and Poly(lactic Acid) Laminates." Polysaccharides 6, no. 2 (2025): 27. https://doi.org/10.3390/polysaccharides6020027.

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New sustainable materials have been developed to replace conventional plastics obtained from non-renewable sources. In this study, cellulose fibres from Posidonia oceanica (PO) were obtained by applying subcritical water extraction and bleaching with hydrogen peroxide or sodium chlorite. The PO fibres were used to obtain cellulose films, chitosan–cellulose composites, and PLA–cellulose laminates. These films were characterised as to their optical properties, mechanical performance, oxygen and water vapour permeability, thermal stability, and microstructure. The cellulose films exhibited low me
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25

Nilsson, Stefan. "Interactions between Water-Soluble Cellulose Derivatives and Surfactants. 1. The HPMC/SDS/Water System." Macromolecules 28, no. 23 (1995): 7837–44. http://dx.doi.org/10.1021/ma00127a034.

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26

Bryszewska, Malgorzata Anita, Daniel Gutierez Pareja, Lukasz Kaczmarek, Anna Sobczyk-Guzenda, Malgorzata Piotrowska, and Damian Batory. "SCOBY Cellulose-Based Materials Hydrophobized Using Stearic Acid and Apple Powder." International Journal of Molecular Sciences 25, no. 24 (2024): 13746. https://doi.org/10.3390/ijms252413746.

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Bacterial cellulose (BC) is a subject of interest for researchers due to its advantageous characteristics, including a straightforward manufacturing process, biocompatibility, and extensive modification potential. The hydrophilic nature of the material is beneficial in some applications, yet a limiting factor in others. This study aimed to develop BC-based materials with goFogureod moisture resistance. The modification of bacterial cellulose (BC) using apple powder, stearic acid, or a combination of these modifiers resulted in the formation of a range of materials, some of which had their surf
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27

Talipova, Aizhan B., Volodymyr V. Buranych, Irina S. Savitskaya, Oleksandr V. Bondar, Amanzhol Turlybekuly, and Alexander D. Pogrebnjak. "Synthesis, Properties, and Applications of Nanocomposite Materials Based on Bacterial Cellulose and MXene." Polymers 15, no. 20 (2023): 4067. http://dx.doi.org/10.3390/polym15204067.

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MXene exhibits impressive characteristics, including flexibility, mechanical robustness, the capacity to cleanse liquids like water through MXene membranes, water-attracting nature, and effectiveness against bacteria. Additionally, bacterial cellulose (BC) exhibits remarkable qualities, including mechanical strength, water absorption, porosity, and biodegradability. The central hypothesis posits that the incorporation of both MXene and bacterial cellulose into the material will result in a remarkable synthesis of the attributes inherent to MXene and BC. In layered MXene/BC coatings, the presen
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28

Harding, Stephen. "H-bonds and DNA." Biochemist 41, no. 4 (2019): 38–41. http://dx.doi.org/10.1042/bio04104038.

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Hydrogen bonds or ‘H-bonds’ are polar, non-covalent bonds or interactions between a hydrogen atom (H) attached to a more electronegative atom, such as oxygen (O) or nitrogen (N), which partially pulls the electron cloud away from the H, leaving it electropositive—with another electronegative atom, such as O or N from a different molecule or from a different part of the same molecule. H-bond interactions play a huge role in the biochemistry of living processes, and in the structures and interactions of biological molecules, with each other and with different molecules including water. Nature's
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29

Kathirgamanathan, Kalyani, Warren J. Grigsby, Jafar Al-Hakkak, and Neil R. Edmonds. "Two-Dimensional FTIR as a Tool to Study the Chemical Interactions within Cellulose-Ionic Liquid Solutions." International Journal of Polymer Science 2015 (2015): 1–9. http://dx.doi.org/10.1155/2015/958653.

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In this study two-dimensional FTIR analysis was applied to understand the temperature effects on processing cellulose solutions in imidazolium-based ionic liquids. Analysis of the imidazolium ionνC2–H peak revealed hydrogen bonding within cellulose solutions to be dynamic on heating and cooling. The extent of hydrogen bonding was stronger on heating, consistent with greater ion mobility at higher temperature when the ionic liquid network structure is broken. At ambient temperatures a blue shiftedνC2–H peak was indicative of greater cation-anion interactions, consistent with the ionic liquid ne
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30

Wei, Weiwei, Qingbao Guan, Chuanting You, et al. "Highly compact nanochannel thin films with exceptional thermal conductivity and water pumping for efficient solar steam generation." Journal of Materials Chemistry A 8, no. 28 (2020): 13927–34. http://dx.doi.org/10.1039/d0ta02921a.

