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Journal articles on the topic 'Charge transfers and SEI'

Author: Grafiati

Published: 9 November 2024

Last updated: 31 July 2025

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1

Qi, Yue. "(Invited) Modeling the Charge Transfer Reactions at Li/SEI/Electrolyte Interfaces in Lithium-Ion Batteries." ECS Meeting Abstracts MA2023-01, no. 45 (2023): 2452. http://dx.doi.org/10.1149/ma2023-01452452mtgabs.

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Two kinds of charge transfer reactions are critical for the performance and life of lithium battery: the desired ion transfer reaction occurring during each charge/discharge cycle, , and the undesired electron transfer reactions leading to the parasitic chemical decomposition of the electrolyte and solid electrolyte interphase (SEI) formation/growth. The heterogeneous multi-component nature of SEI dominates its ionic and electronic transport properties and controls these two charge transfer reactions. Density Functional Theory (DFT)-informed multiscale modeling has been providing valuable insi

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2

Morasch, Robert, Hubert A. Gasteiger, and Bharatkumar Suthar. "Li-Ion Battery Material Impedance Analysis II: Graphite and Solid Electrolyte Interphase Kinetics." Journal of The Electrochemical Society 171, no. 5 (2024): 050548. http://dx.doi.org/10.1149/1945-7111/ad48c0.

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Li-ion battery graphite electrodes form a solid-electrolyte-interphase (SEI) which is vital in protecting the stability and efficiency of the cell. The SEI properties have been studied extensively in the context of formation and additives, however studying its kinetic features after formation have been neglected. In this study we show the dynamic resistive behavior of the SEI after formation. Via electrochemical impedance spectroscopy measurements on Cu-foil after SEI formation we show how the SEI shows a potential-dependent resistance which can be explained by a change in charge carriers (Li+

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3

Lee, Sangyup, and Soon-Ki Jeong. "Investigation of the electrochemical properties of a propylene carbonate-derived SEI in an ethylene carbonate-based solution." BIO Web of Conferences 62 (2023): 04002. http://dx.doi.org/10.1051/bioconf/20236204002.

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Herein, we aim to explore and analyze the influence of electrolytes on the creation of a solid electrolyte interface (SEI) within ethylene carbonate (EC) and propylene carbonate (PC)-based electrolyte solutions. Our investigation reveals that despite variations in the charge consumption during SEI formation, a comparable SEI is generated in a high-concentration PC-based electrolyte as observed in an EC-based electrolyte. However, it is noteworthy that the SEI originating from the PC-based electrolyte exhibits a significantly higher resistance to lithium ion transport when compared to the SEI f

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4

Jeong, Soon Ki. "Effects of Lithium Salt on Interfacial Reactions between SiC and EC-Based Solutions in Lithium Secondary Batteries." Applied Mechanics and Materials 873 (November 2017): 112–16. http://dx.doi.org/10.4028/www.scientific.net/amm.873.112.

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Electrochemical reactions occurring at a SiC electrode were investigated to gain insight into the effects of lithium salts, such as LiPF6, LiClO4, LiCF3SO3, and LiBF4, on the interfacial resistance. Lithium salts were found to exert little effect on the magnitude of the resistance of the solid-electrolyte interphase (SEI). In contrast, the charge-transfer reactions observed in the LiCF3SO3-containing solution exhibited the smallest resistance. Charge-discharge analysis revealed that the nature of the SEI was significantly different from that formed in ethylene carbonate-based solutions contain

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Tsujimoto, Shota, Changhee Lee, Yuto Miyahara, Kohei Miyazaki, and Takeshi Abe. "Effect of Electrolyte on Sodium-Ion Storage Behavior into Non-Graphitizable Carbon Negative Electrode." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 806. http://dx.doi.org/10.1149/ma2023-024806mtgabs.

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Introduction Sodium-ion batteries (SIBs) are expected to be an alternative power source to lithium-ion batteries (LIBs) because their abundant resources reduce the cost of SIBs. As the negative electrode of SIBs, non-graphitizable carbon recieves a lot of attention because it can store ions not only in the graphene interlayer but also in its internal pores.[1] By controlling the pores, it is possible to achieve larger reversible capacity of more than 400 mAh g−1.[2] While many researchers have studied non-graphitizable carbon from the viewpoint of thermodynamics, there are a few reports that p

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Zhou, Xuan, Ping Li, Zhihao Tang, et al. "FEC Additive for Improved SEI Film and Electrochemical Performance of the Lithium Primary Battery." Energies 14, no. 22 (2021): 7467. http://dx.doi.org/10.3390/en14227467.

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The solid electrolyte interphase (SEI) film plays a significant role in the capacity and storage performance of lithium primary batteries. The electrolyte additives are essential in controlling the morphology, composition and structure of the SEI film. Herein, fluoroethylene carbonate (FEC) is chosen as the additive, its effects on the lithium primary battery performance are investigated, and the relevant formation mechanism of SEI film is analyzed. By comparing the electrochemical performance of the Li/AlF3 primary batteries and the microstructure of the Li anode surface under different condi

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7

Li, Galina, Aleksander Rumyantsev, Ekaterina Astrova, and Maxim Maximov. "Growth of the Cycle Life and Rate Capability of LIB Silicon Anodes Based on Macroporous Membranes." Membranes 12, no. 11 (2022): 1037. http://dx.doi.org/10.3390/membranes12111037.

