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Relevant bibliographies by topics / Charge transfer or electron donor-acceptor complex

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Academic literature on the topic 'Charge transfer or electron donor-acceptor complex'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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Journal articles on the topic "Charge transfer or electron donor-acceptor complex"

1

Arunapriya, L., and N. Venkatesh. "Synthesis of Charge Transfer Complexation between 2,5-Dihydroxy-p-benzoquinone and 2-Amino Aniline; Spectral Characterization and DFT Analysis." Asian Journal of Chemistry 37, no. 2 (2025): 284–90. https://doi.org/10.14233/ajchem.2025.32990.

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A charge transfer (CT) complex was synthesized using electron donor 2-amino aniline (AA) and electron acceptor 2,5-dihydroxy benzoquinone (DHBQ) in an acetonitrile medium. The charge transfer complex stoichiometry is 1:1. The Benesi-Hildebrand equation was used to determine the molar absorptivity (εCT), association constant (KCT) and other physical constants. The synthesized solid CT-complex was analyzed by 1H NMR and FT-IR spectroscopic methods. DFT study of the CT complex (gas phase) at the basis set B3LYP/6-31++G also gave similar results of the experimental work. Mulliken atomic charges an

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2

Mo, Yirong, Lingchun Song, Wei Wu, and Qianer Zhang. "Charge Transfer in the Electron Donor−Acceptor Complex BH3NH3." Journal of the American Chemical Society 126, no. 12 (2004): 3974–82. http://dx.doi.org/10.1021/ja039778l.

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Wynne, Klaas, C. Galli, and R. M. Hochstrasser. "Ultrafast charge transfer in an electron donor–acceptor complex." Journal of Chemical Physics 100, no. 7 (1994): 4797–810. http://dx.doi.org/10.1063/1.467201.

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Mohammed, Haider Shanshool, and Nuha Hussain Al-Saadawy. "Synthesis, Characterization, and Theoretical Study of Novel Charge-Transfer Complexes Derived from 3,4-Selenadiazobenzophenone." Indonesian Journal of Chemistry 22, no. 6 (2022): 1663. http://dx.doi.org/10.22146/ijc.76537.

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In the current study, a direct method was used to synthesize a new series of charge-transfer complex compounds. Reaction of different quinones with 3,4-selenadiazo benzophenone in a 1:1 mole ratio by acetonitrile gave a unique charge-transfer complex compound in a good yield. All compounds were characterized by UV-Vis, FTIR, 1H-NMR, and 13C-NMR. The analysis findings agreed with the produced compound’s proposed chemical structures. The molecular structure of the produced charge-transfer complex compounds has been investigated using density functional theory. The basis set of 3–21G geometrical

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Walwyn, Robert J., Bun Chan, Pavel M. Usov, et al. "Spectroscopic, electronic and computational properties of a mixed tetrachalcogenafulvalene and its charge transfer complex." Journal of Materials Chemistry C 6, no. 5 (2018): 1092–104. http://dx.doi.org/10.1039/c7tc03853d.

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The unexplored electron donor molecule triselenathiafulvalene (TSTF) and its corresponding charge transfer complex with the well-known electron acceptor TCNQ exhibit rich electronic, optical and semiconducting properties.

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Sakuda, Eri. "(Invited) Synthesis and Photophysical Properties of Linear Coordination Type Complexes Having Electron Donor/Acceptor Moieties." ECS Meeting Abstracts MA2024-01, no. 13 (2024): 1064. http://dx.doi.org/10.1149/ma2024-01131064mtgabs.

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The energy and electron transfer processes in the organic / inorganic D–A connection system can be freely manipulated by vibronic interaction.Until now, we synthesized the complexes having acceptor moiety was introduced as a substituent to induce electrostatic/coulomb interaction, but from now on, donor and acceptor moieties should be introduced intramolecular or intermolecular in order to induced a donor-acceptor interaction and express dynamic exciton. Then, we synthesized a platinum complex with phenothiazine as a donor and an organoboron compound as an acceptor. Unfortunately, the charge s

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Ho, Hon Eong, Angela Pagano, James A. Rossi-Ashton, et al. "Visible-light-induced intramolecular charge transfer in the radical spirocyclisation of indole-tethered ynones." Chemical Science 11, no. 5 (2020): 1353–60. http://dx.doi.org/10.1039/c9sc05311e.

