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Dissertations / Theses on the topic 'Complexe nitruro'

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Published: 4 June 2021

Last updated: 4 February 2022

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1

Gourdon, André. "Synthèse et étude structurale de clusters de fer contenant un hétéroatome du type carbure, nitrure, phosphure." Paris 6, 1986. http://www.theses.fr/1986PA066404.

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2

Mouton, Olivier. "Étude du comportement biologique de bis (N-ethoxy, N-ethyldithiocarbamato) nitruro 99mTc(V), 99mTcN-NOET, un nouveau marqueur de la perfusion myocardique." Université Joseph Fourier (Grenoble ; 1971-2015), 1997. http://www.theses.fr/1997GRE10296.

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Les traceurs radioactifs emetteurs de rayonnements sont les seuls outils disponibles permettant, par simple injection intraveineuse, l'analyse in vivo de la repartition regionale du debit sanguin coronaire. A l'heure actuelle, le radioelement utilise en medecine nucleaire est le thallium-201, un cation monovalent, considere comme un analogue du potassium. Cependant, le thallium-201 presente certains inconvenients (dosimetre et cout de production eleves). C'est pourquoi les recherches se sont orientees vers la synthese de molecules originales marquees au technetium-99m, les complexes techneties

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3

Belhadj-Tahar, Abdel Hafid. "Complexes du technétium-99 et du rhénium avec de nouveaux ligands polydentates dérivés de l'acide dithiocarboxylique : développement de radiopharmaceutiques oxo et nitrurotechnétiés pour l'évaluation des débits sanguins régionaux." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10001.

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Les travaux presentes dans ce memoire s'inserent dans un projet pluridisciplinaire (chimie de coordination, radiochimie et medecine) visant a la mise au point de nouveaux radiopharmaceutiques oxo- et nitruro-techneties utilisables pour l'evaluation des debits sanguins locaux. Dans la premiere partie, l'auteur rend compte de la synthese et la caracterisation de nouveaux ligands vecteurs polydentes derivant de l'acide aminocyclopentene-dithiocarboxylique et susceptibles d'offrir au metal differentes combinaisons de sites donneurs s#mn#no#o. Dans la deuxieme partie sont decrites les protocoles de

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4

Howick, Christopher J. "Nitrato-complexes of some tri- and tetravalent metals." Thesis, University of Nottingham, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252684.

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5

Lam, Hon-wah. "Synthesis, reactivities and photochemistry of osmium-nitrido complexes /." [Hong Kong : University of Hong Kong], 1990. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12922444.

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6

DAMIANO, JEAN-PIERRE. "Synthese et reactivite de complexes nitrato du fer." Nice, 1995. http://www.theses.fr/1995NICE4886.

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Le travail reporte dans ce memoire concerne la synthese et l'evaluation des proprietes oxydantes de complexes nitrato du fer concus pour l'activation et le transfert de l'oxygene moleculaire sur des composes organiques. Afin de definir l'environnement optimal autour du fer, deux types de ligands ont ete testes: un bidente dissymetrique, 2-(diphenylphosphine oxyde)pyridine (opph#2#p#y) et un ligand bidente susceptible de participer comme relais electronique a l'acte catalytique, 1,1'-bis(diphenylphosphine oxyde)ferrocene (fcp#2o#2) et son oxyde fc#+p#2o#2. Les complexes mono et dinitrates du li

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7

Leung, Ka-yan Sarana. "Complexes of iminato, nitrido, imido, and hydrazido ruthenium of osmium porphyrins /." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25212072.

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8

García, Serres Ricardo. "Mononuclear (nitrido)- and (nitrosyl)iron complexes with functionalised tetraazamacrocyclic ligands." [S.l.] : [s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=971273987.

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9

Harris, Nigel James. "Synthesis and internal redox reactions of oximic and nitroso complexes." Thesis, London Metropolitan University, 1985. http://repository.londonmet.ac.uk/3311/.

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M(cup)n complexes have been prepared (M = Cu, Ni, Fe, Co, Mn, or Zn ; n=2, M-=Fe ; n=3 cupH = cupferron) and structures have been proposed on the basis of spectroscopic, thermal and magnetic techniques. Their behaviour towards the Lewis bases pyridine, triphenyl- phosphine and hydroxylamine has been investigated. All of the M(cup)2 complexes, except when M = Zn or Fe, affords adducts on reaction with pyridine, whereas the complex Fe(cup)3 underwent an internal redox reaction. Internal redox behaviour was also observed when the complexes Cu(cup)2 and Fe(cup)3 were treated with triphenylphosphin

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10

Lam, Ngai Man. "Synthesis, crystal structures, and reactivity of ruthenium and osmium nitrido complexes /." View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202006%20LAMN.

