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Journal articles on the topic 'Complexe homochiral'

Author: Grafiati

Published: 21 December 2024

Last updated: 31 July 2025

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1

Kaźmierczak, Magdalena, Łukasz Dobrzycki, Maciej Dranka, and Paweł Horeglad. "The Effect of Alkyl Substituents on the Formation and Structure of Homochiral (R*,R*)-[R2Ga(µ-OCH(Me)CO2R′)]2 Species—Towards the Factors Controlling the Stereoselectivity of Dialkylgallium Alkoxides in the Ring-Opening Polymerization of rac-Lactide." Molecules 30, no. 1 (2025): 190. https://doi.org/10.3390/molecules30010190.

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Building on our previous studies, which have demonstrated that homochiral propagating species—(R*,R*)-[Me2Ga(µ-OCH(Me)CO2R)]2—were crucial for the heteroselectivity of [Me2Ga(µ-OCH(Me)CO2Me)]2 in the ring-opening polymerization (ROP) of racemic lactide (rac-LA), we have investigated the effect of alkyl groups on the structure and catalytic properties of dialkylgallium alkoxides in the ROP of rac-LA. Therefore, we have isolated and characterized the rac-[R2Ga(µ-OCH(Me)CO2Me]2 (R = Et (1), iPr (2) and rac-[R2Ga(µ-OCH(Me)C5H4N]2 (R = Et (3), iPr (4)) complexes, to demonstrate the effect of alkyl

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2

Ma, Ting-Ting, Xiao-Peng Sun, Zi-Shuo Yao, and Jun Tao. "Homochiral versus racemic polymorphs of spin-crossover iron(ii) complexes with reversible LIESST effect." Inorganic Chemistry Frontiers 7, no. 5 (2020): 1196–204. http://dx.doi.org/10.1039/c9qi01590f.

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3

Roithová, Jana. "Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin in the gas phase." Collection of Czechoslovak Chemical Communications 74, no. 2 (2009): 243–54. http://dx.doi.org/10.1135/cccc2008185.

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Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin (1) with butan-2-amine (2) are studied by means of the DFT calculations and mass spectrometry. The calculations reveal that 2 is bound via proton to only one nitrogen atom of the bicyclic base 1. The homochiral complex is favored by about 4 kJ/mol over the heterochiral complex. For a more loosely bound ion-pair complex [(1H)I(2H)]+ of the protonated bases 1 and 2 with an iodine counterion the energy difference drops to about 2 kJ/mol. Chiral effects in the formation of [(1)H(2)]+ are studied by the collision-induced dissociation

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4

Liu, Yu-Ling, Jia-Zhen Ge, Zhong-Xia Wang, and Ren-Gen Xiong. "Metal–organic ferroelectric complexes: enantiomer directional induction achieved above-room-temperature homochiral molecular ferroelectrics." Inorganic Chemistry Frontiers 7, no. 1 (2020): 128–33. http://dx.doi.org/10.1039/c9qi01197h.

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5

Howard, Philip W., G. Richard Stephenson, and Stephen C. Taylor. "Convenient access to homochiral tricarbonyliron complexes." Journal of the Chemical Society, Chemical Communications, no. 24 (1988): 1603. http://dx.doi.org/10.1039/c39880001603.

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6

Sapotta, Meike, Peter Spenst, Chantu R. Saha-Möller, and Frank Würthner. "Guest-mediated chirality transfer in the host–guest complexes of an atropisomeric perylene bisimide cyclophane host." Organic Chemistry Frontiers 6, no. 7 (2019): 892–99. http://dx.doi.org/10.1039/c9qo00172g.

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7

Gao, Wan-Qing, Yin-Shan Meng, Chun-Hua Liu, Yao Pan, Tao Liu, and Yuan-Yuan Zhu. "Spin crossover and structural phase transition in homochiral and heterochiral Fe[(pybox)2]2+ complexes." Dalton Transactions 48, no. 19 (2019): 6323–27. http://dx.doi.org/10.1039/c8dt04893b.

