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Journal articles on the topic 'Chlor-alkali'

Author: Grafiati

Published: 4 June 2021

Last updated: 7 February 2022

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1

Zhang, Lu-Nan, Zhong-Ling Lang, Yong-Hui Wang, et al. "Cable-like Ru/WNO@C nanowires for simultaneous high-efficiency hydrogen evolution and low-energy consumption chlor-alkali electrolysis." Energy & Environmental Science 12, no. 8 (2019): 2569–80. http://dx.doi.org/10.1039/c9ee01647c.

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2

Li, Kai, Qun Fan, Hongyuan Chuai, Hai Liu, Sheng Zhang, and Xinbin Ma. "Revisiting Chlor-Alkali Electrolyzers: from Materials to Devices." Transactions of Tianjin University 27, no. 3 (2021): 202–16. http://dx.doi.org/10.1007/s12209-021-00285-9.

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AbstractAs an energy-intensive industry, the chlor-alkali process has caused numerous environmental issues due to heavy electricity consumption and pollution. Chlor-alkali industry has been upgraded from mercury, diaphragm electrolytic cell, to ion exchange membrane (IEM) electrolytic cells. However, several challenges, such as the selectivity of the anodic reaction, sluggish kinetics of alkaline hydrogen evolution, degradation of membranes, the reasonable design of electrolytic cell structure, remain to be addressed. For these reasons, this paper mainly reviews the research progress of the ch

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3

Yeager, Howard L. "Modern chlor-alkali technology." Journal of Membrane Science 51, no. 1-2 (1990): 227–28. http://dx.doi.org/10.1016/s0376-7388(00)80905-9.

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4

Pletcher, D. "Modern chlor-alkali technology." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 210, no. 2 (1986): 337–38. http://dx.doi.org/10.1016/0022-0728(86)80589-7.

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5

Keating, James T. "Modern Chlor-Alkali Technology." Journal of Membrane Science 115, no. 1 (1996): 109–10. http://dx.doi.org/10.1016/0376-7388(96)00020-8.

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6

Pletcher, D. "Modern chlor alkali technology." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 282, no. 1-2 (1990): 296–97. http://dx.doi.org/10.1016/0022-0728(91)85108-2.

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7

Harris, N. C. "Modern chlor-alkali technology." Chemical Engineering Journal 37, no. 1 (1988): 61–62. http://dx.doi.org/10.1016/0300-9467(88)80008-x.

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8

Fantozzi, Laura, Nicoletta Guerrieri, Giovanni Manca, Arianna Orrù, and Laura Marziali. "An Integrated Investigation of Atmospheric Gaseous Elemental Mercury Transport and Dispersion Around a Chlor-Alkali Plant in the Ossola Valley (Italian Central Alps)." Toxics 9, no. 7 (2021): 172. http://dx.doi.org/10.3390/toxics9070172.

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We present the first assessment of atmospheric pollution by mercury (Hg) in an industrialized area located in the Ossola Valley (Italian Central Alps), in close proximity to the Toce River. The study area suffers from a level of Hg contamination due to a Hg cell chlor-alkali plant operating from 1915 to the end of 2017. We measured gaseous elemental Hg (GEM) levels by means of a portable Hg analyzer during car surveys between autumn 2018 and summer 2020. Moreover, we assessed the long-term dispersion pattern of atmospheric Hg by analyzing the total Hg concentration in samples of lichens collec

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9

AINSWORTH, SUSAN J. "MARKET STEADIES FOR CHLOR-ALKALI." Chemical & Engineering News 75, no. 1 (1997): 12–13. http://dx.doi.org/10.1021/cen-v075n001.p012.

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10

MORSE, PAIGE MARIE. "GOOD TIMES FOR CHLOR-ALKALI." Chemical & Engineering News 75, no. 42 (1997): 19–21. http://dx.doi.org/10.1021/cen-v075n042.p019.

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11

Jaccaud, M., F. Leroux, and J. C. Millet. "New chlor-alkali activated cathodes." Materials Chemistry and Physics 22, no. 1-2 (1989): 105–19. http://dx.doi.org/10.1016/0254-0584(89)90033-3.

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12

Saksono, Nelson, Fakhrian Abqari, and Setijo Bismo. "Aplikasi teknologi elektrolisis plasma pada proses produksi Klor-Alkali." Jurnal Teknik Kimia Indonesia 11, no. 3 (2018): 141. http://dx.doi.org/10.5614/jtki.2012.11.3.3.

