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Dissertations / Theses on the topic 'Complexes du platine(II)'

Author: Grafiati
Published: 4 June 2021
Last updated: 9 February 2022

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1

Blondel, Benoît. "Complexes de platine(II) pour des diodes organiques électroluminescentes (OLEDs) rouges et bistables." Thesis, Toulouse 3, 2017. http://www.theses.fr/2017TOU30173/document.

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Ce travail de thèse décrit l'utilisation de complexes de platine(II) dans les diodes électroluminescentes organiques (OLEDs). Ces complexes ([Pt(II) (tetra-tert-butylSalophen)] et [Pt(II) Salophen]) ont été caractérisés par les méthodes usuelles (1H RMN, spectroscopie UV-visible, électrochimie, diffraction des rayons X pour le [Pt(II) (tetra-tert-butylSalophen)]). Des calculs DFT ont corroboré les données expérimentales qui ont guidé le choix du Tris(8-hydroxyquinolinato) aluminum (Alq3) en tant que matrice. Des dispositifs bistables, susceptibles d'être utilisés en tant que mémoires, ont été
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2

Soares, Marie C. "Synthèses et études de la réactivité des complexes ferrocénylphosphines du platine(II) et du palladium(II) /." [S.l.] : [s.n.], 1997. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=12178.

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3

Diring, Stéphane Ziessel Raymond. "Synthèse de complexes luminescents de platine (II) appliquée à la construction d'édifices multichromophoriques." Strasbourg : Université de Strasbourg, 2009. http://eprints-scd-ulp.u-strasbg.fr:8080/1085/01/DIRING_Stephane_2008.pdf.

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4

Diring, Stéphane. "Synthèse de complexes luminescents de platine (II) appliquée à la construction d’édifices multichromophoriques." Strasbourg, 2009. https://publication-theses.unistra.fr/public/theses_doctorat/2009/DIRING_Stephane_2009.pdf.

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Les travaux réalisés durant cette thèse s’articulent autour de deux grands axes. La première partie des travaux a consisté à étudier des complexes luminescents de platine(II). Une méthodologie de synthèse reposant sur une réaction de Diels-Alder nous a permis d’obtenir une série de ligands de type phényl-bipyridine diversement fonctionnalisés. Nous avons obtenu les complexes de platine(II) correspondants et avons étudié et la variation de leurs propriétés photophysiques, en fonction de la nature des groupes fonctionnels présents sur le ligand ou directement connectés au centre métallique. La s
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5

Hamel, Matthieu. "Les phénylphosphonates ortho-sulfinylés : nouvelle synthèse asymétrique et préparation de complexes de platine (II)." Caen, 2005. http://www.theses.fr/2005CAEN2036.

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Ce travail a porté sur la synthèse, notamment asymétrique, de composés aromatiques ortho-difonctionnalisés phosphorosulfurés, et de leurs applications dans le domaine thérapeutique, en tant que ligands du cisplatine et en tant qu'inhibiteurs d'enzymes. Une nouvelle méthode de synthèse de sulfinates diastéréoenrichis (précurseurs de sulfoxydes), basée sur l'oxydation asymétrique de sulfénates énantiopurs a été développée. Cette méthode a permis d'accéder à des ortho-sulfinylbenzènephosphonates optiquement actifs avec des excès énantiomériques atteignant 86 %. Le réarrangement sigmatropique [1,3
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6

Souchard, Jean-Pierre. "Synthèse, propriétés physico-chimiques, et activités pharmacologiques de complexes antitumoraux dérivés du platine (II): relations structure-activité." Toulouse 3, 1990. http://www.theses.fr/1990TOU30128.

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L'auteur a mis au point une methode de synthese rapide et fiable des complexes cis-pta#2(ono#2)#2 (a etant une amine ou une pyridine substituee a partir des complexes cis-pta#2i#2 dissous dans l'acetone. L'etude rmn #1h des complexes cis- et trans-pta#2x#2 (x etant un iodure, un chlorure ou un nitrate) a mis en evidence une constante de couplage j(pt-h) permettant d'identifier sans ambiguite l'isomerie des complexes. Les derives cis-pta#2 (ono#2)#2 s'hydrolysent rapidement en solution aqueuse pour donner les complexes diaquo (cis(pta#2(h#2o)#2#2#+, 2 no#3) qui sont stables pendant au moins deu
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7

REDON, SOPHIE. "Structures quadruplexes de sequences telomeriques : etudes structurales et pontages a l'aide de complexes du platine(ii)." Paris 11, 2001. http://www.theses.fr/2001PA112200.