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This work investigated the possibility of increasing the cycle life and rate capability of silicon anodes, made of macroporous membranes, by adding fluoroethylene carbonate (FEC) to the complex commercial electrolyte. It was found that FEC leads to a decrease in the degradation rate; for a sample without FEC addition, the discharge capacity at the level of Qdch = 1000 mAh/g remained unchanged for 220 cycles and the same sample with 3% FEC added to the electrolyte remained unchanged for over 600 cycles. FEC also improves the power characteristics of the anodes by 5–18%. Studies of impedance hod

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8

Housel, Lisa M., Alyson Abraham, Genesis D. Renderos, Kenneth J. Takeuchi, Esther S. Takeuchi, and Amy C. Marschilok. "Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry." MRS Advances 3, no. 11 (2018): 581–86. http://dx.doi.org/10.1557/adv.2018.294.

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ABSTRACTIn battery systems, a solid electrolyte interphase (SEI) is formed through electrolyte reaction on an electrode surface. The formation of SEI can have both positive and negative effects on electrochemistry. The initial formation of the layer protects the electrode from further reactivity, which can improve both shelf and cycle life. However, if the layer continues to form, it can impede charge transfer, which increases cell resistance and limits cycle life. The role of SEI is particularly important when studying conversion electrodes, since phase transformations which unveil new electr

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9

Zhuang, Qinqin, Weihuang Yang, Wei Lin, Linxi Dong, and Changjie Zhou. "Gas Sensing of Monolayer GeSe: A First-Principles Study." Nano 14, no. 10 (2019): 1950131. http://dx.doi.org/10.1142/s1793292019501315.

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The adsorption of various gas molecules (H2, H2O, CO, NH3, NO and NO[Formula: see text] on monolayer GeSe were investigated by first-principles calculations. The most stable configurations, the adsorption energies, and the amounts of charge transfer were determined. Owing to the appropriate adsorption energies and the non-negligible charge transfers, monolayer GeSe could be a promising candidate as a sensor for NH3, CO, NO and NO2. According to the band structures of the H2O, CO, NH3, NO and NO2 adsorbed systems, the reductions of the bandgaps are caused by the orbital hybridizations between t

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10

Potapenko, Anna V., Oleksandr V. Potapenko, Oleksandr V. Krushevskyi, and Miaomiao Zhou. "EIS Analysis of Sulfur Cathodes with Water-Soluble Binder NV-1A for Lithium-Sulfur Batteries." ECS Transactions 105, no. 1 (2021): 225–29. http://dx.doi.org/10.1149/10501.0225ecst.

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The paper discusses the electrochemical behavior of a Li-S battery with a new water-soluble binder NV-1A. It is shown that the main contribution is made by the interface, which is formed on the lithium counter electrode. It is noteworthy that the nonlinear growth of the resistance of SEI layer during the discharge process correlates with the change in the resistance of charge transfer through the interface.

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11

Singh, Triesha, and Bryan D. McCloskey. "Correlating Solid-Electrolyte Interface Composition to Charge Transfer Resistance for Improved Low-Temperature Performance of Lithium-Ion Batteries." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 883. http://dx.doi.org/10.1149/ma2023-025883mtgabs.

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The adverse impact of low temperatures on Li-ion batteries (LIBs) is a well known challenge. Currently, at subfreezing temperatures, the efficiency of conventional LIBs greatly decreases compared to their room temperature performance, which of course severely limits the performance of applications using LIBs in the colder regions on the planet. From a fundamental perspective, the causes of such performance decreases are yet to be fully understood, but are believed to be related to the ability of ions to move through the various phases (as well as move across phase interfaces) that exist in the

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Li, Yunsong, and Yue Qi. "Energy landscape of the charge transfer reaction at the complex Li/SEI/electrolyte interface." Energy & Environmental Science 12, no. 4 (2019): 1286–95. http://dx.doi.org/10.1039/c8ee03586e.

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Kallel, Ahmed Yahia, Viktor Petrychenko, and Olfa Kanoun. "State-of-Health of Li-Ion Battery Estimation Based on the Efficiency of the Charge Transfer Extracted from Impedance Spectra." Applied Sciences 12, no. 2 (2022): 885. http://dx.doi.org/10.3390/app12020885.

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Several studies show that impedance spectroscopy is a suitable method for online battery diagnosis and State-of-Health (SoH) estimation. However, the most common method is to model the acquired impedance spectrum with equivalent circuits and focus on the most sensitive parameters, namely the charge-transfer resistance. This paper introduces first a detailed model of a battery cell, which is then simplified and adapted to the observable spectrum behavior. Based on the physical meaning of the model parameters, we propose a novel approach for SoH assessment combining parameters of the impedance s

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14

Gu, Xin, Li Zhang, Wenchao Zhang, et al. "A CoSe–C@C core–shell structure with stable potassium storage performance realized by an effective solid electrolyte interphase layer." Journal of Materials Chemistry A 9, no. 18 (2021): 11397–404. http://dx.doi.org/10.1039/d1ta01107c.

