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Dissertations / Theses on the topic 'Complexes of Pyridine'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Shipton, Mark Ralph. "Pyridine chromium tricarbonyl complexes." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.276844.

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2

Couchman, Samantha M. "Syntheses and structural studies of complexes of mixed donor pyridine/phenol and pyridine/pyrazole ligands." Thesis, University of Bristol, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299312.

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3

Pater, Boke Chan de. "Terpyridine complexes of rhodium (I, III)." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/70850.

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4

Jiang, Bing. "Nickel and cobalt bis (imino)pyridine complexes as catalysts for the hydrogen evolution reaction." Doctoral thesis, Universitat Autònoma de Barcelona, 2019. http://hdl.handle.net/10803/667777.

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El subministrament d'energia sostenible és un desafiament crític que enfronta la humanitat. La dependència dels combustibles fòssils ha despertat l'interès en el desenvolupament de fonts d'energia lliures de carboni, entre les quals el dihidrogen que té una alta densitat d'energia seria un dels més prometedors sempre que es generi a partir d'alternatives renovables. En aquest context, dissociar l'aigua per produir hidrogen com a combustible és de gran interès i, per tant, s'estan desenvolupant una gran quantitat de catalitzadors per accelerar la velocitat d'aquesta reacció, preferiblement obti

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5

Taylor, Kenneth John. "Electrochemical and spectroelectrochemical studies on mixed halo/pyridine osmium complexes." Thesis, University of Edinburgh, 1990. http://hdl.handle.net/1842/13079.

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The complexes [OsCl<SUB>6</SUB>-<SUB>n</SUB>PY<SUB>n</SUB>]<SUP>(n-y)</SUP>+ , where n = 0, 1, 2(<i>trans</i>), 2(<i>cis</i>), 3(<i>mer</i>), 4(<i>trans</i>), 5 and 6, and y varies between 2 and 4, have been synthesised <i>via</i> redox induced substitution reactions of [OsCl<SUB>6</SUB>]<SUP>2-</SUP>. The series has been fully characterised using electrochemical and spectroelectrochemical techniques. Several key members namely <i>trans</i>-[TPA] [OsCl<SUB>4</SUB>py<SUB>2</SUB>], <i>cis</i>-[OsCl<SUB>4</SUB>py<SUB>2</SUB>], <i>trans</i>-[OsCl<SUB>2</SUB>py<SUB>4</SUB>] and [Ospy<SUB>6</SUB>]9B

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6

Taktak, Sonia. "Biomimetic amino-pyridine iron complexes for catalysis and small molecule activation /." Thesis, Connect to Dissertations & Theses @ Tufts University, 2005.

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Thesis (Ph.D.)--Tufts University, 2005.<br>Adviser: Elena V. Rybak-Akimova. Submitted to the Dept. of Chemistry. Includes bibliographical references. Access restricted to members of the Tufts University community. Also available via the World Wide Web;

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7

Manuel, Antonio David. "Dioxygen activation with Bis(arylimino)pyridine radical anion complexes of nickel." Diss., University of Iowa, 2014. https://ir.uiowa.edu/etd/4686.

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Complexes of redox-active ligands have received increasing attention, in part, because they have been shown to facilitate a variety of bond-forming and bond-breaking reactions, including the activation of small molecules. Unique attributes of redox-active ligands include that they influence the electronic properties of transition metal complexes and may participate in their multielectron redox chemistry. In this work, the utility of Ni complexes of redox-active bis(arylimino)pyridine ligands for the activation of dioxygen was explored. A series of bis(arylimino)pyridine complexes [Ni{2,6-(ArN=

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8

Travers, Guy. "New bis(benzimidazol-2-ylidene)pyridine-nickel complexes as homogeneous catalysts." Thesis, Curtin University, 2015. http://hdl.handle.net/20.500.11937/450.

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New nickel-based catalysts for carbon-carbon bond formation reactions were synthesized and tested. The catalysts were found to be effective, but not strongly influenced by changes in the catalyst structure. During the course of this work, an organic precursor was found to catalyse the decomposition of dimethylsulfoxide. A product of the decomposition was isolated in good yield and identified. This product was found to be a useful reagent for epoxidation reactions.

