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Dissertations / Theses on the topic 'Coil to Globule transition'

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1

Sinha, Prashant. "Intermediate states in bivalent ion induced shrinking of polyacrylate coils on surfaces and in solution." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2009. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-24839.

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Specifically binding ions induce the transition of anionic polyacrylate coils from extended conformation to collapsed globules passing through a cascade of intermediate states when solution conditions approach the L-type precipitation threshold. It is the conformation of these intermediate states on surfaces and in solution which is at the focus of this thesis. In comparing the surface and solution conformations of intermediate states, we were able to qualitatively and quantitatively underline the effects of sample history. Two types of quantitative comparisons have been emphasized. In r
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2

Arashiro, Everaldo. "Dinâmica crítica de modelos de spin, autômatos celulares e polipeptídeos." Universidade de São Paulo, 2005. http://www.teses.usp.br/teses/disponiveis/59/59135/tde-13052008-154801/.

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Nesse trabalho, são investigadas as propriedades dinâmicas de modelos da mecânica estatística na criticalidade. Inicialmente, trabalhando com modelos de spin e utilizando os conceitos de persistência global e de dimensão anômala da magnetização inicial, mostramos que o modelo de Baxter-Wu não está na mesma classe de universalidade dos modelos de Potts com quatro estados e de Ising com interação de três spins em uma direção, todos bidimensionais. Na segunda parte da tese, estudamos o fenômeno de crescimento da superfície gerada pela deposição segundo as regras que definem os autômatos celulares
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3

Gornall, Joanne Louise. "The helix-coil transition in gelatin." Thesis, University of Cambridge, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.612077.

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4

Lin, Meng-Chih. "Pressure effects on DNA helix-coil transition kinetics." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape17/PQDD_0001/NQ33909.pdf.

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5

Alessi, Michael Louis. "Coil-to-helix transition of poly (ethylene oxide) in solution." College Park, Md. : University of Maryland, 2004. http://hdl.handle.net/1903/1747.

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Thesis (Ph. D.) -- University of Maryland, College Park, 2004<br>Thesis research directed by: Chemical Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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6

Tapadia, Prashant Subhashchandra. "NONLINEAR RHEOLOGY OF ENTANGLED POLYMERS." University of Akron / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=akron1136007343.

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7

Kalafut, Bennett Samuel. "Optical Tweezers studies of Nucleic Acids and their Interaction with Proteins." Diss., The University of Arizona, 2011. http://hdl.handle.net/10150/202969.

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Mechanics and biological function of nucleic acids are intimately coupled. The DNA double helix must be opened to allow base pairing of RNA during transcription; RNA must bend and fold in its many cellular functions. Presented in this dissertation are two investigations of mechanical deformations of nucleic acids, conducted with optical tweezers.In the introduction, the mechanical properties of DNA and RNA and their relevance to their cellular functions are introduced, to give the reader context for the results presented in the Chapters 2 and 3. This is followed by an introduction to the theor
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8

Lecrevisse, Thibault. "Contribution à l'étude des aimants supraconducteurs utilisant des matériaux supraconducteurs à haute température de transition." Phd thesis, Université de Grenoble, 2012. http://tel.archives-ouvertes.fr/tel-00875176.

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L'apparition ces dernières années de supraconducteurs réalisés industriellement utilisant des composés à haute température de transition offre la possibilité de nouveaux développements en magnétisme supraconducteur. En effet ils permettent d'augmenter le champ magnétique généré en conservant une cryogénie classique à 4,2K d'une part, et ils ouvrent la voie à des développements d'aimants supraconducteurs fonctionnant entre 10 et 30K d'autre part. Les matériaux supraconducteurs à haute température critique sont alors indispensables pour dépasser les inductions magnétiques de 16 T (cas de l'inser
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9

Wicht, Stefan [Verfasser], Thomas [Gutachter] Kiefhaber, Mike [Gutachter] Schutkowski, and Ralf [Gutachter] Seidel. "Characterization of the boundary diffusion mechanism for the Helix-Coil transition in peptides by Triplet-Triplet energy transfer / Stefan Wicht ; Gutachter: Thomas Kiefhaber, Mike Schutkowski, Ralf Seidel." Halle (Saale) : Universitäts- und Landesbibliothek Sachsen-Anhalt, 2019. http://d-nb.info/1210730847/34.

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10

Wicht, Stefan [Verfasser], Thomas Gutachter] Kiefhaber, Mike [Gutachter] Schutkowski, and Ralf [Gutachter] [Seidel. "Characterization of the boundary diffusion mechanism for the Helix-Coil transition in peptides by Triplet-Triplet energy transfer / Stefan Wicht ; Gutachter: Thomas Kiefhaber, Mike Schutkowski, Ralf Seidel." Halle (Saale) : Universitäts- und Landesbibliothek Sachsen-Anhalt, 2019. http://nbn-resolving.de/urn:nbn:de:gbv:3:4-1981185920-140249.

