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Dissertations / Theses on the topic 'Complex compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Malgas, Rehana. "The application of novel multinuclear catalysts derived from dendrimeric ligands in the polymerization and oligomerization of unsaturated hydrocarbons." Thesis, University of the Western Cape, 2007. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_7858_1183727432.

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<p>G1 and G2 dendrimeric salicylaldimine ligands containing both substituted and unsubstituted aryl rings were synthesized via a Schiff base condensation of the appropriate salicylaldehyde and the peripheral amino groups of the corresponding G1 and G2 polypropyleneimine dendrimers. The new ligands were characterized using FTIR, 1H NMR and 13C NMR spectroscopy, elemental analysis and ESI mass spectrometry. The dendrimeric ligands were converted to multinuclear nickel complexes by reaction with nickelacetate. The metal complexes were characterized by FTIR spectroscopy, elemental analysis and ESI

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2

Kean, Suzanna Dawn. "Modified cyclodextrins and their complexes." Title page, contents and abstract only, 1999. http://web4.library.adelaide.edu.au/theses/09PH/09phk243.pdf.

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Addendum page pasted onto front end paper. Copies of author's previously published articles inserted. Includes bibliographical references. Investigates the factors that govern the stability of cyclodextrin inclusion complexes with a range of systematically modified cyclodextrins.

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3

Pyrka, Gloria Jean. "Electrochemical and structural studies of one-dimensional copper charge transfer complexes." Diss., The University of Arizona, 1988. http://hdl.handle.net/10150/184493.

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The electrochemistry of solid electrodes of charge transfer complexes of tetracyanoquinodimethane (TCNQ) and copper complexes with nitrogen containing chelates, such and dipyridylamine (dpaH), bipyridyl (bpy) and 1,10-dimethyl-2,9-phenanthroline (dmp), has been investigated with cyclic voltammetry. Pressed pellet electrodes of these complexes exhibit a broad electrochemically stable region. The oxidative and reductive breakdown reactions involve solid state reactions into the bulk electrode. These materials also act as electron mediators for glucose oxidation in glucose oxidase modified electr

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4

Leung, Wai-ho Wilkie. "Synthesis, reactivities and electrochemistry of ruthenium and osmium oxo complexes with polypyridine ligands /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12474332.

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5

Hui, Ching-sum, and 許正心. "Study of photosensitizing properties in some rhenium diimine complex containing polymers." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B26666650.

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6

McQuaid, Michael James. "Spectroscopic characterization of metal-based complexes and metal-based complex oxidation processes." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/30334.

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7

Stander, Elzet. "Nuwe reaksies van gedeprotoneerde Fischer-tipe karbeenkomplekse." Thesis, Link to the online version, 2005. http://hdl.handle.net/10019/1222.

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8

Salam, Md Abdus. "Studies in vanadium chemistry /." Title page, contents and summary only, 1986. http://web4.library.adelaide.edu.au/theses/09PH/09phs1595.pdf.

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9

Simpson, Linda. "Trivalent group 13 metal complexes of N-substituted-3-hydroxy-2-methyl-4-pyridinones." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/28885.

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The compounds tris(N-ռ-propyl-3-hydroxy-2-methyl-4-pyridinonato) aluminum(III), -gallium(III), and -indium(III) and tris(N-ռ-butyl-3-hydroxy-2-methyl-4-pyridinonato)aluminum(III), -gallium(III), and -indium(III) were synthesized. All six compounds were prepared via the metal template effect. They were characterized by IR, FAB-MS, ¹H NMR, ²⁷Al NMR, and elemental analysis. Three of the six complexes were studied by single-crystal X-ray diffraction. They formed trihydrates, unlike their N-methyl and N-ethyl analogues, which formed dodecahydrates. The ռ-butyl complex Al(C₁₀H₁₄N0₂)₃‧3H₂0 (1) and ռ-

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10

Birtles, John. "Solution based studies of tetranuclear (mu₄-oxo)-Cu(II) complexes /." Thesis, Connect to Dissertations & Theses @ Tufts University, 2004.