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11

梁嘉茵 and Ka-yan Sarana Leung. "Complexes of iminato, nitrido, imido, and hydrazido ruthenium of osmium porphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243307.

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12

Parkin, David. "Decomposition pathways of an S-nitroso sugar, S-nitroso dithiols and the reaction of S-nitrosothiols with iron complexes." Thesis, Durham University, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251214.

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13

Desfontaines, Marie. "Mise en forme, usinage à cru, déliantage et frittage de pièces complexes en nitrure d'aluminium." Lyon, INSA, 2000. http://www.theses.fr/2000ISAL0056.

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Le nitrure d'aluminium (AlN) est une céramique intéressante par ses bonnes propriétés de conductivité thermique. Les coût de matière première et de fabrication sont cependant élevés. La pratique de l'usinage à cru sur les pièces après mise en forme et avant frittage est un moyen de réduire les coûts. Nous avons travaillé sur des pièces crues mises en forme par compaction uniaxiale de granules fabriquées par atomisation d'une barbotine. L'objectif de cette étude a donc été de mettre au point une composition de granules et un procédé d'élaboration optimisés pour produire des pièces crues en AlN

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14

VEYRET, JEAN-BERNARD. "Comportement a l'oxydation de ceramiques a base de nitrure de silicium en atmosphere complexe air/so#2." Limoges, 1989. http://www.theses.fr/1989LIMO0078.

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L'etude de l'influence de la microstructure de nitrures de silicium frittes sur les lois de comportement dans l'air charge de gaz sulfureux a haute temperature a permis de preciser dans un premier temps leur resistance a l'oxydation en atmosphere exempte de soufre. On peut distinguer deux grands types de materiaux, ceux comportant des phases vitreuses residuelles resultant de l'emploi d'ajouts alcalino-terreux et ceux beaucoup plus rares, presentant des phases secondaires cristallines precipitant aisement; c'est le cas de l'yttrium utilise comme ajout de frittage. Une atmosphere complexe air-s

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15

林曉楓 and Hiu-fung Lam. "Photophysical and photochemical properties of oxo and nitrido complexes of osmium(VI)." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B42576490.

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16

Lam, Hiu-fung. "Photophysical and photochemical properties of oxo and nitrido complexes of osmium(VI)." Click to view the E-thesis via HKUTO, 2001. http://sunzi.lib.hku.hk/hkuto/record/B42576490.

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17

何毅雯 and Ngai-man Emmie Ho. "The chemistry of ruthenium carbonyl clusters containing nitrene and nitrido ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B3124029X.

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18

Ho, Ngai-man Emmie. "The chemistry of ruthenium carbonyl clusters containing nitrene and nitrido ligands /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21982351.

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19

Daniel, Leonidia Maria de Castro. "Remoção de nitrogênio via nitrito em reator operado em bateladas seqüenciais contendo biomassa imobilizada e aeração intermitente." Universidade de São Paulo, 2005. http://www.teses.usp.br/teses/disponiveis/18/18138/tde-07072006-101536/.

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Um reator de leito fixo, preenchido com biomassa imobilizada em espuma de poliuretano, foi operado em bateladas seqüenciais, alimentado com substrato sintético com concentração de nitrogênio amoniacal de 125, 250, 500 e 40 mg/L. O principal objetivo da pesquisa foi verificar a possibilidade de se promover a nitrificação curta no reator submetido à aeração intermitente, com a formação de nitrito como principal composto intermediário, seguida da desnitrificação. Para concentração de nitrogênio amoniacal de 125 e 250 mg/L o perfil temporal das concentrações de nitrogênio monitoradas evidenciou qu

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20

Lees, Audrey. "Nitrosation and other studies of iron sulphur nitrosyl complexes." Thesis, University of St Andrews, 1993. http://hdl.handle.net/10023/14976.

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A structure for the selenium analogue of the Roussin's black anion, [Fe4S3(NO)7]− had been proposed, on the basis of 15N.N.M.R. spectroscopy results, as being similar to that of the sulphur molecule. X-Ray crystallography was carried out on a crystal of Ph4AS Fe4Se 3(NO)7]− to determine whether this conclusion was correct. The crystal, Mr=1053.67, was triclinic of space group p1̅ with a=13.122 (9), b=13.936 (9), c=9.908 (8)A, α =99.30 (6), β =97.04 (6), γ=71.94 (5)° and Z=2. This structure was refined from diffractometer data to an R value of 0.047 and was found to consist of isolated Ph4As+ c

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21

Korswagen, Richard, and Manfred L. Ziegler. "Formación de un complejo BIS-µ-Nitreno por reacción de azidoformiato de etilo con BIS." Revista de Química, 2013. http://repositorio.pucp.edu.pe/index/handle/123456789/99178.

