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Dissertations / Theses on the topic 'Compounds of nickel(II)'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Doddridge, Bruce Germein. "Ligand exchange and substitution on five-coordinate complexes of copper (II), nickel (II) and cobalt (II) /." Title page, contents and summary only, 1986. http://web4.library.adelaide.edu.au/theses/09PH/09phd641.pdf.

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2

Altahan, Mohammed Abdulredha. "Cobalt(III), copper(II), and nickel(II) coordination compounds as cations in polyborate chemistry." Thesis, Bangor University, 2017. https://research.bangor.ac.uk/portal/en/theses/cobaltiii-copperii-and-nickelii-coordination-comppounds-as-cations-in-polyborate-chemistry(ba5f189b-2229-481f-9d8d-0bdce17903a8).html.

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This thesis describes the synthesis and characterization of a number of polyborate compounds containing transition metal complex cations; most of these compounds contain 6-membered B3O3 boroxole rings within their structures. A total of twenty-six transition metal complex polyborate salts are reported: one contains the triborate monoanion, [B3O3(OH)4]-, three contain the tetraborate dianion [B4O5(OH)4]2-, twelve contain the pentaborate anion, [B5O6(OH)4]-, three contain the hexaborate dianion, [B6O7(OH)6]2- and five contain heptaborate anions (three of which are [B7O9(OH)5]2-, and two are [B7O

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3

Mountford, H. Scott. "The structure and spectroscopy of compounds with 1,4,8,11-tetraazacyclotetradecane and manganese (III), nickel (II), and iron (II) : [thesis]." Scholarly Commons, 1991. https://scholarlycommons.pacific.edu/uop_etds/2221.

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This thesis involves reactions of cyclam with Mn(III), Ni(II) and Fe(II). The chemistry of each metal with cyclam will be presented in sections discussing each metal. The initial intent of this thesis was to examine and compare the structures and electronic spectra of a series of trans monomeric first row transition metal cyclam compounds. Both Mn(III) and Ni(II) form such trans monomeric complexes with cyclam and their structural and electronic characteristics are, indeed, examined in this thesis. However, in the course of our study, we found that Fe(II) and cyclam in acetonitrile in the pres

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4

Oliveira, Denise de. "Complexos de níquel (II) com sulfóxidos dialquílicos." Universidade de São Paulo, 1985. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-10072012-095042/.

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Este trabalho consiste no estudo de complexos de Ni(II) com dialquilsulfóxidos. Os compostos foram sintetizados e caracterizados através de espectroscopia vibracional e eletrônica, medidas magnéticas e de condutância e determinação de ponto de fusão. Obtiveram-se os seguintes complexos: [Ni(R2SO)6](ClO4)2 (R = Me, n-Pr, n-Bu e i-Bu); [Ni (Me2SO)6] (NO3)2; [Ni (Me2SO)4 (NO3)](NO3); [Ni(R2SO)3 (NO3)2] (R = Me2SO, Me2SO-d6, n-Bu e i-Bu) e [Ni(R2SO)2 (N03)2] (R = n-Pr, i-Bu e t-Bu). O método de síntese é crítico para a obtenção de compostos bem definidos, principalmente no caso dos nitratos onde e

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5

Navick, Caldentey Martine. "Contribution à l'étude des phénomènes de synergie en extraction liquide-liquide : application à l'extraction du nickel(II) et du cobalt(II) en milieu acide." Paris 6, 1986. http://www.theses.fr/1986PA066297.

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Etude des propriétés d'agent d'extraction des acides di(alkyl)dithiophosphoriques ; ils ne peuvent pas être utilisés industriellement car ils s'hydrolysent rapidement au contact d'une phase aqueuse des 35**(o). En fait il semble que les anions di(alkyl) monothiophosphoriques conviennent, utilises en même temps qu'une oxime. Effet de divers facteurs sur la cinétique d'extraction. On peut séparer à ph1, ni et co par une extraction par acide di(ethyl)monothiophosphorique et quinoleinols-8 substitués.