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9

Wang, Ban. "Synthesis of Bis(imino)pyridine Iron(II) Complexes and Development of Bis(imino)pyridine Iron(II) Catalyzed Carbene Transfer Reactions." TopSCHOLAR®, 2019. https://digitalcommons.wku.edu/theses/3159.

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Metal catalysis of symmetric and asymmetric carbene transfer reactions has been widely applied in natural product synthesis and material science over years. Metal carbene can be easily generated from the extrusion of nitrogen under the catalysis of metal complexes to further undergo various organic reactions, O/N/C-H insertions, cycloadditions, and ylide formations. Currently, the dominant effective catalysts for carbene reactions are built with expensive precious metal, for example, rhodium, ruthenium, palladium, gold. Notably, the effective reactivity and enantioselectivity of the dirhodium(

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10

鄭睦奇 and Luk-ki Cheng. "Photophysics and photochemistry of some platinum (II) complexes with polypyridine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B31234689.

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11

Faudot, dit Bel Pierre. "Développement de nouveaux complexes d'or et leurs applications en catalyse homogène." Palaiseau, Ecole polytechnique, 2015. http://www.theses.fr/2015EPXX0101.

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12

Cheng, Luk-ki. "Photophysics and photochemistry of some platinum (II) complexes with polypyridine ligands /." Hong Kong : University of Hong Kong, 1996. http://sunzi.lib.hku.hk/hkuto/record.jsp?B17489970.

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13

Karabaeva, Kanykey E. "Photochemistry of dipyridyl-phenanthrenedioxin-copper complexes." Bowling Green State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1530026213399288.

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14

Lai, Siu-wai. "Luminescent organoplatinum chemistry : photophysical and supramolecular properties of metallacyclic and polypyridine platinum(II) complexes /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B20792943.

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15

Guérin, Frédéric. "Pyridine diamide complexes of early transition metals, activation of small organic molecules." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ27151.pdf.

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16

Pugh, David Charles. "Transition metal complexes of bis(carbene)pyridine 'pincer' ligands : synthesis and reactivity." Thesis, University of Southampton, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.484957.

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A new (CNC) pmcer ligand, (2,6-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)-3,5dimethylpyridine, has been synthesised. the previously reported ligand (2,6bis( 2,6-diisopropylphenyl)imidazol-2-ylidene)pyridine, (CNC) pincer complexes of transition metals across the from titanium to iridium, have been synthesised, fully characterised and investigated. NHCs, trialkylphosphines and imines as canied out. complexes of (CNC) and (PNP) were better a-donors than tpJI,;TP) ligands, in complexes of (CNC), (PNP) and (NNN) better a-donors, contrary to literature reports. keeping ligands A comparison of th

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17

Wong, Chi-tak. "Synthesis and light emitting properties of poly(phenylenevinylene)s incorporated with pendant ruthenium polypyridine complexes /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21827308.

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18

King, Adam Charles. "Rhodium complexes of some functionalised pyridine ligands incorporating nitrogen and sulphur donor sets." Thesis, University of Cambridge, 1991. https://www.repository.cam.ac.uk/handle/1810/271927.

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19

Liu, Peng. "Oxidation and nitrene transfer reactions catalyzed by iron-oligopyridine complexes." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B42664275.

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20

Chan, Hoi-yiu. "Design and synthesis of luminescent mono- and dinuclear platinum(II) alkynyl terpyridine complexes : from photophysics to aggregation and self-assembly /." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B36929232.

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21

Shumbula, Poslet Morgan. "Pyridine carboxamide and pyrazole palladium(II) complexes as catalyst precursors for phenylacetylene polymerization." Thesis, University of the Western Cape, 2005. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=init_4818_1180438754.

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<p>The objectives of this project were to synthesize and characterise pyridine carboxamide ligands and their palladium complexes and investigate their catalytic activity in the polymerization process of phenylactylene.</p>

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22

GHAITH, ABDULATIF MOHAMMAD. "THE EMISSION OF PYRIDINE AND POLYPYRIDINECHROMIUM(III) COMPLEXES IN RIGID AND FLUID MEDIA." Diss., The University of Arizona, 1987. http://hdl.handle.net/10150/184143.

