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Journal articles on the topic 'Chloropyridine complex'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Saberov, Vagiz, Alexander Avksentiev, Gennady Rayenko, et al. "CATALYSIS OF HYDRODEHALOGENATION REACTION OF HALOARENES BY CARBENE PEPPSI-PALLADIUM COMPLEXES." Ukrainian Chemistry Journal 88, no. 1 (2022): 67–81. http://dx.doi.org/10.33609/2708-129x.88.01.2022.67-81.

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The synthesis of a number of carbene PEPPSI-complexes of palladium with various pyridine and carbene ligands was carried out by reactions of 1,3-bis-(2,6-dibenzhydryl-4-methylphenyl)imidazolium chloride IPr*.HCl [compounds 7a-c IPr*PdCl2L’, L’ = pyridine (а), 3-chloropyridine (b), 4-dimethylaminopyridine (с)], 1,3-bis-(2,6-diisopropylphenyl)imidazolium perchlorate IPr.HClO4 [compounds 8a,b IPr.PdCl2L’, L’ = 3-chloropyridine (а), о-phenanthroline (b)], 1,3-diphenyl-4-(2,6-diisopropylphenyl)-1,2,4-triazolium perchlorate L.HClO4 (complex 9 LPdCl2L’, L’ = 3-chloropyridine) and 1,3-dicetylimi

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2

Shukla, Satyendra N., Pratiksha Gaur, Ripul Mehrotra, and Radhey S. Srivastava. "Experiences during Synthesis of a Dinucleating Spacer Incorporating 2-Chloropyridine Units Through Sandmayer Reaction." E-Journal of Chemistry 9, no. 2 (2012): 593–97. http://dx.doi.org/10.1155/2012/646397.

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A bimetallic cuprous complex was accidentally reported, during synthesis of a dinucleating spacer incorporating two 2-chloropyridine units through Sandmayer reaction. The product was characterized by elemental analysis, FAB-Mass, FT-IR, UV, magnetic susceptibility and1H-NMR spectroscopic method. A possible mechanism is also proposed.

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3

Helle, Niklas, Tim Raeker, and Juergen Grotemeyer. "Investigation of the complex vibronic structure in the first excited and ionic ground states of 3-chloropyridine by means of REMPI and MATI spectroscopy and Franck–Condon analysis." Physical Chemistry Chemical Physics 23, no. 33 (2021): 17917–28. http://dx.doi.org/10.1039/d1cp02406j.

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3-Chloropyridine has been investigated by means of REMPI and MATI spectroscopy to elucidate the effect of m-chlorine substitution on the vibronic structure of the first electronically excited and ionic ground states.

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4

Czarnik-Matusewicz, B., and J. P. Hawranek. "Infrared dispersion of the hydrogen-bonded pentachlorophenol - 3-chloropyridine complex." Journal of Molecular Structure 219 (March 1990): 221–26. http://dx.doi.org/10.1016/0022-2860(90)80059-s.

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5

Ilkimen, Halil. "Synthesis and characterization of mixed ligand Cu(II) complexes of 2-methoxy-5-sulfamoylbenzoic acid and 2-aminopyridine derivatives." Macedonian Journal of Chemistry and Chemical Engineering 38, no. 1 (2019): 13. http://dx.doi.org/10.20450/mjcce.2019.1698.

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A novel Cu(II) complex 1 of 2-methoxy-5-sulfamoylbenzoic acid (Hsba) and eight novel mixed-ligand Cu(II) complexes 2–9 have been prepared using Hsba and 2-aminopyridine derivatives [2,3-diaminopyridine (2,3dap), 2,3-diamino-5-bromopyridine (2,3da5Brp), 2,3-diamino-5-chloropyridine (2,3da5Clp), 2-amino-3-benzyloxypyridine (2a3bxp), 2-amino-3-hydroxypyridine (2a3OHp), 2-amino-3-methylpiridine (2a3mp), 2-amino-3-methyl-6-ethylpiridine (2a3m6Etp) and 2-amino-3-nitro-6-methylpiridine (2a3NO26mp)], respectively. The structures of the amorphous metal complexes have been proposed by evaluating the dat

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6

Nbili, Wijdene, Kamel Kaabi, Valeria Ferretti, Frederic Lefebvre, and Cherif Ben Nasr. "Synthesis, structure and characterization of a new noncentrosymmetric Zn(II) complex with the 2-amino-5-chloropyridine ligand (AClPy)." JOURNAL OF ADVANCES IN CHEMISTRY 10, no. 9 (2014): 3116–26. http://dx.doi.org/10.24297/jac.v10i9.877.

