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Journal articles on the topic 'Circular dichroism'

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1

Furusawa, Gaku, and Tetsuo Kan. "Au Nanospirals Transferred onto PDMS Film Exhibiting Circular Dichroism at Visible Wavelengths." Micromachines 11, no. 7 (2020): 641. http://dx.doi.org/10.3390/mi11070641.

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We propose a thin, single-layered circular dichroic filter with Au nanospiral structures on a polydimethylsiloxane (PDMS) thin film that has strong circular dichroism at visible wavelengths. Au nanospiral structures with a diameter of 70 nm were fabricated by cryogenic glancing angle deposition on a substrate with a nanodot array template patterned with the block copolymer PS-PDMS. The Au nanospiral structures were transferred onto a transparent and flexible PDMS thin film to fabricate a thin, single-layered circular dichroic filter. The filter had a very large circular dichroism peak of −830
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2

Rogalev, Andrei, Alexei Bosak, Fabrice Wilhelm, and Jose Goulon. "X-ray Natural Circular Dichroism." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1518. http://dx.doi.org/10.1107/s2053273314084812.

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Natural Circular Dichroism was only recently discovered in the x-ray range[1]. This effect stems from the interference terms which mix multipole transition moments of opposite parity: the Electric Dipole-Electric Quadrupole (E1.E2) and the Electric Dipole-Magnetic Dipole (E1.M1) exist only in structures with broken space inversion symmetry. The scalar E1.M1 term known to be responsible for Circular Dichroism at optical wavelengths is usually considered to be vanishingly small for core level spectroscopies. The E1.E2 interference term, on the contrary, can be large in the X-ray region, but it i
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3

Kuball, Hans-Georg. "Circular Dichroism and Linear Dichroism." Zeitschrift für Physikalische Chemie 212, Part_1 (1999): 118–19. http://dx.doi.org/10.1524/zpch.1999.212.part_1.118.

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4

Ishijima, Shizuo, Miwako Higashi, and Hiroyuki Yamaguchi. "Magnetic Circular Dichroism and Circular Dichroism Spectra of Xanthones." Journal of Physical Chemistry 98, no. 41 (1994): 10432–35. http://dx.doi.org/10.1021/j100092a008.

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5

K, Manish. "Pharmaceutical Applications of Circular Dichroism for Nanomaterial’s." Advances in Clinical Toxicology 4, no. 4 (2019): 1–5. http://dx.doi.org/10.23880/act-16000173.

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6

Stephens, P. J., and M. A. Lowe. "Vibrational Circular Dichroism." Annual Review of Physical Chemistry 36, no. 1 (1985): 213–41. http://dx.doi.org/10.1146/annurev.pc.36.100185.001241.

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7

Waldron, Daniel E., Rachel Marrington, Marcus C. Grant, Matthew R. Hicks, and Alison Rodger. "Capillary circular dichroism." Chirality 22, no. 1E (2010): E136—E141. http://dx.doi.org/10.1002/chir.20878.

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8

Magyarfalvi, Gábor, György Tarczay, and Elemér Vass. "Vibrational circular dichroism." Wiley Interdisciplinary Reviews: Computational Molecular Science 1, no. 3 (2011): 403–25. http://dx.doi.org/10.1002/wcms.39.

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9

Warnke, Ingolf, and Filipp Furche. "Circular dichroism: electronic." WIREs Computational Molecular Science 2, no. 1 (2011): 150–66. http://dx.doi.org/10.1002/wcms.55.

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10

Shindo, Yohji, and Masayuki Nakagawa. "Circular dichroism measurements. I. Calibration of a circular dichroism spectrometer." Review of Scientific Instruments 56, no. 1 (1985): 32–39. http://dx.doi.org/10.1063/1.1138467.

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11

Partini, Juliasih. "Efek Circular Dichroism pada Metamaterial Chiral Planar." Risalah Fisika 2, no. 2 (2018): 49–52. http://dx.doi.org/10.35895/rf.v2i2.113.

