Academic literature on the topic 'Chemistry|Organic chemistry|Physical chemistry'

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Journal articles on the topic "Chemistry|Organic chemistry|Physical chemistry"

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Murphy, John A. "Physical organic chemistry." Beilstein Journal of Organic Chemistry 6 (November 3, 2010): 1025. http://dx.doi.org/10.3762/bjoc.6.116.

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Westheimer, F. H. "Physical organic chemistry." Pure and Applied Chemistry 69, no. 2 (February 28, 1997): 285–86. http://dx.doi.org/10.1351/pac199769020285.

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Wille, Uta. "Physical Organic Chemistry." Australian Journal of Chemistry 67, no. 5 (2014): 685. http://dx.doi.org/10.1071/ch14106.

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Fox, Marye Anne. "A Perspective on Organic Chemistry: Physical Organic Chemistry." Journal of Organic Chemistry 74, no. 22 (November 20, 2009): 8497–509. http://dx.doi.org/10.1021/jo901731t.

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Kosower, E. M. "Rethinking physical organic chemistry." Pure and Applied Chemistry 69, no. 2 (February 28, 1997): 249–54. http://dx.doi.org/10.1351/pac199769020249.

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Kostikov, R. R., and B. A. Shainyan. "Physical organic chemistry 2004." Russian Journal of Organic Chemistry 40, no. 12 (December 2004): 1838–39. http://dx.doi.org/10.1007/s11178-005-0113-2.

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Savéant, J. M. "Physical organic chemistry. Electron transier chemistry. Molecular electrochemistry." Pure and Applied Chemistry 69, no. 2 (February 28, 1997): 269–72. http://dx.doi.org/10.1351/pac199769020269.

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Popov, A. F. "Problems in physical organic chemistry and coal chemistry." Theoretical and Experimental Chemistry 23, no. 5 (1988): 571–83. http://dx.doi.org/10.1007/bf01128461.

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Chaloner, Penny A. "Topics in current chemistry, volume 146, physical organic chemistry." Journal of Organometallic Chemistry 353, no. 1 (September 1988): C20. http://dx.doi.org/10.1016/0022-328x(88)80314-0.

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Keinan, Ehud. "Rosarium Philosophorum: Physical Organic Chemistry." Israel Journal of Chemistry 56, no. 1 (January 2016): 8. http://dx.doi.org/10.1002/ijch.201510016.

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Dissertations / Theses on the topic "Chemistry|Organic chemistry|Physical chemistry"

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Portal, Christophe. "Approaches to high throughput physical organic chemistry." Thesis, University of Edinburgh, 2008. http://hdl.handle.net/1842/2434.

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Over the past ten years, the development of High Throughput (HT) synthetic chemistry techniques has allowed the rapid preparation of libraries of hundreds to thousands of compounds. These tools are now extensively used for drug and material discovery programmes. The subsequent development of analytical capabilities to carry out qualitative and quantitative assessment of the compounds generated by HT synthesis as well as their HT screening has led to a dramatic broadening of the scope of HT techniques, ranging from image based analysis techniques to mass spectrometry (MS). Based on the latter, a range of solid phase and solution phase analytical constructs was developed to enable the qualitative and quantitative assessment of mixtures of small compounds, using positive electrospray MS as the sole analytical tool. A version of the construct allowed HT reactivity profiling to be carried out on a range of ten carboxylic acids, ten aldehydes and ten isonitriles in the Ugi 4-component condensation reaction. The effect of various parameters such as the concentration of the monomers on the reactivity was investigated. The elaboration of a HT Hammett parameter assessment method was made possible by the development of an electrophilic version of the construct. The value of the Hammett value was afforded by means of combinatorial Hammett plots and values were successfully evaluated in a HT mode for around thirty anilines with substituents in the meta and para position of the aromatic ring. Finally, analytical constructs were used in an attempt to evaluate enzyme reaction kinetics via the labelling of peptides and small drug fragment with coded constructs, to afford affinity determinations between the enzyme (protease) and peptidic or fragment based substrates.
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Wan, Nan Chi. "Physical organic chemistry of N-substituted N'-cyanoguanidines." Thesis, University of Surrey, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308493.

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Geremia, Kara L. "Computational Estimation of the pKa's of Purines and Related Compounds." Wright State University / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=wright1449754930.