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8

Míšek, Jiří, Miloš Tichý, Irena G. Stará, Ivo Starý, and Detlef Schröder. "Preferential formation of homochiral silver(I) complexes upon coordination of two aza[6]helicene ligands to Ag+ ions." Collection of Czechoslovak Chemical Communications 74, no. 2 (2009): 323–33. http://dx.doi.org/10.1135/cccc2008184.

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By means of selective deuterium labeling of 1-aza[6]helicene combined with resolution of the enantiomers, chiral discrimination in silver(I)-bound dimers of the type [LAgL′]+ is probed by electrospray mass spectrometry. The analysis of the results reveals a pronounced preference for the formation of homochiral dimers (P,P and M,M, respectively) over the statistically preferred heterochiral variant (P,M), which is fully consistent with previous data about the formation of homochiral dimers in the condensed phase. Further, competitive experiments with mixtures of 1- and 2-aza[6]helicene suggest

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9

Kataeva, Olga, Kirill Metlushka, Kamil Ivshin, et al. "Supramolecular chirality in the crystals of mononuclear and polymeric cobalt(ii) complexes with enantiopure and racemic N-thiophosphorylated thioureas." CrystEngComm 23, no. 10 (2021): 2081–90. http://dx.doi.org/10.1039/d0ce01871f.

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The control of stereochemistry in Co(ii) complexes was provided by additional pyridine and pyrazine ligands. 1D and 2D supramolecular homochiral arrangements in racemic crystals of mononuclear complexes are transferred to their polymeric counterparts.

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10

Jiao, Luyang, Mengying Du, Yameng Hou, Yuan Ma, and Xianglei Kong. "Homochiral or Heterochiral: A Systematic Study of Threonine Clusters Using a FT ICR Mass Spectrometer." Symmetry 14, no. 1 (2022): 86. http://dx.doi.org/10.3390/sym14010086.

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The strong chiral preferences of some magic clusters of amino acids have attracted continually increasing interests due to their unique structures, properties and possible roles in homochirogenesis. However, how chirality can influence the generation and stability of cluster ions in a wild range of cluster sizes is still unknown for most amino acids. In this study, the preference for threonine clusters to form homochiral and heterochiral complex ions has been investigated by electrospray ionization (ESI) mass spectrometry. Abundant cluster [Thrn+mH]m+ ions (7 ≤ n ≤ 78, 1 ≤ m ≤ 5) have been obs

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11

Fowler, Jonathan M., Flora L. Thorp-Greenwood, Stuart L. Warriner, Charlotte E. Willans, and Michaele J. Hardie. "M12L8 metallo-supramolecular cube with cyclotriguaiacylene-type ligand: spontaneous resolution of cube and its constituent host ligand." Chemical Communications 52, no. 56 (2016): 8699–702. http://dx.doi.org/10.1039/c6cc04130b.

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12

Ren, Min, Zhong-Li Xu, Ting-Ting Wang, et al. "Homochiral mononuclear Dy-Schiff base complexes showing field-induced double magnetic relaxation processes." Dalton Transactions 45, no. 2 (2016): 690–95. http://dx.doi.org/10.1039/c5dt03800f.

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Homochiral mononuclear complexes (Et<sub>3</sub>NH)[Dy((R,R)/(S,S)-3-NO<sub>2</sub>salcy)<sub>2</sub>] (1R/1S), where 3-NO<sub>2</sub>salcyH<sub>2</sub> is N,N′-(1,2-cyclohexanediylethylene)bis(3-nitrosalicylideneiminato), are reported, and their optical and magnetic behaviors are studied.

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13

Horie, Miki, Naoki Ousaka, Daisuke Taura, and Eiji Yashima. "Chiral tether-mediated stabilization and helix-sense control of complementary metallo-double helices." Chemical Science 6, no. 1 (2015): 714–23. http://dx.doi.org/10.1039/c4sc02275k.

