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Journal articles on the topic 'Composés diazo'

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1

Backer, H. J. "La réaction de composés diazo sur les bis-alcoylsulfonyl-méthanes: Propriétés du groupe sulfonyle xxi." Recueil des Travaux Chimiques des Pays-Bas 70, no. 8 (2010): 733–37. http://dx.doi.org/10.1002/recl.19510700814.

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2

Ferreira, Vítor F., Letícia O. R. Pereira, Maria Cecília B. V. de Souza, and Anna C. Cunha. "Compostos alfa-diazo carbonílicos: uma estratégia atraente para a síntese orgânica." Química Nova 24, no. 4 (2001): 540–53. http://dx.doi.org/10.1590/s0100-40422001000400016.

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3

Maeno, Kenichi, Bhargav R. Patel, Tatsuro Endo, and Kagan Kerman. "Angle-Sensitive Photonic Crystals for Simultaneous Detection and Photocatalytic Degradation of Hazardous Diazo Compounds." Micromachines 11, no. 1 (2020): 93. http://dx.doi.org/10.3390/mi11010093.

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Congo Red (CR) and Amido Black 10B (AB-10B) are anionic diazo dyes, which are metabolized to produce a bioaccumulative and persistent carcinogen, benzidine. In this regard, an angle sensitive sensor composed of photonic crystal supported photocatalyst was fabricated for the simultaneous detection and photocatalytic degradation of diazo dyes from aqueous solutions. Reflectance spectroscopy was used in the detection of CR and AB-10B, which was based on the emergence of the incident angle dependent reflection peaks from the TiO2 coated two-dimensional photonic crystal (2D-PhC) surfaces and their
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4

Nery, Antonio Augusto. "O "Mefistófeles" de Eça de Queirós." Abril – NEPA / UFF 4, no. 8 (2012): 85–94. http://dx.doi.org/10.22409/abriluff.v4i8.29724.

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A crônica “Mefistófeles” foi escrita por Eça de Queirós em 1867 e publicada nesse mesmo ano no jornal Gazeta de Portugal. O texto faz parte do volu­me Prosas bárbaras, publicação póstuma de 1903, em que estão compilados alguns dos primeiros textos escritos por Eça. Toda a narrativa da crônica é centrada na análise da ópera Fausto, composta pelo francês Charles Gou­nod, em 1859, obra esta baseada na ficção homônima de Goethe. Por in­termédio da personagem principal da ópera, Mefistófeles, o cronista sobre­carrega a “figura” do diabo com características positivas que se sobrepõem às poucas propo
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5

Duthu, Brigitte, Karim El Abed, Douraid Houalla, Robert Wolf, and Joël Jaud. "Structure cristalline et moléculaire d'un composé tricyclique contenant le cycle à dix chaînons dioxo diaza diphosphécine." Canadian Journal of Chemistry 70, no. 3 (1992): 809–16. http://dx.doi.org/10.1139/v92-106.

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The sulfuration of the tricyclic organophosphorous dimer 2 leads easily to the dithiotricyclic derivative 3, which has been characterized by 31P, 1H, and 13C NMR, elemental analysis, and mass spectroscopy. Its crystal and molecular structure has been established by X-ray diffraction and compared to that of 2, which was previously determined. The comparative analysis of X-ray diffraction and NMR parameters gives accurate information about the molecular structure of both compounds. A numerical value of the anistropy cone of the P=S double bond is proposed. Keywords: phosphecine, NMR, X-ray, tric
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6

Umetani, Masataka, Takayuki Tanaka, and Atsuhiro Osuka. "Synthesis of azabenziporphyrinoids by SN Ar reactions." Journal of Porphyrins and Phthalocyanines 24, no. 05n07 (2020): 794–801. http://dx.doi.org/10.1142/s1088424619501827.

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While most of porphyrins and related macrocycles have been synthesized by classical acid-catalyzed condensation and oxidation reactions, nucleophilic aromatic substitution reactions have recently emerged as a new protocol to construct novel porphyrinoids. [Formula: see text]-Dibromotripyrrin 3 was developed as a useful building block composed of three pyrrolic segments and two meso-carbons, which was allowed to react with various nucleophiles. Herein, we applied this strategy to synthesize carbaporphyrinoids containing two nitrogen atoms at the meso-positions. Reaction of [Formula: see text]-d
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7

Diallo, O., M. T. Boisdon, L. Lopez, C. Malavaud, and J. Barrans. "Composes du phosphore dicoordonne: Reaction de diaza-1,4 dienes-1,3 disubstitues sur les derives de diazaphosphole. Du triazaphosphole-1,2,4,3 et de precurseurs de composes du phosphore dicoordonne." Tetrahedron Letters 27, no. 26 (1986): 2971–74. http://dx.doi.org/10.1016/s0040-4039(00)84693-6.

