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Journal articles on the topic 'Chemial bath deposition'

Author: Grafiati

Published: 28 May 2022

Last updated: 30 July 2025

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1

B. A. Ezekoye, B. A. Ezekoye, P. O. Offor P.O. Offor, V. A. Ezekoye V. A. Ezekoye, and F. I. Ezema F. I. Ezema. "Chemical Bath Deposition Technique of Thin Films: A Review." International Journal of Scientific Research 2, no. 8 (2012): 452–56. http://dx.doi.org/10.15373/22778179/aug2013/149.

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2

Basha, K. A. Jamal, Phaneendra Reddy Guddeti, and Tulasi Ramakrishna Reddy Kotte. "Effect of Deposition Time on the Properties of NiS Films Prepared by Chemical Bath Deposition." Indian Journal Of Science And Technology 15, no. 45 (2022): 2492–99. http://dx.doi.org/10.17485/ijst/v15i45.1783.

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3

Bansode, Sanjay, Ramesh Kapadnis, Vasant Wagh, Sampat Kale, and Habib Pathan. "Comparative Studies on Physico-Chemical Properties of Indium Sulfide Films Deposited under Different Deposition Conditions by Chemical Bath Deposition." Chemistry & Chemical Technology 8, no. 4 (2014): 441–44. http://dx.doi.org/10.23939/chcht08.04.441.

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4

Xie, Zhen Hai, and Jian Kang Li. "Preparation and Characterization of Chemical Bath Deposited CdS Thin Films for Solar Cells." Materials Science Forum 743-744 (January 2013): 438–42. http://dx.doi.org/10.4028/www.scientific.net/msf.743-744.438.

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Chemical bath deposition of CdS thin film for solar cells was investigated in this study. CdS thin films were prepared by chemical-bath deposition (CBD) from a bath containing cadmium acetate, ammonium chloride, ammonium hydroxide and thiourea in aqueous solution on the glass substrate at certain bath temperature. The characterization of samples was conducted by using different methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet spectrophotometry (UV). The crystal quality of CdS thin films was improved after CdCl2 thermal annealing at 400C. The results s

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5

G. R. Patil, G. R. Patil, and B. N. Pawar B. N. Pawar. "Effect of pH on the Poroperties of ZnO thin Films Grown by Chemical Bath Deposition." International Journal of Scientific Research 2, no. 4 (2012): 329–31. http://dx.doi.org/10.15373/22778179/apr2013/119.

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6

B. A. Ezekoye, B. A. Ezekoye, V. A. Ezekoye V. A. Ezekoye, F. I. Ezema F. I. Ezema, P. O. Offor P.O. Offor, and D. C. Obiegbunna D. C. Obiegbunna. "Syntheses and Properties Characterizations of Titanium Oxide/ Cadmium Sulphide Nanocomposites by Chemical Bath Deposition Technique." International Journal of Scientific Research 2, no. 8 (2012): 448–51. http://dx.doi.org/10.15373/22778179/aug2013/148.

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7

Neves, Márcia C., and Tito Trindade. "Chemical bath deposition of BiVO4." Thin Solid Films 406, no. 1-2 (2002): 93–97. http://dx.doi.org/10.1016/s0040-6090(01)01787-4.

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8

Q Hamzah, M., Abdullah Hasan Jabbar, and Salim Oudah Mezan. "Synthesis and Characterization of Cu2ZnSnS4 (CZTS) Thin Film by Chemical Bath Deposition (CBD) for Solar Cell Applications." International Journal of Scientific Engineering and Research 5, no. 12 (2017): 35–37. https://doi.org/10.70729/ijser172084.

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9

Usha Rajalakshmi, P., and Rachel Oommen. "Structural and Optical Characterization of Chemically Deposited Cuprous Oxide (Cu₂O) Thin Film." Advanced Materials Research 678 (March 2013): 118–22. http://dx.doi.org/10.4028/www.scientific.net/amr.678.118.