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Arena, A., S. Lo Schiavo, A. M. Mezzasalma, S. Patané, P. Piraino, and G. Saitta. "Electron spectroscopy on the charge transfer complex [(7-amino-2,4 dimethyl-1,8 naphthyridine) (TCNQ)] (TCNQ = 7,7',8,8'-tetracyanoquinodimethane)." Journal of Materials Research 9, no. 10 (1994): 2706–11. http://dx.doi.org/10.1557/jmr.1994.2706.

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Reflection electron energy loss spectroscopy (REELS) and optical reflectivity measurements have been used to characterize in the valence energy region the dielectric behavior of 7-amino-2,4 dimethyl-1,8 naphthyridine and of the charge transfer complex formed by this compound and the 7,7',8,8'-tetracyanoquinodimethane (TCNQ). The effects of the charge transfer interaction on the core energy levels have been investigated by comparing the line shape of the carbon and nitrogen Is core photoelectron peaks of the electron-donor and electron-acceptor molecules and of the charge transfer complex forme

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Jado, Demelash, Khalid Siraj, and Nathan Meka. "Electron Donor-Acceptor Interaction of 8-Hydroxyquinoline with Citric Acid in Different Solvents: Spectroscopic Studies." Journal of Applied Chemistry 2014 (August 17, 2014): 1–7. http://dx.doi.org/10.1155/2014/484361.

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Charge transfer complex formation between 8-hydroxyquinoline as the electron donor and citric acid as the electron acceptor has been studied spectrophotometrically in ethanol and methanol solvents at room temperature. Absorption band due to charge transfer complex formation was observed near 320 and 325 nm in ethanol and methanol, respectively. The stoichiometric ratio of the complex has been found 3 : 1 by using Job’s and conductometric titration methods. Benesi-Hildebrand equation has been applied to estimate the formation constant and molecular extinction coefficient. It was found that the

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Nalewajski, Roman F. "Phase Equalization, Charge Transfer, Information Flows and Electron Communications in Donor–Acceptor Systems." Applied Sciences 10, no. 10 (2020): 3615. http://dx.doi.org/10.3390/app10103615.

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Subsystem phases and electronic flows involving the acidic and basic sites of the donor (B) and acceptor (A) substrates of chemical reactions are revisited. The emphasis is placed upon the phase–current relations, a coherence of elementary probability flows in the preferred reaction complex, and on phase-equalization in the equilibrium state of the whole reactive system. The overall and partial charge-transfer (CT) phenomena in alternative coordinations are qualitatively examined and electronic communications in A—B systems are discussed. The internal polarization (P) of reactants is examined,

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Dissertations / Theses on the topic "Charge transfer or electron donor-acceptor complex"

1

Furman, Gary S. "The contribution of charge-transfer complexes to the color of kraft lignin." Diss., Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/5644.

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Bhattacharyya, Anjan Kumar. "Intramolecular and intracomplex electron transfer in water soluble redox proteins." Diss., The University of Arizona, 1988. http://hdl.handle.net/10150/184339.

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Electron transfer to and between the redox centers of milk xanthine oxidase was investigated by laser flash-photolysis. Evidence is presented for slow equilibration of electrons (k < 38 s⁻¹) between the various redox centers of the enzyme. The enzyme-bound flavin and the heme moieties of the flavoprotein and cytochrome subunits of p-cresol methyl hydroxylase from Pseudomonas putida are both reduced rapidly in a second order manner by 5-dRF generated by the laser flash, followed by slower first order intramolecular electron transfer (k = 220 s⁻¹) from the protein-bound neutral flavin radical to

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Zilic, Elvis. "Radiation curing and grafting of charge transfer complexes." Thesis, View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/19385.

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Charge transfer (CT) complexes have been used in a number of radiation polymerisation processes including grafting and curing. The complexes studied include donor (D) monomers like vinyl ethers and vinyl acetate (VA) with acceptor (A) monomers such as maleic anhydride (MA). Both UV and EB have been utilised as radiation sources. The complexes are directly grafted to these substrates in the presence of radiation. The complexes yield novel copolymers when radiation cured with concurrent grafting improving the properties of the finished product. The term cure grafting has been proposed for this c

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Zilic, Elvis. "Radiation curing and grafting of charge transfer complexes." View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/19385.

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Thesis (Ph.D.)--University of Western Sydney, 2008.<br>Thesis submitted to the University of Western Sydney, College of Health and Science, School of Natural Sciences, in fulfilment of the requirements for admission to the Doctor of Philosophy. Includes bibliography.