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6

Ferretti, Eleonora. "Reductive Activation of Nitric Oxide and Nitrosobenzene at a Dinickel(II) Dihydride Complex and New Pyrazole-Based Diiron Compounds." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E594-D.

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7

Esteban, Jarne Jordi. "Síntesi i estudi magnètic de compostos polinuclears de Ni(II) amb lligands piridiloxima." Doctoral thesis, Universitat de Barcelona, 2014. http://hdl.handle.net/10803/279221.

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L’objectiu marcat a l’inici d’aquesta tesi era la síntesi i caracterització estructural i magnètica de nous compostos obtinguts a partir de lligands 2‐piridiloxima i NiII. Per a tal efecte, es va treballar, bàsicament, amb els lligands 2,6‐diacetilpiridildioxima (dapdoH2) i 2‐acetonitrilpiridiloxima (pyC{CN}NOH). Finalment, es va estudiar el sistema 2‐piridiloxima/azida/amina per tal de formar ponts oxima/azida ferromagnètics. En primer lloc, es va treballar amb el lligand dapdoH2. Es van obtenir 20 nous compostos (els primers compostos polinuclears d’aquest lligand amb NiII), que permeten

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8

PETIT, JEAN-FRANCOIS. "Les squarates de lanthanoides : synthese, structure, comportement thermique et proprietes optiques, synthese et structure de dithiosquarates bimetalliques de nickel (ii) et de cerium (iii)." Toulouse 3, 1988. http://www.theses.fr/1988TOU30133.

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Cinq familles de composes isotypes ont ete identifiees en milieu aqueux. Etude radiocristallographique, comportement thermique dans differentes atmospheres, preparation du squarate de cerium anhydre et de trois nouvelles phases hydratees. Etude spectrometrique du derive de l'europium

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9

Herdin, Sven. "Heteroleptische Nickel(II)- und Zink(II)-Polyolato-Komplexe." Diss., lmu, 2004. http://nbn-resolving.de/urn:nbn:de:bvb:19-20621.

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10

Zhang, Yousheng. "Polynuclear magnetic complexes of manganese(II), cobalt(II), nickel(II) and copper(II)." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape2/PQDD_0014/NQ52856.pdf.

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11

Lindahl, Erik. "Thin Film Synthesis of Nickel Containing Compounds." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-111484.

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12

Pascu, Sofia I. "Nickel (II), palladium (II), platinum (II) and rhodium (I) complexes of iminophosphine ligands." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270258.

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13

Wurzenberger, Franz-Xaver. "Ungewöhnliche Koordinationsﬁguren in High-Spin-Eisen(II)-, -Cobalt(II)- und -Nickel(II)-Komplexen". Diss., Ludwig-Maximilians-Universität München, 2014. http://nbn-resolving.de/urn:nbn:de:bvb:19-168283.

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14

Tang, Wing-suen, and 鄧詠璇. "Design and synthesis of luminescent metal polypyridyl complexes of platinum(II), ruthenium(II) and osmium(II) for chemosensing andbiological studies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B38767624.

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15

Tang, Wing-suen. "Design and synthesis of luminescent metal polypyridyl complexes of platinum(II), ruthenium(II) and osmium(II) for chemosensing and biological studies." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38767624.

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16

Pratt, David E. "Properties of biological copper, molybdenum and nickel compounds." Thesis, De Montfort University, 1985. http://hdl.handle.net/2086/4181.

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17

Piga, Francesco. "Magnetostructural correlations in iron(II)- and nickel(II)-based cluster complexes." Thesis, University of Nottingham, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.604299.

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This thesis presents a study of the magnetic properties of cluster complexes of nickel and iron, with a focus on the relationships between structure and magnetism. Chapter 1 gives an introduction to the concepts involved in molecular magnetism, with particular attention to single-molecule magnets (SMMs). The main types of SMMs are outlined, and the origin of magnetic anisotropy and its role in the single-molecule magnetism phenomena are discussed, as well as the potential applications of SMMs as data storage devices. The chapter also describes the experimental techniques employed for the chara

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18

Liu, Li. "The chemistry of luminescent mercury (II) alkynyl complexes and their platinum (II) and gold (I) counterparts." HKBU Institutional Repository, 2005. http://repository.hkbu.edu.hk/etd_ra/627.