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Thin films of cuprous oxide are grown on microscope glass slides by chemical bath deposition technique. Molar solutions of copper nitrate, hydrazine and TEA constituted the chemical bath. The depositions are made by optimizing the concentration of precursor solution. X-ray diffraction measurements revealed the phase formation in the oxide films. The optical characteristics of Cu2O films are analyzed by means of UV-Vis-NIR spectrophotometer. The effect of annealing on the structural and optical properties of the film is investigated. The calculated direct optical band gap of the films is in the

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10

Mousa, Ali M., Selma M. Al-Jawad, and Suad M. Kadhim Al-Shammari. "Structural and Optical Properties Evolution of ‘Fused’ Multilayer Nano PbS Thin Films Deposited by Chemical Bath Deposition." International Letters of Chemistry, Physics and Astronomy 25 (January 2014): 16–25. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.25.16.

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Here, we report the unusual behavior shown by the PbS samples prepared using a multilayer deposition approach by chemical solution deposition method. Thin samples were prepared by depositing several films at different deposition conditions on glass substrates. X-ray diffraction showed that final multilayer samples showed a peculiar variation. Even when they showed well defined structure the intensities of the peaks do not correspond to those of the initial films.

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11

Mousa, Ali M., Selma M. Al-Jawad, and Suad M. Kadhim Al-Shammari. "Structural and Optical Properties Evolution of ‘Fused’ Multilayer Nano PbS Thin Films Deposited by Chemical Bath Deposition." International Letters of Chemistry, Physics and Astronomy 25 (January 10, 2014): 16–25. http://dx.doi.org/10.56431/p-8v6x5o.

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Here, we report the unusual behavior shown by the PbS samples prepared using a multilayer deposition approach by chemical solution deposition method. Thin samples were prepared by depositing several films at different deposition conditions on glass substrates. X-ray diffraction showed that final multilayer samples showed a peculiar variation. Even when they showed well defined structure the intensities of the peaks do not correspond to those of the initial films.

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12

Herrero, J., M. T. Gutiérrez, C. Guillén, et al. "Photovoltaic windows by chemical bath deposition." Thin Solid Films 361-362 (February 2000): 28–33. http://dx.doi.org/10.1016/s0040-6090(99)00830-5.

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13

Shiva, Prasad, A. Marinho Fabiano, and B. Silva Leonardo. "A comparative study on electrodeposition of Fe-W-B and Fe-Mo-B alloys." Journal of Indian Chemical Society Vol. 77, Jun 2000 (2000): 311–13. https://doi.org/10.5281/zenodo.5870399.

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Department of Chemical Engineering, Center for Sciences and Technology, Universidade Federal da Paraiba, 58109-970 Campina Grande, PB. Brazil <em>Manuscript received 26 August 1999, revised 28 February 2000. accepted 3 March 2000</em> Electrodeposition processes for depositing boron-containing iron-tungsten and iron-molybdenum alloys on copper cathode from baths having ferrous sulfate, sodium tungstate (or molybdate), boron phosphate, ammonium citrate, 1-dodecylsulfate-Na and ammonia or sulfuric acid for pH adjustments have been developed. Bath stability, cathode current efficiency and qu

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14

Abubakar, D., N. Mahmoud, and Sh Mahmud. "Investigation on the Structural and Optical Properties of NiO Nanoflakes. Chemical Bath Deposition of Ni(OH)2 Thin Films." Ukrainian Journal of Physics 62, no. 11 (2017): 970–77. http://dx.doi.org/10.15407/ujpe62.11.0970.

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15

Bansode, Sanjay B., Ramesh S. Kapadnis, Abu S. Ansari, et al. "Indium selenide microrod films: chemical bath deposition from acidic bath." Journal of Materials Science: Materials in Electronics 27, no. 12 (2016): 12351–56. http://dx.doi.org/10.1007/s10854-016-5145-6.

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16

Al-Thani, Hamda A., Abeer A. Al Yafeai, and Falah S. Hasoon. "Effect of Ammonium Acetate Concentration on the Structural and Optical Properties of CdS Thin Film Grown by Chemical Bath Deposition Technique." MRS Advances 1, no. 37 (2016): 2603–16. http://dx.doi.org/10.1557/adv.2016.368.