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Control of the helical sense and stability enhancement of Pt<sup>II</sup>-linked double helices by interstrand cross-linking using chiral diphosphines and complete homochiral self-sorting is demonstrated.

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14

García-Rubiño, M. E., M. C. Núñez-Carretero, D. Choquesillo-Lazarte, J. M. García-Ruiz, Yolanda Madrid, and J. M. Campos. "Stereospecific alkylation of substituted adenines by the Mitsunobu coupling reaction under microwave-assisted conditions." RSC Adv. 4, no. 43 (2014): 22425–33. http://dx.doi.org/10.1039/c4ra01968g.

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The Mitsunobu reaction under microwave-assisted conditions reveals a complete inversion of the stereogenic centre of the secondary alcohol giving an alkylated purine linked to a homochiral six-membered ring.

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15

Lincoln, Per, and Bengt Nordén. "Binding of dimeric homochiral ruthenium complexes to DNA." Journal of Inorganic Biochemistry 59, no. 2-3 (1995): 156. http://dx.doi.org/10.1016/0162-0134(95)97264-q.

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16

Bagi, Péter, Réka Herbay, Gábor Györke, et al. "Preparation of Palladium(II) Complexes of 1-substituted-3-phospholene Ligands and their Evaluation as Catalysts in Hydroalkoxycarbonylation." Current Organic Chemistry 23, no. 25 (2020): 2873–79. http://dx.doi.org/10.2174/1385272823666191204151311.

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: A series of palladium(II) complexes incorporating 1-substituted-3-methyl-3- phospholenes as the P-ligands were prepared from phospholene oxides by deoxygenation followed by complexation with PdCl2(PhCN)2. The two 1-substituted-3-methyl-3- phospholene ligands were trans position to each other in the Pd(II)-complexes. As the ligands contain a P-stereogenic center, the Pd-complexes were obtained as a 1:1 mixture of two stereoisomers, the homochiral (R,R and S,S) and the meso (R,S) forms, when racemic starting materials were used. An optically active Pd-complex containing (R)-1-propyl- 3-phospho

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17

Weller, Michael G. "The Mystery of Homochirality on Earth." Life 14, no. 3 (2024): 341. http://dx.doi.org/10.3390/life14030341.

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Homochirality is an obvious feature of life on Earth. On the other hand, extraterrestrial samples contain largely racemic compounds. The same is true for any common organic synthesis. Therefore, it has been a perplexing puzzle for decades how these racemates could have formed enantiomerically enriched fractions as a basis for the origin of homochiral life forms. Numerous hypotheses have been put forward as to how preferentially homochiral molecules could have formed and accumulated on Earth. In this article, it is shown that homochirality of the abiotic organic pool at the time of formation of

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18

Breu, Josef, and Andrea Zwicknagel. "Chirale Erkennung bei Tris(diimin)-Metallkomplexen, 10. Vergleich der intermolekularen Wechselwirkungs- und Packungsmuster in der Reihe [Cr(bpy)3]n+(PF6)n (n = 0 – 3) / Chiral Recognition among Tris(diimine)-metal Complexes, 10. Comparison of Intermolecular Interactions and Packing Patterns in the Series [Cr(bpy)3]n+(PF6)n (n = 0–3)." Zeitschrift für Naturforschung B 59, no. 9 (2004): 1015–25. http://dx.doi.org/10.1515/znb-2004-0911.

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Due to their conformational rigidity, the corrugated, chiral molecular structure, and the variability in the central metal and its oxidation state, [M(bpy)3]n+ complexes are particularly well suited to study chiral recognition and to identify intermolecular interaction patterns in the crystalline state. For [Cr(bpy)3]n+(PF6)n (n=0 - 3) four oxidation states are readily accessible which allows to investigate the influence of the cation/anion ratio on the observed packing patterns.The crystal structures of all four oxidation states are governed by so-called ‘π-π-interactions’. Apparently, in mol

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19

Kataeva, Olga, Kirill Metlushka, Zilya Yamaleeva, et al. "Chirality Control in Crystalline Ni(II) Complexes of Thiophosphorylated Thioureas." Crystals 9, no. 12 (2019): 606. http://dx.doi.org/10.3390/cryst9120606.