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8

Vetromilla, Clayton. "Guerra-Peixe: da trilha sonora do filme O diabo mora no sangue ao Prelúdio nº 2 para violão." Per Musi, no. 21 (2010): 19–24. http://dx.doi.org/10.1590/s1517-75992010000100003.

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O presente texto apresenta as conclusões a que chegamos ao verificar a afirmação do violonista Nélio Rodrigues, segundo a qual o Prelúdio nº 2 para violão (1970) de César Guerra-Peixe foi "idealizado" a partir da trilha sonora do filme O diabo mora no sangue (1967) de Cecil Albery Thiré. Depois de discutir questões gerais acerca da partitura dos cinco Prelúdios para violão publicada em 1973, aproximamos as características do Prelúdio nº 2 não só com os recursos anteriormente utilizados por Guerra-Peixe na música composta para o citado filme, como também nos duos para canto e violão Nesta manhã
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9

Padwa, Albert, and Marcus Mandolesi Sá. "Reações de inserção intramolecular de diazo compostos polifuncionais catalisadas por ródio(II): síntese de oxetan-3-ona-2-carboxilato e outros heterociclos funcionalizados." Química Nova 22, no. 6 (1999): 815–20. http://dx.doi.org/10.1590/s0100-40421999000600008.

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10

Viswanathan, Vijayan, Ayyavu Thirunarayanan, Perumal Rajakumar, and Devadasan Velmurugan. "An amide cyclophane." Acta Crystallographica Section E Structure Reports Online 70, no. 8 (2014): o865. http://dx.doi.org/10.1107/s1600536814015621.

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The title compound, 8,18-dithia-2,6-diaza-13(1,4)-piperidina-1(1,2),4(1,3),7(1,2)-tribenzenaoctadecaphane-10,15-diyne-3,6-dione, C32H30N4O2S2, is composed of a relatively planar bis(2-mercaptophenyl)isophthalamide unit linked to a bridging 1,4-di(but-2-yn-1-yl)piperazine unit, forming a macrocycle. The isophthalamide ring is inclined to the outer mercaptophenyl rings by 8.18 (11) and 5.59 (10)°, while these two rings are inclined to one another by 9.10 (12)°. The piperazine ring adopts a chair conformation. There are two intramolecular N—H...S hydrogen bonds generatingS(5) ring motifs. In the
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11

Dias, Marcelo Pires, and Marilucia Barros de Oliveira. "Religião e crenças no Atlas Geossociolinguístico Quilombola do Nordeste do Pará." MOARA – Revista Eletrônica do Programa de Pós-Graduação em Letras ISSN: 0104-0944, no. 55 (July 31, 2020): 379. http://dx.doi.org/10.18542/moara.v0i55.9151.

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Este trabalho busca descrever e discutir a variação lexical a partir de dados do campo semântico religião e crenças que integra o Atlas Geossociolinguístico Quilombola do Nordeste do Pará (AGQUINPA). O referido atlas descreve e mapeia a variedade linguística do português afro-brasileiro falado nas comunidades remanescentes de quilombos da Mesorregião Nordeste do Pará. O campo semântico escolhido para análise é composto por questões que expressam a dimensão religiosa e as crenças dos informantes entrevistados na pesquisa. Neste estudo apresentaremos e discutiremos os resultados das seguintes ca
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12

Dadfarnia, Shayessteh, and Mojtaba Shamsipur. "Highly Selective Membrane Transport of Zn2+Ion by a Cooperative Carrier Composed of 1,10-Diaza-18-crown-6 and Palmitic Acid." Bulletin of the Chemical Society of Japan 65, no. 10 (1992): 2779–83. http://dx.doi.org/10.1246/bcsj.65.2779.

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13

Dadfarnia, Shayessteh, and Mojtaba Shamsipur. "Specific membrane transport of copper(II) ion by a cooperative carrier composed of 1,7-diaza-15-crown-5 and palmitic acid." Journal of Membrane Science 75, no. 1-2 (1992): 61–68. http://dx.doi.org/10.1016/0376-7388(92)80006-6.

