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Journal articles on the topic 'Chlorochromate'

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1

Fun, Hoong-Kun, Jia Hao Goh, Arnab Kar, and Shyamaprosad Goswami. "Guanidinium chlorochromate." Acta Crystallographica Section E Structure Reports Online 66, no. 2 (2010): m203. http://dx.doi.org/10.1107/s1600536810002710.

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2

Moon, Dohyun, and Jong-Ha Choi. "Crystal structure of 1,4,8,11-tetramethyl-1,4,8,11-tetraazoniacyclotetradecane bis[chloridochromate(VI)] dichloride from synchrotron X-ray data." Acta Crystallographica Section E Crystallographic Communications 76, no. 4 (2020): 523–26. http://dx.doi.org/10.1107/s2056989020003059.

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The crystal structure of title compound, (C14H36N4)[CrO3Cl]2Cl2, has been determined by synchrotron radiation X-ray crystallography at 220 K. The macrocyclic cation lies across a crystallographic inversion center and hence the asymmetric unit contains one half of the organic cation, one chlorochromate anion and one chloride anion. Both the Cl− anion and chlorochromate Cl atom are involved in hydrogen bonding. In the crystal, hydrogen bonds involving the 1,4,8,11-tetramethyl-1,4,8,11-tetraazoniacyclotetradecane (TMC) N—H groups and C—H groups as donor groups and three O atoms of the chlorochrom
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3

Mohammadpoor-Baltork, Iraj, Hamid R. Memarian, and Kiumars Bahrami. "3-Carboxypyridinium chlorochromate – aluminium chloride — An efficient and inexpensive reagent system for the selective oxidation of sulfides to sulfoxides and sulfones in solution and under microwave irradiation." Canadian Journal of Chemistry 83, no. 2 (2005): 115–21. http://dx.doi.org/10.1139/v05-008.

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3-Carboxypyridinium chlorochromate (CPCC) in the presence of aluminium chloride is a very efficient reagent for the selective oxidation of sulfides to sulfoxide and sulfones in solution and under microwave irradiation. It is noteworthy that different functional groups including carbon–carbon double bonds, ketones, oximes, aldehydes, ethers, and acetals were tolerated under these reaction conditions.Key words: sulfoxides, sulfones, oxidation, chlorochromate, Lewis acid.
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4

Carlsen, Per H. J., and Kari Aasb⊘. "Oxidation with Magnesium Chlorochromate." Synthetic Communications 24, no. 1 (1994): 89–94. http://dx.doi.org/10.1080/00397919408012630.

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5

Jain, Sapana, B. L. Hiran, and C. V. Bhatt. "Oxidation of Some Aliphatic Alcohols by Pyridinium Chlorochromate -Kinetics and Mechanism." E-Journal of Chemistry 6, no. 1 (2009): 237–46. http://dx.doi.org/10.1155/2009/907071.

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Kinetics of oxidation of some aliphatic primary and secondary alcoholsviz.,ethanol, propan-1-ol, propan-2-ol, butan-1-ol, butan-2-ol and 2-methyl butanol by pyridinium chlorochromate (PCC) have been studied in water- perchloric acid medium. The reaction shows first order dependence with respect to pyridinium chlorochromate [PCC] and hydrogen ion [H+]. The rate of oxidation decreases with increase in dielectric constant of solvent suggests ion-dipole interaction. Activation parameters have been evaluated. Products are carbonyl compounds and free radical absence was proved. A tentative mechanism
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6

Tamami, Bahman, Roghaye Heiran, and Riazi Montazer. "Modified polyacrylamide supported chlorochromate as a new polymeric oxidizing agent." Journal of the Serbian Chemical Society 77, no. 5 (2012): 685–97. http://dx.doi.org/10.2298/jsc110131216t.

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Modified polyacrylamide supported chlorochromate was synthesized and used as a versatile and efficient oxidizing agent for the oxidation of various organic compounds such as hydroxyl compounds, silylethers, oximes, thiols, and other compounds. Over oxidation of the products (aldehydes to carboxylic acids) was not observed with this oxidizing agent. The oxidant was insoluble in oxidation media and chromium (VI) ions remained firmly bound to the insoluble polymeric support after the oxidation reaction. The mild reaction condition, easy work-up, short reaction times, regenerability of the reagent
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7

Mohammadpoor-Baltork, Iraj, Majid M. M. Sadeghi, Hamid Reza Memarian, and Raihaneh Pairow. "3-Carboxypyridinium Chlorochromate (CPCC): An Inexpensive and Convenient Reagent for Efficient Oxidation of Hantzsch 1,4-dihydropyridines." Journal of Chemical Research 2000, no. 1 (2000): 40–41. http://dx.doi.org/10.3184/030823400103165626.