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Thesis (Ph.D.)--Tufts University, 2004.<br>The [mu] in the title is depicted as a Greek letter mu, followed by a subscript 4. Adviser: Samuel P. Kounaves. Submitted to the Dept. of Chemistry. Includes bibliographical references. Access restricted to members of the Tufts University community. Also available via the World Wide Web;

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11

Mitchell, S. H. "Structural studies on some complex compounds containing imines." Thesis, Cardiff University, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332450.

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12

Ko, Hyunjin. "Structural and electronic investigations of complex intermetallic compounds." [Ames, Iowa : Iowa State University], 2008.

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13

Williams, Michael Lloyd. "New aspects of organometallic chemistry /." Title page, contents and abstract only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phw725.pdf.

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14

梁偉豪 and Wai-ho Wilkie Leung. "Synthesis, reactivities and electrochemistry of ruthenium and osmium oxo complexes with polypyridine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231883.

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15

Khotseng, Lindiwe Eudora. "Separation and speciation of biodegradable complexes using capillary zone electrophoresis." Thesis, Stellenbosch : Stellenbosch University, 2004. http://hdl.handle.net/10019.1/50092.

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Thesis (PhD)--Stellenbosch University, 2004.<br>ENGLISH ABSTRACT: Separation of the metal ions Cu2+, Pb2+, Cd2+ Mn2+, Cr3+, Fe3+ and Zn2+ with poly ethylenediamine tetra-acetic acid (EDTA), ethylenediamine disuccinic acid ([S,S']- EDDS) and ethylenediamine dimalonic acid (EDDM) was performed by Capillary Electrophoresis. The electropherograms obtained by Capillary Electrophoresis were validated with a speciation model Joint Expert Speciation System (JESS). Excellent agreement was observed for the speciation diagrams for these species with the pH curves determined by capillary electroph

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16

Khotseng, Lindiwe Eudora. "Separation and speciation of biodegradable complexes using capillary zone electrophersis." Thesis, Stellenbosch : Stellenbosch University, 2004. http://hdl.handle.net/10019.1/52052.

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Thesis (PhD)--Stellenbosch University, 2004.<br>ENGLISH ABSTRACT: Separation of the metal ions Cu2+, Pb2+, Cd2+ Mn2+, Cr3+, Fe3+ and Zn2+ with poly ethylenediamine tetra-acetic acid (EDTA), ethylenediamine disuccinic acid ([S,S']- EDDS) and ethylenediamine dimalonic acid (EDDM) was performed by Capillary Electrophoresis. The electropherograms obtained by Capillary Electrophoresis were validated with a speciation model Joint Expert Speciation System (JESS). Excellent agreement was observed for the speciation diagrams for these species with the pH curves determined by capillary electroph

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17

Liao, Jing-Piin. "Investigation of Copper-Natural Ligand Complexes by RP-HPLC Photodiode Array UV-VIS and Fluorescence Detection." Thesis, University of North Texas, 1992. https://digital.library.unt.edu/ark:/67531/metadc332502/.

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In this study, reversed phase HPLC with dual UV photodiode (PDA) and fluorescence (FL) detection were used to investigate copper complexes with fulvic, caffeic, vanillic, salicylic, and adipic acids. Application of the RE method provided valuable information on the retention behavior and spectral characteristics of FA and model compounds. Even though the method was only applicable to VA, the use of the PDA detector allowed the UV-V is scanning of the separated peaks. This allowed the comparison between the UV-Vis spectra of uncomplexed species. The overall results provide an experimental frame

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18

Cheung, Ka Man. "Syntheses and reactivity of cyclometalated iridium and ruthenium complexes /." View abstract or full-text, 2005. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202005%20CHEUNG.

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19

Yip, Sung-kong. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes strategies towards supramolecular architectures and host guest chemistry /." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B31941734.

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20

Tong, Wai-yip, and 唐煒燁. "Luminescent platinum(II) complexes containing dianionic tetradentate ligands having mixed oxygen, nitrogen and carbon donor atoms and platinum(II)-containing phosphorescent polymers : synthesis, photophysical properties and material applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/198829.

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21

Lam, Ngai Man. "Synthesis, crystal structures, and reactivity of ruthenium and osmium nitrido complexes /." View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202006%20LAMN.

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22

Habtu, Michael M. "A study of the transport, extraction and co-ordination chemistry of a number of thiourea ligands with a series of transition and post-transition metal ions." Thesis, Stellenbosch : Stellenbosch University, 2003. http://hdl.handle.net/10019.1/97374.