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A new noncentrosymmetric Zn(II) complex with the monodentate ligand 2-amino-5-chloropyridine (AClPy), ZnCl2(C5H5ClN2)2, has been prepared at room temperature and characterized by single crystal X-ray diffraction, 13C CP-MAS-NMR and IR spectroscopies. The basic coordination pattern of the AClPy coordinated metal cations is slighly distorted tetrahedral. The crystal structure is characterized by ZnCl2N2 tetrahedra interconnected via N-H···Cl hydrogen bonds generated by the NH2 amino group to form chains extending along the (a-c) direction. The exocyclic N atom is an electron receiving center, wh

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7

Kurian, Thomas, and Rani Sebastian. "Molecular Docking Study of Heterocyclic Compounds for Antifungal Activity Against Granulomatous Amoebic Encephalitis." Journal of Pharmaceutical Research 23, no. 3 (2024): 174–77. http://dx.doi.org/10.18579/jopcr/v23.3.101.

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Our study identified seven unique heterocyclic compounds: 2-(m Tolylthio) Chalcone, chitosan oligosaccharide, and 2-hydroxy chalcone. Six-chloropyridine, 4-naphthoquinone, Thiobenzimidazole, 2-thiobenzoxazole, 6-carboxylic acid ethyl ester, and Anthrimide are probable choices that may be found in a chemical database. Posaconazole and Isuvuconazole are reference compounds found in a literature study. The isuvuconazole-bound complex of Acanthamoeba castellanii CYP51 of PDBID 6UX0 is the focus of our investigation. Docking simulations were carried out to evaluate these drugs' binding affinity to

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8

Sundaram, Ganeshraja Ayyakannu, Karthikeyan Vaithinathan, and Krishnamoorthy Anbalagan. "New monomeric mixed-ligand complex of iron(III)-3-chloropyridine: Synthesis, structure, luminescence, electrochemical and magnetic properties." Journal of Molecular Structure 1225 (February 2021): 129160. http://dx.doi.org/10.1016/j.molstruc.2020.129160.

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9

Gautam, Ramesh Kumar, Chandra Prakash Singh, Shiv Govind Prasad, Rajul Saxena, and Devendra Pratap Rao. "Synthesis and Antibacterial Activity of Novel Molybdenum Complexes with Macrocyclic Schiff Base Derived from Furanylethanedione." Asian Journal of Chemistry 31, no. 11 (2019): 2607–12. http://dx.doi.org/10.14233/ajchem.2019.22242.

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A new MoO2(VI) complex of formulation [MoO2(L)](acac)2 prepared by a Schiff base, synthesized via reaction of di-2-furanylethanedione with 5-chloropyridine-2,3-diamine and four new MoO2(VI) complexes having formule [MoO2(ML)](acac)2, derived from cyclization of [MoO2(L)](acac)2 with β-diketones are reported in this work. The synthesized MoO2(VI) complexes were characterized on the basis of various analyses like thermal studies, UV-Vis, elemental analyses, NMR, IR and molar conductance. The coordination number of molybdenum metal is six. All the MoO2(VI) complexes have distorted octahedral stru

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10

Kitazawa, T., Mi Takahashi, Ma Takahashi, et al. "57Fe Mössbauer spectroscopic and magnetic study of a spin-crossover polymer complex, Fe(3-chloropyridine)2Ni(CN)4." Journal of Radioanalytical and Nuclear Chemistry 239, no. 2 (1999): 285–90. http://dx.doi.org/10.1007/bf02349498.

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11

Bondarenko, M. A., A. S. Novikov, and S. A. Adonin. "Mononuclear Zn(II) 3,5-Diiodosalicylate Complex with 3-Chloropyridine: Synthesis and Features of Non-Covalent Interactions in the Solid State." Russian Journal of Inorganic Chemistry 66, no. 6 (2021): 814–19. http://dx.doi.org/10.1134/s0036023621060061.

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12

Gogoi, Pallavi, Uttam Mohan, Manash Protim Borpuzari, Abhijit Boruah, and Surjya Kumar Baruah. "UV-Visible spectroscopy and density functional study of solvent effect on halogen bonded charge-transfer complex of 2-Chloropyridine and iodine monochloride." Arabian Journal of Chemistry 12, no. 8 (2019): 4522–32. http://dx.doi.org/10.1016/j.arabjc.2016.07.011.

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13

Belay, Alebel Nibret, Johan Andries Venter, Orbett Teboho Alexander, and Andreas Roodt. "Synthesis, Single Crystal X-ray Structure, Spectroscopy and Substitution Behavior of Niobium(V) Complexes Activated by Chloranilate as Bidentate Ligand." Inorganics 10, no. 10 (2022): 166. http://dx.doi.org/10.3390/inorganics10100166.