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11

Zhi-XinHuang and 黃智新. "Microrheological Study on Coil-Globule Transition of Single Molecule Polymer." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/19644820106278766968.

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碩士<br>國立成功大學<br>化學工程學系碩博士班<br>100<br>This thesis is to explore the use of particle-tracking microrheology techniques in studying the coil-globule transition of single molecule polymer. This approach is validated by comparing the measured results with predictions by the classical Flory-deGennes theory and those using the Ostwald viscometer (Chapter 3). As a complementary study, small angle X-ray scattering (SAXS) is also employed to probe the microstructures of a polymer chain (Chapter 4). In Chapter 3 we measure how the viscosity of a dilute poly-2-vinylpyridine (P2VP) solution changes with pH
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12

Simmons, David Samuel. "Phase and conformational behavior of LCST-driven stimuli responsive polymers." 2009. http://hdl.handle.net/2152/18155.

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Several analytical mean field models are presented for the class of stimuli responsive polymers that are driven by the lower critical solution temperature (LCST) transition. For solutions above the polymer crossover concentration, a hybrid model combines lattice-fluid excluded volume and van-der-Waals interactions with a combinatorial approach for the statistics of hydrogen bonding, hydration, and ionic bonding. This approach yields models for the LCST of both neutral polymers and lightly charged polyelectrolytes in aqueous salt solution. The results are shown to be in semi-quantitative agreem
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13

Wu, Ying-Ting, and 吳穎婷. "Morphological Transition of Coil-Rod-Coil Triblock Copolymer Blend with Homopolymer via Dissipative Particle Dynamics Simulation." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/89020400174728672598.

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碩士<br>國立清華大學<br>化學工程學系<br>99<br>Dissipative particle dynamics simulation was performed on rich equilibrium phase structure by blending coil-rod-coil triblock copolymers and homopolymers, in which the influence of blending ratio as well as the chain length of rod block of coil-rod-coil triblock copolymers were studied systematically. We also investigated some statistic properties (e.g., End- to- End Distance, Radius of Gyration). The results show that bond bending force is not only a promising strategy to control the angle between the bonds, but also made a great impact on polymer morphology
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14

Dietz, Mirko [Verfasser]. "Helix-coil-transition in solid polypeptides / vorgelegt von Mirko Dietz." 2007. http://d-nb.info/985565063/34.

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15

Lin, Yi Chun, and 林怡君. "Phase Transition Behavior and Nanostructure Orientation of PS-b-P4VP(DBSA) Supramolecular Comb-coil Block Copolymer." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/69225732150693900533.

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16

Hu, Hung Yu, and 胡宏瑀. "Morphological Transition of X-shaped Rod-Coil Polyphilic Block Copolymer in Solution via Dissipative Particle Dynamics Simulation." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/7z46ze.

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碩士<br>國立清華大學<br>化學工程學系<br>103<br>Dissipative Particle Dynamics Simulations are used to investigate the morphological transition of X-shaped rod-coil polyphilic molecules in solution. These X-shaped molecules consist of a rod-like core, with a polar group at each end and two lateral chains. The influences of changing the two lateral chains relative miscibility, lateral chains length and solvent concentration in solution on the morphologies are discussed. The results show that changing the two lateral chains length and the solvent concentration can effectively control the morphologies. And the h
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17

Lin, Yu-Chen, and 林喻偵. "I.Metal Ion-Responsive Functional Polymers with Different Backbone Structures: Flexible/Rigid Hydrocarbon Chain and Ether LinkageII.Metal Ion-Induced Random Coil/Helix Conformation Transition of Functional Oligo-L-Lysine Based OctamersIII.Acridinium Sal." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/54682272402370073819.

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博士<br>國立臺灣大學<br>化學研究所<br>99<br>Chapter I describes the development of side-chain functionalized polymers containing metal ion-responsive units with flexible/rigid backbone structures that have potential in developing metal ions sensory materials or self-assembly into hierarchical ordered structures. Poly-norbornene based homopolymer derived from ring-opening metathesis polymerization (ROMP) is regarded as rigid backbones because of the bicyclic constraints of norbornene. Decrease of backbone rigidity can be achieved through the alternating copolymerization of an appropriate cyclic olefin comon
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18

(8407140), Saadia T. Chaudhry. "CHAIN-LENGTH PROPERTIES OF CONJUGATED SYSTEMS: STRUCTURE, CONFORMATION, AND REDOX CHEMISTRY." Thesis, 2021.

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The development of solution-processable semiconducting polymers has brought mankind’s long-sought dream of plastic electronics to fruition. Their potential in the manufacturing of lightweight, flexible yet robust, and biocompatible electronics has spurred their use in organic transistors, photovoltaics, electrochromic devices, batteries, and sensors for wearable electronics. Yet, despite the successful engineering of semiconducting polymers, we do not fully understand their molecular behavior and how it influences their doping (oxidation/reduction) properties. This is especially true for donor
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