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En trabajos anteriores [ 1-4] hemos reportado algunas reacciones de generadores - o precursores de nitrenos con sustratos organometálicos, habiendo sido éstos, generalmente, complejos mononucleares del Mo o del W. Los precursores de nitrenos utilizados fueron azidas de ácidos y ésteres carboxílicos así como azidas organometálicas del tipo R 3 MN 3 (M= Si, Ge, Sn), y la mayoría de las reacciones llevadas a cabo fueron de tipo fotolítico (liberación de N 2 a partir de la azida bajo irradiación ultravioleta, con la consiguiente posible formación de nitrenos libres).

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22

Isci, Umit. "Novel N-bridged diiron phthalocyanine complexes : synthesis, characterization and application in oxidation." Phd thesis, Université Claude Bernard - Lyon I, 2010. http://tel.archives-ouvertes.fr/tel-00881309.

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The synthetic approach was developed for the preparation of N-bridged diiron phthalocyanines substituted by different electron-withdrawing alkylsulfonyl substituents. Six novel phthalocyanines bearing small (methylsulfonyl, ethylsulfonyl and hexylsulfonyl) and bulky (t-butylsulfonyl, adamantylsulfonyl and cyclohexylsulfonyl) substituents have been prepared and characterized by electrospray ionization mass spectrometry (ESI-MS), UV-Vis, FT-IR and EPR. Two complexes (with hexylsulfonyl and t-butylsulfonyl substituents) were characterized in addition by Mössbauer techniques, X-ray photoelectron s

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23

Emirandetti, Amanda. "Influencia do MHC classico (Ia) e não-classico (Ib) e da oxido nitrico sintase induzivel (iNOS) na reação glial e na plasticidade das sinapses apos axotomia periferica." [s.n.], 2009. http://repositorio.unicamp.br/jspui/handle/REPOSIP/316435.

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Orientador: Alexandre Leite Rodrigues de Oliveira<br>Tese (doutorado) - Universidade Estadual de Campinas. Instituto de Biologia<br>Made available in DSpace on 2018-08-15T19:14:30Z (GMT). No. of bitstreams: 1 Emirandetti_Amanda_D.pdf: 10405230 bytes, checksum: 86b2578427126b457b8a4ebeac01a1f5 (MD5) Previous issue date: 2009<br>Resumo: Após uma lesão de um nervo periférico, astrócitos e microglia tornam-se reativos, desencadeando a chamada gliose reativa. Adicionalmente, uma porcentagem significativa dos botões sinápticos em íntima relação com os motoneurônios é eliminada, sendo este mecanism

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24

趙永康 and Wing-hong Chiu. "Syntheses, reactivities and electrochemistry of high-valent amido, imido and nitrido complexes of ruthenium." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1995. http://hub.hku.hk/bib/B3123477X.

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25

Chiu, Wing-hong. "Syntheses, reactivities and electrochemistry of high-valent amido, imido and nitrido complexes of ruthenium /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B17538397.

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26

Barner, Claudia Jane. "Part I. Coordination chemistry of high-valent osmium polyanionic chelating ligand complexes with imine, imido and nitrido ligands. : Part II. Asymmetric hydrogenation using a resolved chiral scandium hydride complex /." Diss., Pasadena, Calif. : California Institute of Technology, 1990. http://resolver.caltech.edu/CaltechETD:etd-06112007-095040.

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27

Richter-Addo, George Bannerman. "Synthetic utilization of the redox properties of some group 6 organometallic nitrosyl complexes." Thesis, University of British Columbia, 1988. http://hdl.handle.net/2429/29174.

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The redox behavior of a series of organometallic complexes containing Cp'M(NO) groups (Cp' = ƞ⁵-C₅H₅(Cp) or ƞ⁵-C₅Me₅(Cp*) ; M = Mo or W) has been investigated both by cyclic voltammetry and by chemical means. The neutral 16-electron Cp'Mo(N0)X₂ compounds (X = CL, Br or I) undergo a single, essentially reversible, one-electron reduction in CH₂CL₂/O.1M [n-Bu₄N]PF₆ at relatively low potentials (<-0.1 V vs SCE). The electrochemically observed reductions can be effected on a preparative scale by employing CP₂C0 as the chemical reductant. The isolable 17-electron [Cp'Mo (NO)X₂]•⁻ radical anions are

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28

Kidwell, Andy R. "Factors influencing the metathesis of group VI transition metal complexes containing Nitrido and Alkylidyne Ligands." The Ohio State University, 2002. http://rave.ohiolink.edu/etdc/view?acc_num=osu1413370830.

