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Relevant bibliographies by topics / Cl insertion

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Academic literature on the topic 'Cl insertion'

Author: Grafiati

Published: 5 June 2025

Last updated: 2 August 2025

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Journal articles on the topic "Cl insertion"

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Mbuvi, Harun M., Erik R. Klobukowski, Gina M. Roberts, and L. Keith Woo. "O-H insertion and tandem N-H insertion/cyclization reactions using an iron porphyrin as catalyst with diazo compounds as carbene sources." Journal of Porphyrins and Phthalocyanines 14, no. 03 (2010): 284–92. http://dx.doi.org/10.1142/s1088424610001982.

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Iron(III) tetraphenylporphyrin chloride, Fe(TPP)Cl , efficiently catalyzed the insertion of carbenes derived from methyl 2-phenyldiazoacetates into O-H bonds of aliphatic and aromatic alcohols, with yields generally above 80%. Although the analogous N-H insertions are rapid at room temperature, the O-H insertion reactions are slower and required heating in refluxing methylene chloride for about 8 hours using 1.0 mol.% catalyst. Fe(TPP)Cl was also found to be effective for tandem N-H insertion/cyclization reactions when 1,2-diamines and 1,2-alcoholamines were treated with diazo reagents to give

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Song, Young-Youn, Jung-Yul Cha, and Chung-Ju Hwang. "Mechanical Characteristics of Various Orthodontic Mini-screws in Relation to Artificial Cortical Bone Thickness." Angle Orthodontist 77, no. 6 (2007): 979–85. http://dx.doi.org/10.2319/090606-363.1.

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Abstract Objective: To evaluate the effect of cortical bone thickness on the maximum insertion and removal torque of different types of self-drilling mini-screws and to determine if torque depends on the screw design. Materials and Methods: Three different types of self-drilling mini-screws (cylindrical type [Cl], taper type [Ta], taper type [Tb]) were inserted with the use of a driving torque tester at a constant speed of 3 rotations per minute. Experimental bone blocks with different cortical bone thicknesses were used as specimens. Results: Differences in the cortical bone thickness had lit

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Helling, Christoph, Chelladurai Ganesamoorthy, Christoph Wölper, and Stephan Schulz. "Geminal C–Cl and Si–Cl bond activation of chloromethanes and chlorosilanes by gallanediyl LGa." Dalton Transactions 51, no. 5 (2022): 2050–58. http://dx.doi.org/10.1039/d1dt04192d.

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Reactions of chloromethanes and chlorosilanes EHxCl4−x (E = C, x = 0–2; E = Si, x = 0, 1) with gallanediyl LGa occurred with E–Cl bond insertion and formation of mono- and bis-oxidative addition products.

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Su, Linan, Dawei Yang, Yixin Zhang, Baomin Wang, and Jingping Qu. "Methylene insertion into an Fe2S2 cluster: formation of a thiolate-bridged diiron complex containing an Fe–CH2–S moiety." Chemical Communications 54, no. 93 (2018): 13119–22. http://dx.doi.org/10.1039/c8cc07418f.

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Lee, Richard G., Junjie Gao, Stefan J. Siira, et al. "Cardiolipin is required for membrane docking of mitochondrial ribosomes and protein synthesis." Journal of Cell Science 133, no. 14 (2020): jcs240374. http://dx.doi.org/10.1242/jcs.240374.

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ABSTRACTThe mitochondrial inner membrane contains a unique phospholipid known as cardiolipin (CL), which stabilises the protein complexes embedded in the membrane and supports its overall structure. Recent evidence indicates that the mitochondrial ribosome may associate with the inner membrane to facilitate co-translational insertion of the hydrophobic oxidative phosphorylation (OXPHOS) proteins into the inner membrane. We generated three mutant knockout cell lines for the CL biosynthesis gene Crls1 to investigate the effects of CL loss on mitochondrial protein synthesis. Reduced CL levels cau

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Mochida, Kunio, and Asako Hasegawa. "Dimethylgermylene Insertion into the Si–H Bond." Chemistry Letters 18, no. 6 (1989): 1087–88. http://dx.doi.org/10.1246/cl.1989.1087.