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Chirality control over the formation of Ni(II) complexes with chiral thiophosphorylated thioureas was achieved via breaking the symmetry of nickel coordination geometry by the introduction of the pyridine ligand, while centrosymmetric meso-complexes are formed from racemic ligands in case of square-planar nickel coordination. Centrosymmetric heterochiral arrangement is observed in crystals of ligands themselves through N–H⋅⋅⋅S hydrogen bonds in intermolecular dimers. Molecular homochirality in tetragonal pyramidal complexes is further transferred to supramolecular homochiral arrangement via ke

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20

Kumar, Navnita, Sadhika Khullar, and Sanjay K. Mandal. "Controlling the self-assembly of homochiral coordination architectures of CuII by substitution in amino acid based ligands: synthesis, crystal structures and physicochemical properties." Dalton Transactions 44, no. 12 (2015): 5672–87. http://dx.doi.org/10.1039/c4dt03643c.

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In this paper we report six chiral ligands based on l-tyrosine, l-serine and l-phenylalanine and their homochiral Cu<sup>II</sup> complexes to study the effect of various substitutions in the ligands on the formation of diverse coordination architectures.

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21

Nugent, William A., and Richard L. Harlow. "Early Transition Metal Alkoxide Complexes Bearing Homochiral Trialkanolamine Ligands." Journal of the American Chemical Society 116, no. 14 (1994): 6142–48. http://dx.doi.org/10.1021/ja00093a011.

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22

Liu, Cai-Ming, Xiang Hao, and Xi-Li Li. "Assembly of Homochiral Magneto-Optical Dy6 Triangular Clusters by Fixing Carbon Dioxide in the Air." Molecules 29, no. 14 (2024): 3402. http://dx.doi.org/10.3390/molecules29143402.

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A new hydrazone Schiff base bridging ligand (H2LSchiff (E)-N′-((1-hydroxynaphthalen-2-yl)methylene)pyrazine-2-carbohydrazide) and L/D-proline were used to construct a pair of homochiral Dy6 cluster complexes, [Dy6(CO3)(L-Pro)6(LSchiff)4(HLSchiff)2]·5DMA·2H2O (L-1, L-HPro = L-proline; DMA = N,N-dimethylacetamide) and [Dy6(CO3)(D-Pro)6(LSchiff)4(HLSchiff)2]·5DMA·2H2O (D-1, D-HPro = D-proline), which show a novel triangular Dy6 topology. Notably, the fixation of CO2 in the air formed a carbonato central bridge, playing a key role in assembling L-1/D-1. Magnetic measurements revealed that L-1/D-1

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23

Fraschetti, Caterina, Marco Pierini, Claudio Villani, Francesco Gasparrini, Antonello Filippi, and Maurizio Speranza. "Gas-phase structure and relative stability of proton-bound homo- and heterochiral clusters of tetra-amide macrocycles with amines." Collection of Czechoslovak Chemical Communications 74, no. 2 (2009): 275–97. http://dx.doi.org/10.1135/cccc2008155.

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The structure, stability, and CID pattern of proton-bound homochiral and heterochiral complexes, formed in the gas phase by the combination of two molecules of a chiral macrocyclic tetra-amide and an amine B, i.e. CH3NH2, (CH3)2NH, or (S)-(–)-1-phenylethylamine, have been examined by ESI-ITMS-CID mass spectrometry. With B = CH3NH2, the CID pattern is characterized by the predominant loss of B, accompanied by a much less extensive release of one tetra-amide molecule. With (S)-(–)-1-phenylethylamine, loss of a tetra-amide molecule efficiently competes with loss of B. Finally, with (CH3)2NH, loss

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24

Malinkina, O. N., and A. B. Shipovskaya. "Energy of Salt Formation and Supramolecular Ordering of Chitosan L- and D-Ascorbates." Высокомолекулярные соединения А 65, no. 5 (2023): 351–61. http://dx.doi.org/10.31857/s2308112023600059.