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A CoSe–C@C core–shell structure is designed as a novel potential anode for PIBs. The introduction of KFSI salt is found to contribute to the formation of an inorganic-compound-rich SEI layer, benefiting the K ion diffusion and charge transfer dynamics.

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15

Park, Kyoung Soo, Soon Ki Jeong, and Yang Soo Kim. "Electrochemical Properties of NbO as a Negative Electrode Material for Lithium Secondary Batteries." Applied Mechanics and Materials 835 (May 2016): 126–30. http://dx.doi.org/10.4028/www.scientific.net/amm.835.126.

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The electrochemical properties of niobium monoxide, NbO, were investigated as a negative electrode material for lithium-ion batteries. Lithium ions were inserted into and extracted from NbO material at potentials < 1.0 V versus Li/Li+, involving formation of a solid electrolyte interface (SEI) on the NbO surface in the first cycle. Its reversible capacity is ~67 mAh g–1 with the capacity retention of ~109% after 50 cycles. The magnitude of charge transfer resistance was greatly decreased by ball-milling the pristine NbO, whereas the ball-milling had no effect on the SEI resistance.

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16

Tsujimoto, Shota, Changhee Lee, Yuto Miyahara, Kohei Miyazaki, and Takeshi Abe. "Effect of Solid Electrolyte Interphase on Sodium-Ion Insertion and Deinsertion in Non-Graphitizable Carbon." Journal of The Electrochemical Society 170, no. 9 (2023): 090526. http://dx.doi.org/10.1149/1945-7111/acf8fe.

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Non-graphitizable carbon allows reversible sodium-ion intercalation and hence enables stable and high-capacity sodium storage, making it a promising material for achieving long-term cycling stability in sodium-ion batteries (SIBs). This study investigated the interfacial reactions between various electrolytes and a non-graphitizable carbon electrode for their use in SIBs. The morphology and particle diameter of the non-graphitizable carbon, HC-2000, remained unchanged after heat treatment, indicating its stability. The X-ray diffraction pattern and Raman spectrum suggested a disordered structu

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17

Saito, Morihiro, Yoshiyuki Nakano, Mikihiro Takagi, et al. "Effect of Surface Fluorination on the Charge/Discharge Properties of High Potential Negative Electrode TiO₂(B) for LIBs." Key Engineering Materials 582 (September 2013): 127–30. http://dx.doi.org/10.4028/www.scientific.net/kem.582.127.

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Surface fluorination of TiO2(B) powder was conducted by pure F2 gas at room temperature for 1 h and the effect on the charge/discharge properties was examined as a negative electrode of Li-ion batteries (LIBs). X-ray diffraction (XRD) pattern was not changed before and after the surface fluorination though the peak intensities became weaker than that of the pristine sample, indicating the etching of the surface of SF-TiO2(B) power. This was supported by scanning electron microscopy (SEM) observation. However, X-ray photoelectron spectroscopy (XPS) analysis clearly revealed that F atoms exist o

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18

Yao, Koffi Pierre, Rownak Jahan Mou, and Sattajit Barua. "Electrophoretic Deposition of Chitosan as Synthetic SEI for Silicon Anode: A Model System Investigation." ECS Meeting Abstracts MA2023-01, no. 2 (2023): 523. http://dx.doi.org/10.1149/ma2023-012523mtgabs.

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The cycling performance of high-energy silicon (Si) based lithium-ion (Li-ion) battery is greatly hindered by the instability of the solid electrolyte interphase (SEI). Large volume change of Si during (de)-lithiation causes continuous cracking and re-formation of the SEI on the anode surface, eventually resulting in loss of Li inventory and extensive consumption of electrolyte. Our work aims to devise, ex situ, an artificial polymeric SEI that retains its integrity against the large volume expansion of Si (~300%) during lithiation, passivates the anode surface, and thus prolongs the cycling a

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19

Wu, Liang-Ting, Santhanamoorthi Nachimuthu, Daniel Brandell, et al. "Role of Copper as Current Collectors in the Reductive Reactivity of Polymers for Anode-Free Lithium Metal Batteries - Insights from DFT and AIMD Studies." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 845. http://dx.doi.org/10.1149/ma2023-025845mtgabs.

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Understanding the role of current collectors (CCs) in the reductive reactivity of polymers on Li metal and the resultant solid electrolyte interphase (SEI) formation is essential for improving the performance of anode-free lithium metal batteries (AFLMBs). In this study, we have examined the reactivity of three polymeric hosts: poly(ethylene oxide) (PEO), poly(ε-caprolactone) (PCL), and poly(trimethylene carbonate) (PTMC) at Li metal supported on Cu surfaces (Li/Cu) using density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations. In particular, the effect of copper (C

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20

Ovejas, Victoria, and Angel Cuadras. "Impedance Characterization of an LCO-NMC/Graphite Cell: Ohmic Conduction, SEI Transport and Charge-Transfer Phenomenon." Batteries 4, no. 3 (2018): 43. http://dx.doi.org/10.3390/batteries4030043.