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Zysman-Colman, Eli. "The chemical and physical properties of polychalcogens." Thesis, McGill University, 2003. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=84864.

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The optimized synthesis of acyclic dialkoxy disulfides and aromatic polysulfides is described and their physical properties probed. A theoretical survey of dialkoxy disulfides and thionosulfites was undertaken in order to determine the most efficacious method for accurately modeling these compounds. In particular, the origin of the high barrier to rotation in the dialkoxy disulfides was determined to be due to a generalized anomeric effect resulting from two lone pair donations of each sulfur atom into each of their respective sulfur-oxygen antibonding orbitals. The origin of the high rotational barrier was also verified experimentally, in particular with respect to solvent and substituent effects. Complimentary to this thermal process, the decomposition of dialkoxy disulfides was also investigated. It was determined that these compounds decompose under first order kinetics via an initial asymmetric S-O homolytic cleavage. Activation parameters for both of these processes were determined.
Theoretical modeling on the relative ground state energies of dialkoxy disulfides is also described. It has been ascertained that the equilibrium position between the two isomers can be influenced by the ring size of the molecule; larger rings promote the dialkoxy disulfide isomer. These modeling studies were successfully corroborated experimentally. Of note is the synthesis of a new 8-membered ring dialkoxy disulfides as well as novel 7-membered ring thionosulfites. These compounds were also confirmed by single X-ray crystallography.
The kinetics of desulfurization of acyclic aromatic tri- and tetrasulfides is described. Tetrasulfides were found to transfer a sulfur atom to triphenylphosphine over ten times faster than their trisulfide analogues.
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Milton, D. M. P. "Applications of mass spectrometry in physical, organic and inorganic chemistry." Thesis, Swansea University, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.638196.

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Proton transfer reactions to monosubstituted benzenes have been studied in the gas phase as a function of protonation exothermicity using tandem mass spectrometry. The results have been interpreted in terms of competitive ring and substituent protonation and intramolecular proton migration with the aid of molecular orbital calculations. It is shown that during the reaction of CHs+ with fluorobenzene at temperatures less than 330K, proton transfer occurs preferentially to the F atom even though its proton affinity is approximately 180kJmol-1 less than the ring. Samples of ruthenium dioxide hydrate have been studied using the technique of mass spectral thermal analysis, before and after thermal activation. Two types of chemically bound water are identified, of which the loss of one is associated with the thermal activation. Headspace analysis of isotopically enriched gases evolved during reactions of these two forms indicates that the decomposition products contain oxygen atoms originating from the solvent. A glow discharge ion source has been constructed to fit an MS9 mass spectrometer. This source has been demonstrated to compare well with previous configurations for the analysis of metals in pin form. Fundamental studies show that the majority of the sputtering flux is observed to possess low energies, due to de-energising symmetrical charge transfer reactions in the cathode dark space. Ions of the cathode material possess higher energies, and it appears that sputtering of the cathode is mainly caused by atoms of the cathode material itself. Analysis of solutions has been performed using the flow discharge ion source. Lead and platinum were monitored at the ppb level in the urine of patients receiving cancer chemotherapy with the drug cis-platin. The data obtained support the idea that normally stored body lead is displaced by the platinum complexed in the drug, but only to a small extent. A novel investigation was made into the suitability of the technique for the analysis of organic species deposited on the cathode. The spectra of a wide variety of compounds are very similar to desorption chemical ionisation spectra. Although some sputtering does occur, the principal desorption process appears to be caused by rapid localised heating at the cathode surface.
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Korell, Ulrich. "Electrochemistry at organic conducting salt electrodes." Thesis, McGill University, 1991. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=61171.

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Yach, Kimberly. "Miscibility and organization of organic monolayers : a solid-state NMR approach." Thesis, McGill University, 2001. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=33044.

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The chemisorption, organization and dynamics of fatty acid self-assembled monolayers (SAMs) were investigated. Three types of fatty acid SAMs were studied: (i) alkane phosphonates, (ii) alkanoic acids and (iii) hydroxy carboxylates. The samples were produced by adsorbing the surfactants on the metal oxides and were characterized primarily by solid-state NMR techniques.
Mixed monolayers were produced by co-adsorbing two different types of fatty acids, one of which was perdeuterated. The degree of miscibility was assessed by 1H-2H cross-polarization magic-angle-spinning (CP/MAS) experiments. Whereas phase separation in bulk fatty acid mixtures could be qualitatively detected, chain end intercalation in the case of mixed monolayers on colloidal substrates made determination of miscibility inconclusive.
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Wei, Ling 1961. "Structure and reactivity of monolayer and micelle interfaces." Thesis, McGill University, 1992. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=56973.