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Using two samples of chitosan (D-glucan) with viscosity-average molecular mass 40 × 103 and 200 × 103 as the example, the influence of diastereomer form (L- and D-) of ascorbic acid on the energetics of formation, structure, and supramolecular ordering of hetero- (D‒L) and homochiral (D‒D) polymer–acid salt complexes has been studied. It has been found that heat effect during the interaction of chitosan with L-ascorbic acid in aqueous medium and degree of protonation of the (D‒L)-salts are lower in comparison with D-isomer of the acid. The homochiral (D‒D)-salts, in contrast to the heterochira

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25

Qin, Ling, Qing Hu, Yang Wu, Jia-Le Cai, and Yun-Yun Li. "Three novel Co(ii)/Ni(ii)-based coordination polymers as efficient heterogeneous catalysts for dye degradation." CrystEngComm 20, no. 28 (2018): 4042–48. http://dx.doi.org/10.1039/c8ce00860d.

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Three novel Co(ii)/Ni(ii)-based coordination polymers have been synthesized and characterized. Compound 2 shows a rare 2D + 2D heterogeneous framework. Compound 3 is a chiral 0-D molecular complex driven by the solvent-assisted homochiral helix. The photocatalytic oxidation activities and mechanism have been studied.

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26

Brewer, Greg, Raymond J. Butcher, and Peter Zavalij. "Use of Pyrazole Hydrogen Bonding in Tripodal Complexes to Form Self Assembled Homochiral Dimers." Materials 13, no. 7 (2020): 1595. http://dx.doi.org/10.3390/ma13071595.

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The 3:1 condensation of 5-methyl-1H-pyrazole-3-carboxaldehyde (MepyrzH) with tris(2-aminoethyl)amine (tren) gives the tripodal ligand tren(MePyrzH)3. Aerial oxidation of a solution of cobalt(II) with this ligand in the presence of base results in the isolation of the insoluble Co(tren)(MePyrz)3. This complex reacts with acids, HCl/NaClO4, NH4ClO4, NH4BF4, and NH4I to give the crystalline compounds Co(tren)(MePyrzH)3(ClO4)3, {[Co(tren)(MePyrzH0.5)3](ClO4)1.5}2 {[Co(tren)(MePyrzH0.5)3](BF4)1.5}2 and [Co(tren)(MePyrzH)3][Co(tren)(MePyrzH)3]I2. The latter three complexes are dimeric, held together

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27

Wen, He-Rui, Xin-Rong Xie, Sui-Jun Liu, et al. "Homochiral luminescent lanthanide dinuclear complexes derived from a chiral carboxylate." RSC Advances 5, no. 119 (2015): 98097–104. http://dx.doi.org/10.1039/c5ra14559g.

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A family of chiral Ln<sub>2</sub> clusters based on a chiral monocarboxylate ligand has been successfully constructed via a diffusion method, and Eu, Tb and Dy analogues display good luminescent properties.

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28

Kostyanovsky, Remir G., Konstantin A. Lyssenko, and Vasily R. Kostyanovsky. "Homochiral and pseudoracemic 3,3- and 1,2-dimethyldiaziridine–silver nitrate complexes." Mendeleev Communications 10, no. 2 (2000): 44–46. http://dx.doi.org/10.1070/mc2000v010n02abeh001261.

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29

Li, Gao, Xiaobing Xi, Weimin Xuan, Taiwei Dong, and Yong Cui. "Homochiral helical coordination polymers of metallosalen complexes with tunable pitches." CrystEngComm 12, no. 8 (2010): 2424. http://dx.doi.org/10.1039/c001121e.