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L'adn telomerique simple-brin riche en guanines (g), situe aux extremites des chromosomes, adopte in vitro et en presence de cations monovalents, des structures quadruplexes qui correspondent a des empilements de quartets de g. Ces structures inhibent la telomerase, une enzyme active dans la plupart des cellules cancereuses et responsable de leur immortalisation. Le but etait de figer avec des complexes du platine(ii) des structures quadruplexes de tetrahymena (t 2g 4) 4 et humaines (t 2)ag 3(t 2ag 3) 3 en pontant deux purines. Le complexe monofonctionnel pt(nh 3) 3(h 2o)(no 3) 2 est une sonde
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8

Soliman, Ahmed M. "Synthèses et propriétés photophysiques de nouveaux complexes hétérométalliques de platine(II)-iridium(III) et leurs polymères." Mémoire, Université de Sherbrooke, 2012. http://hdl.handle.net/11143/5765.

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Platinum(1I) and charged cationic iridium(III) complexes have attracted great interest as luminophores in a myriad of applications. Notably, each class of these complexes has been incorporated into organic light emitting diodes (OLEDs), light-emitting electrochemical cells (LEECs), nonlinear optical materials and photovoltaic devices. This thesis reports the synthesis of hybrid Pt-Ir-containing organometallic complexes and polymers with the goal of obtaining high performance luminophores for electroluminescent devices. As a first step towards the polymer construction, the synthesis of a series
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9

Fourmy, Kévin. "Complexes d'or(I) et de platine(II) portant des ligands phospholes : synthèse et applications dans l'activation d'alcynes." Toulouse 3, 2013. http://thesesups.ups-tlse.fr/2108/.

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L'activation homogène d'alcynes par des complexes d'or(I) et de platine(II) a connu un important essor ces 10 dernières années. Initialement, les sels métalliques, AuCl ou PtCl2, étaient utilisés. La conception de nouveaux ligands est primordiale afin d'améliorer l'activité, la sélectivité, mais aussi la stabilité des catalyseurs. Historiquement, des ligands phospholes sont utilisés au laboratoire pour développer des nouveaux outils catalytiques. C'est dans ce contexte que nous nous sommes intéressés aux applications des ligands phospholes dans l'activation d'alcyne. Des complexes d'or(I), [Au
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10

Chantson, Janine. "Platinum (II) complexes of heteroaromatic derivatives." Pretoria : [s.n.], 2002. http://upetd.up.ac.za/thesis/available/etd-08012005-143742/.

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11

Wang, Xiaorong. "Polymères push-pull sur la base de platine ( II ) complexes ou porphyrinzinc ( II ) et des dérivés quinoniques : synthèse et étude photophysique." Thèse, Université de Sherbrooke, 2015. http://hdl.handle.net/11143/7698.

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Résumé : Au cours des dernières décennies, la conception de nouveaux polymères «push-pull» a été le sujet d'intenses recherches pour les cellules photovoltaïques. Cette thèse de doctorat comprend deux sujets principaux de recherche, l'une est la synthèse et la caractérisation de polymères organométalliques contenant l’unité trans-bis(éthynyl)bis(tributylphosphine)platine(II) comme l’un de deux blocs de construction et des dérivés quinoniques et anthraquinoniques agissant respectivement comme donneur et accepteur de densité électronique, et ainsi que des composés modèles correspondants pour fin
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12

Rahmouni, Abderrahim. "Réaction de la drogue antitumorale, le cis-dichlorodiammine-platine (II) avec l'acide désoxyribonucléique étude des complexes interbrins /." Grenoble 2 : ANRT, 1987. http://catalogue.bnf.fr/ark:/12148/cb37609133s.

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13

Rouquette, Rémi. "Self-assembly of platinum(II) complexes with tunable photophysical properties in confined spaces and in solution." Thesis, Strasbourg, 2017. http://www.theses.fr/2017STRAF075/document.

