Academic literature on the topic 'Chemistry, Radiation'

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Journal articles on the topic "Chemistry, Radiation"

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Silverman, Joseph. "Applied Radiation Chemistry: Radiation Processing." Nuclear Technology 109, no. 2 (February 1995): 306. http://dx.doi.org/10.13182/nt95-a35062.

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Taylor, David M. "Applied radiation chemistry; radiation processing." Applied Radiation and Isotopes 45, no. 10 (October 1994): 1053. http://dx.doi.org/10.1016/0969-8043(94)90180-5.

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Kaplan, I. G. "Cherenkov radiation in radiation chemistry." Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 248, no. 1 (July 1986): 263–66. http://dx.doi.org/10.1016/0168-9002(86)90526-7.

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O'Neill, Peter, and Peter Wardman. "Radiation chemistry comes before radiation biology." International Journal of Radiation Biology 85, no. 1 (January 2009): 9–25. http://dx.doi.org/10.1080/09553000802640401.

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Charlesby, A. "Applied radiation chemistry." Radiation Physics and Chemistry 47, no. 4 (April 1996): 664–65. http://dx.doi.org/10.1016/s0969-806x(96)90045-6.

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Belloni, J., M. O. Delcourt, C. Houée-Lévin, and M. Mostafavi. "7 Radiation chemistry." Annual Reports Section "C" (Physical Chemistry) 96, no. 1 (July 26, 2000): 225–95. http://dx.doi.org/10.1039/b001203n.

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Ramos-Bernal, Sergio, and Alicia Negrón-Mendoza. "Radiation Chemistry Approach to Cometary Chemistry." International Astronomical Union Colloquium 161 (January 1997): 143–48. http://dx.doi.org/10.1017/s0252921100014652.

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AbstractThe chemistry of comets is analyzed in the light of radiolytic processes occurring in the life-time of the comet due to its interaction with radiation. A simple model of a cometary nucleus is carried out at the laboratory which simulates as a first approximation the behavior of the organics in the comet. Most of the results obtained confirm that the parent molecules of the observed ones can be deduced from these simple simulated experiments. A variety of molecules were obtained (amino acids, carboxylic acids, gaseous products, etc.), even in frozen solutions the formation of oligomers was observed. The simplified mixture consisted of five compounds in a proportion in which they appear in a dense interstellar cloud (HCN/CH3OH/CH3CN/C2H5CN/HCOOH = 1:0.6:0.2:0.1:0.05). The total amount was adjusted to correspond to a C/N ratio 1.8. At this end, radiation chemistry can be a very precise and useful tool to simulate the evolution of organic molecules exposed to high energy radiation, as cosmic rays, during the life time of a comet.
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Salmon, G. Arthur. "The radiation chemistry connection." Physica B: Condensed Matter 326, no. 1-4 (February 2003): 46–50. http://dx.doi.org/10.1016/s0921-4526(02)01575-2.

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Chmielewski, Andrzej G. "Chitosan and radiation chemistry." Radiation Physics and Chemistry 79, no. 3 (March 2010): 272–75. http://dx.doi.org/10.1016/j.radphyschem.2009.11.002.

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Kabanov, V. Ya, V. I. Feldman, B. G. Ershov, A. I. Polikarpov, D. P. Kiryukhin, and P. Yu Apel’. "Radiation chemistry of polymers." High Energy Chemistry 43, no. 1 (January 2009): 1–18. http://dx.doi.org/10.1134/s0018143909010019.

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Dissertations / Theses on the topic "Chemistry, Radiation"

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Pimblott, Simon M. "Application of stochastic models to radiation chemistry." Thesis, University of Oxford, 1988. http://ora.ox.ac.uk/objects/uuid:7b7fa46c-dd6f-4c8a-a98f-9e43b536ace5.