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30

Yin, Jun, and Ronald L. Elsenbaumer. "Syntheses of Homochiral Multinuclear Ru Complexes Based on Oligomeric Bibenzimidazoles." Inorganic Chemistry 46, no. 17 (2007): 6891–901. http://dx.doi.org/10.1021/ic062148a.

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31

Schrader, Malcolm E. "Polypeptide formation on polar mineral surfaces: possibility of complete chirality." International Journal of Astrobiology 16, no. 1 (2015): 10–13. http://dx.doi.org/10.1017/s1473550415000427.

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AbstractIn the present work, it is shown that thermodynamically feasible polymerization of cyanomethanol, which can be formed from formaldehyde and hydrogen cyanide, can lead to synthesis of polypeptides as well as to the previously reported synthesis of RNA. If the polymerization takes place on a one-dimensional feature of a mineral, such as for example a crack on its surface, the concept of quasi-chirality is introduced to describe the adsorbed polypeptide. This, in principle, would lead to formation of proteins that are completely homochiral in their alpha carbon groups. The concept of quas

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32

Matveevskaya, Vladislava, Dmitry Pavlov, and Andrei Potapov. "Iridium(III) and Rhodium(III) Half-Sandwich Coordination Compounds with 11H-Indeno[1,2-b]quinoxalin-11-one Oxime: A Case of Spontaneous Resolution of Rh(III) Complex." Inorganics 10, no. 11 (2022): 179. http://dx.doi.org/10.3390/inorganics10110179.

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Two half-sandwich iridium(III) and rhodium(III) complexes with 11H-indeno[1,2-b]quinoxalin-11-one oxime (IQ-1) ligand were prepared by the reaction of the proligand with [M(Cp*)Cl2]2 (M = Ir, Rh) dimers. The reaction between IQ-1 and [Ir(Cp*)Cl2]2 in methanol gave the complex [Ir(Cp*)(IQ-1)Cl] (1), which crystallized in a centrosymmetric space group as a true racemate. Whereas complex [Rh(Cp*)(IQ-1)Cl] (2) in the form of a racemic conglomerate was obtained by the reaction of [Rh(Cp*)Cl2]2 and IQ-1 in methanol. The crystal structures of complexes 1 and 2 (R and S enantiomers) were determined by

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33

Fox, Allison C., Jason D. Boettger, Eve L. Berger, and Aaron S. Burton. "The Role of the CuCl Active Complex in the Stereoselectivity of the Salt-Induced Peptide Formation Reaction: Insights from Density Functional Theory Calculations." Life 13, no. 9 (2023): 1796. http://dx.doi.org/10.3390/life13091796.

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The salt-induced peptide formation (SIPF) reaction is a prebiotically plausible mechanism for the spontaneous polymerization of amino acids into peptides on early Earth. Experimental investigations of the SIPF reaction have found that in certain conditions, the l enantiomer is more reactive than the d enantiomer, indicating its potential role in the rise of biohomochirality. Previous work hypothesized that the distortion of the CuCl active complex toward a tetrahedral-like structure increases the central chirality on the Cu ion, which amplifies the inherent parity-violating energy differences

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34

Alcock, Nathaniel W., Graham A. Pike, Christopher J. Richards, and Susan E. Thomas. "Generation of homochiral quaternary carbon centres from (vinylketenimine)tricarbonyliron(0) complexes." Tetrahedron: Asymmetry 1, no. 8 (1990): 531–34. http://dx.doi.org/10.1016/s0957-4166(00)80542-x.

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35

Zhai, Halei, Yan Quan, Li Li, Xiang-Yang Liu, Xurong Xu, and Ruikang Tang. "Spontaneously amplified homochiral organic–inorganic nano-helix complexes via self-proliferation." Nanoscale 5, no. 7 (2013): 3006. http://dx.doi.org/10.1039/c3nr33782k.