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Svarovsky, Serge A. "Structure, stability and reactivity of small organic sulfinic and sulfonic acids toxicological implications ; Role of charge transfer complexes in oxidation cleavage of benzpinacols by iron (III) trispenanthroline /." Morgantown, W. Va. : [West Virginia University Libraries], 2000. http://etd.wvu.edu/templates/showETD.cfm?recnum=1231.

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Khajehpour, Mazdak. "Solvent effects upon the charge-transfer reaction of the ADMA molecule in the excited state /." free to MU campus, to others for purchase, 2001. http://wwwlib.umi.com/cr/mo/fullcit?p3025621.

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Kinayyigit, Solen. "Platinum (II) charge transfer chromophores electrochemistry, photophysics, and vapochromic sensing applications /." Bowling Green, Ohio : Bowling Green State University, 2007. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=bgsu1182802954.

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Buker, Nicholas D. "Guanidine donors in nonlinear optical chromophores /." Thesis, Connect to this title online; UW restricted, 2006. http://hdl.handle.net/1773/8669.

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Mecker, Christoph J. Chemistry Faculty of Science UNSW. "The synthesis of advanced " special pair " models for the photosynthetic reaction centre." Awarded by:University of New South Wales. School of Chemistry, 2000. http://handle.unsw.edu.au/1959.4/17835.

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Multi-step photoinduced electron transfer takes place over a large distance in the photosynthetic reaction centres (PRCs). Electron donor in this life-spending event is the photo-excited 'special pair', a unit of two electronically coupled porphyrinoid chromophores. Bacteriopheophytin and two quinone molecules function as electron acceptors and contribute to the charge separation with almost unit quantum efficiency. The natural photosynthetic reaction centre is the most sophisticated molecular electronic device to date and interest is high in increasing our understanding of the basic quantum

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Soper, Jake D. "Reactions at nitrogenous ligands on oxidizing group 8 metal centers /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8589.

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Books on the topic "Charge transfer or electron donor-acceptor complex"

1

Paulson, Basil Pavlatos. A study of electronic interactions in intramolecular charge transfer. 1993.

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(Editor), Joshua Jortner, and M. Bixon (Editor), eds. Advances in Chemical Physics, Electron TransferFrom Isolated Molecules to Biomolecules (Advances in Chemical Physics). Wiley-Interscience, 1999.

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(Editor), Joshua Jortner, and M. Bixon (Editor), eds. Advances in Chemical Physics, Electron TransferFrom Isolated Molecules to Biomolecules (Advances in Chemical Physics). Wiley-Interscience, 1999.

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Book chapters on the topic "Charge transfer or electron donor-acceptor complex"

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Zgierski, Marek Z., Takashige Fujiwara, and Edward C. Lim. "Non-Adiabatic Photoprocesses of Fundamental Importance to Chemistry: From Electronic Relaxation of DNA Bases to Intramolecular Charge Transfer in Electron Donor-Acceptor Molecules." In Challenges and Advances In Computational Chemistry and Physics. Springer Netherlands, 2008. http://dx.doi.org/10.1007/978-1-4020-8184-2_15.

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Enoki, Toshiaki, Morinobu Endo, and Masatsugu Suzuki. "Introduction." In Graphite Intercalation Compounds and Applications. Oxford University Press, 2003. http://dx.doi.org/10.1093/oso/9780195128277.003.0003.

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There are two important features in the structure and electronic properties of graphite: a two-dimensional (2D) layered structure and an amphoteric feature (Kelly, 1981). The basic unit of graphite, called graphene is an extreme state of condensed aromatic hydrocarbons with an infinite in-plane dimension, in which an infinite number of benzene hexagon rings are condensed to form a rigid planar sheet, as shown in Figure 1.1. In a graphene sheet, π-electrons form a 2D extended electronic structure. The top of the HOMO (highest occupied molecular orbital) level featured by the bonding π-band touc

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3

Atkins, Peter, Julio de Paula, and James Keeler. "Electron transfer in homogeneous systems." In Atkins’ Physical Chemistry. Oxford University Press, 2022. http://dx.doi.org/10.1093/hesc/9780198847816.003.0105.