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Thesis (MSc)--Stellenbosch University, 2003.<br>ENGLISH ABSTRACT: In this study, a number of mono- and di-substituted acyl(aroyl)thioureas were investigated for potential application as specific carriers (ionophores) for the transport and extraction of Ag(l) from a mixture of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(lI) ions. The experimental arrangement for the transport experiments employed a liquid membrane set up involving a 3-phase system - 2 aqueous phases (source and receiving phase) separated by a chloroform membrane incorporating the ligand. Competitive metal ion transport

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23

Yohannes, Desta Yonas. "Synthesis and electrochemistry of biodegradable ligands - iminodiglutaric acid and iminoglutaricsuccinic acid - and their complexes with selected metal ions (Zn²⁺, Cd²⁺, Cu²⁺)." Thesis, Stellenbosch : Stellenbosch University, 2004. http://hdl.handle.net/10019.1/50112.

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Thesis (MSc)--Stellenbosch University, 2004.<br>ENGLISH ABSTRACT: Two new potentially biodegradable aminopolycarboxylic acid ligands, iminodiglutaric acid tetra sodium salt (IDG-4Na) and iminoglutaricsuccinic acid tetra sodium salt (IGS- 4Na), were synthesized in reasonably good yield and purity. The commercially unavailable precursor for the two ligands, ethyl p-aminoglutarate, was synthesised in high yield and purity, and together with the two ligands were fully characterized by means of melting point measurements and various spectrometric techniques CH-NMR, 13C-NMR, MS and IR). For

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24

Ng, Fei-yeung. "Structure and properties of self-assembled coordination compounds : homoleptic d10-metal aryl/alkylacetylides, ruthenium n-heterocycles and picolinates." View the Table of Contents & Abstract, 2006. http://sunzi.lib.hku.hk/hkuto/record/B36587126.

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25

Clarke, Ronald James. "Kinetic and equilibrium studies of cyclodextrin-azo dye inclusion complexes /." Title page, contents and abstract only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phc5992.pdf.

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Thesis (Ph. D.)--University of Adelaide, Dept. of Physical and Inorganic Chemistry, 1985.<br>Offprints of two author's journal articles inserted at end of the v. Includes bibliographical references (leaves 10-12).

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26

Ng, Fei-yeung, and 吳飛洋. "Structure and properties of self-assembled coordination compounds: homoleptic d10-metal aryl/alkylacetylides, ruthenium n-heterocyclesand picolinates." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B37878566.

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27

Wolfgong, William J. "Solvent and Ionic Complexes of the Calix[6]arenes." Thesis, University of North Texas, 1997. https://digital.library.unt.edu/ark:/67531/metadc278436/.

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One of the more attractive attributes of calixarenes is their wide variety of possible conformations and hence cavity shapes. However, the flexibility that allows this long-range benefit gives rise to major synthetic challenges when working with the larger members of the family. O-alkylations have proven to be the most widely employed synthetic routes to "functionalization" of the calixarenes, and these have shown a dependence upon both solvent and the metal ions present. Surprisingly, there have been no structural data presented concerning the complexes between the simple unsubstituted calix[

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28

Tikilili, Phumza Vuyokazi. "Biodegradation of complex aromatic compounds in nuclear process water." Diss., University of Pretoria, 2010. http://hdl.handle.net/2263/25979.

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Nuclear energy generation results in the production of effluents and radioactive waste that are very difficult to treat and dispose. A considerable fraction of nuclear waste is discharged in the form of complex mixtures of hazardous organic compounds and metallic radionuclides. The most serious pollution is caused by polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls that are very difficult to remove from the environment. The nuclear industry faces certain challenges related to treatment and safe disposal of these mixed radioactive organic wastes due to the toxicity and reca

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29

Liu, Li. "The chemistry of luminescent mercury (II) alkynyl complexes and their platinum (II) and gold (I) counterparts." HKBU Institutional Repository, 2005. http://repository.hkbu.edu.hk/etd_ra/627.

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30

Lock, Julia. "Cyclodextrins : molecular wheels for supramolecular chemistry /." Title page, table of contents and abstract only, 2004. http://web4.library.adelaide.edu.au/theses/09PH/09phl8131.pdf.