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Cette thèse se focalise sur le design, la synthèse et la caractérisation photophysiques de complexes de platine(II) neutres contenant un ligand chromophore tridenté et un ligand auxiliaire monodenté avec des groupes fonctionnels différents. De tels complexes montrent des changements drastiques de leurs propriétés de photoluminescence à cause de leur auto-assemblage, déclenché par l’établissement de faibles liaisons non covalents tels que l’empilement p-p et des interactions métallophiliques. Il a été démontré que ces complexes de platine(II) peuvent être attaché de manière covalente à des surf
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14

Miyoshi, Emi. "Platinum(II) complexes studied by diffusion NMR /." View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/33587.

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Thesis (M.Sc.) (Hons)--University of Western Sydney, 2008.<br>A thesis presented to the University of Western Sydney, College of Health and Science, School of Biomedical and Health Sciences, in fulfilment of the requirements for the degree of Master of Science (Honours). Includes bibliographies.
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15

Pascu, Sofia I. "Nickel (II), palladium (II), platinum (II) and rhodium (I) complexes of iminophosphine ligands." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270258.

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16

Esteves, Lucas Fagundes. "Investigação teórica do mecanismo de ação de compostos binucleares de platina(II)." Universidade Federal de Juiz de Fora, 2012. https://repositorio.ufjf.br/jspui/handle/ufjf/2048.

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17

尹錦濤 and Kam-to Wan. "Syntheses and photochemistry of monomeric platinum (II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1990. http://hub.hku.hk/bib/B31209476.

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18

Wan, Kam-to. "Syntheses and photochemistry of monomeric platinum (II) complexes /." [Hong Kong : University of Hong Kong], 1990. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12757949.

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19

Grove, Levi James. "Synthesis and Characterization of Vapochromic Platinum(II) Complexes." University of Cincinnati / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1196030530.

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20

Fazio, Daniela. "Synthesis and mesomorphism of polycatenar complexes of palladium (II) and platinum (II)." Thesis, University of Exeter, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366619.

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21

Barkhuysen, Shani. "High resolution 195Pt and 119Sn NMR characterization of platinum(II)-tin(II) complexes." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/17841.

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22

Rapolu, Chaitanya. "Inhibition of Cysteine Protease by Platinum (II) Diamine Complexes." TopSCHOLAR®, 2011. http://digitalcommons.wku.edu/theses/1137.

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Chemotherapy is the first line of treatment used in cancer. Chemotherapy drugs such as cisplatin, carboplatin and oxaliplatin are used in treatment. Cisplatin enters the cell through copper transporter CTR1 by passive diffusion and bind to DNA and proteins. Cisplatin is found to inhibit several enzymes targeting cysteine, histidine and methionine residues, which are expected to be responsible for its anticancer activity. A better understanding of how the size and shape and leaving ligands of platinum complexes affect cysteine protease, papain enzyme are studied. This could give new ways to opt
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23

鄺海倫 and Hoi-lun Kwong. "Photochemistry of binuclear platinum (II) and gold (I) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31208678.

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24

Quyoum, Ruhksana. "Pentamethylcyclopentadienyl complexes of platinum(II) : their synthesis and reactivity." Thesis, University of Salford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315362.

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25

Newman, Christopher P. "Phenylpyridine and N-heterocyclic carbene complexes of platinum (II)." Thesis, University of Warwick, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425555.

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26

Kwong, Hoi-lun. "Photochemistry of binuclear platinum (II) and gold (I) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12434000.

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27

Li, Jian-Jun. "Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes /." free to MU campus, to others for purchase, 1996. http://wwwlib.umi.com/cr/mo/fullcit?p9720553.

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28

Hua, Fei. "Synthesis and Photophysics of Platinum (II) Diimine Acetylide Complexes." Bowling Green State University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1187329346.

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29

Sinn, Stephan. "Pt(II) complexes as scaffolds in supramolecular assemblies." Thesis, Strasbourg, 2017. http://www.theses.fr/2017STRAF015/document.

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Cette thèse se concentre sur la synthèse et l’analyse photophysique de complexes de Pt(II) luminescents and leur assemblage après agrégation. Multiples motifs supramoléculaires ont été utilisé pour acquérir un contrôle sur l’assemblage de ces complexes plan-carrés.Des ossatures de type couronne-éther furent attachés à des complexes métalliques phosphorescents pour donner un bouton supramoléculaire qui peut être actionné par des cations potassium. De plus, l’altération de l’arrangement de l’empilage des Pt(II) après coordination d’un ligand fut exploité pour la réalisation d’un senseur chimique
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Davis, John Christopher. "A Speciation study of the chloro-hydroxo complexes of Pt(II)." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1213.