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Currently, Li-ion cells are the preferred candidates as energy sources for existing portable applications and for those being developed. Thus, a proper characterization of Li-ion cells is required to optimize their use and their manufacturing process. In this study, the transport phenomena and electrochemical processes taking place in LiCoO2-Li(NiMnCo)O2/graphite (LCO-NMC/graphite) cells are identified from half-cell measurements by means of impedance spectroscopy. The results are calculated from current densities, instead of absolute values, for the future comparison of this data with other c

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21

Wang, Qi, Rui Zhang, Dan Sun, Haiyan Wang, and Yougen Tang. "Manipulating Electrolyte Interface Chemistry Enables High-Performance TiO2 Anode for Sodium-Ion Batteries." Batteries 10, no. 10 (2024): 362. http://dx.doi.org/10.3390/batteries10100362.

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Titanium dioxide (TiO2) has emerged as a candidate anode material for sodium-ion batteries (SIBs). However, their applications still face challenges of poor rate performance and low initial coulomb efficiency (ICE), which are induced by the unstable solid-electrolyte interface (SEI) and sluggish Na+ diffusion kinetics in conventional ester-based electrolytes. Herein, inspired by the electrode/electrolyte interfacial chemistry, tetrahydrofuran (THF) is exploited to construct an advanced electrolyte and reveal the relationship between the improved electrochemical performance and the derived SEI

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22

Liu, Shuangyi, Shota Tsujimoto, Ryo Sakamoto, et al. "Electrochemical Properties of Lif-Coated Graphite Negative Electrode Modelized By Atomic Layer Deposition." ECS Meeting Abstracts MA2024-02, no. 67 (2024): 4476. https://doi.org/10.1149/ma2024-02674476mtgabs.

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Introduction In recent years, carbon dioxide emissions are rapidly increasing, and electric vehicles (EVs) are expected to play a significant role towards achieving a carbon-neutral society with most of them utilizing Lithium-Ion Batteries (LIBs). The negative electrode active material of LIB is typically made of graphite, and during initial charging, the electrolyte undergoes reductive decomposition at the graphite/electrolyte interface, forming a Solid-Electrolyte Interphase (SEI). SEI exhibits lithium-ion conductivity while being electronically insulating, facilitating highly efficient char

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23

Higaki, Yusuke, Takashi Teranishi, Shinya Kondo, et al. "Mechanism of Charge Transfer Via Dielectric Interfaces in Li Ion Battery." ECS Meeting Abstracts MA2024-02, no. 67 (2024): 4429. https://doi.org/10.1149/ma2024-02674429mtgabs.

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Lithium-ion batteries (LIBs) are utilized into the power source of the electric vehicles (EVs) due to their relatively high energy density (~200 Whkg-1), originating from high theoretical capacity of the bulk oxide electrodes. In order to deliver both excellent acceleration and better fuel efficiency, LIBs is required to achieve a good balance between high power density (low cell resistance) and high electric capacity. The high-rate capability of LIBs is generally limited by the slow charge transfer at the electrolyte–electrode interface. In particular, the slow Li diffusion through the solid

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Kondo, Yasuyuki, Tomokazu Fukutsuka, Yuko Yokoyama, Yuto Miyahara, Kohei Miyazaki, and Takeshi Abe. "Kinetic properties of sodium-ion transfer at the interface between graphitic materials and organic electrolyte solutions." Journal of Applied Electrochemistry 51, no. 4 (2021): 629–38. http://dx.doi.org/10.1007/s10800-020-01523-z.

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AbstractGraphitic materials cannot be applied for the negative electrode of sodium-ion battery because the reversible capacities of graphite are anomalously small. To promote electrochemical sodium-ion intercalation into graphitic materials, the interfacial sodium-ion transfer reaction at the interface between graphitized carbon nanosphere (GCNS) electrode and organic electrolyte solutions was investigated. The interfacial lithium-ion transfer reaction was also evaluated for the comparison to the sodium-ion transfer. From the cyclic voltammograms, both lithium-ion and sodium-ion can reversibly

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Sunderraj, Niranjan, Shankar Raman Dhanushkodi, Ramesh Kumar Chidambaram, et al. "Development of Semi-Empirical and Machine Learning Models for Photoelectrochemical Cells." Energies 17, no. 21 (2024): 5313. http://dx.doi.org/10.3390/en17215313.

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We introduce a theoretical model for the photocurrent-voltage (I-V) characteristics designed to elucidate the interfacial phenomena in photoelectrochemical cells (PECs). This model investigates the sources of voltage losses and the distribution of photocurrent across the semiconductor–electrolyte interface (SEI). It calculates the whole exchange current parameter to derive cell polarization data at the SEI and visualizes the potential drop across n-type cells. The I-V model’s simulation outcomes are utilized to distinguish between the impacts of bulk recombination and space charge region (SCR)

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Schlaier, Jonas, Roman Fedorov, Shixian Huang, et al. "Electrochemical Characterization of Artificial Solid Electrolyte Interphase Developed on Graphite Via ALD." ECS Meeting Abstracts MA2023-02, no. 60 (2023): 2909. http://dx.doi.org/10.1149/ma2023-02602909mtgabs.