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Thesis (Ph.D.)--University of Adelaide, School of Chemistry and Physics, Discipline of Chemistry, 2005?<br>"July 2004" Includes copies of publications by the author as appendix. Includes bibliographical references.

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31

Tang, Yongping. "Investigation of the stereochemistry of macrocyclic ligand complexes: [Ni(tetramethylcyclam)][superscript]2+ and [brace]Co(Me[subscript]6[14]dieneN[subscript]4)CI[subscript]2+[brace]." Thesis, Georgia Institute of Technology, 1990. http://hdl.handle.net/1853/26951.

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32

Foster, Keith A. "Preparative, structural, and electrochemical investigation of metal complexes of tetraazamacrocyclic ligands containing tertiary amine donors." Diss., Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/30370.

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33

Pan, Jie. "Organometallic porphyrin based complexes for photophysical and biological application." HKBU Institutional Repository, 2016. https://repository.hkbu.edu.hk/etd_oa/331.

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This thesis focuses on the development of porphyrin-based complexes as multi-modal bio-imaging probes. Detailed studies of photophysical and biological properties were included.;In chapter 1, the general background of porphyrin and its derivatives, their structure specialty, synthetic methods, photophysical properties, and applications in biological system were described.;Curcumin-bridged porphyrin-copper complex (Por-Cu-Cur) which can permeate through the high blood-brain barrier, accumulate fast in brain tissues, and emit brilliant and stable two photon excited emission has been developed. A

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34

Bolte, Stephanie Elizabeth. "Vanadium-51 solid state NMR of inorganic vanadium(V) dipicolinic acid complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 76 p, 2009. http://proquest.umi.com/pqdweb?did=1889078501&sid=7&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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35

Ghebregziabiher, Berhe Haile. "Synthesis of chiral thiourea ligands and their transition metal complexes." Thesis, Stellenbosch : Stellenbosch University, 2003. http://hdl.handle.net/10019.1/53610.

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Thesis (MSc)--Stellenbosch University, 2003.<br>ENGLISH ABSTRACT: Modification of chitosan with benzoylisothiocyanate was attempted, however due to solvent problem the study was left incomplete till appropriate solvent is designed. N,N-diethyl-N -camphanoylthiourea (HL8), N-piperidyl-N '-camphanoylthiourea (HL9), N-pyrrolidyl-N -camphanoylthiourea (HL10) and N,N-diethyl-N -adamantylcarbonyl thiourea (HL11)have been synthesised and characterised for the first time. Two of these ligands HL8 and HL11, were used to form a number of transition metal complexes, namely H30+{fae-[Co(L8-S,Obn, c

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36

Pinkes, John R. "The attempted synthesis of novel bis (quadridentate) niobium (IV) complexes and the analyses of the products resulting from the attempted synthesis of tetrakis (8-hydroxyquinolinato) niobium (IV) /." Online version of thesis, 1989. http://hdl.handle.net/1850/10690.

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37

Hung, Ling-ling. "Novel luminescent cyclometalated gold (III) alkynyls design, synthesis, photophysics and their multinuclear assemblies /." Click to view the E-thesis via HKUTO, 2007. http://sunzi.lib.hku.hk/hkuto/record/B3963453X.

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38

何國強 and Kwok-keung Paul Ho. "Molecular structures and physicochemical properties of some chiral andhelical transition metal complexes with polypyridines and tetradentateanionic ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B31234884.

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39

He, Xiaoming. "Design, synthesis and characterization of alkynyl- and thiolato- gold (I) complexes with various receptor groups for host-guest chemistry." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43571979.

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40

Cheung, Kai-leung. "Syntheses and luminescence studies of di- and polynuclear gold(1) and copper(1) complexes, design strategies towards metalloreceptors and mixed-metal complexes /." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B23736136.

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41

Shea, James Christopher 1964. "Hyperfine structure in the microwave spectra of the iodine fluorides iodine heptafluoride and iodine pentafluoride and of the weakly bound complex hydrochloric acid...nitrous oxide." Thesis, The University of Arizona, 1989. http://hdl.handle.net/10150/277178.