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36

Wang, Ruihu, Lijin Xu, Jianxin Ji, et al. "Metal-Directed Stereoselective Syntheses of Homochiral Complexes ofexo-Bidentate Binaphthol Derivatives." European Journal of Inorganic Chemistry 2005, no. 4 (2005): 751–58. http://dx.doi.org/10.1002/ejic.200400659.

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37

Zee, Chih-Te, Calina Glynn, Marcus Gallagher-Jones, et al. "Homochiral and racemic MicroED structures of a peptide repeat from the ice-nucleation protein InaZ." IUCrJ 6, no. 2 (2019): 197–205. http://dx.doi.org/10.1107/s2052252518017621.

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The ice-nucleation protein InaZ from Pseudomonas syringae contains a large number of degenerate repeats that span more than a quarter of its sequence and include the segment GSTSTA. Ab initio structures of this repeat segment, resolved to 1.1 Å by microfocus X-ray crystallography and to 0.9 Å by the cryo-EM method MicroED, were determined from both racemic and homochiral crystals. The benefits of racemic protein crystals for structure determination by MicroED were evaluated and it was confirmed that the phase restriction introduced by crystal centrosymmetry increases the number of successful t

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38

Očić, Marko, and Lidija Androš Dubraja. "Intermolecular Interactions in Molecular Ferroelectric Zinc Complexes of Cinchonine." Crystals 14, no. 11 (2024): 978. http://dx.doi.org/10.3390/cryst14110978.

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The use of chiral organic ligands as linkers and metal ion nodes with specific coordination geometry is an effective strategy for creating homochiral structures with potential ferroelectric properties. Natural Cinchona alkaloids, e.g., quinine and cinchonine, as compounds with a polar quinuclidine fragment and aromatic quinoline ring, are suitable candidates for the construction of molecular ferroelectrics. In this work, the compounds [CnZnCl3]·MeOH and [CnZnBr3]·MeOH, which crystallize in the ferroelectric polar space group P21, were prepared by reacting the cinchoninium cation (Cn) with zinc

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39

Setsune, Jun-ichiro, Miku Kawama, and Takeshi Nishinaka. "Helical binuclear CoII complexes of pyriporphyrin analogue for sensing homochiral carboxylic acids." Tetrahedron Letters 52, no. 15 (2011): 1773–77. http://dx.doi.org/10.1016/j.tetlet.2011.02.013.

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40

Zheng, Xiao-Dan, Yan-Long Hua, Ren-Gen Xiong, Jia-Zhen Ge, and Tong-Bu Lu. "Cyano-Bridged Homochiral Heterometallic Helical Complexes: Synthesis, Structures, Magnetic and Dielectric Properties." Crystal Growth & Design 11, no. 1 (2011): 302–10. http://dx.doi.org/10.1021/cg101314j.

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41

Uozumi, Yasuhiro. "Heterogeneous Asymmetric Catalysis in Water with Amphiphilic Polymer-Supported Homochiral Palladium Complexes." Bulletin of the Chemical Society of Japan 81, no. 10 (2008): 1183–95. http://dx.doi.org/10.1246/bcsj.81.1183.

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42

Ren, Dong-Hong, Xiao-Li Sun, Ling Gu, Dan Qiu, Zaijun Li, and Zhi-Guo Gu. "A family of homochiral spin-crossover iron(II) imidazole Schiff-base complexes." Inorganic Chemistry Communications 51 (January 2015): 50–54. http://dx.doi.org/10.1016/j.inoche.2014.11.006.

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43

Uozumi, Yasuhiro. "Asymmetric allylic substitution of cycloalkenyl esters in water with an amphiphilic resin-supported chiral palladium complex." Pure and Applied Chemistry 79, no. 9 (2007): 1481–89. http://dx.doi.org/10.1351/pac200779091481.