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This thesis addresses one area of major interest in reaction kinetics, the theoretical description of recombination in nonhomogeneous systems. The reaction of the highly reactive particles formed by the passage of ionising radiation through a medium is an important example of this type of system. Stochastic effects are apparent in every stage of the development of a radiolysis system: in the interaction between the radiation and the medium and in the diffusion and reaction processes that follow. Conventional models for nonhomogeneous kinetics in radiation chemistry are based upon a deterministic analysis. These models are appraised together with an alternative stochastic approach. Three stochastic methods are discussed: a full Monte Carlo simulation of the diffusion and reaction and two approximate models based upon an independent pairs approximation. It is important that any kinetic model accurately describes the system it purports to represent and this can only be assured by extensive validation. The stochastic models are developed to encompass the diffusion-controlled reactions of ions and radicals and to include the effects of a bulk electrolyte upon the reactions between ions. To model a realistic radiation chemistry reaction scheme, it is necessary to consider reactions that are not fully diffusion-controlled. The radiation boundary condition is introduced and used to extend stochastic modelling to partially diffusion-controlled reactions. Recombination in an anisotropic environment is also considered. Although a complete analysis of the chemistry of a radiolysis system requires a complex reaction scheme, the scheme can be simplified, in acid and in alkali, by the use of an instantaneous scavenging approximation. In acid, this approximation produces a simple three reaction mechanism based upon five species: H, OH, H2 , H20 and H202 . The acid system is used to demonstrate the stochastic treatment of realistic kinetics. The instantaneous scavenging approximation is examined in detail and techniques are developed for the explicit modelling of reactions with a homogeneously distributed scavenger. A stochastic treatment of nonhomogeneous reaction kinetics requires a description of the initial spatial distribution of the reacting particles. A rudimentary Monte Carlo simulation is used to determine a simple distribution of clusters of reactive particles similar to that found along the path of a high energy electron in water. This distribution provides a suitable basis for kinetic simulation. The kinetics of a more detailed idealised track structure are also considered and the stochastic and deterministic kinetics of extended particle distributions are discussed.
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Piña-Sandoval, Flora Marcela. "The application of microwave radiation in materials chemistry." Thesis, University of Edinburgh, 2007. http://hdl.handle.net/1842/27193.

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We have developed tuned or tunable microwave cavities to be used in conjunction with an X-ray diffractometer working either in transmission mode with a capillary sample, or in reflection mode, with a flat plate. We have also developed further a microwave cavity that enables high-resolution neutron powder diffraction patterns to be taken, and tested it successfully on the High Resolution Powder Diffractometer (HRPD), at the ISIS Facility UK. One application that was planned was the elucidation of synthetic steps in the microwave-assisted formation of the zeolite ZSM-5. We also studied microwave-assisted processing of zeolites Na-Y and H-ZSM-5, accelerating the insertion of nickel, copper of molybdenum ions in the solid-state. Phase transitions in the ferroelectric materials BaTiO3, and KNbO3 were studied by in situ diffraction to determine whether microwave irradiation can influence the transition between phases of different dielectric susceptibility, and evidence for a lower transition temperature in both cases compared to that of conventional heating. In situ neutron diffraction measurements have provided the first direct evidence of a differential heating under microwave irradiation of heterogeneous catalysts in the form of MoS2 or Ni particles dispersed over a high surface area Al2O3 support. Finally, we performed in situ X-ray diffraction on a sample of AgI held in a glass capillary to observe the transformation between the dense β phase, and the more open, fast-ion conducting α phase; this revealed a significant reduction in the transition temperature, possibly arising from a strong interaction between the microwave field and the defects or lattice modes implicated in the transition.
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Wilkinson, Susan Anne. "Aspects of radiation curing." Thesis, City University London, 1989. http://openaccess.city.ac.uk/7720/.