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Abstrak – Penelitian ini mengkaji efek circular dichroism pada metamaterial chiral planar. Bidang polarisasi akan terotasi ketika cahaya yang terpolarisasi linear melewati metamaterial chiral planar. Pada efek circular dichroism, cahaya yang terpolarisasi circular putaran kanan dan putaran kiri akan mempunyai perbedaan absorpsi dalam interaksinya dengan partikel penyusun metamaterial chiral planar. Spektrum eliptisitas metamaterial chiral planar menunjukkan eliptisitas bahan yang bernilai positif untuk sampel putar kanan dan bernilai negatif untuk sampel putar kiri. Nilai eliptisitas diperoleh
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12

Lees, J. G., and B. A. Wallace. "Synchrotron radiation circular dichroism and conventional circular dichroism spectroscopy: A comparison." Spectroscopy 16, no. 3-4 (2002): 121–25. http://dx.doi.org/10.1155/2002/280646.

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Conventional circular dichroism (cCD) spectroscopy is a valuable tool for secondary structure analyses of proteins. In recent years, it has been possible to use synchrotrons as light sources for CD, with the technique being known as Synchrotron Radiation Circular Dichroism (SRCD). In this study, the spectra of two proteins, the primarily helical myoglobin and the primarily beta‒sheet concanavalin A, have been collected on both a cCD instrument and on the SRCD at the Daresbury synchrotron and their characteristics were compared. Over the wavelength regions where both instruments are capable of
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13

Stephens, P. J., G. M. Jensen, F. J. Devlin, et al. "Circular dichroism and magnetic circular dichroism of Azotobacter vinelandii ferredoxin I." Biochemistry 30, no. 13 (1991): 3200–3209. http://dx.doi.org/10.1021/bi00227a007.

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14

Brown, Zachary, and Ronald Starkey. "Circular Birefringence and Circular Dichroism Simulation." Journal of Chemical Education 82, no. 7 (2005): 1100. http://dx.doi.org/10.1021/ed082p1100.2.

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15

Lehmann, Carl Stefan, and Karl-Michael Weitzel. "Coincident measurement of photo-ion circular dichroism and photo-electron circular dichroism." Physical Chemistry Chemical Physics 22, no. 24 (2020): 13707–12. http://dx.doi.org/10.1039/d0cp01376e.

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Photo-ion circular dichroism (PICD) and photo-electron circular dichroism (PECD) have been measured for the first time simultaneously in a coincidence experiment detecting the chirality of R- and S-Methyloxirane.
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16

Sharma, Vishakha, Yogita Kalra, and Ravindra Kumar Sinha. "Chiral perovskite based metasurface for linear and circular dichroism." Journal of Optics 26, no. 12 (2024): 125103. http://dx.doi.org/10.1088/2040-8986/ad80a7.

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Abstract Chiral metasurfaces provide ultracompact devices for polarization modification and detection. In this paper, high linear dichroism (LD) and dual band circular dichroism (CD) using superstructural chiral structure with inbuilt resonance cavities based on metal perovskite metal layer is proposed. Under circularly polarised incident waves, the metasurface exhibits a dual-band CD with a maximum value of 0.81. On the other hand, the suggested design also accomplishes efficient LD of 0.95. Additionally, independent control over each resonance wavelength may be attained by modifying paramete
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17

Polavarapu, Prasad L., and Gang-Chi Chen. "Polarization-Division Interferometry: Far-Infrared Dichroism." Applied Spectroscopy 48, no. 11 (1994): 1410–18. http://dx.doi.org/10.1366/0003702944028119.

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We report the first far-infrared dichroism measurements using a polarization-division interferometer (PDI) developed in our laboratory. This interferometer uses a free-standing wire-grid beamsplitter made of tungsten wires. In conjunction with a linear polarizer in front of the source and two roof-top mirrors (one in each arm of the interferometer), the PDI divides the input beam into two orthogonal linear polarization components, recombines them for interference at the beamsplitter, and directs the output beam at 90° to the direction of the input beam. Light exiting the interferometer is mani
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18

Polavarapu, Prasad L., Gang-Chi Chen, and Stephen Weibel. "Development, Justification, and Applications of a Mid-Infrared Polarization-Division Interferometer." Applied Spectroscopy 48, no. 10 (1994): 1224–35. http://dx.doi.org/10.1366/0003702944027381.

