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Journal articles on the topic 'Cluster poly-Oxo'

Author: Grafiati
Published: 22 June 2023

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1

Martin, Nicolas P., Christophe Volkringer, Pascal Roussel, et al. "{Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides." Chemical Communications 54, no. 72 (2018): 10060–63. http://dx.doi.org/10.1039/c8cc03744b.

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2

Trabelsi, Sondes, Giulia Fornasieri, Laurence Rozes, et al. "Tailoring the structure of hybrid organic inorganic nanomaterials built on tetra- and polyfunctional alco-oxo-titanium clusters in polystyrene." Journal of Applied Crystallography 39, no. 5 (2006): 656–60. http://dx.doi.org/10.1107/s0021889806028871.

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Functional titanium oxo-clusters Ti16O16(OEt)32−x(OPhCH=CH2)xwith different numbers of styrenic groups, wherex= 4 (tetra) andx= 16 (poly), have been synthesized and copolymerized with styrene. The resulting hybrid nanomaterials present three-dimensional networks in which the inorganic nano-fillers are covalently linked to the inorganic polymer. The influence of the number of functional groups borne by the oxo clusters on the structure of the resulting hybrid nanomaterials has been investigated by a combination of small-angle X-ray scattering, transmission electron microscopy and energy-filteri
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3

Dufaye, Maxime, Nicolas P. Martin, Sylvain Duval, Christophe Volkringer, Atsushi Ikeda-Ohno, and Thierry Loiseau. "Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)2 followed by the formation of molecular poly-oxo cluster {U14} containing hemimellitate uranium(iv)." RSC Advances 9, no. 40 (2019): 22795–804. http://dx.doi.org/10.1039/c9ra03707a.

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4

Patrahau, Bianca, Clément Chaumont, Laurent Barloy, et al. "From a bulk solid to thin films of a hybrid material derived from the [Ti10O12(cat)8(py)8] oxo-cluster and poly(4-vinylpyridine)." New Journal of Chemistry 43, no. 3 (2019): 1581–88. http://dx.doi.org/10.1039/c8nj05410j.

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Homogeneous coloured hybrid materials are prepared from the [Ti<sub>10</sub>O<sub>12</sub>(cat)<sub>8</sub>(py)<sub>8</sub>] oxo-cluster and poly(4-vinylpyridine). SiO<sub>2</sub> surfaces are functionalized with thin films of this material.
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5

Falaise, Clément, Christophe Volkringer, Jean-François Vigier, et al. "Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium." Journal of the American Chemical Society 135, no. 42 (2013): 15678–81. http://dx.doi.org/10.1021/ja4067207.

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6

Falaise, Clément, Christophe Volkringer, Christoph Hennig, and Thierry Loiseau. "Ex-Situ Kinetic Investigations of the Formation of the Poly-Oxo Cluster U38." Chemistry - A European Journal 21, no. 46 (2015): 16654–64. http://dx.doi.org/10.1002/chem.201502207.

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7

Akashi, Daisuke, Hiroaki Kido, Yoichi Sasaki, and Tasuku Ito. "Preparation and Electrochemical Response of Poly(4-vinylpyridine)-Coordinated Oxo-acetato Triruthenium Cluster Film." Chemistry Letters 21, no. 1 (1992): 143–46. http://dx.doi.org/10.1246/cl.1992.143.

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8

Louisy, Elodie, Séverine Bellayer, Gaëlle Fontaine, Laurence Rozes, and Fanny Bonnet. "Novel hybrid poly(l-lactic acid) from titanium oxo-cluster via reactive extrusion polymerization." European Polymer Journal 122 (January 2020): 109238. http://dx.doi.org/10.1016/j.eurpolymj.2019.109238.

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9

Armstrong, Fraser A. "Why did Nature choose manganese to make oxygen?" Philosophical Transactions of the Royal Society B: Biological Sciences 363, no. 1494 (2007): 1263–70. http://dx.doi.org/10.1098/rstb.2007.2223.