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The electron beam induced polymerisation of dialkyltin diacrylates, as well as the UV and electron beam induced polymerisation of some novel silicon containing acrylates are discussed. The reactivity and film forming properties of these materials are compared with that of some commercial diluents such as, tripropyleneglycol diacrylate, TPGDA and trimethylolpropane triacrylate, TMPTA. Mechanistic studies concerning the initiation of free radical polymerisation of the acrylate ester, isodecylacrylate, IDA on electron beam irradiation are presented. Addition of electron and hole scavengers revealed that slow electrons contribute significantly to the initiation of electron beam induced polymerisation of acrylate esters. The film forming properties of phenyl acrylate and mono-, di- and tri- halophenyl acrylates on exposure to electron beam irradiation are evaluated in terms of their ability to produce tackfree films. The sensitivity of catechol diacrylate compared with t-butyl catechol diacrylate is also presented. Mechanistic studies concerning the initiation of both UV and electron beam induced cationic polymerisation of 3,4-epoxycyclohexylmethyl-31,41 -epoxycyclohexanecarboxylate, with the aid of diphenyliodonium hexafýuorophosphate, triphenylsulphonium hexafluorophosphate and (n -2,4-cyclopentadien- I-yl) [(I, 2,3,4,5,6-n) (-I-methylethyl) benzene] -iron(I+) hexafluorophosphate, as well as the radiolysis of 6,7-epoxy- 3,7-dimethyloctylacrylate in the presence of diphenyliodonium hexafluorophosphate are presented. The decomposition of the salts was monitored in situ by infrared and UV spectroscopy and hydrogen fluoride is credited as the true initiator of the cationic polymerisation of epoxides in an open system. The UV photolysis of the aforementioned onium salts led to the production of volatiles, resulting in the polymerisation of thin films of 3,4-epoxycyclohexylmethyl-31,41 - epoxycyclohexanecarboxylate, providing further evidence of hydrogen fluoride evolution. The use of FTIR- photoacoustic spectroscopy was proven to be an invaluable tool in monitoring the polymerisation of thin epoxide or acrylate films on an opaque substrate.
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MUSICO, FILHO WALTER. "Efeito da radiacao ionizante no prolipropileno nacional." reponame:Repositório Institucional do IPEN, 1995. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10453.

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Bazzi, Sophia [Verfasser], and Robin [Akademischer Betreuer] Santra. "Ab initio radiation chemistry / Sophia Bazzi ; Betreuer: Robin Santra." Hamburg : Staats- und Universitätsbibliothek Hamburg, 2019. http://d-nb.info/1201087171/34.

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Preston, Christopher M. L. "Poly(dimethylsiloxane) : blends with poly(urethane) & radiation chemistry /." [St. Lucia, Qld.], 2000. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe16169.pdf.

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Khan, Niaz Ahmad. "Aspects of radiation curing." Thesis, City University London, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241483.

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Mohajerani, Shahroo. "A study of the radiation chemistry of poly(tetrafluoroethylene-co-hexafluoropropylene) /." St. Lucia, Qld, 2001. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe16518.pdf.

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Hasan, N. M. "Effects of ionizing radiation on biomolecules." Thesis, University of Salford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234702.

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Astill, David Timothy. "Synthesis and radiation stability of silicone elastomers." Thesis, Sheffield Hallam University, 1985. http://shura.shu.ac.uk/19292/.

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A wide range of polymer samples based upon polydimethylsiloxane (PDMS) have been subject to gamma irradiation, and the subsequent effects analysed using a variety of techniques. The preparation of a series of blends and block copolymers of PDMS containing small amounts of polystyrene (PS) is described, and their characterisation by spectroscopic and thermal analytical methods is discussed. A PD11S gum gave a G(X) value of 2.8 which is in good agreement with other reported values. Thermal analysis revealed a shift of 20°C. in the glass transition temperature, and disappearance of the exotherm band, upon onset of gelation. Within the sol component of a cross-linked sample, a complex range of reactions are evident which are related to the absorbed dose. It was found with PS-PDMS blends, upon absorption of low doses of radiation, that the amount of gel produced is very much lower than that observed with PDMS. A substantial degree of radiation protection was observed with a 3% W/w PS blend, which required a gelation dose of almost five times that of homopolymer PDMS. A selected number of block copolymers were irradiated and the gelation dose was again found to be far greater than would be expected of PDMS of similar relative molecular mass. Morphological studies allowed calculation of the size of the PS average domain size which increased with % w/w PS in the blend or copolymer. It is proposed that the radiation protection observed with polymers containing PS is related to the PS average domain size. The large surface area/volume ratio found with a 3% w/w PS blend would facilitate a considerable degree of miscibility of PS with PDMS, thereby decreasing the susceptibility of PDMS to cross-link formation.
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Books on the topic "Chemistry, Radiation"

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K, Pikaev A., ed. Applied radiation chemistry: Radiation processing. New York: Wiley, 1994.