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19

Wasmund, Eric Bain Coley Ken. "A study of powder making by the decomposition of nickel carbonyl in an aerosol tube reactor." *McMaster only, 2005.

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20

Wasiowych, Christine Dara. "A study of nickel-sulfur catalysis." Thesis, The University of Sydney, 1994. https://hdl.handle.net/2123/26674.

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The [Ni(sacsac)PBu3C1]/A1EtnCl3_n (where n = 1, 2) catalyst system is investigated (Section I) by studying the isomerisation of 2,3-dimethyl-1-butene. Three parameters were varied - the temperature, and the concentrations of the nickel precursor and aluminum cocatalyst species. The temperature studies illustrated subtleties in the reaction, such as the induction period observed for the isomerisation experiment carried out at -10 °C. The isomerisation data was simulated using the SCoPfit computer program, and rate coefficients were calculated, and a kinetic model was proposed. The simulation st

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21

Zhou, Congying. "Ruthenium porphyrins and dirhodium (II, II) carboxylates catalyzed ylide-mediated cycloadditions and carbenoid transfer reactions." Click to view the E-thesis via HKUTO, 2004. http://sunzi.lib.hku.hk/hkuto/record/B31046484.

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22

Chung, Kimberly. "Investigation of the structure and properties of lanthanum strontium nickel oxide." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 360 p, 2008. http://proquest.umi.com/pqdweb?did=1609293431&sid=5&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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23

Tran, Khoa V. "Spectroscopic studies of tetranuclear Pd(II) and Pt(II) macrocyclic square complexes." Virtual Press, 2000. http://liblink.bsu.edu/uhtbin/catkey/1191722.

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Two macrocyclic squares (one with four Pd 21 corners, the other with four Pte+ corners) were synthesized according to literature methods."2 The charge-transfer complexes which formed when each were mixed with a bis(thiol)hydroquinone were then studied by UV-VIS, NMR, and IR spectroscopy. The UV-VIS data obtained indicated a stoichiometric relationship of I mole of molecular square to 2 moles of dithiol and a very large binding constant. Further evidence for the association between each macrocyclic square and the dithiol was observed in the NMR spectrum by the shifting of the proton resonances

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24

Zhou, Congying, and 周聰穎. "Ruthenium porphyrins and dirhodium (II, II) carboxylates catalyzed ylide-mediated cycloadditions and carbenoid transfer reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31046484.

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25

Dougherty, William G. Jr. "Synthesis, structure and reactivity of nickel-nickel complexes for understanding the A cluster in acetyl coenzyme A synthase." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 167 p, 2007. http://proquest.umi.com/pqdweb?did=1464120791&sid=6&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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26

Griffiths, D. C. "Thermal rearrangements of organoplatinum (II) compounds." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37713.

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27

Harron, Eilis Antonia. "Imido and amido compounds of Sn(II) and Mn(II)." Thesis, University of Cambridge, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.619780.

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28

Jupp, Kathleen M. "Dynamically sourced intensity in octahedral nickel(II) complexes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241013.

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29

Mattioli, Tony A. (Tony Andrea) Carleton University Dissertation Chemistry. "Resonance raman study of nickel (II) pheophytin a." Ottawa, 1988.

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30

Grill, Joseph Michael. "The design of new ligands and transition metal compounds for the oxidation of organic compounds." [College Station, Tex. : Texas A&M University, 2006. http://hdl.handle.net/1969.1/ETD-TAMU-1746.

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31

Xiao, Jie. "Layered lithium nickel manganese cobalt dioxide as a cathode material for Li-ion batteries." Diss., Online access via UMI:, 2008.

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32

Karwasara, Surendar. "Synthesis and reactivity of base-stabilized Ge(II) compounds, their terminal chalcogenides, and base-stabilized Sn(II) compounds." Thesis, IIT Delhi, 2016. http://localhost:8080/iit/handle/2074/7007.