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Szkop, Kevin M., Michael B. Geeson, Douglas W. Stephan, and Christopher C. Cummins. "Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer." Chemical Science 10, no. 12 (2019): 3627–31. http://dx.doi.org/10.1039/c8sc05657a.

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Acyl(chloro)phosphines RC(O)P(Cl)(t-Bu) have been prepared by formal insertion of tert-butyl phosphinidene (t-Bu–P) from t-BuPA (A = C<sub>14</sub>H<sub>10</sub> or anthracene) into the C–Cl bond of acyl chlorides.

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YAN, BING-FEI, WEN-ZUO LI, YU-WEI PEI, QING-ZHONG LI, and JIAN-BO CHENG. "THEORETICAL INVESTIGATION ON THE INSERTION REACTIONS OF THE GERMYLENOIDH2GeLiFWITHRH(R=Cl,SH,PH2)." Journal of Theoretical and Computational Chemistry 12, no. 03 (2013): 1350003. http://dx.doi.org/10.1142/s021963361350003x.

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The insertion reactions of the germylenoid H2GeLiF with RH (R = Cl, SH , PH2) were studied for the first time by using the DFT B3LYP and QCISD methods. The geometries of the stationary points on the potential energy surfaces of the reactions were optimized at the B3LYP/6-311+G (d,p) level of theory. The calculated results indicated that the mechanisms of the insertion reactions of H2GeLiF with HCl , H2S , and PH3are identical to each other. The QCISD/6-311++G(d,p)//B3LYP/6-311+G(d,p) calculated potential energy barriers of the three reactions are 81.80, 123.39 and 205.56 kJ/mol, and the reacti

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Yamamura, Satoru, Hiromichi Koshika, Matsuhiko Nishizawa, Tomokazu Matsue, and Isamu Uchida. "Photo-Assisted Lithium Insertion to Li1−xMn2O4Film Electrodes." Chemistry Letters 27, no. 6 (1998): 495–96. http://dx.doi.org/10.1246/cl.1998.495.

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Ozawa, Fumiyuki, Yasunobu Sakamoto, Takashi Sagawa, Rika Tanaka, and Hiroyuki Katayama. "Insertion of Phenylacetylene intocis-Silyl(stannyl)platinum Complexes." Chemistry Letters 28, no. 12 (1999): 1307–8. http://dx.doi.org/10.1246/cl.1999.1307.

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Book chapters on the topic "Cl insertion"

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Ulrich, H. "By Insertion of Methylene into C—Cl Bonds." In Chlorine, Bromine, and Iodine. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00132.

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Aresta, Michele, Eugenio Quaranta, Immacolata Tommasi, Joëlle Mascetti, Michel Tranquille, and Marek Borowiak. "Formation of peroxocarbonates from L3Rh(O2)Cl and L2Ni(CO2) : a unique reaction mechanism with carbon dioxide insertion into the O-O bond." In Studies in Surface Science and Catalysis. Elsevier, 1998. http://dx.doi.org/10.1016/s0167-2991(98)80850-1.

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Taber, Douglass F. "The Vanderwal Synthesis of Echinopine B." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0099.

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Intramolecular cyclopropanation has long been a powerful strategy for stereoselective polycarbocyclic construction. For many years, this was limited to diazo carbonyl insertion. More recently, alternative strategies for intramolecular cyclopropane construction have been developed. The power of such an approach is illustrated by the total synthesis of echinopine B 3 reported (Angew. Chem. Int. Ed. 2012, 51, 7572) by Christopher D. Vanderwal of the University of California, Irvine. The starting material for the synthesis was the commercial keto ester 4. Enol ether formation followed by cycloprop

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Taber, Douglass F. "The Lee Synthesis of (−)-Crinipellin A." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0098.

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The crinipellins are the only tetraquinane natural products. The enone crinipellins, including crinipellin A 3, have anticancer activity. Hee-Yoon Lee of the Korea Advanced Institute of Science and Technology (KAIST) envisioned (J. Am. Chem. Soc. 2014, 136, 10274) the assembly of 2 and thus 3 by the intramolecular dipolar cycloaddition of the diazoalkane derived from the tosylhydrazone 1. The initial cyclopentene was prepared from commercial 4 following the Williams procedure. Conjugate addition of the Grignard reagent 5 in the presence of TMS-Cl led to the silyl enol ether 6. Regeneration of

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Beier, Samara Pedroso, Chaiane Guerra da Conceição, Eracilda Fontanela, Lanes Beatriz Acosta Jaques, Camila Fontoura Nunes, and Vinícius dos Santos Cunha. "Chemical treatment, different conditions and storage periods on the physiological quality of rice seeds." In Engineering and its advancements. Seven Editora, 2024. http://dx.doi.org/10.56238/sevened2024.004-002.