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During formation of Li-ion batteries, a ‘natural’ solid electrolyte interphase (SEI) is formed at the anode side by decomposition products of the electrolyte. The properties of the SEI are extremely decisive for the overall battery properties, such as rate capability and cycling stability. However, the SEI formation consumes Li, leading to so called ‘formation losses’ that can make up to 15% of the theoretical energy density of the battery. Several approaches have been presented to overcome formation losses while preserving excellent overall battery properties. Particularly, electrochemical pr

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Stich, Michael, Jesus Eduardo Valdes Landa, Isabel Pantenburg, Bernhard Roling, and Andreas Bund. "Combined Operando Investigations Reveal Correlation between Formation Parameters and Transport Mechanisms in Solid Electrolyte Interphases of Lithium-Ion Battery Anodes." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 887. http://dx.doi.org/10.1149/ma2023-025887mtgabs.

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Despite its thickness being only in the nanometer range, the solid electrolyte interphase (SEI) of lithium-ion battery anodes has proven to be a crucial component, contributing critically to the battery’s longevity and long-term rate capability. This is due to the SEI’s passivating properties, protecting the battery electrolyte from further decomposition during operation while maintaining a good conductivity for lithium ions to be intercalated into the active anode material. Notwithstanding prolonged scientific efforts, a reliable SEI characterization is still very challenging, due to its frag

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Fodouop, Kouam Arthur William. "China's mobile payment: lessons for African countries." International Journal of Science and Business 15, no. 1 (2022): 87–93. https://doi.org/10.5281/zenodo.7005831.

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In Kenya in 2007, Safaricom launched its M-PESA solution for peer-to-peer money transfer, known as the start of mobile money. Nowadays, Africa is the global leader in mobile money. However, many see China as the leader in terms of mobile payment. In many African countries, mobile money transactions such as peer-to-peer transfers and personal account withdrawals are costly. While in China, the cost of these transactions is meager; some are even free of charge. This study aims to assess the lessons African countries can learn from China’s mobile payment. The empirical research question is

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Oh, Jin-Young, Jinhong Seok, Da-ae Lim, Seong-Jae Lim, and Dong-Won Kim. "Ester-Based Dual Co-Solvents for Improving Low Temperature Performance of Lithium Iron Phosphate Battery." ECS Meeting Abstracts MA2024-02, no. 7 (2024): 938. https://doi.org/10.1149/ma2024-027938mtgabs.

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Lithium iron phosphate (LFP) batteries are widely expanded in electrical vehicles and energy storage systems (ESS) due to their enhanced safety and low cost. However, their low temperatures performance is a major obstacle for their applications. The sluggish Li+ iondiffusion within electrode at low temperatures suppresses the lithiation or de-lithiation process and ion transport through solid electrolyte interphase (SEI), resulting in poor discharge capacity. To overcome these problems, the electrolytes with improved ionic conductivity and reduced de-solvation energy are being actively investi

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Yamamoto, Satoshi, Ryotaro Sakakibara, Munekazu Motoyama, Norikazu Ishigaki, Wataru Norimatsu, and Yasutoshi Iriyama. "LiPON/Multilayer-Graphene Interface Enables High-Rate Charging and Discharging." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 839. http://dx.doi.org/10.1149/ma2023-025839mtgabs.

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Graphite is the anode-active material commonly used in LIBs. In LIB, solid electrolyte interphase (SEI) is formed by the reduction of the liquid electrolyte, and the SEI plays a role as a passive film. In the charging process, Li ions transport in the liquid electrolyte and SEI, desolvation reactions of Li ions occur, and then Li ions insert into the graphite anode. It has been reported that the desolvation reaction of Li ions is the rate-limiting process[1]. Lithium phosphorous oxynitride glass (LiPON) is a well-known material as a solid electrolyte. However, it has been reported that the ele

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Mosallanejad, Behrooz, Mehran Javanbakht, Zahra Shariatinia, and Mohammad Akrami. "Phenyl Vinylsulfonate, a Novel Electrolyte Additive to Improve Electrochemical Performance of Lithium-Ion Batteries." Energies 15, no. 17 (2022): 6205. http://dx.doi.org/10.3390/en15176205.

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Irreversible capacity fading, originating from the formation of the solid electrolyte interphase (SEI), is a common challenge encountered in lithium-ion batteries (LIBs) containing an electrolyte based on ethylene carbonate (EC). In this research, phenyl vinyl sulfonate (PVS) is examined as a novel electrolyte additive to mitigate this issue and subsequently enhance the cyclic stability of LIBs. As evidenced by density functional theory (DFT) calculations, PVS has a higher reduction potential than that of EC, which is in accordance with the cyclic voltammetry (CV) measurements. Accordingly, th

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Schmidt-Meinzer, Noah, and Ingo Krossing. "Synthesis and Electrochemical Characterization of Novel Electrolyte Additives for High Performance in Lithium-Ion Batteries with Si-Based Anodes." ECS Meeting Abstracts MA2023-02, no. 65 (2023): 3093. http://dx.doi.org/10.1149/ma2023-02653093mtgabs.