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8

Viana, Hugo, Elisabete P. Carreiro, Albertino Goth, et al. "Sequential alcohol oxidation/putative homo Claisen–Tishchenko-type reaction to give esters: a key process in accessing novel biologically active lactone macrocycles." RSC Advances 6, no. 68 (2016): 63214–23. http://dx.doi.org/10.1039/c6ra07547a.

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9

Pressprich, M. R., R. D. Willett, W. W. Paudler, and G. L. Gard. "Crystal structure of pyrazinium chlorochromate." Inorganic Chemistry 29, no. 15 (1990): 2872–73. http://dx.doi.org/10.1021/ic00340a031.

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10

Kolitsch, Uwe. "Redetermination of potassium chlorochromate, KCrO3Cl." Acta Crystallographica Section E Structure Reports Online 58, no. 11 (2002): i105—i107. http://dx.doi.org/10.1107/s1600536802019396.

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11

Kotlyar, Sergei A., Roman I. Zubatyuk, Oleg V. Shishkin, Gennady N. Chuprin, Andrey V. Kiriyak, and Gerbert L. Kamalov. "(18-Crown-6)potassium chlorochromate." Acta Crystallographica Section E Structure Reports Online 61, no. 2 (2005): m293—m295. http://dx.doi.org/10.1107/s1600536805000085.

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12

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "Microwave-assisted Oxidation of Alcohols by Pyridinium Chlorochromate." Journal of Chemical Research 23, no. 2 (1999): 118–19. http://dx.doi.org/10.1177/174751989902300226.

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13

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "Deoximation by Pyridinium Chlorochromate under Microwave Irradiation." Journal of Chemical Research 23, no. 2 (1999): 120–21. http://dx.doi.org/10.1177/174751989902300227.

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14

Chimatadar, S. A., S. T. Guddalli, and S. T. Nandibewoor. "oxidation of Palladium(Ii) by Chromium(Vi) in Aqueous Ethanoic Acid and Chloride Media: A Kinetic and Mechanistic Study." Journal of Chemical Research 2003, no. 4 (2003): 186–87. http://dx.doi.org/10.3184/030823403103173679.

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15

Tajbakhsh, Mahmood, Rahman Hosseinzadeh, and Mohammad Yazdani Niaki. "Synthesis and Application of 2,6-Dicarboxypyridinium Chlorochromate as a new Oxidising Reagent for Alcohols, Silyl Ethers, and THP ethers under Mild and Non-Aqueous Conditions." Journal of Chemical Research 2002, no. 10 (2002): 508–10. http://dx.doi.org/10.3184/030823402103170556.

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16

H., N. Sheikh, Sharma Madhu, and L. Kalsotra B. "Kinetics and mechanism of oxidation of alcohols by piperidinium chlorochromate." Journal of Indian Chemical Society Vol. 82, Oct 2005 (2005): 913–16. https://doi.org/10.5281/zenodo.5827046.

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Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu-180 006, India <em>E-mail </em>: hnsheikh@rediffmail.com <em>Manuscript received 19 May 2005, accepted 14 July 2005</em> Piperidinium chlorochromate is an efficient oxidizing agent for oxidation of primary alcohols to aldehydes. Kinetics of oxidation of alcohols to the corresponding carbonyl compounds have been studied in aqueous-acetic acid medium in presence of perchloric acid. The reaction shows first order kinetics each in [PipCC] and [H<sup>+</sup>]. Michaelis-Menten type kinetics have been observed with respect
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17

Li, Ji-Tai, and Xian-Tao Meng. "Deoximation of Ketoximes to Ketones with Ammonium Chlorochromate/Montmorillonite K10 in Dichloromethane." E-Journal of Chemistry 6, no. 1 (2009): 156–60. http://dx.doi.org/10.1155/2009/258328.