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A novel homochiral phosphine ligand, (3R,9aS)[2-aryl-3-(2-diphenylphosphino)phenyl]tetrahydro-1H-imidazo[1,5-a]indole-1-one, was designed, prepared, and anchored onto an amphiphilic polystyrene-poly(ethylene glycol) copolymer (PS-PEG) resin. Catalytic asymmetric substitution of a racemic mixture of cycloalkenyl esters with carbon, nitrogen, and oxygen nucleophiles was achieved in water as the single reaction medium under heterogeneous conditions by using the PS-PEG resin-supported palladium-imidazoindole phosphine complex to give optically active substituted cycloalkenes with up to 99 % ee.

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44

Wölper, Christoph, Sara Durán Ibáńez, and Peter G. Jones. "Amine-rich Silver Complexes of rac-trans-1,2-Diaminocyclohexane." Zeitschrift für Naturforschung B 65, no. 10 (2010): 1249–57. http://dx.doi.org/10.1515/znb-2010-1012.

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The use of the diamine rac-trans-1,2-diaminocyclohexane (LL) as a major component of the solvent system allows the isolation of crystalline silver complexes with higher ratios of LL to silver (up to 4 : 1, compared to the previously obtained 1 : 1 in ethanolic solution). The complexes obtained and crystallographically characterized were (LL)2AgNO3 (1), (LL)3Ag(OAc)(H2O)2 (2) and (LL)4AgBr(H2O)3 (3). Additionally, the silver-free compounds (LL)・(H2O) (4) and (LL)3・HCl (5) were obtained as by-products. Complex 1 is a chain polymer with one bridging and one terminal LL ligand; the chains are homo

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Kühne, Irina A., Andrew Ozarowski, Aizuddin Sultan, et al. "Homochiral Mn³⁺ Spin-Crossover Complexes: A Structural and Spectroscopic Study." Inorganic Chemistry 61, no. 8 (2022): 3458–71. http://dx.doi.org/10.1021/acs.inorgchem.1c03379.

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Wang, Yong-Tao, Gui-Mei Tang, Wen-Zhu Wan, et al. "New homochiral ferroelectric supramolecular networks of complexes constructed by chiral S-naproxen ligand." CrystEngComm 14, no. 10 (2012): 3802. http://dx.doi.org/10.1039/c2ce25138h.

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Howell, James A. S., Andrew G. Bell, Paula J. O'Leary, et al. "Access to Homochiral Acyclic (diene)Fe(CO)3 Complexes Containing Electron Donor Substituents." Organometallics 13, no. 5 (1994): 1806–12. http://dx.doi.org/10.1021/om00017a043.

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48

Lamberts, Kevin, Mihaela-Diana Şerb та Ulli Englert. "Unexpected proline coordination in the copper chain polymer [Cu(μ-Cl)2(μ-DL-proline-κ2O:O′)]1∞". Acta Crystallographica Section C Structural Chemistry 71, № 4 (2015): 271–75. http://dx.doi.org/10.1107/s205322961500426x.

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Abstract:

Incatena-poly[copper(II)-di-μ-chlorido-μ-proline-κ2O:O′], [CuCl2(C5H9NO2)]n, two symmetry-independent metal cations adopt distorted octahedral coordination, typical ford9Jahn–Teller systems. Each chloride bridge is involved in both a short and a very long interaction with a CuIIcentre. The centrosymmetric crystal structure contains homochiral chains of opposite handedness which extend along the shortest lattice parameter (i.e. a). TheO:O′-bridging coordination mode of proline, although a common motif for such complexes in general, is remarkable for CuII; the vast majority of amino acid derivat

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Boer, Stephanie A., and David R. Turner. "Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality." Chemical Communications 51, no. 98 (2015): 17375–78. http://dx.doi.org/10.1039/c5cc07422c.

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50

Uozumi, Yasuhiro, Kazuhiko Kato, and Tamio Hayashi. "Asymmetric aza-Claisen rearrangement of allyl imidates catalyzed by homochiral cationic palladium(II) complexes." Tetrahedron: Asymmetry 9, no. 6 (1998): 1065–72. http://dx.doi.org/10.1016/s0957-4166(98)00059-7.

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