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33

Tao, Chi-hang, and 陶志恆. "Synthesis and luminescence studies of branched carbonrich platinum(II)and palladium(II) alkynyl complexes: versatile building blocks for multinuclear assemblies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31246011.

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34

McLeod, John Edward. "Marker studies of nickel silicide formation." Master's thesis, University of Cape Town, 1988. http://hdl.handle.net/11427/15903.

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Includes bibliographical references.<br>Atomic diffusion during the solid state formation of thin films of nickel silicides (Ni2Si and NiSi) from nickel and amorphous silicon has been investigated using 31Si radioactive tracer and inert marker techniques. Samples were prepared by vacuum deposition of thin films of nickel and silicon, followed by thermal annealing to effect silicide growth. The radioactive tracer investigation of Ni2Si showed nickel to be the diffusing species during silicide growth. Sharply defined Ni2si* profiles of 100% radioactive concentration at the sample surface were -

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35

Hameury, Sophie. "Oxygen-functionalized NHC ligands and their nickel(II), silver(I) and palladium(II) complexes." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF010.

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L’objectif de cette thèse portait sur la synthèse de complexes portant un ligand NHC associé à une fonction oxygénée et à leur application en catalyse d’oligomérisation de l’éthylène. Dans le but de synthétiser des complexes avec des ligands NHCalcool, les complexes d’argent correspondants ont été synthétisés et utilisés en transmétallation. Aucun résultat concluant n’a pu être obtenu avec le nickel à cause de l’acidité du proton alcoolique. Mais un ligand NHC-alcoolate a pu être obtenu par déprotonation directe du pro-ligand avec une base forte. Il fut alors possible d’accéder à des complexes

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36

Marelli, Enrico. "Nickel- and palladium-catalysed deprotonative cross-couplings." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/15603.

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Transition metal-catalysed cross coupling chemistry is a valuable tool for synthetic organic chemistry, enabling the preparation of compounds of great interest. The catalytic metal of choice is usually palladium, which generally offer better performances in term of catalytic activity and easy handling. On the other hand, the use of nickel in this class of reactions is gaining attention, as it would provide more economically and environmentally sustainable processes. Deprotonative cross couplings are a subgroup of these reactions, in which the nucleophile is generated in situ by direct deproton

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37

Johnston, Simon Richard. "Characterisation of basic lead(II) and tin(II) compounds from aqueous systems." Thesis, Brunel University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294510.

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38

OLIVEIRA, MARIA STELLA NUNES DE. "SYNTHESIS AND CHARACTERIZATION OF COMPLEXES INVOLVING POLYAMINES AND THE METAL IONS ZINC (II), NICKEL (II) AND PALLADIUM (II)." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2010. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=16447@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>O presente trabalho descreve a síntese e a caracterização de treze complexos envolvendo as poliamina etilenodiamina, diaminopropano, diaminobutano, espermidina e espermina e os íons metálicos Zn (II), Ni (II) e Pd (II). Todas as sínteses foram realizadas em água, um solvente de importância biológica, e em condições próximas às fisiológicas, com o objetivo de mimetizar as ligações e compreender como ocorre a interação das poliaminas com ânions no ciclo biológico, haja vista que em pH fisiológico essas moléculas se encontram primordialmente n

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39

Perry, Richard John. "Structural studies on high oxidation state nickel complexes and their nickel(II) precursors using EXAFS spectroscopy." Thesis, University of Southampton, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.358484.

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40

Jessop, Philip Gregory. "The syntheses and reactions of carbonyl(phosphine)(thiolator)ruthenium(II) complexes." Thesis, University of British Columbia, 1991. http://hdl.handle.net/2429/30928.