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This chapter uses transition-state theory to examine the transfer of electrons in homogeneous systems, which include oxidation–reduction reactions in solution. It introduces Marcus theory, which establishes a relation between the activation parameters and the rate constant of electron transfer and can be expressed in terms of structural parameters of the species involved. It also explores how electron transfer reactions between protein-bound cofactors or between proteins play an important role in a variety of biological processes. The chapter discusses the rate constant of electron transfer in

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Mathews, F. Scott. "Electron transporters." In Molecular Structures in Biology. Oxford University PressOxford, 1993. http://dx.doi.org/10.1093/oso/9780198547716.003.0007.

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Abstract 7.1 Introduction Electron transporters can be defined for our present purposes as low molecular weight (8–15 kDa) protein molecules that contain a redox active cofactor and have no catalytic function other than as an electron sink. There are four types of cofactors utilized by this protein class: haem, iron-sulphur centres, flavin mononucleotide (FMN), and copper. The cofactor, when bound to the protein, can normally exist in only two stable oxidation states. The protein environment can mediate the midpoint oxidation/reduction (redox) potential and establish the equilibrium level of t

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Kumar Cheedarala, Ravi. "3D Ionic Networked Hydrophilic-Hydrophobic Nano Channeled Triboelectric Nanogenerators." In Novel Nanomaterials. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.95324.

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The power demand is increasing day by day owing to the diminishing of fossil fuel reserves on the globe. To overcome the future energy crises, there is a strong need to fulfill the energy loophole by novel technologies such as triboelectric nanogenerators to harvest miniature resources from renewable natural resources. Here, I discussed the synthesis and fabrication of novel triboelectric nanogenerators (TENGs) using highly reproducible power generators as electropositive surfaces from the monomers of naphthalene tetracarboxylic dianhydride, benzdiene diamine, and sulfonated polyimide (Bno-Spi

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Nitzan, Abraham. "Electron Transfer and Transmission at Molecule–Metal and Molecule–Semiconductor Interfaces." In Chemical Dynamics in Condensed Phases. Oxford University Press, 2006. http://dx.doi.org/10.1093/oso/9780198529798.003.0024.

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This chapter continues our discussion of electron transfer processes, now focusing on the interface between molecular systems and solid conductors. Interest in such processes has recently surged within the emerging field of molecular electronics, itself part of a general multidisciplinary effort on nanotechnology. Notwithstanding new concepts, new experimental and theoretical methods, and new terminology, the start of this interest dates back to the early days of electrochemistry, marked by the famous experiments of Galvani and Volta in the late eighteenth century. The first part of this chapt

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Zaier, Rania, and Sahbi Ayachi. "Computational Study on Optoelectronic Properties of Donor-Acceptor Type Small π-Conjugated Molecules for Organic Light-Emitting Diodes (OLEDs) and Nonlinear Optical (NLO) Applications." In Density Functional Theory - Recent Advances, New Perspectives and Applications. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.98590.

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Recently, donor-acceptor type molecule that contains electron-rich (D) and electron-deficient (A) moiety has emerged as an interesting approach of molecular design strategy to develop organic light-emitting diodes (OLEDs) and non-linear optical (NLO) devices. In this work, we report a theoretical investigation based on two donor-acceptor (D-A) type small π-conjugated molecules based on dithieno [3,2-b: 2′,3′-d] pyrrole (DTP) and anthracene derivatives. All of the theoretical calculations were performed by Density Functional Theory (DFT) approach at B3LYP/6-31 g(d) level of theory. The structur

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Enoki, Toshiaki, Morinobu Endo, and Masatsugu Suzuki. "Electron Transport Properties." In Graphite Intercalation Compounds and Applications. Oxford University Press, 2003. http://dx.doi.org/10.1093/oso/9780195128277.003.0008.

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In GICs, charge transfer between graphite and intercalate produces a large concentration of charge carriers, featuring an electron or hole nature in donor or acceptor GICs, respectively, as discussed in Chapter 5. GICs are therefore metallic, in contrast with the semi-metallic properties of host graphite. The typical inplane conductivity values for GICs are in the range of ~ 105 Ω−1 cm−1, which is one order of magnitude larger than the in-plane conductivity of pristine graphite (Delhaes, 1977). It is well known that the conductivity of some GICs, such as AsF5, exceeds that of copper, suggestin

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Wasielewski, Michael R., George L. Gaines, Michael P. O'Neil, et al. "SOLVENT EFFECTS ON THE RATE vs FREE ENERGY DEPENDENCE OF PHOTOINDUCED CHARGE SEPARATION IN FIXED-DISTANCE DONOR-ACCEPTOR MOLECULES." In Dynamics and Mechanisms of Photoinduced Electron Transfer and Related Phenomena. Elsevier, 1992. http://dx.doi.org/10.1016/b978-0-444-89191-4.50013-6.