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Highly compact nano-channelled thin films, assembled from cellulose nanofibers and reduced graphene oxide via van der Waals' interactions, exhibit exceptional thermal conductivity and water pumping, allowing for efficient solar-steam generation.
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31

Edler, Karen, Duygu Celebi, Yun Jin, and Janet Scott. "Partially Oxidised Cellulose Nanofibril Gels for Rheology Modification." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1320. http://dx.doi.org/10.1107/s2053273314086793.

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Partially C6-oxidised cellulose nanofibrils form a transparent, slightly viscous suspension in water. These materials, sourced from soft-wood waste, have shown excellent potential for use as a rheology modifier in aqueous formulations, when mixed with salt and minimal amounts of anionic surfactants [1] or with short chain alcohols. The interaction with anionic surfactants is particularly surprising as the cellulose fibrils themselves carry a net negative charge. The gels formed are transparent, mild on the skin and have excellent suspending properties while also being strongly shear thinning m
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32

Delwiche, Stephen R., Ronald E. Pitt, and Karl H. Norris. "Examination of Starch-Water and Cellulose-Water Interactions With Near Infrared (NIR) Diffuse Reflectance Spectrospocy." Starch - Stärke 43, no. 3 (1991): 85–92. http://dx.doi.org/10.1002/star.19910430304.

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33

Delwiche, Stephen R., Ronald E. Pitt, and Karl H. Norris. "Examination of Starch-Water and Cellulose-Water Interactions With Near Infrared (NIR) Diffuse Reflectance Spectroscopy." Starch - Stärke 43, no. 11 (1991): 415–22. http://dx.doi.org/10.1002/star.19910431102.

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34

Costa, Medronho, Filipe, et al. "Emulsion Formation and Stabilization by Biomolecules: The Leading Role of Cellulose." Polymers 11, no. 10 (2019): 1570. http://dx.doi.org/10.3390/polym11101570.

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Emulsion stabilization by native cellulose has been mainly hampered because of its insolubility in water. Chemical modification is normally needed to obtain water-soluble cellulose derivatives. These modified celluloses have been widely used for a range of applications by the food, cosmetic, pharmaceutic, paint and construction industries. In most cases, the modified celluloses are used as rheology modifiers (thickeners) or as emulsifying agents. In the last decade, the structural features of cellulose have been revisited, with particular focus on its structural anisotropy (amphiphilicity) and
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35

Popescu, Maria-Cristina, Bianca-Ioana Dogaru, and Carmen-Mihaela Popescu. "Effect of Cellulose Nanocrystals Nanofiller on the Structure and Sorption Properties of Carboxymethyl Cellulose–Glycerol–Cellulose Nanocrystals Nanocomposite Systems." Materials 13, no. 13 (2020): 2900. http://dx.doi.org/10.3390/ma13132900.

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Biobased materials present a great interest due to their properties and biodegradability. Cellulose nanocrystals (CNC) nanofiller, in various amounts, was incorporated into a carboxymethyl cellulose (CMC)–glycerol (G) matrix in order to obtain nanocomposite systems with improved properties. The effect of the nanofiller on the structural features was investigated by Fourier transform infrared (FT-IR) spectroscopy, principal component analysis (PCA), two-dimensional correlation spectroscopy (2D-COS), and X-ray diffraction, while the sorption properties were evaluated by water vapor isotherms usi
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36

Larraza, Izaskun, Julen Vadillo, Tamara Calvo-Correas, et al. "Effect of Cellulose Nanofibers’ Structure and Incorporation Route in Waterborne Polyurethane–Urea Based Nanocomposite Inks." Polymers 14, no. 21 (2022): 4516. http://dx.doi.org/10.3390/polym14214516.

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In order to continue the development of inks valid for cold extrusion 3D printing, waterborne, polyurethane–urea (WBPUU) based inks with cellulose nanofibers (CNF), as a rheological modulator, were prepared by two incorporation methods, ex situ and in situ, in which the CNF were added after and during the synthesis process, respectively. Moreover, in order to improve the affinity of the reinforcement with the matrix, modified CNF was also employed. In the ex situ preparation, interactions between CNFs and water prevail over interactions between CNFs and WBPUU nanoparticles, resulting in strong
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37

Felby, Claus, Lisbeth G. Thygesen, Jan B. Kristensen, Henning Jørgensen, and Thomas Elder. "Cellulose–water interactions during enzymatic hydrolysis as studied by time domain NMR." Cellulose 15, no. 5 (2008): 703–10. http://dx.doi.org/10.1007/s10570-008-9222-8.

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38

Eckelt, John, Doris Richardt, K. Christian Schuster, and Bernhard A. Wolf. "Thermodynamic interactions of natural and of man-made cellulose fibers with water." Cellulose 17, no. 6 (2010): 1079–93. http://dx.doi.org/10.1007/s10570-010-9443-5.

