Relevant bibliographies by topics / Chemistry, Organic. Electrolysis

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers

Academic literature on the topic 'Chemistry, Organic. Electrolysis'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Chemistry, Organic. Electrolysis"

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Schulz, Lara, and Siegfried Waldvogel. "Solvent Control in Electro-Organic Synthesis." Synlett 30, no. 03 (2018): 275–86. http://dx.doi.org/10.1055/s-0037-1610303.

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Exploiting the solvent control within electro-organic conversions is a far underestimated parameter in prep-scale electrolysis. The beneficial application in several transformations is outlined and in particular discussed for the dehydrogenative coupling of arenes and heteroarenes. This simple electrolytic strategy in fluorinated solvents allows the modulation of the substrate’s nucleophilicity and the stabilization of the intermediates as well as of the final product from over-oxidation.1 Introduction2 Solvent Effects in Kolbe Electrolysis and Anodic Fluorination3 Unique Solvent Effects of 1,
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Sbei, Najoua, Tomas Hardwick, and Nisar Ahmed. "Green Chemistry: Electrochemical Organic Transformations via Paired Electrolysis." ACS Sustainable Chemistry & Engineering 9, no. 18 (2021): 6148–69. http://dx.doi.org/10.1021/acssuschemeng.1c00665.

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Gu, Z. H., T. Z. Fahidy, R. Hornsey, and A. Nathan. "A study of the electrochemical synthesis of ZnO thin films." Canadian Journal of Chemistry 75, no. 11 (1997): 1439–44. http://dx.doi.org/10.1139/v97-173.

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The principal characteristics of the cathode deposition of zinc oxide from slightly acidified aqueous zinc nitrate solution at 65 °C were studied via potentiodynamic electrolysis, potentiostatic electrolysis, and X-ray diffraction patterns. The results indicate the reliability of a low-temperature electrolytic path of synthesis, and avenues of further exploration. Keywords: zinc oxide, cathode deposition, XRD patterns, FBM theory.
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Pletcher, Derek, Robert A. Green, and Richard C. D. Brown. "Flow Electrolysis Cells for the Synthetic Organic Chemistry Laboratory." Chemical Reviews 118, no. 9 (2017): 4573–91. http://dx.doi.org/10.1021/acs.chemrev.7b00360.

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Ren, Jie, Mengqi Yao, Wu Yang, Yan Li, and Jinzhang Gao. "Recent progress in the application of glow-discharge electrolysis plasma." Open Chemistry 12, no. 12 (2014): 1213–21. http://dx.doi.org/10.2478/s11532-014-0575-6.

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AbstractNon-equilibrium plasma makes it is possible to modify surface chemistry, synthetize polymer materials, and oxidize some organic compounds completely by generation of energetic and chemically active species in gas or liquid phases. Glow-discharge electrolysis plasma (GDEP) has been intensely studied for applications in chemistry and in material, environmental, and biomedical engineering during the last few years because of the very highly active chemical species produced during the glow-discharge electrolysis (GDE) process. A brief review is already available regarding applications of g
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Hlavatý, Jaromír, and Jiří Volke. "Use of Nafion membranes in laboratory organic electrosynthesis." Collection of Czechoslovak Chemical Communications 53, no. 12 (1988): 3164–70. http://dx.doi.org/10.1135/cccc19883164.

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Electrolysis of quaternary ammonium bromides and iodides in a divided cell with a Nafion membrane yields quaternary polyhalogenides at a carbon anode in water-ethanolic anolytes. The electrodialysis of tetrabutylammonium iodide in a cell with a Nafion membrane enables generation of tetrabutylammonium hydroxide. In electrolytic reduction of nitrobenzene in presence of 1,3-dibromopropane, N-phenylisooxazolidine results in an approx. 60% yield. This electrosynthesis takes place in dimethylformamide with tetrabutylammonium bromide at a glassy-carbon cathode in a divided cell. In the electroreducti
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Bouchard, Luc, Ian Marcotte, Jean Marc Chapuzet, and Jean Lessard. "Electroreduction of 1-methyl 5-nitroindole, 5-nitrobenzofurane, and 5-nitrobenzothiophene in acidic and basic hydroorganic media: Generation and trapping of iminoquinone-type intermediates and electrosynthesis of ring-substituted amino derivatives." Canadian Journal of Chemistry 81, no. 10 (2003): 1108–18. http://dx.doi.org/10.1139/v03-149.