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A convenient, mild and efficient method for oxidative cleavage of ketoximes to their parent carbonyl compounds with ammonium chlorochromate (ACC) / montmorillonite K10 in dichloromethane at room temperature is described
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18

Heravi, Majid M., and Maryam M. Aghayan. "Microwave-Assisted Oxidation of Alcohols Using Wet Alumina Supported Ammonium Chlorochromate in Solventless System." Zeitschrift für Naturforschung B 54, no. 6 (1999): 815–17. http://dx.doi.org/10.1515/znb-1999-0618.

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A simple and selective method for the oxidation of alcohols to carbonyl compounds is described that occurs on wet alumina supported ammonium chlorochromate under microwave irradiation in solventless system
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19

M. Venkatapathy, A. M. Shanmugesh, and K. Anbarasu. "KINETICS AND MECHANISTIC PERSPECTIVES FOR THE OXIDATION OF PHENOXYACETIC ACID AND ITS SUBSTITUTIONS BY 3, 5 - DIMETHYL PYRAZOLIUM CHLOROCHROMATE." RASAYAN Journal of Chemistry 17, no. 04 (2024): 1663–69. http://dx.doi.org/10.31788/rjc.2024.1748999.

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The oxidation of phenoxyacetic acid, along with certain para- and meta-substituted phenoxyacetic acid derivatives, which reacts with 3,5-dimethyl pyrazolium chlorochromate within a 50% (v/v) aqueous acetic acid solution at 308 K. The observed reaction exhibits a unit order with respect to both the 3,5-dimethyl pyrazolium chlorochromate and the substrates involved. This phenomenon demonstrates fractional-order kinetics in the case of perchloric acid and oxalic acid. The computation of ∆H# , ∆S# , ∆G# , and Ea values from Eying’s equation, according to the results of the experiment. In all the c
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20

Pandey, Jitendra. "An Analytical Studies of Pyridinium Chlorochromate Oxidation Species." Journal of Advances and Scholarly Researches in Allied Education 21, no. 7 (2024): 59–62. https://doi.org/10.29070/2z06tk04.

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A study has been analyzed the “Pyridinium Chlorochromate Oxidation Species.” The method was analysed on reaction initial reaction of pyridinium chlorochromate. Further, This reaction has a mostly [cysteine] dependent effect. So, the plot study has been taken from 1/k` VS 1/[cysteine] It is a straight line with a positive slope and intersected at the valence axis, providing kinetic evidence for the complexation of cysteine ​​with reactive species. And the Chromium (III), It was determined that one of the products had no effect on the vaccine. As [H+] increases, the reaction increases and the [H
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21

Ammilal, Rao, Kumar Ganesh, and Singh Neha. "EDAS and TOPSIS based Estimation of Oxidation of Methionine by Cr(VI) Reagents." Indian Journal of Science and Technology 14, no. 43 (2021): 3190–98. https://doi.org/10.17485/IJST/v14i43.1508.

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<strong>Objectives:</strong>&nbsp;To find the suitable solvent for the oxidation of methionine by Cr(VI) reagents using EDAS and TOPSIS method.&nbsp;<strong>Methods:</strong>&nbsp;When methionine oxidized by Cr(VI) complexes i.e. tetrakis(pyridine)silver dichromate (TPSD), quinolinium bromochromate (QBC), tetraethylammonium chlorochromate (TEACC) and quonilinium chlorochromate (QCC) formation of corresponding sulfoxide take place. Reaction performed in chloroform (CF), 1,2- dichloroethane (DCE), dichloromethane (DCM), dimethylsulphoxide (DMSO) and acetone solvents.<strong>&nbsp;Findings:</stro
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22

R, GURUMURTHY, MANGALAM G, RAJASEKAR V., and SATHIYANARAYANAN K. "Kinetics and Mechanism of Oxidation of Aromatic Anil by Pyridinium Chlorochromate." Journal of Indian Chemical Society Vol. 72, Jun 1995 (1995): 417–19. https://doi.org/10.5281/zenodo.5905011.

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Department of Chemistry, Annamalai University, Annamalamagar-608 002 <em>Manuscript received 24 August 1993, revised 13 December 1993, accepted 31 December 1993</em> Kinetics and Mechanism of Oxidation of Aromatic Anil by Pyridinium Chlorochromate
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23

Carlsen, Per H. J., Jon Erik Brænden, Yngve Stenstrøm, Arne Jørgen Aasen, and G. W. Fischer. "Oxidation of Alcohols with Potassium Chlorochromate." Acta Chemica Scandinavica 41b (1987): 313–17. http://dx.doi.org/10.3891/acta.chem.scand.41b-0313.