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Plasma electrolysis technology applications in Chlor-Alkali process productionChlor-alkali industry sector is one of the important industrial sectorsin chemical industry. However, the chlor-alkali industry is one of the industry sectors that consume the most electrical energy due to the production using the methodof electrolysis. Plasma electrolysis is an electrolysis process with high voltage so that produce the glow discharge plasma in electrolyte solution. This method can be applied in the production of chlor-alkali and can reduce energy consumption several times. This research is aimed to

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13

Khasawneh, Hussam, Motasem N. Saidan, and Mohammad Al-Addous. "Utilization of hydrogen as clean energy resource in chlor-alkali process." Energy Exploration & Exploitation 37, no. 3 (2019): 1053–72. http://dx.doi.org/10.1177/0144598719839767.

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Hydrogen produced from chlor-alkali plants in Jordan is typically wasted and vented to the atmosphere. If it is recovered and utilized then it can viably play a significant role for process heat on site. This study demonstrates how cleaner production can be applied to the chlor-alkali industry, with focus on utilization of hydrogen as energy resource. A chlor-alkali based on membrane cell process, in northern part of Jordan, was examined as a case of reusing excess hydrogen produced. In the baseline scenario, 47% of produced hydrogen was used in HCl production, 10% in controlling pressure diff

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14

Franco, Filipa, Jorge Prior, Svetlozar Velizarov, and Adélio Mendes. "A Systematic Performance History Analysis of a Chlor-Alkali Membrane Electrolyser under Industrial Operating Conditions." Applied Sciences 9, no. 2 (2019): 284. http://dx.doi.org/10.3390/app9020284.

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The history of the potential and electrical current evolution of an industrial chlor-alkali membrane electrolyser is a powerful tool to track its operational efficiency progress over time and for deciding the required maintenance instants. For this reason, the performance of a dedicated industrial NaCl electrolyser was systematically analysed as a function of its service time for about 8 years, recording the cell potential versus current density. The documented potential values were normalized taking into account the initial current density, which allowed to reduce data scattering due to small

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15

Besson, Jean-Claude, Estelle Augarde, and Michael Nasterlack. "Worker Protection During Mercury Electrolysis Cell Plant Decommissioning." Archives of Industrial Hygiene and Toxicology 63, no. 2 (2012): 117–22. http://dx.doi.org/10.2478/10004-1254-63-2012-2200.

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Worker Protection During Mercury Electrolysis Cell Plant DecommissioningThis article brings information on how to protect worker health during the decommissioning of mercury-based electrolysis facilities. It relies on the Euro Chlor document "Health 2, Code of practice, Control of worker exposure to mercury in the chlor-alkali industry" that provides protection guidelines for both normal production and decommissioning activities, and on hands-on experience gained during chlor-alkali plant decommissioning operations.Decommissioning and dismantling of mercury-containing chlorine production plant

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16

Zhu, Lei, Zhi Yong Guo, Xiu Yi Hua, De Ming Dong, Da Peng Liang, and Ying Ying Sun. "Ammonia Nitrogen Removal from Chlor-Alkali Chemical Industry Wastewater by Magnesium Ammonium Phosphate Precipitation Method." Advanced Materials Research 573-574 (October 2012): 1096–100. http://dx.doi.org/10.4028/www.scientific.net/amr.573-574.1096.

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This study introduces a method of ammonia nitrogen removal from chlor-alkali industry wastewater by magnesium ammonium phosphate (MAP) precipitation. The effect of pH, reagent ratio and temperature were investigated. The pH was found to be the most significant factor. The optimal ammonia nitrogen removal ratio is about 46% under the condition of pH=10, reagent ratio n(Mg) : n(N) : n(P)=1.2 : 1.0 : 1.0 and temperature=35°C. According to this study, MAP precipitation method has the potential ability to be applied to remove ammonia nitrogen from chlor-alkali chemical industry wastewater.

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17

Nevin, M. N. "Modern Chlor-alkali Technology, Vol. 3." Chemical Engineering Science 42, no. 5 (1987): 1275. http://dx.doi.org/10.1016/0009-2509(87)80092-1.

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18

THAYER, ANN. "Chlor-alkali industry focuses on transition." Chemical & Engineering News 68, no. 41 (1990): 18–19. http://dx.doi.org/10.1021/cen-v068n041.p018.

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19

Scott, K. "Modern Chlor Alkali Technology — Volume 4." Electrochimica Acta 36, no. 8 (1991): 1383. http://dx.doi.org/10.1016/0013-4686(91)80021-y.