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We report the development of a polarization-division interferometer (PDI) for the mid-infrared region. This interferometer uses a self-designed beamsplitter constructed in-house from a BaF2 polarizer and a matching substrate. In conjunction with a linear polarizer in front of the source and two roof-top mirrors, one in each arm of the interferometer, the PDI divides the input beam into two orthogonal linear polarization components, recombines them for interference at the beamsplitter, and directs the output beam at 90° to the direction of the input beam. Light exiting the interferometer is man
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19

Vaara, Juha, Antonio Rizzo, Joanna Kauczor, Patrick Norman, and Sonia Coriani. "Nuclear spin circular dichroism." Journal of Chemical Physics 140, no. 13 (2014): 134103. http://dx.doi.org/10.1063/1.4869849.

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20

Yeston, J. "Perils in Circular Dichroism." Science 324, no. 5933 (2009): 1366. http://dx.doi.org/10.1126/science.324_1366c.

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21

Arteaga, Oriol, Zoubir El-Hachemi, and Razvigor Ossikovski. "Snapshot circular dichroism measurements." Optics Express 27, no. 5 (2019): 6746. http://dx.doi.org/10.1364/oe.27.006746.

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22

Marshall, Doug. "Optimizing Circular Dichroism Spectroscopy." Genetic Engineering & Biotechnology News 38, no. 10 (2018): 20–21. http://dx.doi.org/10.1089/gen.38.10.07.

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23

Polavarapu, P. L. "Rotational—vibrational circular dichroism." Chemical Physics Letters 161, no. 6 (1989): 485–90. http://dx.doi.org/10.1016/0009-2614(89)87025-3.

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24

BUCHECKER, R., and K. NOACK. "ChemInform Abstract: Circular Dichroism." ChemInform 26, no. 32 (2010): no. http://dx.doi.org/10.1002/chin.199532314.

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25

Ripperger, Helmut, Claus Lindig, and G�nther Snatzke. "Circular Dichroism of Cardenolides." Journal f�r Praktische Chemie/Chemiker-Zeitung 340, no. 5 (1998): 476–78. http://dx.doi.org/10.1002/prac.19983400512.

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26

Taniguchi, Tohru, and Kenji Monde. "Practical Use of Circular Dichroism and Vibrational Circular Dichroism for Structural Analysis." Journal of Synthetic Organic Chemistry, Japan 75, no. 5 (2017): 522–29. http://dx.doi.org/10.5059/yukigoseikyokaishi.75.522.

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27

Wallace, B. A., and Robert W. Janes. "Circular dichroism and synchrotron radiation circular dichroism spectroscopy: tools for drug discovery." Biochemical Society Transactions 31, no. 3 (2003): 631–33. http://dx.doi.org/10.1042/bst0310631.

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CD spectroscopy is an established and valuable technique for examining protein structure, dynamics and folding. Because of its ability to sensitively detect conformational changes, it has important potential for drug discovery, enabling screening for ligand and drug binding, and detection of potential candidates for new pharmaceuticals. The binding of the anti-tumour agent Taxol to the anti-apoptosis protein Bcl-2 [Rodi, Janes, Sanganee, Holton, Wallace and Makowski (1999) J. Mol. Biol. 285, 197–204] and the binding of the anti-epileptic drug lamotrigine to voltage-gated sodium channels [Croni
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28

WALLACE, B. A., and ROBERT W. JANES. "Circular dichroism and synchrotron radiation circular dichroism spectroscopy: tools for drug discovery." Biochemical Society Transactions 31, no. 6 (2003): 1531. http://dx.doi.org/10.1042/bst0311531.

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29

XU, JING, KEVIN W. PLAXCO, and S. JAMES ALLEN. "THz SPECTROSCOPY OF PROTEINS IN WATER: DIRECT ABSORPTION AND CIRCULAR DICHROISM." International Journal of High Speed Electronics and Systems 17, no. 04 (2007): 709–18. http://dx.doi.org/10.1142/s0129156407004916.