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39

Peresin, Maria Soledad, Arja-Helena Vesterinen, Youssef Habibi, et al. "Crosslinked PVA nanofibers reinforced with cellulose nanocrystals: Water interactions and thermomechanical properties." Journal of Applied Polymer Science 131, no. 11 (2014): n/a. http://dx.doi.org/10.1002/app.40334.

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40

García-Peñas, Alberto, Weijun Liang, Saud Hashmi, Gaurav Sharma, Mohammad Reza Saeb, and Florian J. Stadler. "Hydrogen Bonds in Blends of Poly(N-isopropylacrylamide), Poly(N-ethylacrylamide) Homopolymers, and Carboxymethyl Cellulose." Journal of Composites Science 5, no. 9 (2021): 240. http://dx.doi.org/10.3390/jcs5090240.

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Recently, it was reported that the physical crosslinking exhibited by some biopolymers could provide multiple benefits to biomedical applications. In particular, grafting thermoresponsive polymers onto biopolymers may enhance the degradability or offer other features, as thermothickening behavior. Thus, different interactions will affect the different hydrogen bonds and interactions from the physical crosslinking of carboxymethyl cellulose, the lower critical solution temperatures (LCSTs), and the presence of the ions. This work focuses on the study of blends composed of poly(N-isopropylacryla
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41

Amalia, Vina, Tety Sudiarti, Rafa Mufidah, Yuliarti Yuliarti, Yusrina Nisrin, and Yusuf Rohmatulloh. "Characteristics of Cellulose Acetate Composite Membranes (Ca/Cs, Ca/Pva, Ca/Peg) As Cu(Ii) Metal Ion Filtration Membranes." al Kimiya 11, no. 1 (2024): 45–50. http://dx.doi.org/10.15575/ak.v11i1.34722.

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Industrial development in Indonesia has caused increased pollution, including water pollution by heavy metals, one of which is the metal ion Cu(II). Cellulose acetate composite membranes have been widely used to overcome the problem of Cu(II) metal ion content in water, however, studies on the performance of cellulose acetate membranes with various types of chitosan, polyvinyl alcohol (PVA) and polyethylene glycol (PEG) composites have not been widely reported. This research aims to analyze the characteristics of cellulose acetate composite membranes with chitosan, PEG, and PVA using FTIR and
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Keldibekova, Raushan, Symbat Suleimenova, Gulden Nurgozhina, and Eldar Kopishev. "Interpolymer Complexes Based on Cellulose Ethers: Application." Polymers 15, no. 15 (2023): 3326. http://dx.doi.org/10.3390/polym15153326.

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Interpolymer complexes based on cellulose ethers have gained significant interest in recent years due to their versatile applications. These complexes are formed by combining different polymers through non-covalent interactions, resulting in stable structures. This article provides an overview of the various fields where IPCs based on cellulose ethers find application. IPCs based on cellulose ethers show great potential in drug delivery systems. These complexes can encapsulate drugs and enable controlled release, making them suitable for sustained drug delivery. They offer advantages in terms
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Diamanti, Maria Vittoria, Cristina Tedeschi, Mariagiovanna Taccia, et al. "Suspended Multifunctional Nanocellulose as Additive for Mortars." Nanomaterials 12, no. 7 (2022): 1093. http://dx.doi.org/10.3390/nano12071093.

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Cellulose derivatives have found significant applications in composite materials, mainly because of the increased mechanical performance they ensure. When added to cement-based materials, either in the form of nanocrystals, nanofibrils or micro/nanofibers, cellulose acts on the mixture with fresh and hardened properties, affecting rheology, shrinkage, hydration, and the resulting mechanical properties, microstructure, and durability. Commercial cotton wool was selected as starting material to produce multifunctional nanocelluloses to test as additives for mortars. Cotton wool was oxidized to o
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Imani, Monireh, Katarina Dimic-Misic, Mirjana Kostic, et al. "Achieving a Superhydrophobic, Moisture, Oil and Gas Barrier Film Using a Regenerated Cellulose–Calcium Carbonate Composite Derived from Paper Components or Waste." Sustainability 14, no. 16 (2022): 10425. http://dx.doi.org/10.3390/su141610425.

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It has been a persistent challenge to develop eco-friendly packaging cellulose film providing the required multiple barrier properties whilst simultaneously contributing to a circular economy. Typically, a cellulosic film made from nanocellulose materials presents severe limitations, such as poor water/moisture resistance and lacking water vapour barrier properties, related primarily to the hydrophilic and hygroscopic nature of cellulose. In this work, alkyl ketene dimer (AKD) and starch, both eco-friendly, non-toxic, cost-effective materials, were used to achieve barrier properties of novel c
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Yokota, Shingo, Kumiko Matsuo, Takuya Kitaoka, and Hiroyuki Wariishi. "Specific interaction acting at a cellulose-binding domain/cellulose interface for papermaking application." BioResources 3, no. 4 (2008): 1030–41. http://dx.doi.org/10.15376/biores.3.4.1030-1041.