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14

Erickson-Miller, Connie L., Evelyn Delorme, Maya Iskander, et al. "Species Specificity and Receptor Domain Interaction of a Small Molecule TPO Receptor Agonist." Blood 104, no. 11 (2004): 2909. http://dx.doi.org/10.1182/blood.v104.11.2909.2909.

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Abstract Compounds in the diazo/hydrazino acid class require expression of Tpo receptor (TpoR) for activity. These compounds have demonstrated a remarkable species specificity in their Tpo receptor agonist activity, i.e., the activation of signalling pathways by this class of compounds has only been demonstrated in human and chimpanzee platelets. Platelets of other species demonstrate signalling in response to rhTpo, however, no signalling in response to SB-497115 is detectable by electrophoretic mobility shift assays using platelets of cynomolgus macaques, cat, mouse, mouse, rag, pig, ferret
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15

Diaz, J. J., and D. J. Roufa. "Fine-structure map of the human ribosomal protein gene RPS14." Molecular and Cellular Biology 12, no. 4 (1992): 1680–86. http://dx.doi.org/10.1128/mcb.12.4.1680.

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We have used polymerase chain reaction-mediated chemical mutagenesis (J.-J. Diaz, D. D. Rhoads, and D. J. Roufa, BioTechniques 11:204-211, 1991) to analyze the genetic fine structure of a human ribosomal protein gene, RPS14. Eighty-three DNA clones containing 158 random single-base substitution mutations were isolated. Mutant RPS14 alleles were tested for biological activity by transfection into cultured Chinese hamster cells. The resulting data permitted us to construct a map of the S14-coding sequence that is comparable to available fine-structure genetic maps of many prokaryotic and lower e
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16

Diaz, J. J., and D. J. Roufa. "Fine-structure map of the human ribosomal protein gene RPS14." Molecular and Cellular Biology 12, no. 4 (1992): 1680–86. http://dx.doi.org/10.1128/mcb.12.4.1680-1686.1992.

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We have used polymerase chain reaction-mediated chemical mutagenesis (J.-J. Diaz, D. D. Rhoads, and D. J. Roufa, BioTechniques 11:204-211, 1991) to analyze the genetic fine structure of a human ribosomal protein gene, RPS14. Eighty-three DNA clones containing 158 random single-base substitution mutations were isolated. Mutant RPS14 alleles were tested for biological activity by transfection into cultured Chinese hamster cells. The resulting data permitted us to construct a map of the S14-coding sequence that is comparable to available fine-structure genetic maps of many prokaryotic and lower e
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17

Casatti, Lilian. "Alimentação dos peixes em um riacho do Parque Estadual Morro do Diabo, bacia do Alto Rio Paraná, sudeste do Brasil." Biota Neotropica 2, no. 2 (2002): 1–14. http://dx.doi.org/10.1590/s1676-06032002000200012.

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Neste estudo foi investigada a estrutura trófica de uma comunidade de peixes de um riacho de primeira ordem na bacia do Alto Rio Paraná, empregando métodos habituais de análise da dieta combinados com observações naturalísticas. Três trechos do Córrego São Carlos foram estudados. Foram coletadas 18 espécies de peixes, pertencentes a cinco ordens e dez famílias. A análise de 299 estômagos mostrou que 70% dos itens alimentares são autóctones, 24% alóctones e 6% material de origem não identificada. Dezoito pares de espécies (33%) apresentaram sobreposição alimentar significativa, porém esta sobre
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18

Chalbot, Sonia, Henrik Zetterberg, Kaj Blennow, Tormod Fladby, Inge Grundke-Iqbal, and Khalid Iqbal. "Cerebrospinal Fluid Secretory Ca2+-Dependent Phospholipase A2 Activity Is Increased in Alzheimer Disease." Clinical Chemistry 55, no. 12 (2009): 2171–79. http://dx.doi.org/10.1373/clinchem.2009.130286.

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Abstract Background: The phospholipase A2 (PLA2) family comprises multiple isoenzymes that vary in their physicochemical properties, cellular localizations, calcium sensitivities, and substrate specificities. Despite these differences, PLA2s share the ability to catalyze the synthesis of the precursors of the proinflammatory mediators. To investigate the potential of PLA2 as a biomarker in screening neuroinflammatory disorders in both clinical and research settings, we developed a PLA2 assay and determined the predominant types of PLA2 activity in cerebrospinal fluid (CSF). Methods: We used li
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19

Juhasz, Janos, James H. Davis, and Frances J. Sharom. "Fluorescent probe partitioning in giant unilamellar vesicles of ‘lipid raft’ mixtures." Biochemical Journal 430, no. 3 (2010): 415–23. http://dx.doi.org/10.1042/bj20100516.