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Silicon is a promising active material for the anode in lithium-ion batteries (LIB), since it enables much higher energy densities than graphite - the state-of the art material for LIB-anodes. However, the utilization of silicon brings many challenges, which originate mainly from the enormous volume change between the lithiated and delithiated state (300%). One of the consequences is a constant re-formation of the solid electrolyte interphase (SEI), which is accompanied by a loss of active Li+. This leads to a strong capacity fading, which results in a very short cycle life. [1] An efficient a

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Zheng, Lu, Liang Bin Liu, Xiao Jing Zhou, and Yu Zhong Guo. "An Electrochemical Impedance Spectroscopy (EIS) Study of Zn-Doped Li (Ni_1/3Co_1/3Mn_1/3) O₂Cathode Materials in the First Delithiation Process." Advanced Materials Research 833 (November 2013): 50–55. http://dx.doi.org/10.4028/www.scientific.net/amr.833.50.

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Li (Ni1/3Co1/3Mn1/3) O2 cathode materials doped by Zn were synthesized by a co-precipitation routine, the first delithiation process of the samples with 0-4wt% of Zn doping were studied by electrochemical impedance spectroscopy (EIS) under the polarized voltage of 2.8-4.6V. The fitting results based on EIS data indicate that delithiation reactions happen within the voltage range of 3.7-4.4V ; The resistances of SEI film and charge transfer are both decreased significantly, whereas Li+ diffusion ability through layered crystalline lattice is improved largely with the increase of zinc doping fro

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Aboonasr Shiraz, Mohammad Hossein, Erwin Rehl, Hossein Kazemian, and Jian Liu. "Durable Lithium/Selenium Batteries Enabled by the Integration of MOF-Derived Porous Carbon and Alucone Coating." Nanomaterials 11, no. 8 (2021): 1976. http://dx.doi.org/10.3390/nano11081976.

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Lithium-selenium (Li-Se) batteries are a promising energy storage system in electric vehicles due to their high capacity and good kinetics. However, the shuttle effect issue, caused by polyselenide dissolution from the Se cathode, has hampered the development of Li-Se batteries. Herein, we developed a facile preparation of porous carbon from a metal-organic framework (MOF) to confine Se (Se/CZIF) and protect the Se/CZIF composite with an alucone coating by molecular layer deposition (MLD). The optimal alucone coated Se/CZIF cathode prepared exhibits a one-step reversible charge/discharge proce

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Genov, Ivan, Alexander Tesfaye, Svetlozar Ivanov, and Andreas Bund. "Investigations on the Initial-Stages of Lithium Deposition/Dissolution Processes in Sulfolane Based Electrolytes." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 833. http://dx.doi.org/10.1149/ma2023-025833mtgabs.

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Li metal could be the ideal anode for rechargeable battery technologies, due to its negative redox potential (ca. -3 V vs. SHE), high specific capacity (3860 mAh g−1), and low density (0.534 g cm−3) [1-3]. Recent advances show a new design concept where there are no initial active materials in the anode (no carbon, Si, or Li metal) and the corresponding Li quantity is directly deposited on the current collector during charging. This approach will result in important practical advantages such as enhanced volumetric and gravimetric specific energies, ease of manufacturing and reduced complexity/

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Cora, Saida, and Niya Sa. "Mechanisms of Si Stabilization for Future Anode Design." ECS Meeting Abstracts MA2022-02, no. 4 (2022): 359. http://dx.doi.org/10.1149/ma2022-024359mtgabs.

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Silicon owing to its abundance, low working potential and high theoretical specific capacity has been regarded as one of the promising anode materials for the next generation lithium-ion batteries (LIBs). The bottleneck of Si anode practical application is its large volume variation and formation of reactive silicide species at the anode/electrolyte interface during lithiation which result in continuous SEI formation and consumption of active electrolyte components. The new electrolyte design strategies have shown to stabilize the Si electrode via an in situ electrochemical formation of a meta

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Nesterova, Inara, Liga Britala, Anatolijs Sarakovskis, Beate Kruze, Gunars Bajars, and Gints Kucinskis. "The Impact of Graphene in Na2FeP2O7/C/Reduced Graphene Oxide Composite Cathode for Sodium-Ion Batteries." Batteries 9, no. 8 (2023): 406. http://dx.doi.org/10.3390/batteries9080406.

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This study presents a thorough investigation of Na2FeP2O7 (NFP) cathode material for sodium-ion batteries and its composites with carbon and reduced graphene oxide (rGO). Our findings demonstrate that rGO sheets improve cycling performance in NFP/C/rGO composite in the absence of solid electrolyte interphase (SEI)-stabilizing additives. However, once SEI is stabilized with the help of fluoroethylene carbonate electrolyte additive, NFP with carbon additive (NFP/C) exhibits a superior electrochemical performance when compared to NFP/rGO and NFP/C/rGO composites. The decreases in capacity and rat

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Joshi, Prerna, Katsuhito Iwai, Sai Gourang Patnaik, Raman Vedarajan, and Noriyoshi Matsumi. "Reduction of Charge-Transfer Resistance via Artificial SEI Formation Using Electropolymerization of Borylated Thiophene Monomer on Graphite Anodes." Journal of The Electrochemical Society 165, no. 3 (2018): A493—A500. http://dx.doi.org/10.1149/2.0141803jes.