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Conference papers on the topic "Charge transfer or electron donor-acceptor complex"

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Sarkas, Harry W., and Zakya H. Kafafi. "C60:Electron Donor Nanocomposites and Multilayer Structures for Nonlinear Optics." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1995. http://dx.doi.org/10.1364/otfa.1995.wb.7.

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Since the development of preparative scale syntheses of the fullerenes,1 we have examined the nonlinear optical (NLO) properties of C60 in the solid state.2-4 Following the characterization of solid films of pure C60, we have explored means of altering the optical and NLO properties of this molecule via chemical modification including photopolymerization, oxygen doping, and the creation of charge transfer (CT) complexes in both the ground and excited states.5-7 Studies on solutions of C60 with the electron donor, N,N,N′,N′-tetramethyl-1,4-phenylene-diamine (TMPD) revealed the formation of a 1:

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Adhikarya, Keshab Kumar, and Philippe M. Heynderickxa. "Structure and Properties of Stacking-type Complexes of Triazin at Graphene Surface: A Theoretical Assessment." In 5th World Conference on Chemistry and Chemical Engineering and 5th World Conference on Advanced Materials, Nanoscience and Nanotechnology. Eurasia Conferences, 2024. https://doi.org/10.62422/978-81-970328-7-5-024.

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In recent decades graphene immersed into the technology and industry with its various derivatives including with its immense functionality by making a complex, combination with other organic molecules, atoms and the combination of the both. Noncovalent functionalization creates a wide range of applications for these graphene complexes. Our intention was to characterize the stacking-like two-layered graphene nanoparticles. We selected triazin and its substituted derivatives ((1) 2,4,6-tris(dimethylamine)-1,3,5-triazine (TDA); (2) 2,4,6-triamino-1,3,5-triazine (TAM); (3) 2,4,6-trihydroxy-1,3,5-t

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Schuster, P. R., C. A. Viands, and R. S. Potember. "Nonlinear-optical response in suspensions of organic and inorganic colloidal systems." In OSA Annual Meeting. Optica Publishing Group, 1990. http://dx.doi.org/10.1364/oam.1990.thy21.

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The third-order nonlinear optical response of various colloidal suspensions has been investigated. The transmissive properties of these systems are of particular interest in terms of the speed of the switching response, the switching threshold, the recovery time, and the dynamic range over which optical density is generated. We have seen resonant and non-resonant behavior in the nonlinear response of these materials. These suspensions are composed of both inorganic and organic materials homogeneously distributed within a dielectric matrix. In certain studies, these materials have been synthesi

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Wachtveitl, J., T. Arlt, H. Huber, H. Penzkofer, and W. Zinth. "The Primary Electron Transfer in Bacterial Reaction Centers with Altered Energetics of the Primary Acceptor." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1996. http://dx.doi.org/10.1364/up.1996.tud.2.

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Recent femtosecond experiments on bacterial reaction centers (RCs) could show that a bacteriochlorophyll anion is formed in the first step of the photosynthetic charge separation process [1]. This reaction was interpreted as the reduction of the monomeric bacteriochlorophyll molecule BA, located on one of the two pigment branches, between the primary donor (P, a bacteriochlorophyll dimer) and the secondary acceptor (HA, a bacteriopheophytin molecule).

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O’Neil, Michael P., George L. Gaines, Walter A. Svec, Mark P. Niemczek, and Michael R. Wasielewski. "Low Temperature Ultrafast Charge Separation; Rate vs Free Energy." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1990. http://dx.doi.org/10.1364/up.1990.mc27.

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Photoinduced charge separation reactions in a large series of rigid porphyrin-triptycene-quinone (donor-spacer-acceptor) molecules were studied with picosecond transient absorbance and fluorescence techniques in polar and non-polar solvent at room temperature and at 77K in MTHF glass. At 77k the fluorescence yield as a function of free energy sharply inflects at 0.6eV. However at room temperature in toluene a less pronounced inflection occurs at 0.3eV. These inflection points represent the driving force where the rates of electron transfer approach the fluorescence decay rate of the porphyrin.