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Chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone, caH2) as a bidentate ligand for Nb(V) as a metal center is presented. The different coordination behavior of caH2 is well illustrated by a monomeric (Et4N)cis-[NbO(ca)2(H2O)OPPh3]·3H2O.THF (5) and a novel tetranuclear compound (Et4N)4[Nb4O4(ca)2(μ2-O)2Cl8]·2CH3CN (6) via self-assembly, respectively. These were obtained in > 80% yields and characterized by IR, UV/Vis and NMR (1H, 13C{1H}, 31P{1H}) spectroscopy and single crystal X-ray diffraction, and they included a systematic assessment of the solid-state behavior. The anionic

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14

Chen, Yating, Shaonan Zhang, Yu Xiao, and Shuhua Zhang. "Synthesis, crystal structures and magnetic and electrochemiluminescence properties of three manganese(II) complexes." Acta Crystallographica Section C Structural Chemistry 76, no. 3 (2020): 236–43. http://dx.doi.org/10.1107/s2053229620001850.

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Three novel complexes, namely, penta-μ-acetato-bis(μ2-2-{[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)-μ-formato-tetramanganese(II), [Mn4(C13H11ClN3O2)2(C2H3O2)5.168(CHO2)0.832], 1, hexa-μ2-acetato-bis(μ2-2-{[2-(6-bromopyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)tetramanganese(II), [Mn4(C13H11BrN3O2)2(C2H3O2)6], 2, and catena-poly[[μ2-acetato-acetatoaqua(μ2-2-{[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)dimanganese(II)]-μ2-acetato], [Mn2(C13H11ClN3O2)(C2H3O2)3(H2O)] n , 3, have been synthesized using solvothermal methods. Complexes 1–3

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15

Gurovets, A. S., V. Z. Sharf, and L. I. Belen'kii. "Hydrodehalogenation of bromo- and chloropyridines over palladium complex and palladium metal catalysts." Chemistry of Heterocyclic Compounds 21, no. 9 (1985): 1023–25. http://dx.doi.org/10.1007/bf00515028.

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16

Loginova, S. Ya, V. N. Shсhukina, S. V. Savenko, et al. "Antiviral Activity of 5-chloropyridin-3-yl-1h-indole-4-carboxylate (AMND) Against COVID-19." Antibiot Khimioter = Antibiotics and Chemotherapy 69, no. 11-12 (2025): 49–58. https://doi.org/10.37489/0235-2990-2024-69-11-12-49-58.

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Introduction. The viral disease COVID-19 has caused a global emergency. The rapid and widespread spread of COVID-19 and the urgent need for etiotropic drugs have sparked interest in repositioning existing drugs. SARS-CoV proteases (Mpro) and papain protease (PLpro) have been identified as attractive targets for the development of antiviral agents.The aim of this work was to evaluate the antiviral eﬃcacy of indole chloropyridinyl ethers against the SARS-CoV-2 virus in vitro, as well as against the experimental form of COVID-19 in Syrian golden hamsters.Material and methods. The experiments were

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17

Mei, Yunjun, Shunxi Zhang, Chun Hu, Jian Zhang, and Ming Yang. "Synthesis, characterization, and crystal structures of 2-[(3-chloropyridin-2-yl)hydrazonemethyl]-6-ethoxyphenol and its iron(III) complex." Inorganic and Nano-Metal Chemistry 47, no. 8 (2017): 1266–69. http://dx.doi.org/10.1080/24701556.2017.1284116.

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18

Inada, Kaoru, and Norio Miyaura. "The Cross-Coupling Reaction of Arylboronic Acids with Chloropyridines and Electron-Deficient Chloroarenes Catalyzed by a Polymer-Bound Palladium Complex." Tetrahedron 56, no. 44 (2000): 8661–64. http://dx.doi.org/10.1016/s0040-4020(00)00815-2.

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19

Inada, Kaoru, and Norio Miyaura. "ChemInform Abstract: The Cross-Coupling Reaction of Arylboronic Acids with Chloropyridines and Electron-Deficient Chloroarenes Catalyzed by a Polymer-Bound Palladium Complex." ChemInform 32, no. 10 (2001): no. http://dx.doi.org/10.1002/chin.200110098.

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20

Tallarita, Roberto, Lukas Manuel Jacobsen, Benedict J. Elvers, et al. "Synthesis of Seven Indolizine-Derived Pentathiepines: Strong Electronic Structure Response to Nitro Substitution in Position C-9." Molecules 29, no. 1 (2023): 216. http://dx.doi.org/10.3390/molecules29010216.