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In this study a method was developed to identify and quantify platinum(II) complexes of the type [PtCl4-n(OH)n]2- and [PtCl4-n(H2O)n]2-n. Separation of the various species was achieved with the aid of a hyphenated reversed phase HPLC-ICP-MS technique coupled with an ion-pairing reagent, HMHDCl2. The adsorption of HMHD2+ onto a C-18 column was investigated by generating a series of breakthrough curves. It was found that the selectivity for high charge density anions originates from its low surface coverage relative to TBA+, which on the other hand could not separate Pt(II) complexes. The peaks
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31

Berger, Gilles. "Synthesis of chiral vicinal diamines and in vitro anticancer properties of their platinum(II) coordinates." Doctoral thesis, Universite Libre de Bruxelles, 2013. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/209376.

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15N-based nuclear magnetic resonance techniques are considered very powerful to study the molecular properties of platinum-containing anticancer agents, these properties being responsible for the efficacy of the compounds, but also for the understanding of resistance mechanisms and toxicity. Therefore, the first part of the present work aimed to develop a new method for synthesizing 15N-labeled, chiral platinum compounds. A theoretical discussion on the nucleophilic ring-opening of aziridines has also been envisaged, rationalizing an interesting regiochemistry question. Indeed, a surprising in
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32

Chow, Pui-keong, and 周沛強. "Luminescent palladium(II) and platinum(II) complexes with tridentate monoanionic and tetradentate dianionic cyclometallated ligands : structures, photophysical properties and material application." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2013. http://hdl.handle.net/10722/193416.

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Four structural isomers of platinum(II) complexes with C-deprotonated R-C^N^N-R’ cyclometallated ligands (R-C^N^N-R’ = -extended 6-aryl-2,2’-bipyridine derivatives containing 2-naphthyl, 3-isoquinolinyl, 1-isoquinolinyl or 2-quinolinyl moieties) have been synthesized with their photophysical properties investigated. The one bearing a 3-isoquinolinyl moiety shows the highest emission quantum yield among the four and hence has been extensively modified to give a series of complexes with different ancillary ligands (chloride, iodide, phenoxide, or acetylide). Most of these complexes show vibroni
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33

Rahmouni, Abderrahim. "Reaction de la drogue antitumorale, le cis-dichlorodiammineplatine (ii) avec l'acide desoxyribonucleique : etude des complexes interbrins." Orléans, 1987. http://www.theses.fr/1987ORLE2047.

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34

Getty, April D. "Syntheses and reactivity studies of hydroxo-palladium(II) and amido-platinum(IV) complexes /." Thesis, Connect to this title online; UW restricted, 2001. http://hdl.handle.net/1773/8653.

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35

Contaldi, Simone <1982&gt. "Synthesis and Structures of palladium(II) and platinum(II) complexes containing cyclometallated 2-thienylpyridines." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2010. http://amsdottorato.unibo.it/2727/.

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36

Xiang, Haifeng. "Organic optoelectronic devices based on platinum(II) complexes and polymers." Thesis, Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B3483011X.

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37

Li, Jun. "Synthesis, characterization and application studies of ionic platinum(II) complexes." HKBU Institutional Repository, 2017. https://repository.hkbu.edu.hk/etd_oa/394.

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This thesis is dedicated to developing novel charged Pt(II) complexes and exploring their applications in electroluminescence, bio-imaging and the preparation of soft salts. At the beginning, a brief introduction about the development of ionic transition metal complexes and an overview of their applications in electroluminescence, bio-imaging and soft salts are presented. In chapter 2, a series of anionic Pt(II) complexes were successfully synthesized and fully characterized for their application in electroluminescence with relatively small current density. All the complexes show highly intens
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38

Watchman, Elaine Beth. "Platinum(II) aminophosphine anticancer complexes and their interactions with nucleotides." Thesis, University of Edinburgh, 2002. http://hdl.handle.net/1842/14637.

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A series of platinum(II) aminophosphine complexes has been prepared and their interactions with nucleotides studied, such complexes are potential anticancer agents combining cytotoxic phosphines with features of platinum am(m)ine drugs. Ligands of the form Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>3</sub>NRR’ have been prepared, where R and R’ are alkyl groups of varying steric bulk. On complexation with platinum the ligands form six-membered chelate rings bound via P and N and the extent of chelation has been shown to be controlled by the bulk of the substituents. Chelate formation is also pH depen
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Barker, Nathaniel M. "The Influence of Structure in Platinum(II) Polypyridyl Polymorphic Complexes." University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1627665370500068.