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Sharpatyĭ, V. A. Radiation chemistry of biopolymers. Leiden, The Netherlands: VSP, 2006.

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Wishart, James F., and Daniel G. Nocera, eds. Photochemistry and Radiation Chemistry. Washington, DC: American Chemical Society, 1998. http://dx.doi.org/10.1021/ba-1998-0254.

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Fundamentals of radiation chemistry. San Diego: Academic Press, 1999.

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1928-, Woods R. J., ed. An introduction to radiation chemistry. 3rd ed. New York: Wiley, 1990.

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Bednář, Jaroslav. Theoretical foundations of radiation chemistry. Dordrecht: Reidel Pub. Co., 1990.

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Woods, R. J. Applied radiation chemistry: Readiation processing. New York: J. Wiley, 1994.

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Mandelkow, E. Synchrotron radiation in chemistry and biology. Berlin: Springer-Verlag, 1988.

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Okamura, S., ed. Recent Trends in Radiation Polymer Chemistry. Berlin, Heidelberg: Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/bfb0018045.

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Braun, Tibor. Nuclear and Radiation Chemical Approaches to Fullerene Science. Dordrecht: Springer Netherlands, 2000.

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Book chapters on the topic "Chemistry, Radiation"

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Wojnárovits, L. "Radiation Chemistry." In Handbook of Nuclear Chemistry, 1263–331. Boston, MA: Springer US, 2011. http://dx.doi.org/10.1007/978-1-4419-0720-2_23.

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ATTREP, MOSES. "Radiation Detection Principles." In Radioanalytical Chemistry, 7–38. New York, NY: Springer New York, 2006. http://dx.doi.org/10.1007/0-387-34123-4_2.

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Griffin, H. C. "Radiation Detection." In Handbook of Nuclear Chemistry, 2259–86. Boston, MA: Springer US, 2011. http://dx.doi.org/10.1007/978-1-4419-0720-2_48.

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Cadet, J., M. Bardet, T. Delatour, T. Douki, D. Gasparutto, D. Molko, J. P. Pouget, J. L. Ravanat, N. Signorini, and S. Sauvaigo. "Radiation Chemistry of DNA." In Fundamentals for the Assessment of Risks from Environmental Radiation, 91–102. Dordrecht: Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4585-5_13.

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Salmon, G. Arthur. "Development of Radiation Chemistry." In Polymers for High Technology, 5–15. Washington, DC: American Chemical Society, 1987. http://dx.doi.org/10.1021/bk-1987-0346.ch001.

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O'Donnell, James H. "Radiation Chemistry of Polymers." In ACS Symposium Series, 1–13. Washington, DC: American Chemical Society, 1989. http://dx.doi.org/10.1021/bk-1989-0381.ch001.

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Agarwal, Amit. "Introduction to Radiation Chemistry." In Simulation Studies of Recombination Kinetics and Spin Dynamics in Radiation Chemistry, 1–21. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-06272-3_1.

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Wishart, James F. "Ionic Liquid Radiation Chemistry." In Ionic Liquids Further UnCOILed, 259–74. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118839706.ch10.

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Maeda, Y., S. Osaki, and A. Vincze. "Environmental Radiation Protection." In Handbook of Nuclear Chemistry, 2503–64. Boston, MA: Springer US, 2011. http://dx.doi.org/10.1007/978-1-4419-0720-2_55.

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Kiefer, Jürgen. "Elements of Photo- and Radiation Chemistry." In Biological Radiation Effects, 88–103. Berlin, Heidelberg: Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-83769-2_5.

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Conference papers on the topic "Chemistry, Radiation"

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Dujardin, G. "High energy chemistry of condensed species." In Synchrotron radiation and dynamic phenomena. AIP, 1992. http://dx.doi.org/10.1063/1.42529.