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Fort, Alain, Jacques Muller, Joel Azoulay, Marguerite Barzoukas, Valérie Alain, and Mireille Blanchard-Desce. "Characterization of Push-Pull Polyenes of Increasing Size: Linear and Quadratic Polarizabilities in Solution." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1997. http://dx.doi.org/10.1364/otfa.1997.wc.4.

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Push-pull molecules have been extensively studied for their properties in the field of quadratic nonlinear optics. Such molecules consist of electron-donor and electron acceptor substituents connected via a conjugation path. The partial intramolecular charge transfer (ICT) between these end groups can lead to large ground-state dipoles μ. Also, they can display huge static quadratic hyperpolarizabilities β(0) related to the occurence of the ICT transition between the ground and first-excited states [1].

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Dou, Kai, Jisen Zhang, Mingzhen Tian, et al. "Spectral Holeburning in Tetraphenylporphyrin Doped Polymethylcellulose." In Spectral Hole-Burning and Related Spectroscopies: Science and Applications. Optica Publishing Group, 1994. http://dx.doi.org/10.1364/shbs.1994.wd40.

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In our previous works, some holeburning results in organic materials with charge transfer were given. We achieved the photon-gated holeburning in a system containing the electron acceptor (p-hydroxybenzaldhyde (PHBA)) and the electron donor (Zn-tetraphenylbenzoporphyrin (Zn-TPBP) doped in a matrix (poly-methylmethacrylate (PMMA) ) [1-3]. In this paper, we will report the single photon holeburning at 25K in p- tetraphenylporphyrin (TPP) embedded in the matrix of polymethylcellulose. The mechanisms of holeburning and holefilling are discussed.

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Wenger, Bernard, Christophe Bauer, Mohammad K. Nazeeruddin, et al. "Electron donor-acceptor distance dependence of the dynamics of light-induced interfacial charge transfer in the dye-sensitization of nanocrystalline oxide semiconductors." In SPIE Optics + Photonics, edited by Mark Spitler and Frank Willig. SPIE, 2006. http://dx.doi.org/10.1117/12.681538.

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Hamm, P., and W. Zinth. "Ultrafast Fluorescence Spectroscopy of Reaction Centers of Photosynthetic Bacteria." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/up.1992.tuc29.

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In the primary reaction of photosynthesis an electron is transferred through a pigment-protein complex called reaction center (RC). Starting from the primary donor, a dimer of bacteriochlorophyll molecules called special pair P, the electron reaches a quinone (Q) via two intermediate acceptors, a bacteriochlorophyll-monomer (B) and a bacteriopheophytin (H). In a number of publications this electron transfer process was investigated by transient absorption spectroscopy /1/. At least four kinetic constants of 0.9 ps, 3.5 ps, 200 ps and infinity are required to explain the absorption data /2,3/.

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Zyss, Joseph, Ifor Samuel, Céline FIORINI, Fabrice Charra, and Jean-Michel Nunzi. "Permanent All Optical Poling of An Octupolar Dye." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1995. http://dx.doi.org/10.1364/otfa.1995.tue.1.

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The predominant class of molecular systems considered so-far towards applications in the realm of quadratic nonlinear optics has been derived from the all-pervading "molecular diode" template as exemplified by paranitroaniline-like molecules. The underlying basic paradigm consists in the dipolar anchoring of an interacting couple of electron donor and acceptor groups to a conjugated π electron linkage(1). The virtue of such a configuration is to provide a significant electronic charge displacement in the ground state which is further enhanced upon directional optical excitation towards the cha

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Reports on the topic "Charge transfer or electron donor-acceptor complex"

1

Pianwanit, Somsak, and Sirirat Kokpol. Theoretical analysis of photoinduced electron transfer in FMN binding protein : Effect of changes in one charge on electron transfer rate. Chulalongkorn University, 2013. https://doi.org/10.58837/chula.res.2013.32.

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Photoinduced electron transfer (PET) is an important process due to its several applications, e.g. solar energy conversion. Flavoproteins are generally selected as a model for the study of PET. In this research, effect of charge at residue 13 on the PET from Trp32, Tyr35 and Try106 to an excited isoalloxazine (Iso*) in FMN binding protein (FBP) from Desulfovibrio vulgaris (Miyazaki F) was studied. A wild type (E13 with negative charge) and four mutations of FBP at residue 13, E13K and E13R (politive charge), E13T and E13Q (neutral charge), were subjected to molecular dynamics (MD) simulations,

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