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Preparative electrolysis of 1-methyl-5-nitroindole (1b, X = NCH3), 5-nitrobenzofurane (1c, X = O), and 5-nitrobenzothiophene (1d, X = S) at Hg, in acidic hydromethanolic media, leads to the formation of the corresponding 4-substituted amino derivatives 5, which result from the 100% regioselective addition to iminoquinone-type intermediate 4 of methanol or of any other good nucleophile present in the electrolytic solution. In acidic medium, the iminoquinonium intermediates 4b and 4c were trapped in a cycloaddition reaction with cyclopentadiene added to the electrolysis medium. The regiochemistr
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Rodrigo, Sachini, Disni Gunasekera, Jyoti P. Mahajan, and Long Luo. "Alternating current electrolysis for organic synthesis." Current Opinion in Electrochemistry 28 (August 2021): 100712. http://dx.doi.org/10.1016/j.coelec.2021.100712.

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TAKEHARA, Zen-ichiro, and Zempachi OGUMI. "New electrolysis methods." Journal of Synthetic Organic Chemistry, Japan 43, no. 6 (1985): 575–82. http://dx.doi.org/10.5059/yukigoseikyokaishi.43.575.

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Scheide, Marcos R., Celso R. Nicoleti, Guilherme M. Martins, and Antonio L. Braga. "Electrohalogenation of organic compounds." Organic & Biomolecular Chemistry 19, no. 12 (2021): 2578–602. http://dx.doi.org/10.1039/d0ob02459g.

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In this review we target sp, sp<sup>2</sup> and sp<sup>3</sup> carbon fluorination, chlorination, bromination and iodination reactions using electrolysis as a redox medium. Mechanistic insights and substrate reactivity are also discussed.
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Dissertations / Theses on the topic "Chemistry, Organic. Electrolysis"

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Batchelor-McAuley, Christopher. "Multi-electron transfer to and from organic molecules." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:14f0d2d6-da21-4041-9a5a-e0186fb36239.

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Herein, the influence of protonation and adsorption upon the redox and electrocatalysis of quinone species - specifically anthraquinone derivatives – is investigated. Through the comparison of the measured rate constants of one-electron reductions of a family of quinones in acetonitrile at both graphite and gold electrodes, it was confirmed that the redox potential indirectly influences the rate of electron transfer in a manner consistent with the potential-dependence of the density of states. In aqueous media, the voltammetric response of both anthraquione-2-sulfonate (AQMS) and anthraquinone
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Kelly, Michael Jon. "Hybrid ferrocene-based systems." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:fd46594d-98d6-4f8a-a6ab-eb5ee74ba7f3.

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This thesis explores the capacity of sterically and electronically unsaturated boranes to bind substrates of biological and environmental interest, and transduce such binding events into a photo-physical and/or electrochemical response, hence reporting the presence of these substrates. Chapter three details the synthesis of a range of novel ferrocenyl boranes featuring either a proximal hydrogen-bond donor or a second Lewis acidic centre. These novel boranes were shown to be competent at binding both cyanide and fluoride anions, with the role played by a proximal hydrogen-bond donor or a secon
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Binding, Samantha Carys. "Synthesis and characterisation of permethylpentalene complexes and permethylpentalene derivatives." Thesis, University of Oxford, 2015. http://ora.ox.ac.uk/objects/uuid:7855e90d-7ce9-42eb-b962-b68606ade746.