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Ma, Jonathan H., Han Wang, David Prendergast, Andrew R. Neureuther, and Patrick Naulleau. "Investigating EUV radiation chemistry with first principle quantum chemistry calculations." In International Conference on Extreme Ultraviolet Lithography 2019, edited by Kurt G. Ronse, Paolo A. Gargini, Patrick P. Naulleau, and Toshiro Itani. SPIE, 2019. http://dx.doi.org/10.1117/12.2538558.

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Rogers, J. H. "A Novel Spectrometer System For Hard X-Ray Interfacial Environmental Chemistry." In SYNCHROTRON RADIATION INSTRUMENTATION: Eighth International Conference on Synchrotron Radiation Instrumentation. AIP, 2004. http://dx.doi.org/10.1063/1.1757961.

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Negrón-Mendoza, A., and S. Ramos-Bernal. "Gamma irradiation of isocitric and citric acid in aqueous solution: Relevance in prebiotic chemistry." In RADIATION PHYSICS: XI International Symposium on Radiation Physics. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4927189.

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Park, Chul. "Nonequilibrium Chemistry and Radiation for Neptune Entry." In 10th AIAA/ASME Joint Thermophysics and Heat Transfer Conference. Reston, Virigina: American Institute of Aeronautics and Astronautics, 2010. http://dx.doi.org/10.2514/6.2010-4520.

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null. "Radcure chemistry. The basic processes and their resulting properties." In IEE Colloquium on Radiation Cured Industrial Processes - an Update. IEE, 1996. http://dx.doi.org/10.1049/ic:19961053.

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Mehta, Ranjan S., Michael F. Modest, and Daniel C. Haworth. "Radiation Characteristics and Turbulence-Radiation Interactions in Sooting Turbulent Jet Flames." In ASME 2009 Heat Transfer Summer Conference collocated with the InterPACK09 and 3rd Energy Sustainability Conferences. ASMEDC, 2009. http://dx.doi.org/10.1115/ht2009-88078.

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The transported PDF method coupled with a detailed gas-phase chemistry, soot model and radiative transfer equation solver is applied to various turbulent jet flames with Reynolds numbers varying from ∼ 6700 to 15100. Two ethylene–air flames and four flames with a blend of methane–ethylene and enhanced oxygen concentration are simulated. A Lagrangian particle Monte Carlo method is used to solve the transported joint probability density function (PDF) equations, as it can accommodate the high dimensionality of the problem with relative ease. Detailed kinetics are used to accurately model the gas-phase chemistry coupled with a detailed soot model. Radiation is calculated using a particle-based photon Monte Carlo method, which is coupled with the PDF method and the soot model to accurately account for both emission and absorption turbulence–radiation interactions (TRI), using line-by-line databases for radiative properties of CO2 and H2O; soot radiative properties are also modeled as nongray. Turbulence–radiation interactions can have a strong effect on the net radiative heat loss from sooting flames. For a given temperature, species and soot distribution, TRI increases emission from the flames by 30–60%. Absorption also increases, but primarily due to the increase in emission. The net heat loss from the flame increases by 45–90% when accounting for TRI. This ixs much higher than the corresponding increase due to TRI in nonsooting flames. Absorption TRI was found to be negligible in the laboratory scale sooting flames with soot levels on the order of a few ppm, but may be important in larger industrial scale flames.
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Shingledecker, Christopher, Eric Herbst, Romane Le Gal, and Jessica Tennis. "COSMIC RAY-DRIVEN RADIATION CHEMISTRY IN COLD INTERSTELLAR ENVIRONMENTS." In 73rd International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2018. http://dx.doi.org/10.15278/isms.2018.wl04.

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Saji, Genn. "Scientific Bases of Water Chemistry for Corrosion Control of NPPs by Integration of Radiation- and Electro-Chemistry." In 2013 21st International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/icone21-16525.