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ABSTRACTThis study focuses on understanding the influence of incorporating Ammonium Acetate into the chemical bath used for the deposition of CdS thin films, on its optical, morphology, and microstructural properties. Thus, CdS thin films were deposited on 1” × 2” microscopic glass substrates using chemical bath deposition (CBD) technique. The deposition process was carried out in a double jacket beaker with fixed chemical bath temperature of 90°C for a deposition time of 40 min. The chemical bath solution consisted of fixed concentrations of Cadmium Acetate, Thiourea, and Ammonium Hydroxide;

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17

Sengupta, Sucheta, Tzvi Templeman, Chihyu Chen, et al. "Chemical epitaxy and interfacial reactivity in solution deposited PbS on ZnTe." Journal of Materials Chemistry C 4, no. 10 (2016): 1996–2002. http://dx.doi.org/10.1039/c5tc04147c.

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The present work aims at optimizing the conditions for growing PbS thin films on ZnTe using chemical bath deposition. Interfacial chemical reactivity is studied in detail and explained in light of ZnTe dissolution in the alkaline environment of the deposition bath.

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18

Danasuriya, U. I., B. C. Liyanapathirana, C. K. M. D. Jayathilaka, R. P. Wijesundera, and W. G. C. Kumarage. "Recent Advancements in Chemical Bath Deposited Pristine CDs Thin Films For Hotovoltaic Applications." Journal of Desk Research Review and Analysis 2, no. 2 (2025): 95–114. https://doi.org/10.4038/jdrra.v2i2.44.

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Cadmium sulfide (CdS) is (II–VI) group n-type semiconductor with appreciable physical and electronic properties. The wide band gap of about 2.42 eV, large absorption coefficient of 4×104 cm−1 and high mobility (440 cm2 V-1 s-1) make it applicable in photovoltaic energy conversion. Consequently, CdS is considered an excellent window material as well as a buffer layer for almost all chalcogenide thin film technologies, including copper zinc tin selenide (CZTSe), copper indium gallium selenide (CIGS) and CdTe-based solar cells. However, the defects present in the CdS thin films, such as inter-gra

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19

Ouafi, Mouad, Boujemaâ Jaber, Lahoucine Atourki, et al. "In Situ Low-Temperature Chemical Bath Deposition of CdS Thin Films without Thickness Limitation: Structural and Optical Properties." International Journal of Photoenergy 2018 (August 27, 2018): 1–12. http://dx.doi.org/10.1155/2018/4549154.

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In this work, thin CdS films have been deposited using the chemical bath deposition technique (CBD). Different synthesis parameters, such as number of runs, deposition time, and postannealing temperature, are studied and optimized in order to avoid the supersaturation phenomenon and to achieve a low-temperature growth. CdS thin films, of cubic structure, oriented along the (111) direction with homogenous and smooth surface, have been deposited by using the CBD growth process without any annealing treatment. Based on a set of experimental observations, we show that the solution saturation pheno

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20

Lausecker, Clément, Bassem Salem, Xavier Baillin, and Vincent Consonni. "Implementing the Reactor Geometry in the Modeling of Chemical Bath Deposition of ZnO Nanowires." Nanomaterials 12, no. 7 (2022): 1069. http://dx.doi.org/10.3390/nano12071069.

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The formation of nanowires by chemical bath deposition is of great interest for a wide variety of optoelectronic, piezoelectric, and sensing devices, from which the theoretical description of their elongation process has emerged as a critical issue. Despite its strong influence on the nanowire growth kinetics, reactor size has typically not been taken into account in the theoretical modeling developed so far. We report a new theoretical description of the axial growth rate of nanowires in dynamic conditions based on the solution of Fick’s diffusion equations, implementing a sealed reactor of f

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21

Quan, Tai. "Chemical Bath Deposition of ZnS Buffer Layers." Advanced Materials Research 813 (September 2013): 435–39. http://dx.doi.org/10.4028/www.scientific.net/amr.813.435.

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Chemical bath deposited ZnS thin films are promising buffer layers for thin film solar cells, replacing the environmentally hostile CdS buffer layers currently in use. Reflection, absorption and scattering are the three main light loss mechanisms in buffer layers. In this work, improved process conditions, such as magnetic stirring and air annealing, are used in the chemical bath deposition of ZnS thin films to optimize their surface morphology, which effectively reduces light scattering and increases the transmittance, resulting much better ZnS thin films.

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22

Popescu, Violeta, George Liviu Popescu, Emil Indrea, and Dan Teofil Silipas. "CdS Powders Obtained by Chemical Bath Deposition." Materials Science Forum 672 (January 2011): 109–12. http://dx.doi.org/10.4028/www.scientific.net/msf.672.109.