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Direct visualization of raft-like lo (liquid-ordered) domains in model systems and cells using microscopic techniques requires fluorescence probes with known partitioning preference for one of the phases present. However, fluorescent probes may display dissimilar partitioning preferences in different lipid sys-tems and can also affect the phase behaviour of the host lipid bilayer. Therefore a detailed understanding of the behaviour of fluorescent probes in defined lipid bilayer systems with known phase behaviour is essential before they can be used for identifying domain phase states. Using gi
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20

Cardin, L., B. Delecolle, and B. Moury. "Occurrence of Alternaria dichondrae, Cercospora sp., and Puccinia sp. on Dichondra repens in France and Italy." Plant Disease 89, no. 9 (2005): 1012. http://dx.doi.org/10.1094/pd-89-1012a.

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Dichondra repens (kidneyweed or ponysfoot), family Convolvulaceae, is a perennial plant with persistent leaves and is grown alone or in association with turfgrass in subtropical and Mediterranean regions. Because of its prostrate growth habit, it does not need to be mowed. It is also used as a potted plant for house decoration. During surveys of lawns in public gardens of the Franco-Italian Riviera conducted from 1993 to 2003, we noticed 0.1- to 0.5-cm-diameter, brownish, necrotic spots on leaves of D. repens in Antibes, Cannes, Menton, Nice, and Vallauris (France) and in Arma di Taggia, Diano
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21

Li, Y. X., W. X. Chen, A. Y. Liu, Q. L. Chen, and S. J. Feng. "First Report of Gliocephalotrichum bulbilium Causing Fruit Rot of Posthavest Mangosteen in China." Plant Disease 98, no. 7 (2014): 994. http://dx.doi.org/10.1094/pdis-09-13-0917-pdn.

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Mangosteen (Garcinia mangostana L., Guttiferae) is a tropical fruit renowned for its pleasant taste, rich nutrition, and medicinal value. Little research about mangosteen diseases during storage and transport has been reported. In June of 2012, fruit rots on mangosteens imported from Thailand were observed in Guangzhou, China. In infected fruits, pericarps showed an increased firmness, were discolored to deep pink, and the edible aril became brown and rotten. In order to search for the etiological agent of this rot symptom, infected mangosteens were analyzed. Diseased mangosteen tissues were s
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22

Ohta, Hiromichi, Rong Huang, and Yuichi Ikuhara. "Enhanced Seebeck Coefficient of Amorphous Oxide Semiconductor Superlattices." MRS Proceedings 1044 (2007). http://dx.doi.org/10.1557/proc-1044-u09-09.

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AbstractWe propose herein that amorphous oxide semiconductor (AOS) superlattices, which can be deposited on various substrate including glasses or plastics without any substrate heating, are appropriate for the realization of superlattice thermoelectric devices. As an example, thermoelectric properties of AOS superlattices composed of a-In-Zn-O (well) and a-In-Ga-Zn-O (barrier) layers, fabricated on SiO2 glass substrate by pulsed laser deposition at room temperature, were measured to clarify whether enhancement of Seebeck coefficient |S| occurs or not. The |S|2D value increases drastically wit
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23

Leite, Luiza Burgos de Souza. "Libélula." Anais dos Seminários de Iniciação Científica, no. 22 (February 4, 2019). http://dx.doi.org/10.13102/semic.v0i22.4177.

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Libélula, donzelinha, lavadeira, jacinta, cavalo-de-judeu, cavalinho-do-diabo, zigue-zague e cigarrinha, são alguns dos nomes pelos quais são conhecidos os integrantes da ordem Odonata (Costa et al., 2012). A Ordem Odonata é cosmopolita e atualmente está dividida em três subordens: Zygoptera, Anisozygoptera e Anisoptera (Tillyard & Frazer,1938). No Brasil há ocorrência de representantes de Zygoptera e Anisoptera.São insetos hemimetábolos, anfibióticos, com ninfas aquáticas e adultos terrestres, cujo tamanho varia entre 15 e 175 mm de comprimento. Podem ser reconhecidas facilmente pelo form
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