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Seven new 1,2,3,4,5-pentathiepino[6,7-a]indolizines were synthesized in which the pentathiepine moieties bear an indolizine backbone that is derivatized from C–H to F-, Cl-, Br-, I-, NO2-, and CH3-substitutions, respectively, in a meta position relative to the aza group on the pyridine moiety. Their preparation took place via two common steps: (i) a Sonogashira coupling between (4-substituted) 2-bromo- or 2-chloropyridines and propynyl 3,3-diethylacetal, and (ii) a ring closing reaction mediated by a molybdenum oxo-bistetrasulfido complex and elemental sulfur. The latter simultaneously facilit

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21

Martin, Brandon S., Donghui Ma, Takeru Saito, Katelyn S. Gallagher, and Mingji Dai. "Concise Total Synthesis of Complanadine A Enabled by Pyrrole-to-Pyridine Molecular Editing." Synthesis, June 7, 2023. http://dx.doi.org/10.1055/a-2107-5159.

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Lycopodium alkaloid complanadine A, isolated by Kobayashi et al. in 2000, is a complex and unsymmetrical dimer of lycodine. Biologically, it is a novel and promising lead compound for the development of new treatment for neurodegenerative disorders and persistent pain management. Herein, we reported a concise synthesis of complanadine A using a pyrrole-to-pyridine molecular editing strategy. The use of a nucleophilic pyrrole as the precursor of the desired pyridine enabled an efficient and one-pot construction of the tetracyclic core skeleton of complanadine A and lycodine. The pyrrole group w

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22

Ghosh, Biswa Nath, Sourav Sutradhar, Dipankar Das, and Parnashabari Sarkar. "Synthesis, Structure, and Solution Behavior of Trimethylplatinum(Iv) Iodide Complex of 3-Chloropyridine." SSRN Electronic Journal, 2022. http://dx.doi.org/10.2139/ssrn.4230033.

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23

Mohammed, Amera F., and Jassim M. Alyass. "First Transition Metal Complexes Salts of Diazonium Derived from Nitrogen Heterocyclic Compound, Synthesis, Characterization and Biological Activity." Baghdad Science Journal, August 20, 2023. http://dx.doi.org/10.21123/bsj.2023.7872.

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Metal complexes chrome(III), manganese(II), iron(III), cobalt(II), nickel(II), cupper(II) and zinc(II) with diazonium of 3-amino-2-chloropyridine of general formula [2-Cl-C5H3N≡N]n[MXm], where n=2 or 3 for divalent and trivalent metal, m= 4 or 6 were synthesized. The complexes have been characterized by flame atomic absorption, (C.H.N), molar conductance, magnetic susceptibility UV-vis spectra, infrared spectra,1H-NMR spectroscopy and thermo gravimetric analysis (TGA and DTA). The measurements showed that the divalent metal ion complexes (M2+) have (1:2) M:L ratio with tetrahedral geometry aro

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24

Park, Sung Man, Hyojung Kim, and Chan Ho Kwon. "Impact of chlorine substitution on valence orbitals and ionization dynamics in 3-chloropyridine: Insights from high-resolution vacuum ultraviolet mass-analyzed threshold ionization study." Journal of Chemical Physics 161, no. 17 (2024). http://dx.doi.org/10.1063/5.0233300.

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In this study, the effects of chlorine substitution on the valence orbitals and electronic states of 3-chloropyridine (3-CP) were investigated utilizing high-resolution vacuum ultraviolet mass-analyzed threshold ionization (VUV-MATI) spectroscopy and computational methods. High-quality vibrational spectra were obtained from the VUV-MATI spectra of 3-CP isotopomers (35Cl and 37Cl), revealing high-quality vibrational spectra for the lowest cationic states. The adiabatic ionization energies (AIEs) of these isotopomers were accurately determined, providing detailed information about the electronic

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25

Sutradhar, Sourav, Dipankar Das, Parnashabari Sarkar, and Biswa Nath Ghosh. "Synthesis, structure, and solution behavior of trimethylplatinum(IV) iodide complexe of 3-chloropyridine." Polyhedron, November 2022, 116201. http://dx.doi.org/10.1016/j.poly.2022.116201.

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26

GUROVETS, A. S., V. Z. SHARF, and L. I. BELEN'KII. "ChemInform Abstract: Hydrodehalogenation of Bromo- and Chloropyridines on Complex and Metallic Palladium Catalysts." Chemischer Informationsdienst 17, no. 7 (1986). http://dx.doi.org/10.1002/chin.198607145.

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