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24

Palaniappan, S., and C. A. Amarnath. "Pyridinium chlorochromate oxidation route to polyaniline." Polymers for Advanced Technologies 14, no. 2 (2003): 122–28. http://dx.doi.org/10.1002/pat.339.

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25

CARLSEN, P. H. J., and K. AASBOE. "ChemInform Abstract: Oxidation with Magnesium Chlorochromate." ChemInform 25, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199444075.

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26

Singh, Kamaljit, and Kawaljit Singh. "An Efficacious Protocol for the Oxidation of 3,4-Dihydropyrimidin-2(1H)-ones using Pyridinium Chlorochromate as Catalyst." Australian Journal of Chemistry 61, no. 11 (2008): 910. http://dx.doi.org/10.1071/ch07432.

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4-Unsubstituted as well as 4,6-aryl/alkyl-3,4-dihydropyrimidin-2(1H)-ones were oxidized under neutral conditions using pyridinium chlorochromate to obtain the corresponding pyrimidin-2(1H)-ones in a synthetically useful manner.
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27

A., PANDURANGAN, and MURUGESAN V. "Kinetics and Mechanism of Oxidation of Benzyl Alcohol by Tetraethylammonium Chlorochromate : A New Chromium(VI) Oxidant." Journal of Indian Chemical Society Vol. 73, Sep 1996 (1996): 484–86. https://doi.org/10.5281/zenodo.5910388.

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Department of Chemistry, Anna University, Madras-600 025 <em>Manuscript received 7 April 1994, revised 19 October 1994, accepted 18 January 1995</em> Kinetics and Mechanism of Oxidation of Benzyl Alcohol by Tetraethylammonium Chlorochromate: A New Chromium(VI) Oxidant.
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28

Periyasamy, Seplapatty Kalimuthu, H. Satham Hussain, and R. Manikandan. "Reactivity of Phenol and Aniline towards Quinolinium Chloro Chromate: A Comparative Oxidation Kinetic Study." International Letters of Chemistry, Physics and Astronomy 59 (September 2015): 81–92. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.59.81.

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The kinetics of Oxidation of Phenol and aniline by quinolinium Chlorochromate (QCC) in aqueous acetic acid medium leads to the formation of quinone and azobenzene respectively. The reactions are first order with respect to both Phenol and aniline. The reaction is first order with respect to quinolinium chlorochromate (QCC) and is catalyzed by hydrogen ion. The hydrogen-ion dependence has the form: kobs = a+b [H+]. The rate of oxidation decreases with increasing dielectric constant of solvent, indicating the presence of an ion-dipole interaction. The reaction does not induced the polymerization
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29

Periyasamy, Seplapatty Kalimuthu, H. Satham Hussain, and R. Manikandan. "Reactivity of Phenol and Aniline towards Quinolinium Chloro Chromate: A Comparative Oxidation Kinetic Study." International Letters of Chemistry, Physics and Astronomy 59 (September 14, 2015): 81–92. http://dx.doi.org/10.56431/p-31e826.

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The kinetics of Oxidation of Phenol and aniline by quinolinium Chlorochromate (QCC) in aqueous acetic acid medium leads to the formation of quinone and azobenzene respectively. The reactions are first order with respect to both Phenol and aniline. The reaction is first order with respect to quinolinium chlorochromate (QCC) and is catalyzed by hydrogen ion. The hydrogen-ion dependence has the form: kobs = a+b [H+]. The rate of oxidation decreases with increasing dielectric constant of solvent, indicating the presence of an ion-dipole interaction. The reaction does not induced the polymerization
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30

Arora, Bhawana, and Pallavi Mishra. "Comparative Study of Solvent Effect for Mandelic acid Oxidation by Different Oxidants." Oriental Journal Of Chemistry 39, no. 2 (2023): 511–15. http://dx.doi.org/10.13005/ojc/390234.

