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Dissertations / Theses on the topic 'Chemistry, bioinorganic'

Author: Grafiati

Published: 25 July 2024

Last updated: 31 July 2025

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1

Brophy, Megan Brunjes. "Bioinorganic Chemistry of the Human Host-Defense Protein Calprotectin." Thesis, Massachusetts Institute of Technology, 2015. http://hdl.handle.net/1721.1/98823.

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Thesis: Ph. D. in Biological Chemistry, Massachusetts Institute of Technology, Department of Chemistry, 2015.<br>Vita. Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>The human innate immune system responds to bacterial and fungal pathogens by releasing the metal-chelating protein calprotectin (CP) at sites of infection and in the upper layers of the epidermis. CP is a Mn(II)- and Zn(ll)-binding protein. The work described in this thesis elucidates the metal-binding properties of CP, and correlates these properties with in vitro growth inhibition of bacteria an

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2

Yan, Siu-cheong. "Bioinorganic chemistry of antimony : interaction of antimonial with biomolecules /." View the Table of Contents & Abstract, 2004. http://sunzi.lib.hku.hk/hkuto/record/B30575540.

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3

Seifert, S., and J. Van Den Hoff. "Annual Report 2004 - Institute of Bioinorganic and Radiopharmaceutical Chemistry." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-28695.

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4

Seifert, S., and H. Spies. "Annual Report 2003 - Institute of Bioinorganic and Radiopharmaceutical chemistry." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-28959.

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5

Johannsen, Bernd, and Sepp Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 2002." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-29271.

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6

Johannsen, Bernd, and Sepp Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 2001." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-29488.

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7

Seifert, Sepp, and Bernd Johannsen. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 2000." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-29716.

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8

Johannsen, Bernd, and Sepp Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1997." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-30891.

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9

Seifert, Sepp, and Bernd Johannsen. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1996." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-31238.

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10

Seifert, Sepp, and Bernd Johannsen. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1995." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-31653.

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11

Johannsen, Bernd. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1994." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-32143.

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12

Johannsen, Bernd. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1993." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-32438.

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13

Johannsen, Bernd. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1992." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-32587.

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14

Yan, Siu-cheong, and 甄肇昌. "Bioinorganic chemistry of antimony: interaction of antimonial with biomolecules." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B4457017X.

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15

Seifert, S., and J. Van Den Hoff. "Annual Report 2004 - Institute of Bioinorganic and Radiopharmaceutical Chemistry." Forschungszentrum Rossendorf, 2005. https://hzdr.qucosa.de/id/qucosa%3A21696.

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16

Seifert, S., and H. Spies. "Annual Report 2003 - Institute of Bioinorganic and Radiopharmaceutical chemistry." Forschungszentrum Rossendorf, 2004. https://hzdr.qucosa.de/id/qucosa%3A21722.

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17

Johannsen, Bernd, and Sepp Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 2002." Forschungszentrum Rossendorf, 2003. https://hzdr.qucosa.de/id/qucosa%3A21754.

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18

Johannsen, Bernd, and Sepp Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 2001." Forschungszentrum Rossendorf, 2002. https://hzdr.qucosa.de/id/qucosa%3A21775.

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19

Johannsen, Bernd, and Sepp Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1997." Forschungszentrum Rossendorf, 1997. https://hzdr.qucosa.de/id/qucosa%3A21916.

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20

Seifert, Sepp, and Bernd Johannsen. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1996." Forschungszentrum Rossendorf, 1997. https://hzdr.qucosa.de/id/qucosa%3A21950.

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21

Seifert, Sepp, and Bernd Johannsen. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1995." Forschungszentrum Rossendorf, 1996. https://hzdr.qucosa.de/id/qucosa%3A21992.

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22

Johannsen, Bernd. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1994." Forschungszentrum Rossendorf, 1995. https://hzdr.qucosa.de/id/qucosa%3A22041.

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23

Johannsen, Bernd. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1993." Forschungszentrum Rossendorf, 1994. https://hzdr.qucosa.de/id/qucosa%3A22070.

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24

Johannsen, Bernd. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 1992." Forschungszentrum Rossendorf, 1993. https://hzdr.qucosa.de/id/qucosa%3A22085.

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25

Seifert, Sepp, and Bernd Johannsen. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Annual Report 2000." Forschungszentrum Rossendorf, 2001. https://hzdr.qucosa.de/id/qucosa%3A21798.

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26

Johannsen, B., and S. Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry, Report July - December 1999." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-30041.

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27

Howson, Suzanne E. "Self-assembly and bioinorganic chemistry of optically pure helical complexes." Thesis, University of Warwick, 2011. http://wrap.warwick.ac.uk/35728/.