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Many of the functionally relevant collective vibrations of proteins and other biopolymers are expected to occur at terahertz frequencies. Precise absorption measurements combined with careful titration of biopolymers in water have allowed us to directly measure the terahertz absorption spectra associated with these motions, despite the strong background absorption of the solvent. We have also explored the circular dichroism spectroscopy of biomolecules over this same frequency range. Since circular dichroism requires the presence of net chirality in a molecule and chirality is present in nearl
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30

Safin, F. M., V. G. Maslov, A. Y. Dubavik, E. P. Kolesova, A. V. Baranov, and A. V. Fedorov. "Photochemically Induced Circular Dichroism of Semiconductor Nanocrystals-=SUP=-*-=/SUP=-." Журнал технической физики 128, no. 8 (2020): 1192. http://dx.doi.org/10.21883/os.2020.08.49723.1008-20.

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Here, we report an investigation of optical activity which was photochemically induced by illumination of QRs and DiRs with circularly polarized light; the photo-induced circular dichroism was quantitatively estimated, and it was shown that the photo-induced chemical reaction proceeds selectively, depending on the handedness of circularly polarized light. Keywords: chirality, optical activity, circular dichroism, photoinduced circular dichroism, semiconductor nanocrystals, quantum rods, quantum dot-in-rods.
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31

FECHER, G. H., J. BRAUN, A. OELSNER, CH OSTERTAG, and G. SCHÖNHENSE. "DICHROISM IN ANGLE-RESOLVED PHOTOEMISSION FROM Pt(111)." Surface Review and Letters 09, no. 02 (2002): 883–88. http://dx.doi.org/10.1142/s0218625x0200310x.

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The angular dependence of the circular dichroism in photoemission from Pt(111) was investigated for excitation with VUV and soft X-ray radiation. VUV excitation was used to probe band structure and the circular dichroism for valence band emission. The measurements are compared to full relativistic single step photoemission calculations. XPS was used to investigate the circular dichroism in emission from the 4f core level. In this case, the dichroism is induced by photoelectron diffraction. First results from single step core level calculations are compared to the experimental observations.
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32

Hong, Aram, Changseop Jeong, Heeseon Jang, Myoung Choul Choi, Jiyoung Heo, and Nam Joon Kim. "Fluorescence-detected circular dichroism spectroscopy of jet-cooled ephedrine." Physical Chemistry Chemical Physics 18, no. 11 (2016): 7762–67. http://dx.doi.org/10.1039/c5cp07438j.

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33

Cheng, Bo, Yuxiao Zou, and Guofeng Song. "Full Stokes Mid-Wavelength Infrared Polarization Photodetector Based on the Chiral Dielectric Metasurface." Photonics 11, no. 6 (2024): 571. http://dx.doi.org/10.3390/photonics11060571.

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Conventional imaging techniques can only record the intensity of light while polarization imaging can record the polarization of light, thus obtaining a higher dimension of image information. We use the COMSOL software to numerically propose a circular polarization photodetector composed of the dislocated 2-hole Si chiral metasurfaces controlling the circular polarization lights and the HgCdTe (MCT) photodetector chip to detect the intensity of light signals. The chiral metasurfaces can be equated to a significant radiation source of the Z-type current density under the right circularly polari
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34

Samoshkina, Yu E., and A. V. Chernichenko. "Magnetic Circular Dichroism of Oxide Films: Study of Electronic, Magnetic and Charge States." Devices and Methods of Measurements 15, no. 3 (2024): 240–47. http://dx.doi.org/10.21122/2220-9506-2024-15-3-240-247.

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Semiconductor materials based on ZnO and RE3+MnO3 oxides are considered as potential candidates for spintronics. This article presents the methodology and results of studying the effect of magnetic circular dichroism for Zn1-xCoxO, Zn1-x-yCoxAlyO and RE1-x 3+Ax 2+MnO3 film structures in the visible radiation range. It has been shown that the magnetic circular dichroism behavior of the manganite films reflects not only the magnetic, but also the charge component of the material. This indicates the possibility of studying the magnetic and transport characteristics of the films using the magnetic
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35

Cheng, Yang, Yongfeng Li, He Wang, Jiafu Wang, Zhe Qin, and Shaobo Qu. "Circular dichroism assisted bi-directional absorbers." Journal of Physics D: Applied Physics 55, no. 9 (2021): 095101. http://dx.doi.org/10.1088/1361-6463/ac3301.