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The chemistry of homogeneous transition metal systems offer parallels to the reactions on the surfaces of industrial hydrodesulphurization catalysts. The reactions of several ruthenium complexes with sulphur-containing reagents are described, with an emphasis on the kinetics and mechanisms thereof. The complex Ru(CO)₂(PPh₃)₃ (2), for example, reacts quickly with thiols and disulphides, producing cct-RuH(SR)(CO)₂(PPh₃)₂ (9) and cct-Ru(SR)₂(CO)₂(PPh₃)₂ (14), respectively, although 2 fails to react with unstrained thioethers. Reactions of the related complex Ru(CO)₂(PPh₃)(dpm) (dpm=Ph₂PCH₂PPh₂) a

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41

Li, Jian-Jun. "Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes /." free to MU campus, to others for purchase, 1996. http://wwwlib.umi.com/cr/mo/fullcit?p9720553.

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42

Viveros-Garcia, T. "Adsorption of sulphur compounds on nickel catalysts : poisoning and regeneration studies." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37886.

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43

Hung, Faan-fung, and 孔繁峰. "Luminescent platinum(II), palladium(II) and gold(III) complexes containing isocyanide, alkynyl and N-heterocyclic carbene ligands : synthesis, photophysical properties and material applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/206318.

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44

Lin, Wing-shan, and 林穎珊. "Synthesis and biological studies of anti-cancer rhodium(II, II) carboxylates, anti-inflammatory silver(I) thiourea and microbially fabricated silver nanoparticles." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/206649.

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Discovery of cisplatin as an effective anticancer agent has stimulated the development of metal based medicine. The recent advances in research on platinum, ruthenium and gold complexes have received much attention in medicinal chemistry, and studies of other less explored metal complexes may reveal alternative mode of mechanism as novel therapeutic agents. A series of dirhodium(II,II) complexes with carboxylate and carboxamidate ligands and thiourea complexes of coinage metals have been prepared in this study. Their biological activities and mechanisms of action have been studied. Dirhodiu

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45

de, Almeida Katia Júlia. "Optical and Magnetic Properties of Copper(II) Compounds." Doctoral thesis, KTH, Teoretisk kemi, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4743.

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This thesis encloses quantum chemical calculations and applications of a response function formalism recently implemented within the framework of density functional theory. The optical and magnetic properties of copper(II) molecular systems are the main goal of this work. In this work, the visible and near-infrared electronic transitions, which have shown a key role in studies on electronic structure and structure-function relationships of copper compounds, were investigated in order to explore the correlation of the positions and intensities of these transitions with the geometrical structure

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46

de, Almeida Katia Júlia. "Optical and magnetic properties of copper(II) compounds /." Stockholm : Department of Theoretical Chemistry, School of Biotechnology, Royal Institute of Technology, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4743.

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47

Houlton, Andrew. "Mossbauer spectroscopic studies of iron(II) sandwich compounds." Thesis, University of Essex, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252634.

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48

Money, Victoria A. "Structural studies of iron (II) spin crossover compounds." Thesis, Durham University, 2004. http://etheses.dur.ac.uk/2987/.

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The drive for ever smaller and faster computers has, in recent years, caused much research interest to be focussed on the development of new materials in which individual molecules or assemblies of molecules can be used for information processing. Materials which show spin crossover behaviour have great potential for use not only in molecular computing but also in applications such as optical switches and display devices and are of fundamental interest due to their importance in biological and geological systems. The results of comprehensive variable temperature and excited state crystallograp

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49

Roebuck, James William. "Reagents for selective extraction of nickel(II), cobalt(II) and copper(II) from highly acidic sulfate feeds containing iron." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/17976.

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This thesis focuses on development of new regents which are suitable for recovering nickel, cobalt and copper from laterite leach solutions, specifically focusing on reagent requirements for novel base metal flowsheets developed by Anglo American. The work aims to design reagents which can extract nickel(II), cobalt(II) and copper(II) from a highly acidic aqueous sulfate solutions whilst showing selectivity over iron(II) and iron(III). Chapter 1 reviews current extractive metallurgy processes for separating and concentrating metals in laterite ores and describes new flowsheets proposed by Angl

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50

Jouini, Mohamed. "Etude physico-chimique de complexes peptidiques du cuivre (II) et du nickel (II) en solution." Paris 7, 1985. http://www.theses.fr/1985PA077054.

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