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29

Righez, Rosane Claumann. "Síntese e caracterização de novos complexos binucleares como ligante H2BPBPMP nitro substituído." reponame:Repositório Institucional da UFSC, 2013. http://repositorio.ufsc.br/handle/123456789/103055.

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Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-Graduação em Química.<br>Made available in DSpace on 2013-07-16T02:47:37Z (GMT). No. of bitstreams: 1 275447.pdf: 1306263 bytes, checksum: d84b6cd5ee3af7a9bcf499eeb82713dd (MD5)<br>Por exercerem papéis de fundamental importância na manutenção da vida, por seu alto poder catalítico, e por sua alta especificidade e seletividade, a obtenção de informações sobre as propriedades e o modo de ação das enzimas, tem sido de grande interesse para químicos e bioquímicos de todo o mun

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30

Chau, Chung-Nin. "Studies on binuclear iron nitrosyl complexes containing bridging alkylsulfide or diphenylphosphide /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487261553059339.

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31

張碧玉 and Pik-yuk Christine Cheung. "Crystal structure analysis of imido, nitrido and oxo complexes of rhenium (V), osmium (VI) and ruthenium (III) and some complexes oftrinuclear gold (I)." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1991. http://hub.hku.hk/bib/B31210211.

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32

Stüker, Tony [Verfasser]. "Metal-Ligand Multiple Bonds : Nitrido and Fluoroimido Complexes of High-Valent Late Transition Metals / Tony Stüker." Berlin : Freie Universität Berlin, 2021. http://d-nb.info/1237685842/34.

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33

Viswanathan, Subha. "Nitro- and oxazoline-derivatized antennas structural and photophysical characterization of their lanthanide complexes /." Related electronic resource:, 2007. http://proquest.umi.com/pqdweb?did=1362530571&sid=2&Fmt=2&clientId=3739&RQT=309&VName=PQD.

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34

Mabad, Bouchra. "Modelisation du site d'oxydation de l'eau en photosynthese : complexes du manganese avec des bases de schiff polydentees." Toulouse 3, 1987. http://www.theses.fr/1987TOU30103.

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35

Cheung, Pik-yuk Christine. "Crystal structure analysis of imido, nitrido and oxo complexes of rhenium (V), osmium (VI) and ruthenium (III) and some complexes of trinuclear gold (I) /." [Hong Kong : University of Hong Kong], 1991. http://sunzi.lib.hku.hk/hkuto/record.jsp?B13138327.

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36

Bastos, Tanira Matutino. "Avalia??o da atividade anti-Trypanosoma cruzi de nitrosilo/nitro complexos de rut?nio em modelos experimentais in vitro e in vivo." Universidade Estadual de Feira de Santana, 2013. http://localhost:8080/tede/handle/tede/259.

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Submitted by Natalie Mendes (nataliermendes@gmail.com) on 2015-11-12T22:45:09Z No. of bitstreams: 1 Vers?o corrigida - vers?o final.pdf: 1423044 bytes, checksum: 6989a397b0d890ed1cb80eaaf86dcd52 (MD5)<br>Made available in DSpace on 2015-11-12T22:45:09Z (GMT). No. of bitstreams: 1 Vers?o corrigida - vers?o final.pdf: 1423044 bytes, checksum: 6989a397b0d890ed1cb80eaaf86dcd52 (MD5) Previous issue date: 2013-03-27<br>Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPES<br>Nifurtimox and benznidazole have been used to treat Chagas? disease since the 70s. Both drugs can induce s

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37

Colomban, Cédric. "Défluoration oxydante des aromatiques per- et polyfluorés catalysée par des complexes binucléaires à fer hémiques." Thesis, Lyon 1, 2014. http://www.theses.fr/2014LYO10254/document.

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L'oxydation de liaisons C-H fortes et la transformation de liaisons carbone-halogène dans des conditions douces sont particulièrement difficiles et représentent un challenge pour les chimistes. Ces réactions sont réalisées dans la nature par l'intermédiaire des métalloenzymes. Dans le but de reproduire cette chimie efficace, nous développons au laboratoire des catalyseurs inspirés de deux des plus puissantes monooxygenases : les cytochromes P450 et la méthane monooxygenase soluble. Il s'agit de complexes binucléaires où deux atomes de fer sont pontés par un atome et stabilisés par des ligands

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38

Krahe, Oliver Moritz [Verfasser]. "Experimental and theoretical studies of mononuclear high-valent nitrido-iron and oxo-iron complexes / Oliver Moritz Krahe." Bonn : Universitäts- und Landesbibliothek Bonn, 2016. http://d-nb.info/1107184711/34.

