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Journal articles on the topic 'Compartmental Complexes'

Author: Grafiati

Published: 7 June 2025

Last updated: 17 July 2025

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1

Biswas, Arpita. "A Brief Review on Homo-/Hetero-nuclear Co-ordination Compounds Derived from Some Single Compartmentl Acyclic Schiff Base Ligands having N-,O-Donor Centres." Oriental Journal Of Chemistry 38, no. 4 (2022): 957–66. http://dx.doi.org/10.13005/ojc/380417.

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Tetradentate acyclic compartmental Schiff base ligand with N2O2 compartment afford suitable coordination environment for large variety of metal ions. This type of ligands can easily be synthesized by [2+1] condensation of a carbonyl compounds with a diamine. Several metal complexes have been reported from the single- and double-compartment acyclic Schiff base ligands which are the [2+1] condensation products of salicylaldehyde, 2-hydroxyacetophenone, 3-methoxysalicylaldehyde, 3-ethoxysalicylaldehyde and a diamine; The diamine counterpart in these ligands are ethylenediamine, 1,3-diaminopropane

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2

Atkins, Andrew J., Daniel Black, Alexander J. Blake, et al. "Schiff-base compartmental macrocyclic complexes." Chem. Commun., no. 4 (1996): 457–64. http://dx.doi.org/10.1039/cc9960000457.

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3

Abid, Khalil K., and David E. Fenton. "Lanthanide complexes of compartmental ligands." Inorganica Chimica Acta 109, no. 1 (1985): L5—L7. http://dx.doi.org/10.1016/s0020-1693(00)86316-1.

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4

Casellato, U., D. Fregona, S. Sitran, P. A. Vigato, and D. E. Fenton. "Uranyl complexes with acyclic compartmental ligands." Journal of the Less Common Metals 122 (August 1986): 249–56. http://dx.doi.org/10.1016/0022-5088(86)90418-2.

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5

Guerriero, P., U. Casellato, S. Tamburini, P. A. Vigato, and R. Graziani. "Lanthanide complexes with compartmental schiff bases." Inorganica Chimica Acta 129, no. 1 (1987): 127–38. http://dx.doi.org/10.1016/s0020-1693(00)85915-0.

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6

Benetollo, F., V. Peruzzo, S. Tamburini, and P. A. Vigato. "Manganese complexes with acyclic compartmental Schiff bases." Inorganic Chemistry Communications 15 (January 2012): 84–87. http://dx.doi.org/10.1016/j.inoche.2011.09.044.

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7

Shipra, Srivastava, Srivastava Ankita, Tripathi Namrata, and K. Sharma V. "Mononuclear and binuclear ruthenium(III) complexes of macrocyclic compartmental ligands : synthetic, spectral speciation, electrochemical behaviour and antimicrobial studies." Journal of Indian Chemical Society Vol. 84, Jun 2007 (2007): 524–31. https://doi.org/10.5281/zenodo.5820460.

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Department of Chemistry, University of Lucknow, Lucknow-226 007, Uttar Pradesh, India <em>E-mail </em>: vksharma2l@hotmail.com <em>Manuscript received 26 December 2006, revised 28 March 2007, accepted 30 March 2007</em> The macrocyclic compartmental Schiff base ruthenium(lll) complexes have been synthesized. A variety of complexes have been obtained by different procedures and also depending on the choice of lateral diamine fragments with ruthenium ions. The compounds were characterized by elemental analyses, conductometric and magnetochemical behaviour, as well as by IR, ESR, TG, electrochemi

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8

Chakraborty, Prateeti, Ishani Majumder, Kazi Sabnam Banu, et al. "Mn(ii) complexes of different nuclearity: synthesis, characterization and catecholase-like activity." Dalton Transactions 45, no. 2 (2016): 742–52. http://dx.doi.org/10.1039/c5dt03659c.

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The origin of catecholase-like activity of Mn(ii)–Schiff-base complexes has been explored by studying structurally characterized mono-, di- and polynuclear Mn(ii) complexes of two “end-off” compartmental Schiff-base ligands.