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Specific and strong cellulose-binding characteristics were utilized for promoting retention of additives in contaminated papermaking systems. Cellulose-binding domain (CBD) of cellulase derived from Trichoderma viride was separated by digestion with papain, and then introduced into anionic polyacrylamide (A-PAM) through a condensation reaction using water-soluble carbodiimide. The CBD-modified A-PAM (CBD-A-PAM) showed good retention on pulp fibers, resulting in high tensile strength paper sheets. The effect remained almost unchanged in the presence of model interfering substances such as ligni
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Papapetros, Konstantinos, Labrini Sygellou, Charalampos Anastasopoulos, Konstantinos S. Andrikopoulos, Georgios Bokias, and George A. Voyiatzis. "Spectroscopic Study of the Interaction of Reactive Dyes with Polymeric Cationic Modifiers of Cotton Fabrics." Applied Sciences 13, no. 9 (2023): 5530. http://dx.doi.org/10.3390/app13095530.

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Cotton cationization with low molecular weight or polymeric cationic modifiers allows the effective dyeing of cotton substrates with reactive dyes under salt-free and more environmentally friendly conditions. The current work focuses on the spectroscopic study of the intermolecular interactions, which dictate the physicochemical process associated with fabric dyeing. Water-soluble cationic copolymers of vinyl benzyl chloride (VBC) and vinyl benzyl triethylammonium chloride (VBCTEAM) have been used as cellulose cationic modifiers. Dye uptake was assessed using Remazol Brilliant Blue R and Novac
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Wu, Jiayin, Qilin Lu, Hanchen Wang, Beili Lu, and Biao Huang. "Controllable Construction of Temperature-Sensitive Supramolecular Hydrogel Based on Cellulose and Cyclodextrin." Polymers 14, no. 18 (2022): 3801. http://dx.doi.org/10.3390/polym14183801.

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In temperature sensitive hydrogels, the swelling degree or light transmittance of the gel itself changes with variations in ambient temperature, prompting its wide application in controlled drug release, tissue engineering, and material separation. Considering the amphiphilic structure of β-cyclodextrin (β-CD), a cellulose-based supramolecular hydrogel with superior temperature sensitivity was synthesized based on a combination of cellulose and β-CD as well as the host–guest interaction between β-CD and polypropylene glycol (PPG). In the one-pot tandem reaction process, chemical grafting of β-
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Tan, Jia Ying, Wah Yen Tey, Joongjai Panpranot, Steven Lim, and Kiat Moon Lee. "Valorization of Oil Palm Empty Fruit Bunch for Cellulose Fibers: A Reinforcement Material in Polyvinyl Alcohol Biocomposites for Its Application as Detergent Capsules." Sustainability 14, no. 18 (2022): 11446. http://dx.doi.org/10.3390/su141811446.

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Cellulose fibers isolated from oil palm empty fruit bunches (OPEFB) have been studied as a potential reinforcement for polyvinyl alcohol (PVA) biocomposite. Analysis of variance (ANOVA) showed that all three parameters—hydrolysis temperature, time and acid concentration, as well as their interactions—significantly affected the yield of cellulose. Moving Least Squares (MLS) and Multivariable Power Least Squares (MPLS) models demonstrated good fitness. The model also proved that acid concentration was the dominant parameter, supported by the Fourier transform infrared spectroscopy (FTIR) analysi
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Ottenhall, Anna, Jonatan Henschen, Josefin Illergård, and Monica Ek. "Cellulose-based water purification using paper filters modified with polyelectrolyte multilayers to remove bacteria from water through electrostatic interactions." Environmental Science: Water Research & Technology 4, no. 12 (2018): 2070–79. http://dx.doi.org/10.1039/c8ew00514a.

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Escamilla-García, Monserrat, Mónica Citlali García-García, Jorge Gracida, et al. "Properties and Biodegradability of Films Based on Cellulose and Cellulose Nanocrystals from Corn Cob in Mixture with Chitosan." International Journal of Molecular Sciences 23, no. 18 (2022): 10560. http://dx.doi.org/10.3390/ijms231810560.

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The increase in consumer demand for more sustainable packaging materials represents an opportunity for biopolymers utilization as an alternative to reduce the environmental impact of plastics. Cellulose (C) and chitosan (CH) are attractive biopolymers for film production due to their high abundance, biodegradability and low toxicity. The objective of this work was to incorporate cellulose nanocrystals (NC) and C extracted from corn cobs in films added with chitosan and to evaluate their properties and biodegradability. The physicochemical (water vapor barrier, moisture content, water solubilit
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