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The research in this thesis is focused on the structure and reactivity of monolayer and micelle interfaces.
The kinetic results of ring formations of a series of $ sigma$-($ omega$-bromoalkoxy)phenoxides in a cationic micellar environment (CTAB) revealed that the ring closure rate constants from the 7-membered ring to the 14-membered ring decrease by $ sim$6-fold. This is much smaller than that observed for a homogeneous reaction environment ($ sim$1500-fold). In addition, micellar effective molarities (EM)$ sb{ rm m}$ for these reactions are found to be 7 to 1900 fold greater than in homogeneous solution. This catatysis can be reasoned to originate from an increase in the ground-state free energy of the substrate induced by localization of the phenolate oxygen and alkyl bromide moieties at the polar micelle interface.
Monolayer isotherm studies establish a dependence of isotherm features on the structure of the phospholipid. It is found that the liftoff area increases as the position of the second hydrophilic group is located further from the dominate polar group. The transition pressure reaches its highest value when the substituent is in the 7-position. The condensed area for almost all these substrates gives nearly the same value ($ sim$45 A$ sp2$/molecule). These may be explained by that the molecules lie flatly on the air/water interface at high surface concentration after which the hydrophobic parts in a molecule are forced out of the water surface. The hydrophilic groups remain on the water surphase so as to produce a loop conformation. At high pressure all the molecules are approximately perpendicular to the water surface so as to form a highly dense packing state. The unusually broad first order phase transition in isotherms of some boloform and macrocyclic phospholipids is consistent with these substrates being reorientated at large areas to yield stable bilayers, trilayers, etc.
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Destiné, Jean-Nicolas. "Photodegradation of milled wood lignin." Thesis, McGill University, 1993. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=69666.

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The photodegradation of lignin has been investigated using milled wood lignin (MWL) as a model. Solutions of MWL were exposed to ultraviolet (UV) light under aerobic and anaerobic conditions. Changes in the molecular weight distribution (MWD) of the lignin were assessed by gel permeation chromatography (GPC). To elucidate the chemical changes induced in the lignin by irradiation, infrared (IR) and UV spectra of the irradiated solutions were also studied. Irradiation under nitrogen causes the formation of both high molecular weight (MW) condensation products and low MW fragments; whereas, irradiation under oxygen yields only low MW fragments, similar to those found under nitrogen. Since the formation of condensation products can be attributed to free radical coupling, it follows that oxygen is probably reacting with free radicals to form peroxyl free radicals thereby avoiding condensation to higher MW products. Finally, the chemical basis of the photoinduced changes in the MWD of the lignin are discussed.
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Warner, Stephanie D. "High-pressure vibrational spectroscopic studies : (i) group 14 tetraphenyl compounds: (ii) hydrogen-bonded species." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape11/PQDD_0005/MQ44313.pdf.

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Books on the topic "Chemistry|Organic chemistry|Physical chemistry"

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Isaacs, N. S. Physical organic chemistry. Harlow: Longman, 1987.

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Isaacs, Neil S. Physical organic chemistry. Harlow, Essex, England: Longman Scientific & Technical, 1987.

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Isaacs, Neil S. Physical organic chemistry. 2nd ed. Burnt Mill, Harlow, Essex, England: Longman Scientific & Technical, 1995.

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1952-, Dougherty Dennis A., ed. Modern physical organic chemistry. Sausalito, CA: University Science, 2004.

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Advances in physical organic chemistry.. London: Academic, 2010.

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Burley, Karl T. Physical organic chemistry: New developments. New York: Nova Science Publishers, 2010.

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Advances in physical organic chemistry. San Diego: Academic Press, 1999.

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Advances in physical organic chemistry. Oxford: Elsevier, 2009.

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Taft, Robert W., ed. Progress in Physical Organic Chemistry. Hoboken, NJ, USA: John Wiley & Sons, Inc., 1985. http://dx.doi.org/10.1002/9780470171943.