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Flasque, Miguel, Albert Nguyen Van Nhien, Davide Moia, Piers R. F. Barnes, and Frédéric Sauvage. "Consequences of Solid Electrolyte Interphase (SEI) Formation upon Aging on Charge-Transfer Processes in Dye-Sensitized Solar Cells." Journal of Physical Chemistry C 120, no. 34 (2016): 18991–98. http://dx.doi.org/10.1021/acs.jpcc.6b05977.

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Huang, Yan Dan, Ying Bin Lin, and Zhi Gao Huang. "Enhanced Electrochemical Performances of LiFePO₄/C Cathode Materials by Deposited with Ge Film." Advanced Materials Research 936 (June 2014): 480–85. http://dx.doi.org/10.4028/www.scientific.net/amr.936.480.

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LiFePO4/C-Ge electrodes were prepared with vacuum thermal evaporation deposition by depositing Ge films on as-prepared LiFePO4/C electrodes. The effect of Ge film on the electrochemical performances of LiFePO4/C cells was investigated systematically by charge/discharge testing, cyclic voltammograms and AC impedance spectroscopy, respectively. It was found that Ge-film-surface modified LiFePO4/C showed excellent electrochemical performances compared to that of the pristine one in terms of cyclability and rate capability. At 60°C, LiFePO4/C-Ge film exhibited outstanding cyclability with less tha

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Kim, Tae Hyeon, Sung Su Park, Min Su Kang, et al. "Accelerated Degradation of SiO/NCM Cell Quick Rechargeability Due to Depth-of-Discharge Range Dependent Failure Induced Li Dendrite Formation." Journal of The Electrochemical Society 169, no. 2 (2022): 020562. http://dx.doi.org/10.1149/1945-7111/ac53cf.

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The failure of the quick rechargeability of SiO-based lithium-ion batteries is examined based on different SOC ranges pre-cycling. In detail, the effect of the SiO electrode during normal C-rate applied cycling on the subsequent quick charge is analyzed. The degradation of the SiO electrode is greatly influenced by the design of cycling SOC range of the SiO/NCM811 cell, and severe mechanical and solid electrolyte interphase degradation of the SiO electrode occurred with highly utilized SiO electrodes, resulting in Li plating on the SiO surface under quick charge conditions due to the low open-

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Loghavi, Mohammad Mohsen, Saeed Bahadorikhalili, Najme Lari, Mohammad Hadi Moghim, Mohsen Babaiee, and Rahim Eqra. "The Effect of Crystalline Microstructure of PVDF Binder on Mechanical and Electrochemical Performance of Lithium-Ion Batteries Cathode." Zeitschrift für Physikalische Chemie 234, no. 3 (2020): 381–97. http://dx.doi.org/10.1515/zpch-2018-1343.

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AbstractIn this paper, the effect of the crystalline microstructures of polyvinylidene fluoride (PVDF), as cathode binder, on mechanical and electrochemical properties of the cathode, and on the cell performance is investigated. The crystalline phases of the PVDF films prepared at different temperatures are determined by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) and also mechanical strength of PVDF films evaluated by a tensile test. The cathodes were prepared at altered temperatures to achieve different PVDF phases. The effect of various crystalline phases on

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Oroszová, Lenka, Dávid Csík, Gabriela Baranová, et al. "Utilizing High-Capacity Spinel-Structured High-Entropy Oxide (CrMnFeCoCu)3O4 as a Graphite Alternative in Lithium-Ion Batteries." Crystals 14, no. 3 (2024): 218. http://dx.doi.org/10.3390/cryst14030218.

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In the realm of advanced anode materials for lithium-ion batteries, this study explores the electrochemical performance of a high-entropy oxide (HEO) with a unique spinel structure. The equiatomic composition of CrMnFeCoCu was synthesized and subjected to a comprehensive materials characterization process, including X-ray diffraction and microscopy techniques. The multicomponent alloy exhibited a multiphase structure, comprising two face-centered cubic (FCC) phases and an oxide phase. Upon oxidation, the material transformed into a spinel oxide with a minor presence of CuO. The resulting high-

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Vlčková, Zuzana, Martin Jindra, Gabriela Soukupová, et al. "In Situ Raman Spectroelectrochemical Investigation of Composite Si Nanoparticle-Based Anode for Li-Ion Batteries during (de)Lithiation Process." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 823. http://dx.doi.org/10.1149/ma2023-025823mtgabs.