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This thesis expands the scope for using the permethylpentalene ligand and its precursors in the synthesis of organometallic complexes. <strong>Chapter one</strong> begins with a brief review of linked metallocenes, with which multimetallic compounds bridged by pentalene ligands have often been compared, followed by a comprehensive review of the routes used to make pentalenes and substituted pentalenes. Organometallic compounds of pentalenes are introduced, with a focus on bimetallic systems. <strong>Chapter two</strong> explores the diversification of substituents added to the permethylpentale
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Sarmouk, Khiredine. "Graft copolymers and polymer electrolytes based on polyethers." Thesis, University of Aberdeen, 1990. http://digitool.abdn.ac.uk/R?func=search-advanced-go&find_code1=WSN&request1=AAIU602307.

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This thesis is concerned with the preparation, characterisation and applications of butyl rubber (BR) with poly(tetrahydrofuran) (PTHF) and polymer electrolytes based on polyethers. The first part of this thesis is concerned with the preparation of rubber-PTHF graft copolymers by a cationic "grafting-from" reaction initiated by silver perchlorate at allylic bromine sites on the rubber. In order to optimise the content of grafted PTHF a series of experiments was carried out, in which reaction variables such as reaction temperature and time, and ratio of silver salt to active Br, were changed sy
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Kirkaldy, Niall. "Exploring organic, redox-active materials for electrolytic hydrogen production and electrochemical energy storage." Thesis, University of Glasgow, 2018. http://theses.gla.ac.uk/30842/.

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Proton exchange membrane electrolysers (PEMEs) constitute the state-of-the-art in electrolytic water splitting, capable of producing H2 at high current density and efficiency. However, when operating at low current or under increased pressure, H2 and O2 can cross through the membrane which separates the electrodes, creating a potentially explosive gas mixture and reducing the efficiency. Electron-coupled proton buffers (ECPBs) provide a solution to the issues of gas crossover in electrolytic water splitting, by breaking up the oxygen and hydrogen evolution reactions (OER and HER) into two sepa
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Campion, Christopher Lawrence. "An analysis of the thermal decomposition reactions of organic electrolytes used in lithium-ion batteries /." View online ; access limited to URI, 2005. http://0-wwwlib.umi.com.helin.uri.edu/dissertations/dlnow/3186896.

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Singh, Kulveer. "Structure-function studies of the oxidoreductase bilirubin oxidase from Myrothecium verrucaria using an electrochemical quartz crystal microbalance with dissipation." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:0376cc7e-f572-4e0c-96f0-43b0b4b91d99.

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This thesis presents the development and redesign of a commercial electrochemical quartz crystal microbalance with dissipation (E–QCM–D). This was used to study factors affecting the efficiency of the four electron reduction catalysed by the fuel cell enzyme bilirubin oxidase from Myrothecium verrucaria immobilised on thiol modified gold surfaces. Within this thesis, the E–QCM–D was used to show that application of a constant potential to bilirubin oxidase adsorbed to thiol-modified gold surfaces causes activity loss that can be attributed to a change in structural arrangement. Varying the loa
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Alshahrani, Rasha. "Liquid Organic Electrolytes: Blends of Low Molecular Weight Methoxyoligooxyethylene (MPEGs)/LiTFSI Salt." DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 2017. http://digitalcommons.auctr.edu/cauetds/111.

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Blends containing methoxyoligooxyethyleneglycol (MPEGs) (MW 350 and 550) and bis(trifluoromethane)sulfonimide lithium (LiTFSI) salt were prepared by solution blending process using tetrahydrofuran (THF) as a solvent. The ionic conductivity of the blends of different compositions were determined at four temperatures i.e. 25°C, 40°C, 60°C and 70°C. A maximum ionic conductivity value of 3.9x10-3 S cm-1 at 25°C was obtained for the blends containing MPEG-350 at an ethylene oxide to lithium salt ratio of 1:10. The ionic conductivity increases with increasing temperature and shows that the ion trans
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Bamford, David. "The local free volume and its correlation with the structural, chemical and dynamic properties of branched polymers, polymer electrolytes, highly oriented polyethylene fibres and other polymers." Thesis, University of Bristol, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251091.