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The mandelic acid oxidation has been carried out by benzimidazolium fluorochromate (BIFC), morpholinium fluorochromate (MFC), benzimidazolium dichromate (BIDC), morpholinium chlorochromate (MCC) and tetraethylammonium chlorochromate (TEACC) using different solvents as dimethyl sulphoxide (DMSO), dimethyl formamide (DMF), chloroform (CF), acetone, dichloromethane (DCM) and 1,2-dichloroethane (DCE) at 308K, which results in the corresponding oxoacids formation. By using the TOPSIS method, we analysed the solvent effect and found the order by the solvent’s performance score for the reaction as DM
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31

R, GURUMURTHY, and KARUNAKARAN K. "A Comparative Study on the Kinetics of Oxidation of some Organic Sulphides by Quinolium Chlorochromate and Hexacyanoferrate(III)." Journal of Indian Chemical Society Vol. 72, May 1995 (1995): 349–51. https://doi.org/10.5281/zenodo.5904945.

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Department of Chemistry, Annamalai University, Annamalai Nagar-608 002 <em>Manusript received 23 September 1993, revised 6 December 1993, accepted 10 December 1993</em> A Comparative Study on the Kinetics of Oxidation of some Organic Sulphides by Quinolium Chlorochromate and Hexacyanoferrate(III)
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32

Hajipour, Abdol R., and Arnold E. Ruoho. "Oxidation of Thiols to the Corresponding Disulfides with Tetramethylammonium Chlorochromate under Non-Aqueous Conditions." Journal of Chemical Research 2002, no. 11 (2002): 547–49. http://dx.doi.org/10.3184/030823402103170718.

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This paper describes the preparation of tetramethylammonium chlorochromate (TMACC) as an efficient and mild reagent for oxidation in refluxing acetonitrile of a variety of aromatic and aliphatic thiols, giving the corresponding disulfides; the experimental procedure is simple, and the products are easily isolated in excellent yields.
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33

Kotlyar, Sergei A., Roman I. Zubatyuk, Oleg V. Shishkin, Gennady N. Chuprin, Andrey V. Kiriyak, and Gerbert L. Kamalov. "([1.5]Dibenzo-18-crown-6)potassium chlorochromate." Acta Crystallographica Section E Structure Reports Online 61, no. 10 (2005): m2163—m2165. http://dx.doi.org/10.1107/s1600536805030151.

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34

Kotlyar, S. A., R. I. Zubatyuk, O. V. Shishkin, A. V. Kiriyak, S. M. Pluzhnik-Gladyr, and G. L. Kamalov. "(Benzo-18-crown-6)potassium chlorochromate(VI)." Acta Crystallographica Section E Structure Reports Online 62, no. 8 (2006): m1790—m1792. http://dx.doi.org/10.1107/s1600536806025360.

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35

Parish, Edward J., Sarawanee Chitrakorn, and Tsao-Yi Wei. "Pyridinium Chlorochromate-Mediated Allylic and Benzylic Oxidation." Synthetic Communications 16, no. 11 (1986): 1371–75. http://dx.doi.org/10.1080/00397918608056385.

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36

Hosseinzadeh, Rahman, Mahmood Tajbakhsh, and Hossein Vahedi. "Selective Oxidation of Methylarenes with Pyridinium Chlorochromate." Synlett, no. 18 (2005): 2769–70. http://dx.doi.org/10.1055/s-2005-917118.

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37

Kotlyar, Sergei A., Svetlana V. Shishkina, Oleg V. Shishkin, et al. "(4-Bromobenzo-18-crown-6)potassium chlorochromate." Acta Crystallographica Section E Structure Reports Online 62, no. 1 (2005): m120—m122. http://dx.doi.org/10.1107/s1600536805039796.

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38

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "Deoximation by Pyridinium Chlorochromate under Microwave Irradiation." Journal of Chemical Research, no. 2 (1999): 120–21. http://dx.doi.org/10.1039/a803979h.

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39

Mahieu, B., J. Ladriere, J. Cambier, D. Apers, and P. Capron. "La Décomposition Thermique du Chlorochromate de Potassium." Bulletin des Sociétés Chimiques Belges 81, no. 1 (2010): 343–49. http://dx.doi.org/10.1002/bscb.19720810130.

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40

Şendıl, Kıvılcım, H. Beytiye Özgün, and Ebru Üstün. "Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation." Journal of Chemistry 2016 (2016): 1–7. http://dx.doi.org/10.1155/2016/3518102.