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Chapter 1 introduces the concept of helicates and the importance of chirality in these complexes. The different literature methods used to synthesise optically pure helicates are reviewed and their advantages and disadvantages discussed. Finally, a new approach towards synthesising diastereomerically pure helicatelike complexes is considered. Chapter 2 describes the syntheses of optically and diastereomerically pure factris( diimine) monometallic complexes of Fe(II) with d.r. > 200:1. The origins of this unprecedented stereo- and chemical selectivity are investigated via computational and stru

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28

Johannsen, B., and S. Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry, Report July - December 1999." Forschungszentrum Rossendorf, 2000. https://hzdr.qucosa.de/id/qucosa%3A21831.

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29

Golden, Melissa Lynn. "The bioinorganic chemistry of N2S2 metal complexes: reactivity and ligating ability." Diss., Texas A&M University, 2002. http://hdl.handle.net/1969.1/2198.

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[N,N??-bis-(mercaptoethyl)-1,5-diazacyclooctanato]NiII, Ni-1, is known to undergo metallation reactions with numerous metals. [N,N??-bis-(mercaptoethyl)-1,5-diazacycloheptanato]NiII, (bme-dach)Ni or Ni-1??, differs from Ni-1 by one less carbon in its diazacycle backbone ring producing subtle differences in N2S2Ni geometry. Metallation of Ni-1?? with PdCl2, Pd(NO3)2, and NiBr2 produced three structural forms: Ni2Pd basket, Ni4Pd2 C4-paddlewheel, and Ni3 slant chair. In attempts to provide a rationale for the heterogeneity in the active site of Acetyl coA Synthase, metal ion capture studies of

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30

Johannsen, Bernd, and S. Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Report January 1998 - Juni 1999." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-30215.

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31

Johannsen, Bernd, and S. Seifert. "Institute of Bioinorganic and Radiopharmaceutical Chemistry; Report January 1998 - Juni 1999." Forschungszentrum Rossendorf, 1999. https://hzdr.qucosa.de/id/qucosa%3A21848.

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32

Rae, K. J. "The variation of some bioinorganic parameters in rheumatoid arthritis." Thesis, University of Strathclyde, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.371978.

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33

Razavet, Mathieu. "Synthetic {2Fe3S} assemblies and the active site of all-iron hydrogenases." Thesis, University of East Anglia, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.268566.

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34

Walton, Paul Howard. "The modelling of copper biosites." Thesis, University of Nottingham, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.276371.

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35

Kamp, Norbert W. J. "The catalytic oxidation of phenolic substrates using manganese triazacyclononane complexes and hydrogen peroxide." Thesis, University of York, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265366.

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36

Mars, Craig. "Small molecule models of nitrite reductase." Thesis, University of York, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270037.

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37

Wagner, William John. "Two Methodologies in Pursuit of the Elucidation of Copper (II)—Centered Bioinorganic Chemistry." [Tampa, Fla] : University of South Florida, 2009. http://purl.fcla.edu/usf/dc/et/SFE0002931.

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38

Stasser, Jay Paul. "X-ray Absorption Spectroscopy of Copper: Characterization of the Human Copper Chaperone to Superoxide Dismutase." Full text open access at:, 2006. http://content.ohsu.edu/u?/etd,5.

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39

Lyon, James Thomas III. "Chemical Studies on Oxomolybdenum(VI,IV) Complexes as Bioinorganic Models for the Molybdenum Oxidases." VCU Scholars Compass, 1985. https://scholarscompass.vcu.edu/etd/5227.

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The synthesis, characterization, and chemical properties of Mo(VI)o2(5-X-SSP) and Mo(VI)o2(5-X-SSE), (5-X- SSP2- = 2-((5-X-salicylidene)amino)benzenethiolate; 5-X- SSE2- = 2-((5-X-salicylidene)amino)ethanethiolate; X = Br, Cl, H, CH3O), which contain tridentate (ONS) Schiff base ligands is described. The chemical properties of these molybdenum complexes are compared with those which possess tridentate (ONO) Schiff base ligands. Cyclic voltammetry was used to obtain cathodic reduction potentials (EPC) for the quasi-reversible reduction of the cis-dioxomolybdenum (VI) complexes. Although the red

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40

Cronin, Leroy. "Ligand design : new small molecule models for Carbonic Anhydrase." Thesis, University of York, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288064.

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41

Schilter, David. "Synthesis and DNA-binding of Metallocyclic Architectures." Thesis, The University of Sydney, 2009. http://hdl.handle.net/2123/5317.

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A new family of cationic N-heterocyclic ligand derivatives was prepared and characterised. Among these compounds are halide salts of the dications [Y(spacer)Y]2+, each of which comprise two N heterocyclic donor groups (Y = 4,4′-bipy, pyz, apyz, apym) linked by a conformationally flexible spacer such as (CH2)n, α,α′-xylylene, 2,6-lutidylene or thiabicyclo[3.3.1]nonane-2,6 diyl. The diquaternary halide salts were converted to NO3- and PF6- salts, and interaction of these bridging ligands with labile palladium(II) and platinum(II) precursors afforded several multinuclear complexes. Bis(4,4′-bipyr

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42

Schilter, David. "Synthesis and DNA-binding of Metallocyclic Architectures." University of Sydney, 2009. http://hdl.handle.net/2123/5317.