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We studied the influence of the mixing on the properties of CdS powders obtained by Chemical Bath Deposition. The powders were obtained from baths containing cadmium chloride, thiourea, and ammonia. The obtained powders were characterized using FT-IR, in order to evaluate the purity of the obtained powder. Granulometric studies were made in order to establish the grain size distribution of the particles, and X ray diffraction in order to determine the structure of nanostructured CdS.

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23

Tulenin, Stanislav S., Vyacheslav F. Markov, Larisa N. Maskaeva, and Mikhail V. Kuznetsov. "Chemical bath deposition of In2S3 thin films." European Reviews of Chemical Research 3, no. 1 (2015): 51–55. http://dx.doi.org/10.13187/ercr.2015.3.51.

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24

Neves, M. "Chemical bath deposition of cerium doped BiVO4." Dyes and Pigments 59, no. 2 (2003): 181–84. http://dx.doi.org/10.1016/s0143-7208(03)00103-7.

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25

ARIYANTO, NUGROHO P., H. ABDULLAH, J. SYARIF, BRIAN YULIARTO, and SAHBUDDIN SHAARI. "FABRICATION OF ZINC OXIDE-BASED DYE-SENSITIZED SOLAR CELL BY CHEMICAL BATH DEPOSITION." Functional Materials Letters 03, no. 04 (2010): 303–7. http://dx.doi.org/10.1142/s1793604710001457.

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Zinc oxide film has been fabricated by converting flower-like structure of zinc carbonate hydroxide made by chemical bath deposition technique. Flower-like structure is employed as charge transport network of dye-sensitized photoanode. Analysis of current density–voltage characteristic shows deposition temperature and deposition time of chemical bath deposition influence photovoltaic performance. Analysis of electrochemical impedance spectroscopy reveals short electron lifetime and high effective electron diffusion coefficient of zinc oxide-based dye-sensitized solar cell.

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26

Ali Noor, Hussein, Salam D. Mohammad, and Dakhil Abbas Abdzaid. "Study the structural and optical properties of pure and Aluminum doped CdS thin films prepared by chemical bath deposition method." Journal of Kufa Physics 10, no. 01 (2018): 37–43. http://dx.doi.org/10.31257/2018/jkp/100105.

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27

Donald N, Okoli. "Influence of Complexing Agent (TEA) On the Optical Properties of Bismuth Sulphide Thin Films Deposited By Chemical Bath Deposition Technique." International Journal of Scientific Engineering and Research 4, no. 4 (2016): 17–20. https://doi.org/10.70729/ijser15665.

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28

Chetibi L., Hamana D., and Achour S. "Metal assisted chemical etching of silicon and solution synthesis of Cu-=SUB=-2-=/SUB=-O/Si radial nanowire array heterojunctions." Semiconductors 57, no. 2 (2023): 112. http://dx.doi.org/10.21883/sc.2023.02.55956.3390.

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Cu2O/Si radial nanowire (NWs) array heterojunctions were prepared by depositing Cu2O nanoparticles via chemical bath deposition on n-Si nanowire arrays that were fabricated by metal-assisted electroless etching. After 20 cycles of deposition, large numbers of Cu2O nanoparticles with form shells that wrap the upper segment of each Si nanowire. This method of etching offers exceptional simplicity, flexibility, environmental friendliness, and scalability for the fabrication of three-dimensional silicon nanostructures with considerable depths, because of replacement of harsh oxidants such as H2O2

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29

Geremew, Temesgen. "Thin Film Deposition and Characterization Techniques." Journal of 3D Printing and Applications 1, no. 2 (2022): 1–24. http://dx.doi.org/10.14302/issn.2831-8846.j3dpa-22-4066.

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Thin films are everywhere in the modern world, with many of the technologies we depend upon in daily life being, in turn, dependent upon thin film technology. Chemical bath deposition includes principles of chemical bath deposition (CBD) and concept of solubility product, nucleation and film growth, thin film deposition mechanism in chemical bath deposition. The non-metallic ion source (anions) and metal ion source (cations) then react to form the compound. The nucleation process plays an important role in determining the crystallinity and microstructure of the resultant film. From the discuss

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30

Boyle, David S., Paul O'Brien, David J. Otway, and Odile Robbe. "Novel approach to the deposition of CdS by chemical bath deposition: the deposition of crystalline thin films of CdS from acidic baths." Journal of Materials Chemistry 9, no. 3 (1999): 725–29. http://dx.doi.org/10.1039/a808811j.