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9

Ōkawa, Hisashi, Hideki Furutachi, and David E. Fenton. "Heterodinuclear metal complexes of phenol-based compartmental macrocycles." Coordination Chemistry Reviews 174, no. 1 (1998): 51–75. http://dx.doi.org/10.1016/s0010-8545(97)00082-9.

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10

Vigato, P. A., and S. Tamburini. "Advances in acyclic compartmental ligands and related complexes." Coordination Chemistry Reviews 252, no. 18-20 (2008): 1871–995. http://dx.doi.org/10.1016/j.ccr.2007.10.030.

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11

Schmidt, Markus, Helmar Görls, and Winfried Plass. "Facile high-yield synthesis of unsymmetric end-off compartmental double Schiff-base ligands: easy access to mononuclear precursor and unsymmetric dinuclear complexes." RSC Advances 6, no. 79 (2016): 75844–54. http://dx.doi.org/10.1039/c6ra16870a.

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12

Chakraborty, Tonmoy, Somali Mukherjee, Sanchari Dasgupta, Biplab Biswas, and Debasis Das. "Anion-mediated bio-relevant catalytic activity of dinuclear nickel(ii) complexes derived from an end-off compartmental ligand." Dalton Transactions 48, no. 8 (2019): 2772–84. http://dx.doi.org/10.1039/c8dt04631j.

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13

Ibrahim, Bashar, Peter Dittrich, Stephan Diekmann, and Eberhard Schmitt. "Stochastic effects in a compartmental model for mitotic checkpoint regulation." Journal of Integrative Bioinformatics 4, no. 3 (2007): 77–88. http://dx.doi.org/10.1515/jib-2007-66.

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Summary The proper segregation of sister chromatids at onset of anaphase is surveyed by the mitotic spindle assembly checkpoint. The concentration dynamics of the complexes APC:Cdc20 and MCC:APC determine exit from metaphase to anaphase. We have developed a model based on 14 proteins and complexes to describe concentration dynamics by ordinary differential equations in three compartments coupled by diffusion. One kinetochore in each compartment determines the attachment status to the spindle pole. Here, we focus on the role of noise in the segregation surveillance process. The deterministic di

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14

Suzuki, Masatatsu, Hideki Furutachi, and Hisashi Ōkawa. "Bimetallic dioxygen complexes derived from ‘end-off’ compartmental ligands." Coordination Chemistry Reviews 200-202 (May 2000): 105–29. http://dx.doi.org/10.1016/s0010-8545(00)00323-4.

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15

Zude, Zhang, Zhang Xiong, Zheng Tao, Yu Huaming, and Liu Qingliang. "Structural study of compartmental complexes of europium and copper." Journal of Molecular Structure 478, no. 1-3 (1999): 23–27. http://dx.doi.org/10.1016/s0022-2860(98)00622-x.

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16

Paolucci, G., S. Stelluto, and S. Sitran. "Compartmental ligands: Synthesis and characterization of polynuclear uranyl complexes." Inorganica Chimica Acta 110, no. 1 (1985): 19–23. http://dx.doi.org/10.1016/s0020-1693(00)81346-8.

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17

Bailey, Neil A., Jonathan D. Crane, Matthew J. S. Dwyer, David E. Fenton, Paul C. Hellier, and Paul D. Hempstead. "Dinuclear complexes of molecular clefts and unsymmetrical compartmental ligands." Journal of Inorganic Biochemistry 43, no. 2-3 (1991): 197. http://dx.doi.org/10.1016/0162-0134(91)84189-g.

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18

Jiang, Lin, Yue Liu, Xin Liu, Jinlei Tian, and Shiping Yan. "Three series of heterometallic NiII–LnIII Schiff base complexes: synthesis, crystal structures and magnetic characterization." Dalton Transactions 46, no. 37 (2017): 12558–73. http://dx.doi.org/10.1039/c7dt02351k.