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39

錢國輝 and Kwok-fai Chin. "Syntheses, electrochemistry and photophysical and photochemical properties of some high-valent oxo, nitrido and amido complexes ofosmium." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1995. http://hub.hku.hk/bib/B31234756.

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40

Leung, Hiu-chi, and 梁曉詞. "Syntheses, reactivities and biological activities of ruthenium azido, nitrido and nitrosyl complexes supported by tetradentate tertiaryamine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B43703732.

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41

Furlanetto, Marcos. "Coacervação complexa de compostos nitro-heterocíclicos. Obtenção de microcápsulas e avaliação da atividade antichagásica." Universidade de São Paulo, 2005. http://www.teses.usp.br/teses/disponiveis/9/9135/tde-22012018-123339/.

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A Doença de Chagas atualmente atinge a vida de aproximadamente 18 milhões de portadores do parasita. Assim, este trabalho, parte de um estudo mais amplo, teve como objetivo avaliar a atividade biológica de compostos nitro-heterocíclicos com estrutura análoga à nifuroxazida, 5-nitro-2-furfurilideno 4-hidroxibenzidrazida, frente à cepa Y de Trypanosoma cruzi antes e após a sua microencapsulação por coacervação complexa de gelatina e goma-arábica, que, em geral, se mostram pouco solúveis nos meios e concentração empregados em testes farmacológicos, indicando a necessidade do desenvolvimento de um

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42

Bai, Guangcai. "New methods for the syntheses of amido, imido, nitrido and dinitrogen metal complexes and organometallic hydrides and oxides." Doctoral thesis, [S.l.] : [s.n.], 2001. http://webdoc.sub.gwdg.de/diss/2002/bai/bai.pdf.

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43

Chin, Kwok-fai. "Syntheses, electrochemistry and photophysical and photochemical properties of some high-valent oxo, nitrido and amido complexes of osmium /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B17506128.

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44

Leung, Hiu-chi. "Syntheses, reactivities and biological activities of ruthenium azido, nitrido and nitrosyl complexes supported by tetradentate tertiary amine ligands." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43703732.

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45

Kothe, Thomas. "Reductive Binding of C‒O and Nitro Substrates at a Pyrazolate-Bridged Preorganized Dinickel Scaffold." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://hdl.handle.net/21.11130/00-1735-0000-0005-1524-B.

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46

Carron, Véronique. "Etude du mécanisme d'oxydation des formes dissoutes du ruthénium dans les solutions d'acide nitrique : application à l'élimination du ruthénium des solutions de dissolution des combustibles nucléaires irradiés." Université Joseph Fourier (Grenoble), 2000. http://www.theses.fr/2000GRE10227.

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Le ruthenium est l'un des produits de fission les plus genants lors du retraitement des combustibles nucleaires. Son elimination en amont du procede purex, apres la dissolution du combustible dans l'acide nitrique, est envisagee. Le procede d'elimination ici etudie est l'electrovolatilisation. Il consiste a oxyder en ruo 4 volatil les especes dissoutes du ru : les complexes nitrates et nitres du ruthenium nitrosyle runo 3 +. La 1 e r e partie de ce travail concerne l'etude de l'oxydation directe du runo 3 + sur anode d'or ou de platine par voltammetrie cyclique et spectroscopie infrarouge et u

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47

Wätjen, Florian. "Rhenium and Osmium PNP Pincer Complexes for Nitrogen Fixation and Nitride Transfer." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2019. http://hdl.handle.net/21.11130/00-1735-0000-0005-12D8-3.

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48

陳沛明 and Pui-ming Chan. "Reactivities of nitrido- and oxo-ruthenium(VI) and nitridoosmium(VI) complexes containing chelating multianionic ligands and 1,4,7-trimethyl-1,4,7-triazacyclonoane." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31238208.

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Chan, Pui-ming. "Reactivities of nitrido- and oxo-ruthenium(VI) and nitridoosmium(VI) complexes containing chelating multianionic ligands and 1,4,7-trimethyl-1,4,7-triazacyclonoane /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21021405.

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Murray, Paul Ross. "Electrochemical and spectroelectrochemical studies on nitro-substituted poly-pyridine derivatives and their transition metal co-ordination complexes." Thesis, University of Edinburgh, 2005. http://hdl.handle.net/1842/11208.

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