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20

Goodridge, F. "Modern chlor-alkali technology, volume 3." Electrochimica Acta 32, no. 2 (1987): 361. http://dx.doi.org/10.1016/0013-4686(87)85052-1.

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21

Dranguet, P., C. Cosio, S. Le Faucheur, et al. "Biofilm composition in the Olt River (Romania) reservoirs impacted by a chlor-alkali production plant." Environmental Science: Processes & Impacts 19, no. 5 (2017): 687–95. http://dx.doi.org/10.1039/c7em00033b.

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22

Wang, Lixia, Limin Sun, Yang Cao, and Jing Shen. "Corrosion behavior of Ti/Al laminate composites as electrode of chlor-alkali electrolysis." Advanced Composites Letters 29 (January 1, 2020): 2633366X2092088. http://dx.doi.org/10.1177/2633366x20920888.

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High-performance electrodes can solve problems of high voltage and large electricity consumption existing in chlor-alkali industry. A Ti/Al laminate composite (named as Ti/Al-LC) with three-layered structure (Ti/Al3Ti/Ti) is prepared as a new type of anode electrode for chlor-alkali electrolysis. Scanning electron microscope observation shows that the Ti/Al-LC is composited of a thicker inner layer with thickness about 700 µm and two thinner outer layers with thickness about 300 µm. From the X-ray diffraction pattern, it is known that the outer layers consisted of α-Ti and β-Ti phases, while t

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23

Kovalyuk, Elena. "EFFECTIVE TECHNOLOGIES OF EXTRACTION AND THE BRINE PURIFICATION FOR MEMBRANE ELECTROLYSIS." Bulletin of the Angarsk State Technical University 1, no. 12 (2018): 66–68. http://dx.doi.org/10.36629/2686-777x-2018-1-12-66-68.

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24

James, Olusola O., Waldemar Sauter, and Uwe Schröder. "Towards selective electrochemical conversion of glycerol to 1,3-propanediol." RSC Advances 8, no. 20 (2018): 10818–27. http://dx.doi.org/10.1039/c8ra00711j.

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25

Sánchez-Sánchez, C. M., E. Expósito, A. Frías-Ferrer, J. González-García, V. Montiel, and A. Aldaz. "Chlor–Alkali Industry: A Laboratory Scale Approach." Journal of Chemical Education 81, no. 5 (2004): 698. http://dx.doi.org/10.1021/ed081p698.

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26

Jain, Rakeshkumar M., Kalpana H. Mody, Jitendra Keshri, and Bhavanath Jha. "Biological neutralization of chlor-alkali industry wastewater." Marine Pollution Bulletin 62, no. 11 (2011): 2377–83. http://dx.doi.org/10.1016/j.marpolbul.2011.08.034.

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27

Shabad, Theodore, and Matthew J. Sagers. "THE CHLOR-ALKALI INDUSTRIES IN THE USSR." Soviet Geography 28, no. 6 (1987): 434–55. http://dx.doi.org/10.1080/00385417.1987.10640694.

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28

Park, In Kee, and Chang Hyun Lee. "Chlor-alkali Membrane Process and its Prospects." Membrane Journal 25, no. 3 (2015): 203–15. http://dx.doi.org/10.14579/membrane_journal.2015.25.3.203.

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29

Dötzel, O., and L. Schneider. "Non-asbestos Diaphragms in Chlor-Alkali Electrolysis." Chemical Engineering & Technology 25, no. 2 (2002): 167. http://dx.doi.org/10.1002/1521-4125(200202)25:2<167::aid-ceat167>3.0.co;2-0.

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30

Köppen, A., M. J. Huter, M. Koj, U. Kunz, and T. Turek. "Kohlenstoffbasierte Sauerstoffverzehrkathoden für die Chlor-Alkali-Elektrolyse." Chemie Ingenieur Technik 86, no. 9 (2014): 1448. http://dx.doi.org/10.1002/cite.201450439.

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31

Brooks, Robyn. "Chlor-alkali Production, Safety, and Industry Leadership." Electrochemical Society Interface 26, no. 2 (2017): 77–81. http://dx.doi.org/10.1149/2.f08172if.

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32

Hachiya, Toshinori, Takeaki Sasaki, Kazuyuki Tsuchida, and Hiroyoshi Houda. "Ruthenium Oxide Cathodes for Chlor-Alkali Electrolysis." ECS Transactions 16, no. 39 (2019): 31–39. http://dx.doi.org/10.1149/1.3104645.