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PhD<br>A new family of cationic N-heterocyclic ligand derivatives was prepared and characterised. Among these compounds are halide salts of the dications [Y(spacer)Y]2+, each of which comprise two N heterocyclic donor groups (Y = 4,4′-bipy, pyz, apyz, apym) linked by a conformationally flexible spacer such as (CH2)n, α,α′-xylylene, 2,6-lutidylene or thiabicyclo[3.3.1]nonane-2,6 diyl. The diquaternary halide salts were converted to NO3- and PF6- salts, and interaction of these bridging ligands with labile palladium(II) and platinum(II) precursors afforded several multinuclear complexes. Bis(4,4

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43

Green, Kayla Nalynn. "Immobilized metallodithiolate ligand supports for construction of bioinorganic model complexes." [College Station, Tex. : Texas A&M University, 2007. http://hdl.handle.net/1969.1/ETD-TAMU-2445.

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44

Maugeri, Pearson Thomas Maugeri. "Applications of resonance Raman spectroscopy to the study of bioinorganic macromolecules." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1512093478871388.

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45

Valentine, Ann M. (Ann Margaret) 1971. "Bioinorganic hydrocarbon oxidation : mechanistic and kinetic studies of the soluble methane monooxygenase from Methylococcus capsulates (bath)." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/50508.

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Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1998.<br>Includes bibliographical references (p. 219-233).<br>Chapter 1. Principles of Small Molecule Activation by Metalloproteins as Exemplified by the Soluble Methane Monooxygenase -- Chapter 2. Small Molecule Binding to the Mixed-Valent Diiron Center of Methane Monooxygenase Hydroxylase from Methylococcus capsulatus (Bath) as Revealed by ENDOR Spectroscopy -- Chapter 3. An EPR Study of the Dinuclear Iron Site in the Soluble Methane Monooxygenase Reduced by One Electron at 77 K: the Effect of Component Interactions a

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46

Conger, Matthew A. "Spectroscopic Insight into Oxidative Heme Cleavage by the Non-canonical Heme Oxygenase IsdG from Staphylococcus aureus." ScholarWorks @ UVM, 2018. https://scholarworks.uvm.edu/graddis/944.

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IsdG and IsdI are non-canonical heme oxygenases (HO) from Staphylococcus aureus that catalyze the oxidative cleavage of heme to give novel organic products (staphylobilins) and iron as a nutrient for the pathogen. Comparison of the reported equilibrium dissociation constant (Kd) values for heme from IsdG and IsdI compared to the reported concentration of the labile heme pool called into question whether these enzymes are competent HOs in vivo. We took advantage of a second-sphere Trp whose fluorescence is quenched upon heme binding, which led to Kd values 2-3 orders of magnitude smaller than r

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47

Luo, Haibin. "Biointerfacial studies of nucleic-acid bases using chromatographic and three-dimensional chemometric methods." HKBU Institutional Repository, 2005. http://repository.hkbu.edu.hk/etd_ra/658.

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48

Osborn, Maire. "Cellular RNA Targeting by Platinum (II) Anticancer Therapeutics." Thesis, University of Oregon, 2014. http://hdl.handle.net/1794/17920.

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Cis-diamminedichloroplatinum (II), or cisplatin, is a widely prescribed anticancer compound, currently one of only three platinum (II) complexes FDA approved for cancer treatment. Despite its widespread use, we lack a comprehensive picture of global drug targets, which would lend valuable insights into the molecular mechanisms of action and resistance in different tissues. Drug binding to genomic DNA is an accepted cause of downstream apoptotic signaling, but less than 10% of Pt (in the case of cisplatin) accumulates within genomic DNA. Non-genomic contributions to cisplatin's therapeutic acti

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49

Wilson, Clayton Allan. "Effects of Outer Sphere Mutations on CO Binding to Nickel-Substituted Azurin andImplications for Acetyl Coenzyme A Synthase Substrate Channeling." The Ohio State University, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=osu1557165301317548.

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50

Ekström, Jesper. "Transition Metal Hydrides : Biomimetic Studies and Catalytic Applications." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-7187.

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In this thesis, studies of the nature of different transition metal-hydride complexes are described. The first part deals with the enantioswitchable behaviour of rhodium complexes derived from amino acids, applied in asymmetric transfer hydrogenation of ketones. We found that the use of amino acid thio amide ligands resulted in the formation of the R-configured product, whereas the use of the corresponding hydroxamic acid- or hydrazide ligands selectively gave the S-alcohol. Structure/activity investigations revealed that the stereochemical outcome of the catalytic reaction depends on the liga

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