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Taft, Robert W., ed. Progress in Physical Organic Chemistry. Hoboken, NJ, USA: John Wiley & Sons, Inc., 1987. http://dx.doi.org/10.1002/9780470171950.

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Book chapters on the topic "Chemistry|Organic chemistry|Physical chemistry"

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Craig, Stephen L., and Donghua Xu. "Physical Organic Chemistry of Supramolecular Polymers." In Supramolecular Polymer Chemistry, 269–91. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527639786.ch12.

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Streitwieser, Andrew. "Ionization Potentials in Organic Chemistry." In Progress in Physical Organic Chemistry, 1–30. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171806.ch1.

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Breslow, Ronald. "A Life in Physical Organic Chemistry." In The Foundations of Physical Organic Chemistry: Fifty Years of the James Flack Norris Award, 61–76. Washington, DC: American Chemical Society, 2015. http://dx.doi.org/10.1021/bk-2015-1209.ch004.

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Streitwieser, Andrew. "Hydrogen Isotopes in Physical Organic Chemistry." In The Foundations of Physical Organic Chemistry: Fifty Years of the James Flack Norris Award, 77–92. Washington, DC: American Chemical Society, 2015. http://dx.doi.org/10.1021/bk-2015-1209.ch005.

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Fendler, Eleanor J., and Janos H. Fendler. "The Application of Radiation Chemistry to Mechanistic Studies in Organic Chemistry." In Progress in Physical Organic Chemistry, 229–335. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171868.ch5.

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Szwarc, M. "Chemistry of Radical-Ions." In Progress in Physical Organic Chemistry, 323–438. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171851.ch5.

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Krygowski, Tadeusz Marek. "Correlation Analysis in Organic Crystal Chemistry." In Progress in Physical Organic Chemistry, 239–91. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171967.ch7.

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McLaren, A. D., and G. H. Peterson. "Physical Chemistry and Biological Chemistry of Clay Mineral-Organic Nitrogen Complexes." In Soil Nitrogen, 259–84. Madison, WI, USA: American Society of Agronomy, 2015. http://dx.doi.org/10.2134/agronmonogr10.c6.

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Zuman, P. "Physical Organic Polarography." In Progress in Physical Organic Chemistry, 81–206. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171844.ch2.

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Zalewski, Romuald I. "Application of Principal Component Analysis in Organic Chemistry." In Progress in Physical Organic Chemistry, 77–128. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171974.ch3.

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Conference papers on the topic "Chemistry|Organic chemistry|Physical chemistry"

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Yuen-Zhou, Joel Y., Luis A. Martínez-Martínez, Juan B. Pérez-Sánchez, and Kai Schwennicke. "Polariton chemistry: controlling organic photophysical processes with strong light-matter coupling." In Physical Chemistry of Semiconductor Materials and Interfaces IX, edited by Daniel Congreve, Christian Nielsen, and Andrew J. Musser. SPIE, 2020. http://dx.doi.org/10.1117/12.2569171.

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Ausserré, D., B. Hamdoun, and S. Joly. "Copolymer films for organic coatings." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49434.

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Del Nero, V., C. Siat, M. J. Marti, J. M. Aubry, J. P. Lallier, N. Dupuy, and J. P. Huvenne. "Mechanism of paint removing by organic solvents." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49442.

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Cauvel, Anne, Daniel Brunel, Francesco Di Renzo, and François Fajula. "Organic lining of MCM-41-type silicas." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49443.

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Schott, M. "Study of thin organic overlayers by local probe microscopies." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49491.

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Okazaki, S., M. Kogoma, T. Yokoyama, M. Kodama, H. Nomiyama, and K. Ichinohe. "Organic thin film deposition in atmospheric pressure glow discharge." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49468.

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Kaddami, H., S. Cuney, J. P. Pascault, and J. F. Gérard. "Hybrid organic-inorganic coatings based on alkoxy-terminated macromonomers." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49449.

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Arefi-Khonsari, F., and L. Amouroux. "Plasma for deposition, grafting or etching and the chemistry of the plasma-polymer interface involved." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49467.

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Walter, Ph. "Pigments with or without organic binder? A survey of wall painting techniques during Antiquity." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49446.

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Nicolau, Y. F., and S. Davied. "Layer-by-layer chemical deposition of conducting polymer thin films. Method and procedure." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49476.

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