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The excited state emissions and lifetimes of [Cr(bipy)₃]³⁺, cis – [Cr(bipy)₂Cl₂]⁺, trans – [Cr(py)₄FBr]⁺, cis – [Cr(phen)₂F₂]⁺, and trans – [Cr(py)₄F₂]⁺ were studied in hydroxylic and nonhydroxylic solvents at 77 K and as a function of temperature. The emission characteristics are determined by the relative disposition of ²E and one component of ²T₁. The energy of these two levels is influenced by intramolecular and environmental factors, and solvent-induced level inversion occurs in cis – [Cr(phen)₂F₂]⁺. The influence of temperature and solvent viscosity were studied in several glasses with v

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23

黃志德 and Chi-tak Wong. "Synthesis and light emitting properties of poly(phenylenevinylene)s incorporated with pendant ruthenium polypyridine complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B31223606.

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24

Illes, Jane. "Organic complexes of unrefined and milled kaolin : an infrared spectroscopic study." Thesis, Sheffield Hallam University, 2000. http://shura.shu.ac.uk/19856/.

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Aim: to characterise the surface sites present on unrefined and ball milled Cornish kaolin, with a view to ultimately determining the mode of interaction between the mineral and industrially significant organic molecules. Milling and temperature were found to affect the structure of kaolin and types of surface sites present. These changes were monitored primarily by variable temperature diffuse reflectance infrared Fourier transform spectroscopy (VT DRIFTS) and other complementary techniques including XRD and TGA. Curve fitting of the VT DRIFT spectra was used to aid characterisation of the ty

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25

Lai, Siu-wai, and 黎小慧. "Luminescent organoplatinum chemistry: photophysical and supramolecular properties of metallacyclic andpolypyridine platinum(II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31238737.

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26

Liu, Peng, and 劉鵬. "Oxidation and nitrene transfer reactions catalyzed by iron-oligopyridine complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B42664275.

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27

Haynes, John Stephen. "Spectroscopic and magnetic properties of pyridine and pyrazine complexes of divalent iron and copper." Thesis, University of British Columbia, 1985. http://hdl.handle.net/2429/25821.

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Magneto-structural correlations have been made for a number of pyridine and pyrazine complexes of iron(II) and copper(Il), involving anions of a range of coordinating abilities, for example, sulfonate, RS0₃⁻ (where R is CF₃, CH₃ or p-CH₃C₆H₄); halide, Cl⁻ Br⁻ or I⁻; pseudohalide, NCO⁻ or NCS⁻; perchlorate and hexafluoroarsenate. Structure was determined by infrared, electronic and Mössbauer spectroscopy and differential scanning calorimetry, and, in some instances, by single-crystal X-ray diffraction. Spectroscopic results were used to investigate the nature of both anion and neutral ligand co

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28

Souchard, Jean-Pierre. "Synthèse, propriétés physico-chimiques, et activités pharmacologiques de complexes antitumoraux dérivés du platine (II): relations structure-activité." Toulouse 3, 1990. http://www.theses.fr/1990TOU30128.

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L'auteur a mis au point une methode de synthese rapide et fiable des complexes cis-pta#2(ono#2)#2 (a etant une amine ou une pyridine substituee a partir des complexes cis-pta#2i#2 dissous dans l'acetone. L'etude rmn #1h des complexes cis- et trans-pta#2x#2 (x etant un iodure, un chlorure ou un nitrate) a mis en evidence une constante de couplage j(pt-h) permettant d'identifier sans ambiguite l'isomerie des complexes. Les derives cis-pta#2 (ono#2)#2 s'hydrolysent rapidement en solution aqueuse pour donner les complexes diaquo (cis(pta#2(h#2o)#2#2#+, 2 no#3) qui sont stables pendant au moins deu

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29

Modin, Judit. "Synthesis and Evaluation of Photoactive Pyridine Complexes for Electron Transfer Studies and Photoelectrochemical Applications." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-6146.