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This paper discusses the suitability of manganese for its function in catalysing the formation of molecular oxygen from water. Manganese is an abundant element. In terms of its inherent properties, Mn has a particularly rich redox chemistry compared with other d-block elements, with several oxidizing states accessible. The most stable-state Mn 2+ behaves like a Group 2 element—it is mobile, weakly complexing, easily taken up by cells and redox-inactive in simple aqueous media. Only in the presence of suitable ligands does Mn 2+ become oxidized, so it provides an uncomplicated building unit for
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10

Martin, Nicolas P., Christophe Volkringer, Natacha Henry, et al. "Formation of a new type of uranium(iv) poly-oxo cluster {U38} based on a controlled release of water via esterification reaction." Chemical Science 9, no. 22 (2018): 5021–32. http://dx.doi.org/10.1039/c8sc00752g.

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11

Janek, Maciej, Tadeusz M. Muzioł, and Piotr Piszczek. "Trinuclear Oxo-Titanium Clusters: Synthesis, Structure, and Photocatalytic Activity." Materials 12, no. 19 (2019): 3195. http://dx.doi.org/10.3390/ma12193195.

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The interest in titanium (IV) oxo-complexes is due to their potential application in photodegradation processes and environmental pollutants reduction. Titanium (IV) oxo-complexes (TOCs) of the general formula [Ti3O(OiPr)8(OOCR’)2] (R’ = -C13H9 (1), -p-PhCl (2), -m-PhNO2 (3), -C4H7 (4)) were synthesized and structurally characterized. The use of the different carboxylate ligands allowed modulating the optical band gaps of the produced microcrystals, which were measured via diffuse reflectance ultraviolet and visible spectroscopy (UV-Vis-DRS) and calculated using the density functional theory (
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12

Janek, Maciej, Aleksandra Radtke, Tadeusz Muzioł, Maria Jerzykiewicz, and Piotr Piszczek. "Tetranuclear Oxo-Titanium Clusters with Different Carboxylate Aromatic Ligands: Optical Properties, DFT Calculations, and Photoactivity." Materials 11, no. 9 (2018): 1661. http://dx.doi.org/10.3390/ma11091661.

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Titanium(IV) oxo-clusters of the general formula (Ti4O2(OiBu)10(O2CR’)2) (R’ = C13H9 (1), PhCl (2), PhNO2 (3)) were studied in order to estimate their potential photoactivity. The structure of the resulting tetranuclear Ti(IV) oxo-complexes was then determined via single crystal X-ray diffraction, infrared and Raman spectroscopy, and electron spin resonance (ESR). An analysis of diffuse reflectance spectra (DRS) allowed for the assessment of band gap values of (1)–(3) microcrystalline samples complexes. The use of different carboxylate ligands allowed the band gap of tetranuclear Ti(IV) oxo-cl
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13

Fracasso, Giulio, Paolo Ghigna, Luca Nodari, et al. "Nanoaggregates of iron poly-oxo-clusters obtained by laser ablation in aqueous solution of phosphonates." Journal of Colloid and Interface Science 522 (July 2018): 208–16. http://dx.doi.org/10.1016/j.jcis.2018.03.065.

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14

Chen, Jing-Lin, Li-Yi Zhang, Lin-Xi Shi, Hen-Yun Ye, and Zhong-Ning Chen. "Syntheses, characterization and redox properties of di- and poly-phosphine linked oligomeric complexes of oxo-centered triruthenium clusters." Inorganica Chimica Acta 359, no. 5 (2006): 1531–40. http://dx.doi.org/10.1016/j.ica.2005.12.027.

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15

Périneau, Fabien, Sandrine Pensec, Capucine Sassoye, et al. "New hybrid core–shell star-like architectures made of poly(n-butyl acrylate) grown from well-defined titanium oxo-clusters." Journal of Materials Chemistry 21, no. 12 (2011): 4470. http://dx.doi.org/10.1039/c0jm04047a.

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