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31

Ahmed, Honar S., Raghad Y. Mohammed, and Mohammed Hussein Khalil. "Effects of Deposition Time And PH on The Characterization of Chemically Synthesized Composite Nano-Wires of Cu2S Thin Films." Science Journal of University of Zakho 9, no. 4 (2021): 184–92. http://dx.doi.org/10.25271/sjuoz.2021.9.4.863.

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 The chemical bath deposition technique (CBD) had used for depositing Cu2S thin films on the glass substrates. It found that thickness and deposition rate were significantly dependent on deposition parameters (deposition time and pH value). XRD data indicates that at different deposition times and pH values are given amorphous structure except for the deposited thin film of (8hours) and, pH of (10.4) the structure was crystalline. The morphology of the deposited thin films remarkably changed as the deposition time increased. Optical transmittance measurements illustrate that transmission

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32

Noor, Azie Azura Mohd Arif, and Suk Fun Chin. "Impact on Development of ZnS Nanoparticles Thin Film Deposited by Chemical Bath Deposition and Spin Coating." International Journal of Advanced Engineering and Nano Technology (IJAENT) 4, no. 5 (2021): 1–4. https://doi.org/10.35940/ijaent.D0459.024521.

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Research comparing the advantages of spin coating and chemical bath deposition is going, and there are varied views on these methods. Here, we used spin coating and chemical bath deposition to prepare thin films of ZnS nanoparticles. The film was analysed by photoluminescence (PL) spectrophotometry, field emission scanning electron microscopy (FE-SEM), ultraviolet spectroscopy (UV-Vis), and energy-dispersive X-ray (EDX) spectroscopy. The UV-Vis spectra revealed that the wavelength of ZnS is between 220 nm - 320 nm while the PL spectra showed a peak centred in the blue region. Both spin coating

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33

Dhara, Arpan, Gary Hodes, and Shaibal K. Sarkar. "Two stage chemical bath deposition of MoO3 nanorod films." RSC Adv. 4, no. 96 (2014): 53694–700. http://dx.doi.org/10.1039/c4ra08606f.

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h-MoO<sub>3</sub> nanorods are deposited on a FTO substrate by a two step chemical bath deposition method. The first stage of the deposition is the nucleation step followed by growth at the second stage.

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34

Turan, Evren, Esra Zeybekoğlu, and Metin Kul. "Effects of bath temperature and deposition time on Co3O4 thin films produced by chemical bath deposition." Thin Solid Films 692 (December 2019): 137632. http://dx.doi.org/10.1016/j.tsf.2019.137632.

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35

Gapanovich, Mikhail V., Natalia A. Tikhonina, Tatiana S. Kokovina, et al. "Influence of Bath Temperature on Structural, Optical and Electrical Properties of Cadmium Sulfi de Thin Films Prepared by Chemical Bath Deposition." Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases 21, no. 4 (2019): 490–97. http://dx.doi.org/10.17308/kcmf.2019.21/2360.

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Abstract. The effect of bath temperature (60-90 °C) on structural, optical and electrical propertiesof CdS thin films deposited by chemical bath deposition (CBD) at a constant precursorconcentration and deposition time was studied. From the XRD analysis, it was found that thestructure of CdS thin fi lms varied with temperature. At lower temperature hexagonal structurewas dominated while at high temperature, the cubic structure was prominent. The band gap ofthe as-prepared CdS thin fi lms was calculated from the UV-Vis spectroscopic data, and it wasfound to be decreased with the increase of tem

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36

Hoffmann, Rudolf C., Lars P. H. Jeurgens, Stefanie Wildhack, Joachim Bill, and Fritz Aldinger. "Deposition of Composite Titania/Vanadia Thin Films by Chemical Bath Deposition." Chemistry of Materials 16, no. 22 (2004): 4199–201. http://dx.doi.org/10.1021/cm040178a.

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37

Gao, Chao, Honglie Shen, Lei Sun, and Zhou Shen. "Chemical bath deposition of Bi2S3 films by a novel deposition system." Applied Surface Science 257, no. 17 (2011): 7529–33. http://dx.doi.org/10.1016/j.apsusc.2011.03.080.