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Abstract Chirality, a geometric property that is of great importance in chemistry, biology, and medicine, has spurred many breakthroughs in the field of multi-dimensional metasurfaces that provide efficient ways of flexibly manipulating amplitude and phase of circular polarization (CP) waves. As one of the most important applications, chiral metamaterials can be used to implement novel absorbers. Herein, an ultra-thin wideband circular dichroic asymmetric metasurface was implemented via loading resistive film into chiral resonators. Opposite and reversible polarization conversion and circular
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36

Olesiak-Banska, Joanna, Magdalena Waszkielewicz, and Marek Samoc. "Two-photon chiro-optical properties of gold Au25 nanoclusters." Physical Chemistry Chemical Physics 20, no. 38 (2018): 24523–26. http://dx.doi.org/10.1039/c8cp05256e.

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37

Garab, Győző, and Herbert van Amerongen. "Linear dichroism and circular dichroism in photosynthesis research." Photosynthesis Research 101, no. 2-3 (2009): 135–46. http://dx.doi.org/10.1007/s11120-009-9424-4.

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38

Abbate, Sergio, Giovanna Longhi, John W. Givens, Stefan E. Boiadjiev, David A. Lightner, and Albert Moscowitz. "Observation of Vibrational Circular Dichroism for Overtone Transitions with Commercially Available CD Spectrometers." Applied Spectroscopy 50, no. 5 (1996): 642–43. http://dx.doi.org/10.1366/0003702963905934.

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It is demonstrated that some commercially available circular dichroism spectrometers can be used to gather vibrational circular dichroism data associated with overtone transitions. By way of specific example, the circular dichroism spectra of neat S−(−)−limonene and R-(+)-limonene are measured in the region 800–600 nm. The observed spectral features correspond to the overtone bands Δ v = 5 and 6 for CH-stretching motions. A discussion of the data is also given.
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39

Prabodh, Amrutha, Yichuan Wang, Stephan Sinn, et al. "Fluorescence detected circular dichroism (FDCD) for supramolecular host–guest complexes." Chemical Science 12, no. 27 (2021): 9420–31. http://dx.doi.org/10.1039/d1sc01411k.

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Fluorescence-detected circular dichroism (FDCD) spectroscopy is applied for the first time to supramolecular host–guest and host–protein systems and compared to the more known electronic circular dichroism (ECD).
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40

Miles, Andrew J., Frank Wien, Jonathan G. Lees, A. Rodger, Robert W. Janes, and B. A. Wallace. "Calibration and Standardisation of Synchrotron Radiation Circular Dichroism and Conventional Circular Dichroism Spectrophotometers." Spectroscopy 17, no. 4 (2003): 653–61. http://dx.doi.org/10.1155/2003/379137.

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Synchrotron radiation circular dichroism (SRCD) is an emerging technique in structural biology with particular value in protein secondary structure analyses since it permits the collection of data down to much lower wavelengths than conventional circular dichroism (cCD) instruments. Reference database spectra collected on different SRCD instruments in the future as well as current reference datasets derived from cCD spectra must be compatible. Therefore there is a need for standardization of calibration methods to ensure quality control. In this study, magnitude and optical rotation measuremen
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41

Kawamura, Masahiro, and Miwako Higashi. "Induced Circular Dichroism and Magnetic Circular Dichroism Spectra of Maleimide and Related Molecules." Helvetica Chimica Acta 86, no. 7 (2003): 2342–48. http://dx.doi.org/10.1002/hlca.200390188.

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42

Daly, Steven, Frédéric Rosu, and Valérie Gabelica. "Mass-resolved electronic circular dichroism ion spectroscopy." Science 368, no. 6498 (2020): 1465–68. http://dx.doi.org/10.1126/science.abb1822.