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In this paper, the author continues his investigation on the scientific basis of water chemistry specifications by applying his recent theory, which integrates the elemental radiation- and electro-chemistry reactions in the “Butlar-Volmer equation.” The B-V equation is well established as the basic material balance equation in corrosion science. The author’s new approach has been compared with the published in-pile test results of the electrochemical potential differences between the in-flux and out-flux regions for both the PWR- and BWR water chemistry environment. Although the theoretical estimation generally reproduced the experimental results, there remains significant deviation from the experimental results at the very low DH region (<10cc-STP/kg-water) in PWRs as well as the low DO region (<10ppb) in BWRs. Although these regions are outside of the water chemistry specifications of general interest, the scientific causes of the deviation must be clarified. In this paper, the author found that the deviations are due to the dominant radiation-chemical reactions involving hydrogen ions and hydrogen peroxide at the lower ends. Although the radiation- and electrochemical reaction was further exploited with respect to the potential differences induced by the hydrogen peroxide, the effects were disappointingly small, when estimated in terms of a mixed potential of the electrode reactions. This leads the author to suspect that hydrogen-ion-radical reactions should be the main causes. Currently further analyses are in progress.
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Barnhart, T. E., J. W. Engle, H. F. Valdovinos, G. W. Severin, and R. J. Nickles. "Prompt radiation detectors to monitor target conditions." In 14TH INTERNATIONAL WORKSHOP ON TARGETRY AND TARGET CHEMISTRY. AIP, 2012. http://dx.doi.org/10.1063/1.4773935.

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Reports on the topic "Chemistry, Radiation"

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Mincher, Bruce J., and Christopher A. Zarzana. Radiation Chemistry of Diethylhexylbutyramide (DEHBA). Office of Scientific and Technical Information (OSTI), September 2017. http://dx.doi.org/10.2172/1468755.

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Meisel, D., H. Diamond, E. P. Horwitz, C. D. Jonah, M. S. Matheson, M. C. Jr Sauer, and J. C. Sullivan. Radiation chemistry of synthetic waste. Office of Scientific and Technical Information (OSTI), November 1991. http://dx.doi.org/10.2172/5952489.

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Meisel, D., H. Diamond, E. P. Horwitz, C. D. Jonah, M. S. Matheson, M. C. Jr Sauer, and J. C. Sullivan. Radiation chemistry of synthetic waste. Office of Scientific and Technical Information (OSTI), November 1991. http://dx.doi.org/10.2172/10114257.

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Mincher, Bruce, Dean Peterman, Rocklan Mcdowell, Lonnie Olson, and Gregg J. Lumetta. Radiation Chemistry of Advanced TALSPEAK Flowsheet. Office of Scientific and Technical Information (OSTI), August 2013. http://dx.doi.org/10.2172/1105100.

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Mincher, Bruce J., Andreas Wilden, and Stephen P. Mezyk. Radiation Chemistry of the Hydrophilic DGAs. Office of Scientific and Technical Information (OSTI), September 2017. http://dx.doi.org/10.2172/1468541.

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Bruce J. Mincher, Leigh R. Martin, and Stephen P. Mezyk. Radiation chemistry in solvent extraction: FY2010 Research. Office of Scientific and Technical Information (OSTI), September 2010. http://dx.doi.org/10.2172/993163.

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Mincher, Bruce Jay, and Christopher Andrew Zarzana. Hydrolysis and Radiation Chemistry of the DGAs. Office of Scientific and Technical Information (OSTI), September 2016. http://dx.doi.org/10.2172/1406975.

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Wise, Jonathan. Chemistry of radiation damage to wire chambers. Office of Scientific and Technical Information (OSTI), August 1992. http://dx.doi.org/10.2172/10183880.

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Bruce J. Mincher, Stephen P. Mezyk, and Leigh R. Martin. Radiation chemistry in solvent etxraction: FY2011 research. Office of Scientific and Technical Information (OSTI), September 2011. http://dx.doi.org/10.2172/1042355.

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Wise, J. Chemistry of radiation damage to wire chambers. Office of Scientific and Technical Information (OSTI), August 1992. http://dx.doi.org/10.2172/7035484.

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