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A pulsed-beam fourier transform microwave spectrometer was used to measure the rotational spectra of iodine heptafluoride, iodine pentafluoride, and the weakly bound complex, HCl...NNO. For IF7, only five rotational transitions were observed, and no resolvable hyperfine structure was detected. Based on this data, the A, B, and C rotational constants were determined to be 1746(3) MHz, 1732.0(8) MHz, and 1553.0(2) MHz, respectively. The existence of a pure rotational spectrum confirms that this molecule undergoes polar distortions. Twenty-two hyperfine components of the IF5 spectrum were recorde

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42

Larkin, Scott A. "Synthesis and Supermolecular Chemistry of Biphenylthioatogold(I)Phosphine Complexes." Fogler Library, University of Maine, 2007. http://www.library.umaine.edu/theses/pdf/LarkinSA2007.pdf.

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43

Öberg, Mattias U. L. "Health risk assessment of dioxin-like compounds in complex samples /." Stockholm : Karolinska inst, 2003. http://diss.kib.ki.se/2003/91-7349-692-8.

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44

Lu, Huanjun. "Complex self-assembly of amphiphilic and polyphilic liquid crystalline compounds." Thesis, University of Sheffield, 2017. http://etheses.whiterose.ac.uk/19027/.

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One of the most intriguing properties of liquid crystalline compounds is their ability to selfassembly into nanoscale entities, in the simplest cases as layers, columns, or spherical micelles, leading to their many applications in fields such as microelectronics, nanofabrication, medical etc. Understanding how such self-assembly can be controlled through molecular design is hence of paramount importance. Factors such as molecular shape and flexibility, interactions between different moieties, polarity and chirality all contribute to determine the exact mode of self-assembly of such a compound,

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45

Suginome, Michinori. "Bis-silylation of Unsaturated Compounds Catalyzed by Palladium-Isocyanide Complex." Kyoto University, 1993. http://hdl.handle.net/2433/74624.

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46

Balkus, Kenneth John. "Metal complex faciliated transport and activation of molecular oxygen." Gainesville, FL, 1986. http://www.archive.org/details/metalcomplexfaci00balk.

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47

Sinha, Pankaj. "Phosphorescent Emissions of Coinage Metal-Phosphine Complexes: Theory and Photophysics." Thesis, University of North Texas, 2009. https://digital.library.unt.edu/ark:/67531/metadc12200/.

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The major topics discussed are all relevant to the bright phosphorescent emissions of coinage metal complexes (Cu(I), Ag(I) and Au(I)) with an explanation of the theoretical background, computational results and ongoing work on the application in materials and optoelectronic devices. Density functional computations have been performed on the majority of the discussed complexes and determined that the most significant distortion that occurs in Au(I)-phosphine complexes is a near and beyond a T-shape within the P-Au-P angle when the complexes are photoexcited to the lowest phosphorescent excited

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48

Duan, Gongping. "Design, synthesis, and photophysics and photochromic study of dithienylethene-containing heterocyclic derivatives and N-heterocyclic carbene-ruthenium (II) complexes." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B44248246.

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49

Myburgh, Jolanda. "Synthesis and characterization of novel platinum complexes : their anticancer behaviour." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/d1018621.

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In this dissertation novel non-leaving groups were employed to synthesize platinum complexes which can contribute to the understanding or improvement of anticancer action. These complexes basically consist of (NS)-chelate and amineplatinum complexes. Bidentate (NS)-donor ligands were used as non-leaving ligands in the syntheses of platinum(II) complexes with iodide, chloride, bromide and oxalate anions as leaving groups. These complexes were synthesized and studied since many questions regarding the interaction of sulfur donors and platinum still exists. These relate to thermodynamic and kinet

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50

Haskard, Carolyn Anne. "Multiple recognition by modified cyclodextrins." Title page, contents and abstract only, 1996. http://web4.library.adelaide.edu.au/theses/09PH/09phh349.pdf.

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Copy of author's previously published article inserted. Includes bibliographies This thesis studies the B-cyclodextrins which are modified at the primary rim to incorporate an additional coordination or hydrophobic recognition site. The natural organic host, cyclodextrin and its chemically modified derivatives, are utilised as hosts for the inclusion of a range of guests. The study contributes to understanding the fundamental factors influencing selectivity of binding and the stability of the complexes formed when a guest is bound essentially at two recognition sites.

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