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Three series of Ni<sup>II</sup>–Ln<sup>III</sup> complexes were synthesized using compartmental Schiff base ligands in conjunction with auxiliary ligands. Their magnetic properties have been well studied.

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19

Badannavar, Dr. N. Y. "Exploring the Coordination Chemistry and Biological Applications of Compartmental Complexes of Thiosemicarbazones: Synthesis, Characterization, and Functional Insights." International Journal of Advance and Applied Research 5, no. 44 (2024): 48–57. https://doi.org/10.5281/zenodo.14685664.

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<strong>Abstract:</strong> Compartmental complexes of thiosemicarbazones, a class of versatile ligands derived from thiosemicarbazide and aldehydes or ketones, have garnered significant attention in coordination chemistry due to their ability to form stable chelates with a wide range of metal ions, and their structural flexibility, arising from the presence of both sulfur and nitrogen donor atoms, enables them to adopt diverse coordination modes that facilitate the formation of mono-, bi-, and polynuclear complexes with well-defined geometries, which are not only of theoretical interest but al

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20

Saghatforoush, Lotfali, Keyvan Moeini, Seyed Abolfazl Hosseini-Yazdi, et al. "Theoretical and experimental investigation of anticancer activities of an acyclic and symmetrical compartmental Schiff base ligand and its Co(ii), Cu(ii) and Zn(ii) complexes." RSC Advances 8, no. 62 (2018): 35625–39. http://dx.doi.org/10.1039/c8ra07463a.

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A compartmental Schiff base ligand and its copper, cobalt and zinc complexes were prepared. Thein vitroactivities of all compounds against the human leukemia cell line K562 were investigated along with docking and DFT studies.

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21

Olea-Román, Daniela, Nicolas Bélanger-Desmarais, Marcos Flores-Álamo, et al. "Spectroscopic studies of lanthanide complexes of varying nuclearity based on a compartmentalised ligand." Dalton Transactions 44, no. 39 (2015): 17175–88. http://dx.doi.org/10.1039/c5dt02563j.

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22

Adams, Harry, Laura R. Cummings, David E. Fenton, and Paul E. McHugh. "Dinuclear zinc(II) complexes of a [6,6]-unsymmetrical compartmental ligand." Inorganic Chemistry Communications 6, no. 1 (2003): 19–22. http://dx.doi.org/10.1016/s1387-7003(02)00676-7.

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23

Casellato, U., P. Guerriero, S. Tamburini, P. A. Vigato, and C. Benelli. "Mononuclear, homo- and heteropolynuclear complexes with acyclic compartmental Schiff bases." Inorganica Chimica Acta 207, no. 1 (1993): 39–58. http://dx.doi.org/10.1016/s0020-1693(00)91454-3.

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24

Okawa, Hisashi, Hideki Furutachi, and David E. Fenton. "ChemInform Abstract: Heterodinuclear Metal Complexes of Phenol-Based Compartmental Macrocycles." ChemInform 30, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.199903252.

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25

Liu, Yiting, and Charles Barlowe. "Analysis of Sec22p in Endoplasmic Reticulum/Golgi Transport Reveals Cellular Redundancy in SNARE Protein Function." Molecular Biology of the Cell 13, no. 9 (2002): 3314–24. http://dx.doi.org/10.1091/mbc.e02-04-0204.

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Membrane-bound soluble N-ethylmaleimide-sensitive factor attachment protein receptor (SNARE) proteins form heteromeric complexes that are required for intracellular membrane fusion and are proposed to encode compartmental specificity. In yeast, the R-SNARE protein Sec22p acts in transport between the endoplasmic reticulum (ER) and Golgi compartments but is not essential for cell growth. Other SNARE proteins that function in association with Sec22p (i.e., Sed5p, Bos1p, and Bet1p) are essential, leading us to question how transport through the early secretory pathway is sustained in the absence

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26

Casellato, Umberto, Sergio Tamburini, Patrizia Tomasin, et al. "Hetero-dinuclear sodium–lanthanide(iii) complexes with an asymmetric compartmental macrocycle." Chemical Communications, no. 2 (2000): 145–46. http://dx.doi.org/10.1039/a909367b.