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Huang, Junhua 1973. "A study of plastic crystals as novel solid state electrolytes." Monash University, School of Chemistry, 2003. http://arrow.monash.edu.au/hdl/1959.1/5522.

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Books on the topic "Chemistry, Organic. Electrolysis"

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Fultz, Vickie Lynn. Electrolysis of bio-organic sulfur compounds at modified electrodes. 1991.

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Fultz, Vickie Lynn. Electrolysis of bio-organic sulfur compounds at modified electrodes. 1991.

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Yurkov, Andrey. Refractories for Aluminium: Electrolysis and the Cast House. Springer, 2015.

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Yurkov, Andrey. Refractories for Aluminium: Electrolysis and the Cast House. Springer, 2014.

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Yurkov, Andrey. Refractories for Aluminium: Electrolysis and the Cast House. Springer, 2016.

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Goodridge, F. Electrochemical Process Engineering: A Guide to the Design of Electrolytic Plant. 1995.

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Book chapters on the topic "Chemistry, Organic. Electrolysis"

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Baizer, Manuel M., and John P. Petrovich. "Electrolytic Reductive Coupling: Synthetic and Mechanistic Aspects." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171868.ch4.

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Ribeiro, Ana, Joaquim Natividade, Artur Valente, and Victor Lobo. "Diffusion of Electrolytes and Non-electrolytes in Aqueous Solutions." In Progress in Organic and Physical Chemistry. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b13964-5.

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"Diffusion of Electrolytes and Non-electrolytes in Aqueous Solutions: A Useful Strategy for Structural Interpretation of Chemical Systems." In Progress in Organic and Physical Chemistry. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b13964-11.

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Rathnayake, Hemali, and Sheeba Dawood. "Coordination Polymer Frameworks for Next Generation Optoelectronic Devices." In Optoelectronics [Working Title]. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.94335.

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Metal–organic frameworks (MOFs), which belong to a sub-class of coordination polymers, have been significantly studied in the fields of gas storage and separation over the last two decades. There are 80,000 synthetically known MOFs in the current database with known crystal structures and some physical properties. However, recently, numerous functional MOFs have been exploited to use in the optoelectronic field owing to some unique properties of MOFs with enhanced luminescence, electrical, and chemical stability. This book chapter provides a comprehensive summary of MOFs chemistry, isoreticular synthesis, and properties of isoreticular MOFs, synthesis advancements to tailor optical and electrical properties. The chapter mainly discusses the research advancement made towards investigating optoelectronic properties of IRMOFs. We also discuss the future prospective of MOFs for electronic devices with a proposed roadmap suggested by us. We believe that the MOFs-device roadmap should be one meaningful way to reach MOFs milestones for optoelectronic devices, particularly providing the potential roadmap to MOF-based field-effect transistors, photovoltaics, thermoelectric devices, and solid-state electrolytes and lithium ion battery components. It may enable MOFs to be performed in their best, as well as allowing the necessary integration with other materials to fabricate fully functional devices in the next few decades.
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Conference papers on the topic "Chemistry, Organic. Electrolysis"

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Parajó, Juan José, María Villanueva López, Julio Ramón Rodríguez, Luis Miguel Varela, and Josefa Salgado. "Thermophysical characterization of ionogels of ethylamonium nitrate as advanced electrolytes for electrochemical devices." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04823.

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Ferreira, C. A., S. Aeiyach, J. J. Aaron, and P. C. Lacaze. "Strongly adherent polypyrrole coatings obtained by electropolymerization of pyrrole on oxidizable metals in aqueous electrolytic media. I. Iron and mild steel." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49463.

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Ferreira, C. A., B. Zaid, S. Aeiyach, and P. C. Lacaze. "Strongly adherent polypyrrole coatings obtained by electropolymerization of pyrrole on oxidizable metals in aqueous electrolytic media II. Zinc and zinc coated steel." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49458.

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