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33

Lakshmanan, Shyam, and Thanapalan Murugesan. "The chlor-alkali process: Work in Progress." Clean Technologies and Environmental Policy 16, no. 2 (2013): 225–34. http://dx.doi.org/10.1007/s10098-013-0630-6.

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34

Sue, H. J., J. W. Wilchester, C. H. Wang, and D. L. Caldwell. "Fatigue fracture behavior of chlor-alkali membranes." Journal of Polymer Research 1, no. 2 (1994): 205–9. http://dx.doi.org/10.1007/bf01374096.

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35

Gianadda, P., C. J. Brouckaert, R. Sayer, and C. A. Buckley. "The application of pinch analysis to water, reagent and effluent management in a chlor-alkali facility." Water Science and Technology 46, no. 9 (2002): 21–28. http://dx.doi.org/10.2166/wst.2002.0196.

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South African industry is coming under increasing pressure to reduce the amount of freshwater it uses and the amount of effluent it produces. Water pinch is a cleaner production technique aimed at reducing the freshwater consumption and effluent production within a chemical complex. The design of water-reuse or water pinch networks as applied to the case study of a chlor-alkali complex is considered. Insights are provided into the analysis and formulation of problems for large-scale industrial systems and the application of present techniques and tools to the formulated problem is illustrated.

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36

Liu, Jia, Wei Xia, Weijun Mu, Peizhou Li, Yanli Zhao, and Ruqiang Zou. "New challenge of metal–organic frameworks for high-efficient separation of hydrogen chloride toward clean hydrogen energy." Journal of Materials Chemistry A 3, no. 10 (2015): 5275–79. http://dx.doi.org/10.1039/c4ta06832g.

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Eleven metal–organic frameworks are used for H<sub>2</sub>/HCl separation by real breakthrough experiment and molecular dynamic simulations, affording clean hydrogen energy resource with purity >99.997% from chlor-alkali industry exhaust.

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37

Zhu, Bei, Jianhua Jiang, Tianyu Zhu, Haoming Yang, Yong Jin, and Minfeng Lü. "Synthesis, crystal structures, and magnetic properties of one-dimensional alkali metal copper chlor-tellurites A(NH4)Cu4Te2O6Cl6 (A = K, Cs), NaCu4Te2Cl5O6 and Rb3(NH4)2Cu12Te6Cl16.5O18(OH)0.5." Dalton Transactions 49, no. 28 (2020): 9751–61. http://dx.doi.org/10.1039/d0dt00037j.

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Four alkali metal copper chlor-tellurites formed by S-shaped <sub>∞</sub>[Cu<sub>2</sub>O<sub>3</sub>Cl<sub>3−x</sub>] chains were reproduced by using an alternating antiferromagnetic chain model with a spin gap.

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38

Lakshmanan, Shyam, and Thanapalan Murugesan. "Adsorption performance of coconut shell activated carbon for the removal of chlorate from chlor-alkali brine stream." Water Science and Technology 74, no. 12 (2016): 2819–31. http://dx.doi.org/10.2166/wst.2016.455.

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Activated carbon from coconut shell was used to investigate the adsorption of chlorate from a chlor-alkali plant's brine stream. The effect of pH, flowrate, chlorate and chloride concentration on the breakthrough curves were studied in small-scale column trials. The results obtained show enhanced adsorption at low flowrates, higher chlorate concentrations, and at a pH of 10. These studies show that introducing an activated carbon adsorption column just before the saturator would remove sufficient quantities of chlorate to allow more of the chlor-alkali plant's brine stream to be reused. From c

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39

Liu, Yanxia, Lin Zhao, Yagang Zhang, Letao Zhang, and Xingjie Zan. "Progress and Challenges of Mercury-Free Catalysis for Acetylene Hydrochlorination." Catalysts 10, no. 10 (2020): 1218. http://dx.doi.org/10.3390/catal10101218.

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Activated carbon-supported HgCl2 catalyst has been used widely in acetylene hydrochlorination in the chlor-alkali chemical industry. However, HgCl2 is an extremely toxic pollutant. It is not only harmful to human health but also pollutes the environment. Therefore, the design and synthesis of mercury-free and environmentally benign catalysts with high activity has become an urgent need for vinyl chloride monomer (VCM) production. This review summarizes research progress on the design and development of mercury-free catalysts for acetylene hydrochlorination. Three types of catalysts for acetyle

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40

Lakshmanan, Shyam, and Thanabalan Murugesan. "Chlorate adsorption from chlor-alkali plant brine stream." Water Science and Technology 76, no. 1 (2017): 87–94. http://dx.doi.org/10.2166/wst.2017.182.