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Seed is considered as the main input in agriculture, which must have physiological quality to reach its maximum productive potential. In addition, the germination test is one of the parameters to analyze the viability and represent the emergence in the field when sowing is carried out in ideal soil conditions. Therefore, this work aims to evaluate the germination percentage of rice seeds (Oryza sativa) cultivar IRGA 431 CL from the year 2021 with and without seed treatment, stored for different periods in prototypes of vertical silos and big bags. The experiment was carried out at the Post-Har

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Conference papers on the topic "Cl insertion"

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Thebault, Florian, Anne-Sophie Bureau-Bayart, Laurent Delattre, Diana Koschel, Emmanuel Desdoit, and Bertine Orlans. "Accurate Determination of KIapplied for NACE TM0177 Method D Test." In CORROSION 2013. NACE International, 2013. https://doi.org/10.5006/c2013-02340.

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Abstract NACE TM0177 Method D (DCB) test allows the determination of the critical stress intensity factor KISSC, below which the propagation of a sulfide stress crack in the material is stopped. For a given severity of the sour medium (pH, PH2S, T, [Cl-]…), KISSC is not a material constant since it depends for instance on the testing arm displacement. Recently, the Klimit concept was proposed to circumvent this issue. Klimit is a conservative KISSC value and would be more representative of the material corrosion resistance. For an accurate determination of Klimit it is necessary to know KIappl

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Sugimoto, Toshiki, Yuhei Horiuchi, and Takuto Araki. "Developments of MEMS-Based Thermocouple Array for Sensing Effects of a Flow Channel on PEMFC Local Temperature Distribution." In ASME 2013 11th International Conference on Nanochannels, Microchannels, and Minichannels. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/icnmm2013-73198.

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Measuring temperature inside PEMFCs is necessary for proper water management, because water vapor pressure is a strong function of temperature. In this paper, we have developed thin film thermocouple (TFTC) array to measure temperature distributions near the Cathode Catalyst layer (CCL) with a resolution smaller than the rib-channel scale. The sensor array was placed between CL and gas diffusion layer (GDL) at the cathode. No performance decrement was observed with the insertion of TFTC array. The measurements of temperature distributions showed that the temperature rises at the cathode CL is

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Sugimoto, Toshiki, Yuhei Horiuchi, and Takuto Araki. "Developments of Thin-Film Temperature and Humidity Sensors for PEMFC In-Situ Measurements." In ASME 2014 12th International Conference on Fuel Cell Science, Engineering and Technology collocated with the ASME 2014 8th International Conference on Energy Sustainability. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/fuelcell2014-6480.

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Proton exchange membrane fuel cells (PEMFCs) are useful systems because they operate at lower temperatures than other types of fuel cells. This characteristic causes water management issues. To elucidate effects of water on PEMFC performance, we developed a temperature sensor using micro-electro-mechanical systems (MEMS) techniques. This sensor was placed between the catalyst layer (CL) and the microporous layer (MPL) at the cathode. Slight effects on total cell performance were observed with the insertion of the sensor. This sensor can be applicable to typical PEMFCs without any special equip

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Nishimura, Toshiyasu. "Corrosion Analysis of Reinforcing Steels in Mortar for Nuclear Facilities." In 17th International Conference on Nuclear Engineering. ASMEDC, 2009. http://dx.doi.org/10.1115/icone17-75548.

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It is important to estimate the corrosion of reinforcing steel in mortar facilities, because the nuclear plants are located near the sea side. In the case of environmental factors in mortar, the Cl ion concentration and pH were monitored by inserting microelectrodes into artificial pores in the mortar. At the same time, the corrosion behavior of the reinforcing steel was investigated by EIS (electrochemical impedance spectroscopy). In the EIS measurements of the reinforcing steel, diffusion behavior was confirmed in the initial period, but diffusion could no longer be observed after 35 day. In

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