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30

Tsoureas, Nikolaos. "Synthesis of phosphine - and pyridine - functionalised N-heterocyclic carbene complexes of platinum group metals." Thesis, University of Southampton, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.494717.

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31

El, Ghachtouli Sanae. "Caractérisation, étude thermodynamique et structurale de complexes tétraazamacrocycliques porteurs de groupements pyridine ou pyrazine." Reims, 2007. http://theses.univ-reims.fr/exl-doc/GED00000535.pdf.

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L’objectif poursuivi au cours de ce travail est l’étude de l’influence des paramètres structuraux de complexes mono- et bistétraazamacrocycles de cuivre et de nickel sur leurs propriétés électroniques. Les ligands développés dans ce but sont des cyclens et cyclams monoN-fonctionnalisés par des groupements de type pyridine ou des bismacrocycles basés sur des cavités cyclen ou cyclam séparées par des liens de type pyridine ou pyrazine. L’influence de la présence d’atomes coordinants exomacrocycliques sur les caractéristiques stéréochimiques et électroniques des complexes a ainsi été évaluée. Dan

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32

El, Ghachtouli Sanae Chuburu Françoise. "Caractérisation, étude thermodynamique et structurale de complexes tétraazamacrocycliques porteurs de groupements pyridine ou pyrazine." Reims : S.C.D. de l'Université, 2007. http://scdurca.univ-reims.fr/exl-doc/GED00000535.pdf.

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33

Chan, Hoi-yiu, and 陳凱耀. "Design and synthesis of luminescent mono- and dinuclear platinum(II) alkynyl terpyridine complexes: fromphotophysics to aggregation and self-assembly." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B36929232.

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34

Lepeltier, Marc. "Nouveaux complexes de l'iridium(III) à ligands cyclométallés fonctionnels : synthèse et propriétés photophysiques." Rennes 1, 2005. http://www.theses.fr/2005REN1S143.

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Cette thèse présente la synthèse et les propriétés de phosphorescence de nouveaux complexes cyclométallés de l'iridium(III) à ligands fonctionnels. Nous avons préparé des complexes bis- et tris-cyclométallés à ligands phénylpyridines substitués par des groupements styryles sur les noyaux pyridines. Selon la température de réaction, les complexes bis-cyclométallés formés sont réduits ou non au niveau des groupements styryles. La synthèse des complexes tris-cyclométallés homologues a été mise au point par fonctionnalisation du complexe méthylé précurseur. Nous avons montré que la couleur de l'ém

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35

Smit, Theodoor Martin. "Heteroatom substituted bis(imino)pyridine and bis(phenoxy-amine) transition metal complexes for olefin polymerisation." Thesis, Imperial College London, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420626.

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36

Halut, Desportes Sabine. "Etude de complexes du MG2+ avec le méthanol et la pyridine par diffraction des rayons X et spectroscopie vibrationnelle." Paris 6, 1986. http://www.theses.fr/1986PA066408.

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Synthèse et caractérisation de differents complexes solides. Structures de MG CH3OH6 BR::(2), (MGPY::(4)CL::(2)), (MGPY::(4)BR::(2))PY::(2) (MG(H::(2)O)::(4)PY::(2))CL::(2), (MG(H::(2)O)::(3)PY::(3)) BR::(2)PY::(2) ET (MG(H::(2)O)::(2)PY::(4))I::(2)PY::(2). Analyse des spectres IR de M(ROH)::(6) X::(2), M(ROH)::(4)X::(2) (AVEC M = MG,CA; R = CH::(3),C::(2)H::(5); X = CL,BR) ET DE MG(PY)::(4) CL::(2) ET M(PY)::(4)X::(2)PY::(2) (M = CA,MG)

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37

Steen, Robert. "Molecular Electronic Devices based on Ru(II) Thiophenyl Pyridine and Thienopyridine Architecture." Doctoral thesis, Mälardalens högskola, Akademin för hållbar samhälls- och teknikutveckling, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:mdh:diva-10084.