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27

Chakraborty, Amit, Joydev Acharya, and Vadapalli Chandrasekhar. "Ferrocene-Supported Compartmental Ligands for the Assembly of 3d/4f Complexes." ACS Omega 5, no. 16 (2020): 9046–54. http://dx.doi.org/10.1021/acsomega.0c00654.

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28

Fenton, David E. "Structural diversity in oligonuclear nickel(II) complexes of unsymmetrical compartmental ligands." Inorganic Chemistry Communications 5, no. 7 (2002): 537–47. http://dx.doi.org/10.1016/s1387-7003(02)00477-x.

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29

Fondo, Matilde, Noelia Ocampo, Ana M. García-Deibe, et al. "Ferromagnetic heterotrinuclear Cu–Ni complexes of a compartmental chiral Schiff base." Dalton Transactions 40, no. 44 (2011): 11770. http://dx.doi.org/10.1039/c1dt10897b.

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30

Klingele, Julia, Sebastian Dechert, and Franc Meyer. "Polynuclear transition metal complexes of metal⋯metal-bridging compartmental pyrazolate ligands." Coordination Chemistry Reviews 253, no. 21-22 (2009): 2698–741. http://dx.doi.org/10.1016/j.ccr.2009.03.026.

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31

Benetollo, F., P. Di Bernardo, S. Tamburini, P. A. Vigato, and P. Zanonato. "Mononuclear and polynuclear complexes with a side-off compartmental Schiff base." Inorganic Chemistry Communications 11, no. 3 (2008): 246–51. http://dx.doi.org/10.1016/j.inoche.2007.11.022.

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32

Botta, Mauro, Umberto Casellato, Cristina Scalco, et al. "Heterodinuclear LnNa Complexes with an Asymmetric Macrocyclic Compartmental Schiff Base." Chemistry - A European Journal 8, no. 17 (2002): 3917–26. http://dx.doi.org/10.1002/1521-3765(20020902)8:17<3917::aid-chem3917>3.0.co;2-d.

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33

Corredoira-Vázquez, Julio, Matilde Fondo, Jesús Sanmartín-Matalobos, Pablo Taboada, and Ana García-Deibe. "Filling Tricompartmental Ligands with GdIII and ZnII Ions: Some Structural and MRI Studies." Crystals 8, no. 11 (2018): 431. http://dx.doi.org/10.3390/cryst8110431.

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Here we report the synthesis and characterization of a mononuclear gadolinium complex (Gd) and two heteronuclear Zn-Gd complexes (ZnGd and Zn2Gd), which contain two similar three-armed ligands that display an external compartment suitable for lanthanoid ions, and two internal compartments adequate for zinc (II) ions [H3L′ = (2-(3-formyl-2-hydroxy-5-methyl phenyl)-1,3-bis[4 -(3-formyl-2-hydroxy-5-methylphenyl)-3-azabut-3-enyl]-1,3-imidazolidine; H3L = 2-(5-bromo-2-hydroxy-3-methoxyphenyl)-1,3-bis[4-(5-bromo-2-hydroxy-3-methoxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine]. The synthetic methods us

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34

Andruh, Marius. "Binuclear complexes as tectons in designing supramolecular solid-state architectures." Pure and Applied Chemistry 77, no. 10 (2005): 1685–706. http://dx.doi.org/10.1351/pac200577101685.