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Two new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3and related acid. These reagents are suitable to oxidize various primary and secondary alcohols and oximes to the corresponding carbonyl compounds under solvent-free conditions and microwave irradiation.
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41

Qianchao, Pi Shiqing, and Chen Xinzhi. "Improved Synthesis of Methyl 3-oxo-2,6,6-trimethylcyclohex-1-ene-1-carboxylate, an A-ring intermediate for (±)strigol." Journal of Chemical Research 2007, no. 8 (2007): 494–96. http://dx.doi.org/10.3184/030823407x240881.

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Methyl 3-oxo-2,6,6-trimethylcyclohex-1-ene-1-carboxylate was synthesised over eight steps from the starting material of citral instead of α-ionone. KMnO4, HC(OEt)3 and O2/TEMPO/CuCl were substituted for NaIO4, CH3I and pyridinium chlorochromate, respectively. Every step was simplified and gave a 48% overall yield. The procedure is suitable for large scale production.
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42

Kotlyar, Sergey A., Roman I. Zubatyuk, Oleg V. Shishkin, Gennady N. Chuprin, Andrey V. Kiriyak, and Gerbert L. Kamalov. "Bis(cis-cyclohexano-12-crown-4)potassium chlorochromate." Acta Crystallographica Section E Structure Reports Online 60, no. 7 (2004): m907—m909. http://dx.doi.org/10.1107/s1600536804012966.

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43

Kotlyar, Sergey A., Roman I. Zubatyuk, Oleg V. Shishkin, Gennady N. Chuprin, Andrey V. Kiriyak, and Gerbert L. Kamalov. "(cis-Cyclohexano-18-crown-6)potassium chlorochromate(VI)." Acta Crystallographica Section E Structure Reports Online 60, no. 7 (2004): m1015—m1016. http://dx.doi.org/10.1107/s1600536804015132.

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44

Bonadies, Francesco, and Carlo Bonini. "Oxidation of Active Methylene Compounds by Pyridinium Chlorochromate." Synthetic Communications 18, no. 13 (1988): 1573–80. http://dx.doi.org/10.1080/00397918808081315.

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45

Singh, J. V., and Ashish Tomar. "Oxidation Kinetics of L-Arabinose with Quinolinium Chlorochromate." Asian Journal of Chemistry 30, no. 5 (2018): 1027–30. http://dx.doi.org/10.14233/ajchem.2018.21134.

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46

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "Microwave-assisted Oxidation of Alcohols by Pyridinium Chlorochromate." Journal of Chemical Research, no. 2 (1999): 118–19. http://dx.doi.org/10.1039/a803978j.

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47

SRINIVASAN, R., C. V. RAMESH, W. MADHULATHA, and K. BALASUBRAMANIAN. "ChemInform Abstract: Oxidation of Alcohols by Quinolinium Chlorochromate." ChemInform 27, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199631059.

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48

AGRAWAL, G. L., and S. TIWARI. "ChemInform Abstract: Pyridinium Chlorochromate: Kinetic and Synthetic Aspects." ChemInform 23, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199240305.

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49

Akhtar, Mohammed Shamim, Manju Seth, and Amiya Prasad Bhaduri. "Novel oxidation of tetrasubstituted furans by pyridinium chlorochromate." Journal of Heterocyclic Chemistry 22, no. 5 (1985): 1323–24. http://dx.doi.org/10.1002/jhet.5570220535.

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50

Senapati, Sadhana, Smrutiprava Das, P. Mohanty, and A. Patnaik. "Kinetics and mechanism of electron transfer to pyridinium chlorochromate (VI) from sulfur containing amino acid, L-cysteine in aqueous and micellar media." Polish Journal of Chemical Technology 13, no. 2 (2011): 6–10. http://dx.doi.org/10.2478/v10026-011-0016-7.

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Abstract:
Kinetics and mechanism of electron transfer to pyridinium chlorochromate (VI) from sulfur containing amino acid, L-cysteine in aqueous and micellar media The electron transfer reaction of L-cysteine (RSH) with pyridinium chlorochromate (PCC) has been studied spectrophotometrically over the range 2.0 ≤ 103 [RSH] ≤ 6.0; 0.01 ≤ [H+] ≤ 0.2; 298 ≤ T ≤ 318 K and I = 0.3 mol dm-3 (NaClO4). The electron transfer reaction has also been carried out in the presence of anionic, cationic and neutral micelle. The reaction in acid medium is strongly catalyzed by changing [SDS]T (sodium dodecyl sulfate) up to
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