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According to the famous axiom known as Moore’s Law the number of transistors that can be etched on a given piece of ultra-pure silicon, and therefore the computing power, will double every 18 to 24 months. However, around 2020 hardware manufacturers will have reached the physical limits of silicon. A proposed solution to this dilemma is molecular electronics. Within this field researchers are attempting to develop individual organic molecules and metal complexes that can act as molecular equivalents of electronic components such as wires, diodes, transistors and capacitors. In this work we hav

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38

Jack, Lorna Anne. "Electrochemical and spectroelectrochemical studies on 2,2'-bipyridine and pyridine complexes of Pt(II) and Pd(II)." Thesis, University of Edinburgh, 2003. http://hdl.handle.net/1842/12210.

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This thesis is concerned with the synthesis, electrochemistry and spectroelectrochemistry of three different types of ligands; the 5,5’-(X)<sub>2</sub>-bpys, (bpy = 2,2’-bipyridine), the bidentate dipyridyls, (py), (where py = pyridine and X is a bridging group) and the nitro substituted bpys 4,4’-(NO<sub>2</sub>)<sub>2</sub>-bpy and 4-NO<sub>2</sub>-bpy and 4-NO<sub>2</sub>-py. The Pt(II) complexes of these ligands were also studied along with the Pd(II) complexes of the nitro substituted ligands. The ligands and complexes of general type 5,5’-(X)<sub>2</sub>-bpy and [Pt(5,5’-(X)<sub>2</sub>-

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39

Liu, Tsz-chung Alvin, and 廖子衝. "Design and synthesis of luminescent coumarin-containing platinum (II) terpyridine alkynyl complexes and their spectroscopic, photophysicaland binding studies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B47168353.

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40

Chong, Eugene. "Early transition metal complexes of pyridine derivatives : applications in the catalytic synthesis of amines and N-heterocycles." Thesis, University of British Columbia, 2014. http://hdl.handle.net/2429/50998.

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The work described in this thesis focuses on the development of pyridine-derived group 4 and 5 complexes for application in the catalytic synthesis of selectively substituted amines. Two different catalytic alkene hydrofunctionalization reactions were targeted: hydroamination and hydroaminoalkylation. Respectively, these transformations provide atom-economical strategies for the formation of new C–N and C–C bonds on amines, using simple alkenes as the alkylating agents. A series of bulky mono(2-aminopyridinate)tris(dimethylamido)titanium complexes with varying steric parameters were synthesize

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41

Murray, Paul Ross. "Electrochemical and spectroelectrochemical studies on nitro-substituted poly-pyridine derivatives and their transition metal co-ordination complexes." Thesis, University of Edinburgh, 2005. http://hdl.handle.net/1842/11208.

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42

Feng, Min. "Multiple physical properties in the lanthanide complexes involving 2,6-di(pyrazol-1-yl)- pyridine-based tetrathiafulvalene ligands." Thesis, Rennes 1, 2015. http://www.theses.fr/2015REN1S113.

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Dans ce manuscrit, le premier chapitre introduit la cible matériaux multifonctionnels, y compris les connaissances nécessaires sur les différentes propriétés physiques sélectionnées telles que le magnétisme, la luminescence, et la conductivité, ainsi des contributions précédents de nos et d'autres groupes.Dans le chapitre deux, le ligand à base de tétrathiafulvalène avec deux accepteurs dpp (L1 et L2) (TTF = tétrathiafulvalène, dpp = 2,6-di(pyrazol-1-yl)pyridine) et des complexes lanthanide correspondant sont présentés, y compris la synthèse et les caractérisations physiques: structures crista

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43

Pedrazzini, T. "MODULAR APPROACH TO CHIRAL PYRIDINE CONTAINING MACROCYCLES: SYNTHESIS, CHARACTERIZATION, REACTIVITY AND CATALYTIC ACTIVITY OF THEIR METAL COMPLEXES." Doctoral thesis, Università degli Studi di Milano, 2014. http://hdl.handle.net/2434/243662.