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Oligonuclear complexes as well as coordination polymers with various network topologies can be obtained by using homo- or heterobinuclear complexes as starting materials. These building blocks are stable complexes, where the metal ions are held together by compartmental ligands, or alkoxo-bridged Cu(II) species. The binuclear nodes can be connected through appropriate exo-dentate ligands, or through metal-containing anions (e.g., [M(CN)6]3-, M = CrIII, FeIII, CoIII). A rich variety of 3d-3d and 3d-4f heterometallic complexes, with interesting architectures and topologies of the spin carriers,

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35

Ghosh, Kousik, Klaus Harms, Antonio Bauzá, Antonio Frontera, and Shouvik Chattopadhyay. "Heteronuclear cobalt(iii)/sodium complexes with salen type compartmental Schiff base ligands: methylene spacer regulated variation in nuclearity." Dalton Transactions 47, no. 2 (2018): 331–47. http://dx.doi.org/10.1039/c7dt03929h.

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Three unique heteronuclear cobalt(iii)/sodium Schiff base complexes have been synthesized and characterized. Nuclearity of these complexes changes as a result of alteration of the steric hindrance in the ligand moiety.

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36

Georgiou, Maria, Simone Wöckel, Vera Konstanzer, Sebastian Dechert, Michael John, and Franc Meyer. "Structural Variations in Tetrasilver(I) Complexes of Pyrazolate-bridged Compartmental N-Heterocyclic Carbene Ligands." Zeitschrift für Naturforschung B 64, no. 11-12 (2009): 1542—s1554. http://dx.doi.org/10.1515/znb-2009-11-1238.

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A set of pyrazole-bridged bis(imidazolium) compounds [H3L1]X2 - [H3 L4]X2 (L1 = 3,5-bis[1-(tert-butyl)imidazolium-1-ylmethyl]-1H-pyrazole; L2 = 3,5-bis[1-(tert-butyl)imidazolium- 1-ylmethyl]-4-phenyl-1H-pyrazole; L3 = 3,5-bis[1-(1-adamantyl)imidazolium-1-ylmethyl]-1Hpyrazole; L4 = 3,5-bis[1-(1-adamantyl)imidazolium-1-ylmethyl]-4-phenyl-1H-pyrazole; X = Cl−, BF4 − or PF6 −) has been prepared, and three compounds have been characterized by X-ray crystallography. The unique [H3L4][H2L4](PF6)3 features a dimeric face-to-face arrangement of two molecules due to the involvement of both the pyrazole-

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37

Mathur, Suvigya, and Sartaj Tabassum. "New homodi-and heterotrinuclear metal complexes of Schiff base compartmental ligand: interaction studies of copper complexes with calf thymus DNA." Open Chemistry 4, no. 3 (2006): 502–22. http://dx.doi.org/10.2478/s11532-006-0020-6.

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AbstractThe new homodinuclear complexes 1–4 of the type [LMII 2Cl2], heterotrinuclear complexes 5 and 6 of the type [LMII 2SnIVCl6] where M = CuII, MnII, CoII, NiII and CuII and NiII, respectively have been synthesized and characterized by elemental analysis and various spectroscopic techniques. The homodinuclear complexes possess two different environments (N2 and N2O2donor sets) for holding the metal ions. The metal ion in N2 set exhibits square planar geometry with two chloride ions in the inner sphere but rhombic structure is found in tetradentate N2O2 Schiff base cavity while in heterotri

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38

Atkins, Andrew J., Daniel Black, Rachel L. Finn, et al. "Synthesis and structure of mononuclear and binuclear zinc(ii) compartmental macrocyclic complexes." Dalton Transactions, no. 9 (March 25, 2003): 1730–37. http://dx.doi.org/10.1039/b210936k.

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39

Zude, Zhang, Sun Yan, Zheng Tao, and Su Qingde. "Spectral study of the structure of compartmental complexes of europium and copper." Journal of Molecular Structure 440, no. 1-3 (1998): 9–13. http://dx.doi.org/10.1016/s0022-2860(97)00226-3.

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40

Mautner, Franz, Roland Fischer, Mark Spell, Andres Acevedo, Diana Tran, and Salah Massoud. "Metal(II) Complexes of Compartmental Polynuclear Schiff Bases Containing Phenolate and Alkoxy Groups." Crystals 6, no. 8 (2016): 91. http://dx.doi.org/10.3390/cryst6080091.