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Chlorates are present in the brine stream purged from chlor-alkali plants. Tests were conducted using activated carbon from coconut shell, coal or palm kernel shell to adsorb chlorate. The results show varying levels of adsorption with reduction ranging between 1.3 g/L and 1.8 g/L. This was higher than the chlorate generation rate of that plant, recorded at 1.22 g/L, indicating that chlorate can be adequately removed by adsorption using activated carbon. Coconut based activated carbon exhibited the best adsorption of chlorate of the three types of activated carbon tested. Introducing an adsorp

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41

Tonini, David R., Debra A. Gauvin, Robert W. Soffel, and W. Peter Freeman. "Achieving low mercury concentrations in chlor-alkali wastewaters." Environmental Progress 22, no. 3 (2003): 167–73. http://dx.doi.org/10.1002/ep.670220314.

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42

Gonzalez, Humberto. "Mercury pollution caused by a chlor-alkali plant." Water Air & Soil Pollution 56, no. 1 (1991): 83–93. http://dx.doi.org/10.1007/bf00342263.

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43

Chandran, R. R., and D. T. Chin. "Reactor analysis of a chlor—alkali membrane cell." Electrochimica Acta 31, no. 1 (1986): 39–50. http://dx.doi.org/10.1016/0013-4686(86)80058-5.

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44

Baetens, Jens, Jeroen D. M. De Kooning, Greet Van Eetvelde, and Lieven Vandevelde. "A Two-Stage Stochastic Optimisation Methodology for the Operation of a Chlor-Alkali Electrolyser under Variable DAM and FCR Market Prices." Energies 13, no. 21 (2020): 5675. http://dx.doi.org/10.3390/en13215675.

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The increased penetration of renewable energy sources in the electrical grid raises the need for more power system flexibility. One of the high potential groups to provide such flexibility is the industry. Incentives to do so are provided by variable pricing and remuneration of supplied ancillary services. The operational flexibility of a chlor-alkali electrolysis process shows opportunities in the current energy and ancillary services markets. A co-optimisation of operating the chlor-alkali process under an hourly variable priced electricity sourcing strategy and the delivery of Frequency Con

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45

Moreno-Hernandez, Ivan A., Bruce S. Brunschwig, and Nathan S. Lewis. "Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction." Energy & Environmental Science 12, no. 4 (2019): 1241–48. http://dx.doi.org/10.1039/c8ee03676d.

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Crystalline transition-metal antimonates (TMAs) such as NiSb<sub>2</sub>O<sub>x</sub>, CoSb<sub>2</sub>O<sub>x</sub>, and MnSb<sub>2</sub>O<sub>x</sub> are moderately active, stable catalysts for the electrochemical oxidation of chloride to chlorine under conditions relevant to the commercial chlor-alkali process.

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46

Ming-Yong, WANG, XING Hai-Qing, WANG Zhi, and GUO Zhan-Cheng. "Investigation of Chlor-Alkali Electrolysis Intensified by Super Gravity." Acta Physico-Chimica Sinica 24, no. 03 (2008): 520–26. http://dx.doi.org/10.3866/pku.whxb20080330.

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47

AINSWORTH, SUSAN J. "Vulcan Chemicals Builds Specialties Portfolio Around Chlor-Alkali Core." Chemical & Engineering News 72, no. 36 (1994): 12–14. http://dx.doi.org/10.1021/cen-v072n036.p012.

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48

GREEK, BRUCE F. "Chlor-Alkali Capacity Use Hits Record High for Decade." Chemical & Engineering News 65, no. 44 (1987): 13–14. http://dx.doi.org/10.1021/cen-v065n044.p013.

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49

Wängberg, Ingvar, Hans Edner, Romano Ferrara, et al. "Atmospheric mercury near a chlor-alkali plant in Sweden." Science of The Total Environment 304, no. 1-3 (2003): 29–41. http://dx.doi.org/10.1016/s0048-9697(02)00554-5.

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50

JOHNSON, JEFF. "Olin to end Hg releases from chlor-alkali plants." Chemical & Engineering News 77, no. 17 (1999): 8. http://dx.doi.org/10.1021/cen-v077n017.p008.

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