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In this thesis is reported a simple, fast, economic modular approach for the synthesis of chiral tetraaza-macrocycles containing a pyridine ring (Pc-L*) starting from aminoacids. The characterization of the ligands and of their complexes with copper (I) and silver (I) salts also descrive, including several crystal suitable for X-ray determination. The organometallic reactivity and coordination behavior of these complexes with CO and acetonitrile has been studied. The complexes were succesfully applied as catalysts for cyclopropanation and A3-coupling reaction and for the synthesis of isochrom

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44

Abdel-Rahman, Obadah S. [Verfasser]. "Biphenyl- and Carbazole-Bridged Di- and Trinuclear Alkenyl-Ruthenium Complexes and Mononuclear Alkenyl Complexes with Pyridine- and Quinoline-Derived Bidentate Coligands / Obadah S. Abdel-Rahman." Konstanz : Bibliothek der Universität Konstanz, 2015. http://d-nb.info/1148942327/34.

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45

鄭嘉慧 and Kar-wai Anita Cheng. "Preparation, reactivities and oxidative catalytic activities of ruthenium(II) polypyridines, rhenium(I) carbonyl complexes andruthenium-encapsulated meso- and micro-porous molecular sieves." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31236662.

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46

Molard, Yann. "Assemblages : complémentarité de la chimie de coordination et de la chimie supramoléculaire." Lyon 1, 2000. http://www.theses.fr/2000LYO10282.

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Dans le but de synthétiser dans un premier temps un mimétique de l'anhydrase carbonique, nous décrivons les mimétiques de cette enzyme parus dans la littérature ainsi que les différentes méthodes de couplage d'acides aminés sur un macrocycle de type calixarène. Nous développons ensuite la synthèse de p-tert-butylcalix[4]arènes substitués régiosélectivement par 2, 3 ou 4 esters méthyliques de N[delta]-benzylHistidine. Après une approche structurale de leur caractérisation, l'étude des propriétés de complexation de ces ligands vis-à-vis du cobalt (II) et du zinc (II) est présentée indiquant par

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47

Cheng, Kar-wai Anita. "Preparation, reactivities and oxidative catalytic activities of ruthenium(II) polypyridines, rhenium(I) carbonyl complexes and ruthenium-encapsulated meso- and micro-porous molecular sieves /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B1973816X.

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48

Machkour, Ahmed. "Complexes dichloroferreux à ligands possédants des motifs aminométhyle pyridine substitués : Synthèse, études structurales et activation biomimétique de l'oxygène moléculaire." Université Louis Pasteur (Strasbourg) (1971-2008), 2005. http://www.theses.fr/2005STR13018.

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Ce travail de thèse s'inscrit dans le domaine de la chimie biomimétique de complexes du fer coordinés à des ligands présentant des motifs aminométhyle pyridine. Le travail décrit dans le manuscrit présente une mise en lumière de ce domaine d'étude par le rappel de l'activité de certaines métalloprotéines dites " à fer non héminique " réagissant sur le dioxygène. Est ensuite examinée la synthèse de ligands présentant des motifs aminométhyle pyridine, substitués par des halogènes ou des aromatiques simples ou fonctionnels. Une nouvelle méthode particulièrement simple permettant l'accès à des dér

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Halut-Desportes, Sabine. "Etude de complexes de Mg²⁺ avec le méthanol et la pyridine par diffraction des rayons X et spectroscopie vibrationnelle." Grenoble 2 : ANRT, 1986. http://catalogue.bnf.fr/ark:/12148/cb37598182f.

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Guérin, Frédéric. "Pyridine diamide complexes of early transition metals." Thesis, 1998. http://hdl.handle.net/2429/8411.

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Titanium complexes bearing a pyridine-diamide ligand [2,6-(RNCH2)2NC5H3]2' (R = 2,6-diisopropylphenyl (BDPP); R = 2,6-dimethylphenyl (BDMP)) have been synthesized. The dichloride complexes [2,6-(RNCH2)2NC5H3]TiCl2 are prepared in high yield from {2,6- [(Me3Si)RNCH2J2NC5H3} and TiCl4 via the elimination of 2 equiv of ClSiMe3. Monoalkyl and bis(alkyl) complexes are prepared from [2,6-(RNCH2)2NC5H3]TiCl2 and various Grignard reagents. Reduction of the dichloride precursors (BDPP)TiCl2 and (BDMP)TiCl2 with excess 1% Na/Hg amalgam in the presence of >2 equiv of internal (PhC=CPh, EtC=CEt, PrC

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