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38

Switzer, Jay A., and Gary Hodes. "Electrodeposition and chemical bath deposition of functional nanomaterials." MRS Bulletin 35, no. 10 (2010): 743–50. http://dx.doi.org/10.1557/s0883769400051253.

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39

Gubur, H. Metin, F. Septekin, and S. Alpdogan. "CdSe nanowires grown by using chemical bath deposition." Journal of the Korean Physical Society 67, no. 7 (2015): 1222–27. http://dx.doi.org/10.3938/jkps.67.1222.

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40

Hou, S., C. Li, and G. I. P. De Silva. "Controllable ZnO Nanorods Growth by Chemical Bath Deposition." Transactions of the Materials Research Society of Japan 40, no. 2 (2015): 187–90. http://dx.doi.org/10.14723/tmrsj.40.187.

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41

Cheng, Jie, DongBo Fan, Hao Wang, BingWei Liu, YongCai Zhang, and Hui Yan. "Chemical bath deposition of crystalline ZnS thin films." Semiconductor Science and Technology 18, no. 7 (2003): 676–79. http://dx.doi.org/10.1088/0268-1242/18/7/313.

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42

Kariper, İ. A., and T. Özpozan. "Cobalt Xanthate Thin Film with Chemical Bath Deposition." Journal of Nanomaterials 2013 (2013): 1–9. http://dx.doi.org/10.1155/2013/139864.

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Cobalt xanthate thin films (CXTFs) were successfully deposited by chemical bath deposition, onto amorphous glass substrates, as well as on p- and n-silicon, indium tin oxide, and poly(methyl methacrylate). The structure of the films was analyzed by far-infrared spectrum (FIR), mid-infrared (MIR) spectrum, nuclear magnetic resonance (NMR), and scanning electron microscopy (SEM). These films were investigated from their structural, optical, and electrical properties point of view. Electrical properties were measured using four-point method, whereas optical properties were investigated via UV-VIS

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43

Hedlund, Jenny K., and Amy V. Walker. "Polytype control of MoS2 using chemical bath deposition." Journal of Chemical Physics 150, no. 17 (2019): 174701. http://dx.doi.org/10.1063/1.5089661.

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44

Kozhevnikova, N. S., A. S. Vorokh, and A. A. Uritskaya. "Cadmium sulfide nanoparticles prepared by chemical bath deposition." Russian Chemical Reviews 84, no. 3 (2015): 225–50. http://dx.doi.org/10.1070/rcr4452.

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45

Akhtar, M. Saeed, Saira Riaz, and Shahzad Naseem. "Synthesis of ZnS Nanoparticles by Chemical Bath Deposition." Materials Today: Proceedings 2, no. 10 (2015): 5691–94. http://dx.doi.org/10.1016/j.matpr.2015.11.111.

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46

Jacobs, Klaus, Denis Balitsky, Pascale Armand, and Philippe Papet. "Low-temperature chemical bath deposition of crystalline ZnO." Solid State Sciences 12, no. 3 (2010): 333–38. http://dx.doi.org/10.1016/j.solidstatesciences.2009.09.004.

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47

Zainal, Z., N. Saravanan, K. Anuar, M. Z. Hussein, and W. M. M. Yunus. "Chemical bath deposition of tin selenide thin films." Materials Science and Engineering: B 107, no. 2 (2004): 181–85. http://dx.doi.org/10.1016/j.mseb.2003.11.008.

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48

Lokhande, C. "ZnSe thin films by chemical bath deposition method." Solar Energy Materials and Solar Cells 55, no. 4 (1998): 379–93. http://dx.doi.org/10.1016/s0927-0248(98)00112-3.

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49

Lokhande, C. D., P. S. Patil, A. Ennaoui, and H. Tributsch. "Chemical bath ZnSe thin films: deposition and characterisation." Applied Surface Science 123-124 (January 1998): 294–97. http://dx.doi.org/10.1016/s0169-4332(97)00520-5.

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50

Garcı́a, V. M., P. K. Nair, and M. T. S. Nair. "Copper selenide thin films by chemical bath deposition." Journal of Crystal Growth 203, no. 1-2 (1999): 113–24. http://dx.doi.org/10.1016/s0022-0248(99)00040-8.

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