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The key degradation processes in the composite anode for the Li-ion batteries (LIBs) prepared using Si nanoparticles (SiNPs) with two types of a conductive carbon-based matrix [carbon black (CB) and carbonized polypyrrole (CPPy)] were studied by in situ Raman spectroelectrochemistry (SEC). This combined technique provides non-destructive and real-time monitoring of the chemical and structural changes that occur during battery operation. These processes, such as the crystal lattice changes (expansion/contraction) and possible degradation/amorphization of silicon, the solid electrolyte interphas

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Sanroman Gutierrez, Kenzie Marie, Yi Cui, and Stacey F. Bent. "Interface Engineering of Current Collector Using Resistive ALD-Grown Nanofilms for Fast Charging of Lithium Metal Batteries." ECS Meeting Abstracts MA2024-02, no. 30 (2024): 2257. https://doi.org/10.1149/ma2024-02302257mtgabs.

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Electrification of the transportation sector has been an important development in the global renewable energy transition. However, electric vehicle adoption has been hindered by concerns about the range from a full charge, as well as opposition to hours-long charging times. Thus, more energy-dense batteries that can withstand aggressive fast charging conditions are essential to the widespread adoption of electric vehicles. While lithium-ion batteries have been the staple for rechargeable products, including electric vehicles, they are approaching their theoretical energy density limits. Lithiu

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Eldesoky, A., E. R. Logan, A. J. Louli, et al. "Impact of Graphite Materials on the Lifetime of NMC811/Graphite Pouch Cells: Part II. Long-Term Cycling, Stack Pressure Growth, Isothermal Microcalorimetry, and Lifetime Projection." Journal of The Electrochemical Society 169, no. 1 (2022): 010501. http://dx.doi.org/10.1149/1945-7111/ac42f1.

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Part II of this 2-part series examines the impact of competitive graphite materials on NMC811 pouch cell performance using Ultra-High Precision Coulometry (UHPC), isothermal microcalorimetry, and in-situ stack growth. A simple lifetime projection of the best NMC811/graphite cells as a function of operating temperature is made. We show that graphite choice greatly impacts fractional fade, while fractional charge endpoint capacity slippage was largely unchanged due to identical cathodes. We show that an increase in graphite 1st cycle efficiency due to limited redox-active sites—favourable for mi

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Gossage, Zachary Tyson, Nanako Ito, Tomooki Hosaka, Ryoichi Tatara, and Shinichi Komaba. "Understanding the Development and Properties of SEI in Concentrated Aqueous Electrolytes Via Scanning Electrochemical Microscopy." ECS Meeting Abstracts MA2023-02, no. 60 (2023): 2900. http://dx.doi.org/10.1149/ma2023-02602900mtgabs.

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Solid-electrolyte interphases (SEI) are essential to the stability of high voltage lithium-ion batteries (LIBs) where they act as a protective barrier that prevents electrolyte decomposition during charge-discharge and during storage of the energy. Within emerging water-in-salt electrolytes (WISE), the SEI are thought to play a similar role in preventing electrolyte decomposition and expanding the potential window.(1, 2) The SEI reported in WISE are derived from the electrolyte ions, producing inorganic SEI (e.g. LiF) of similar thickness to non-aqueous batteries.(1) Others suggest the superco

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Lee, Dongsoo, Seho Sun, Chanho Kim, et al. "Highly reversible cycling with Dendrite-Free lithium deposition enabled by robust SEI layer with low charge transfer activation energy." Applied Surface Science 572 (January 2022): 151439. http://dx.doi.org/10.1016/j.apsusc.2021.151439.

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Feng, Deshi, Ruiling Zheng, Li Qiao, et al. "Metal–Organic Framework-Derived Co9S8 Nanowall Array Embellished Polypropylene Separator for Dendrite-Free Lithium Metal Anodes." Polymers 16, no. 13 (2024): 1924. http://dx.doi.org/10.3390/polym16131924.

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Developing a reasonable design of a lithiophilic artificial solid electrolyte interphase (SEI) to induce the uniform deposition of Li+ ions and improve the Coulombic efficiency and energy density of batteries is a key task for the development of high-performance lithium metal anodes. Herein, a high-performance separator for lithium metal anodes was designed by the in situ growth of a metal–organic framework (MOF)-derived transition metal sulfide array as an artificial SEI on polypropylene separators (denoted as Co9S8-PP). The high ionic conductivity and excellent morphology provided a convenie

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Jayawardana, Chamithri, Nuwanthi Dilhari Rodrigo, and Brett L. Lucht. "(Invited) Lithium Tetrafluoroborate Based Ester Electrolyte System for Wide Operating Temperatures Ingraphite/ Lini 0.6 Co 0.2 Mn 0.2 O 2 Cells." ECS Meeting Abstracts MA2023-01, no. 38 (2023): 2237. http://dx.doi.org/10.1149/ma2023-01382237mtgabs.

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As Lithium ion batteries (LIB) are utilized in wider scale of applications, operation at a wide range of operating temperatures without a penalty to the energy density is desired. Current LIB only produces a fraction of the room temperature capacity when operated at subzero temperatures. Optimization of the electrolyte composition has long been considered a way of improving low temperature battery performance, as the electrolyte dictates the ionic mobility and the stability of the solid electrolyte interface (SEI), which in turn determine the Li ion intercalation kinetics and cycle life of the

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