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41

Chandrasekhar, Vadapalli, Amit Chakraborty, and E. Carolina Sañudo. "Ferrocene-based compartmental ligand for the assembly of neutral ZnII/LnIII heterometallic complexes." Dalton Transactions 42, no. 37 (2013): 13436. http://dx.doi.org/10.1039/c3dt51432c.

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42

Visinescu, Diana, Augustin M. Madalan, Victor Kravtsov, et al. "New tetranuclear copper(II) complexes obtained by using compartmental and exo-dentate ligands." Polyhedron 22, no. 10 (2003): 1385–89. http://dx.doi.org/10.1016/s0277-5387(03)00113-x.

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43

Guha, Averi, Tanmay Chattopadhyay, Nanda Dulal Paul, et al. "Radical Pathway in Catecholase Activity with Zinc-Based Model Complexes of Compartmental Ligands." Inorganic Chemistry 51, no. 16 (2012): 8750–59. http://dx.doi.org/10.1021/ic300400v.

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44

Ackermann, Jens, Franc Meyer, and Hans Pritzkow. "Unusual Oligonuclear Copper(II) Complexes based on a Bis( tridentate) Compartmental Pyrazolate Ligand." Zeitschrift f�r anorganische und allgemeine Chemie 630, no. 15 (2004): 2627–31. http://dx.doi.org/10.1002/zaac.200400346.

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45

Fenton, David E. "ChemInform Abstract: Structural Diversity in Oligonuclear Nickel(II) Complexes of Unsymmetrical Compartmental Ligands." ChemInform 33, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.200249206.

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46

Chakraborty, Amit, Prasenjit Bag, Eric Rivière, Talal Mallah, and Vadapalli Chandrasekhar. "Assembly of heterobimetallic NiII–LnIII (LnIII = DyIII, TbIII, GdIII, HoIII, ErIII, YIII) complexes using a ferrocene ligand: slow relaxation of the magnetization in DyIII, TbIII and HoIII analogues." Dalton Trans. 43, no. 23 (2014): 8921–32. http://dx.doi.org/10.1039/c4dt00209a.

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Structure and characterization of a new family of dinuclear 3d–4f heterobimetallic complexes [LNi(H<sub>2</sub>O)(μ-OAc)Ln(NO<sub>3</sub>)<sub>2</sub>]·CH<sub>3</sub>CN; {Ln = Dy<sup>III</sup> (1), Tb<sup>III</sup> (2), Ho<sup>III</sup> (3), Gd<sup>III</sup> (4), Er<sup>III</sup> (5), Y<sup>III</sup> (6)} using a ferrocene-based compartmental ligand H<sub>2</sub>L.

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47

Topor, Alexandru, Dan Liu, Catalin Maxim, et al. "Design of FeIII–LnIII binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis." Journal of Materials Chemistry C 9, no. 33 (2021): 10912–26. http://dx.doi.org/10.1039/d1tc00894c.

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48

Mousavi, Maliheh, Virginie Béreau, Jean-Pierre Costes, Carine Duhayon, and Jean-Pascal Sutter. "Oligomeric and polymeric organizations of potassium salts with compartmental Schiff-base complexes as ligands." CrystEngComm 13, no. 19 (2011): 5908. http://dx.doi.org/10.1039/c1ce05127j.

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49

Andruh, Marius, Diana G. Branzea, Ruxandra Gheorghe, and Augustin M. Madalan. "Crystal engineering of hybrid inorganic–organic systems based upon complexes with dissymmetric compartmental ligands." CrystEngComm 11, no. 12 (2009): 2571. http://dx.doi.org/10.1039/b909476h.

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50

Adams, Harry, Scott Clunas, David E. Fenton, and Sharon E. Spey. "Dinuclear nickel(ii) complexes of reduced asymmetric compartmental ligandsIn memoriam Noel McAuliffe (1941–2002)." Dalton Transactions, no. 4 (January 15, 2003): 625–30. http://dx.doi.org/10.1039/b209437c.

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