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張子俊 and Tsz-chun Cheung. "Structures and photoluminescence of polypyridine and cyclometallated complexes of Pt(II), Pd(II) and Au(III)." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B31235657.

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Cheung, Tsz-chun. "Structures and photoluminescence of polypyridine and cyclometallated complexes of Pt(II), Pd(II) and Au(III) /." Hong Kong : University of Hong Kong, 1997. http://sunzi.lib.hku.hk/hkuto/record.jsp?B18598158.

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Datt, Michael Steven. "Synthesis and characterisation of novel platinum (II) complexes potential chemotherapeutic drugs." Thesis, Rhodes University, 2001. http://hdl.handle.net/10962/d1005031.

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The present study involves the preparation of novel mixed-ligand platinum(II) complexes in the hope of expanding the range of platinum(II) complexes that exhibit anticancer activity and which are less toxic and have a broader spectrum of activity than cisplatin and its analogues. To this end, N-(3-R-benzoyl)-N’,N’-diethylthiourea, N-(3-R-benzoyl)-N’-morpholinothiourea, N-(3-Rbenzoyl)-N’,N’-di(2-hydroxyethyl)thiourea (R = NO2, Cl, H, CH3, OCH3), N,N-diethyl-N’-menthyloxycarbonylthiourea and N-menthyloxycarbonyl-N’-morpholinothiourea ligands, and their corresponding mixed-ligand platinum(II) com
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43

Hudson, Joshua M. Omary Mohammad A. "Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices." [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-5165.

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44

曾炳堯 and Biing-chiau Tzeng. "Design, structures, spectroscopic, and photophysical properties of supramoleculsar gold(I), platinum(II), and palladium(II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237782.

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Tzeng, Biing-chiau. "Design, structures, spectroscopic, and photophysical properties of supramoleculsar gold(I), platinum(II), and palladium(II) complexes /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19471397.

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46

Septiadi, Dedy. "Optical imaging and drug delivery using soft- and hard- nanomaterials." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAF036/document.

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Le travail décrit dans cette thèse se concentre sur le développement de matériaux « durs et mous » ainsi que leur interaction avec les cellules biologiques pour une application finale dans le domaine de la théranostique couvrant l'imagerie, la détection, la thérapie génique et la thérapie du cancer. Dans ce contexte, nous avons tout d'abord étudié l'utilisation de complexes (II) de platine phosphorescents auto-assemblés comme sonde cellulaire. Nous avons étendu l'idée de bio-imagerie en introduisant un concept d’imagerie basée sur l’émission stimulée où nous étions en mesure de générer un lase
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47

Zhao, Shengliang. "Supramolecular Ru II, Pt II Complexes Bridged by 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz)." Diss., Virginia Tech, 2010. http://hdl.handle.net/10919/77321.

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The main theme of this dissertation is the study of two racemic compounds: a bimetallic complex, [(tpy)Ru(tppz)PtCl](PF₆)₃, and a trimetallic complex, [ClPt(tppz)Ru(tppz)PtCl](PF₆)₄, in solution and in the solid state, where tpy is 2,2':6',2''-terpyridine and tppz is 2,3,5,6-tetrakis(2-pyridyl)pyrazine. These two supramolecular assemblies display remarkably different stereochemistry, electrochemistry and photochemistry. The chapters in this document deal with a multidisciplinary project that is fundamental to the design and synthesis of similar entities with potential applications as antitumor
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48

羅政藩 and Chang-fan Lo. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231901.

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Lo, Chang-fan. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12505304.

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Hudson, Joshua M. "Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices." Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc5165/.

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Abstract:
This dissertation deals with two major topics that involve spectroscopic studies of (a) divalent group 10 metals and (b) silver(I)-phosphine complexes. The scope of the work involved the delineation of the electronic structure of these complexes in different environments and their use in electronic devices. The first topic is a look at the luminescence of tetrahedral silver(I)-phosphine complexes. Broad unstructured emissions with large Stokes shifts were found for these complexes. Computational analysis of the singlet and triplet state geometries suggests that this emission is due to a Jahn-T
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