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DNA and proteins are chiral: Their three-dimensional structures cannot be superimposed with their mirror images. Circular dichroism spectroscopy is widely used to characterize chiral compounds, but data interpretation is difficult in the case of mixtures. We recorded the electronic circular dichroism spectra of DNA helices separated in a mass spectrometer. We studied guanine-rich strands having various secondary structures, electrosprayed them as negative ions, irradiated them with an ultraviolet nanosecond optical parametric oscillator laser, and measured the difference in electron photodetac
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43

Ru, Jing, Ru-Fen Zhang, Yang Shi, Shao-Liang Zhang, Qian-Li Li, and Chun-Lin Ma. "Synthesis, structures and magnetic properties of heterobimetallic RuIII–3d (3d = Mn, Ni) compounds based on the chiral RuIII building block." New Journal of Chemistry 42, no. 19 (2018): 16237–43. http://dx.doi.org/10.1039/c8nj03747g.

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Two pairs of new chiral Ru<sup>III</sup>–Mn/Ni compounds have been successfully synthesized and characterized by IR spectroscopy, X-ray crystallography, circular dichroism (CD) and vibrational circular dichroism (VCD) spectra.
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44

Rustam, Ya, B. Bakhodir, M. Ikbol, and N. Shokhrukh. "ON THE THEORY OF ONE-PHOTON ABSORPTION OF POLARIZED LIGHT IN NARROW-GAP CRYSTALS. TAKING INTO ACCOUNT THE EFFECT OF COHERENT SATURATION." EurasianUnionScientists 5, no. 1(82) (2021): 56–59. http://dx.doi.org/10.31618/esu.2413-9335.2021.5.82.1235.

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In the article, from a microscopic point of view, the linear-circular dichroism of one-photon between band absorption of light in the Kane approximation in narrow-gap crystals is investigated.&#x0D; The linear-circular dichroism of one-photon absorption of polarized light is calculated taking into account the effect of coherent saturation in photoexcited charge carriers.&#x0D; The matrix elements of one-photon interband optical transitions and the corresponding linear-circular dichroism and the spectral dependence of the light absorption coefficient are calculated.
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45

Górecki, Marcin. "A configurational and conformational study of (−)-Oseltamivir using a multi-chiroptical approach." Organic & Biomolecular Chemistry 13, no. 10 (2015): 2999–3010. http://dx.doi.org/10.1039/c4ob02369b.

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Four chiroptical methods, i.e. electronic circular dichroism (ECD), optical rotatory dispersion (ORD), vibrational circular dichroism (VCD), and Raman optical activity (ROA) were employed to discover a set of the most probable conformations of (−)-Oseltamivir in solution.
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46

Pagni, R. M. "Circular Dichroism and Linear Dichroism (Rodger, Alison; Norden, Bengt)." Journal of Chemical Education 75, no. 9 (1998): 1095. http://dx.doi.org/10.1021/ed075p1095.

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47

Zhang, Ranran, Qiuling Zhao, Xia Wang, Wensheng Gao, Jensen Li, and Wing Yim Tam. "Measuring circular phase-dichroism of chiral metasurface." Nanophotonics 8, no. 5 (2019): 909–20. http://dx.doi.org/10.1515/nanoph-2019-0061.

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AbstractThe ability of chiral media to differentiate circularly polarized light is conventionally characterized by circular dichroism (CD) which is based on the difference in the absorption of the incident light for different polarizations. Thus, CD probes the bulk properties of chiral media. Here, we introduce a new approach termed as circular phase-dichroism that is based on the surface properties and is defined as the difference of the reflection phase for different circularly polarized incident lights in characterizing chiral media. As a demonstration, we measure the reflection phase from
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48

Rodger, Alison, and Doug Marshall. "Beginners guide to circular dichroism." Biochemist 43, no. 2 (2021): 58–64. http://dx.doi.org/10.1042/bio_2020_105.

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Circular dichroism (CD) is used to give information about the chirality or handedness of molecular systems. It is particularly widely applied to determine the secondary structure of proteins such as biopharmaceutical products.
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49

Kim, Jae-Young. "X-Ray Magnetic Circular Dichroism." Journal of the Korean Magnetics Society 20, no. 5 (2010): 201–5. http://dx.doi.org/10.4283/jkms.2010.20.5.201.

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50

TERAMAE, Norio. "Measurements of infrared circular dichroism." Journal of the Spectroscopical Society of Japan 35, no. 1 (1986): 65–67. http://dx.doi.org/10.5111/bunkou.35.65.

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