Academic literature on the topic 'Confined Diffusion in Zeolite and BCC solid'

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Journal articles on the topic "Confined Diffusion in Zeolite and BCC solid"

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Tonutti, Lucas G., Lourdes Vergara, Carlos A. Querini, and Bruno O. Dalla Costa. "On the Location and Accessibility of Active Acid Sites in MFI Zeolites Modified by Alkaline Treatment." Processes 12, no. 11 (2024): 2567. http://dx.doi.org/10.3390/pr12112567.

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An MFI zeolite (Si/Al = 40) was desilicated by alkaline treatment in order to generate mesopores. Temperature, alkali concentration and treatment duration were adjusted to maximize mesoporosity while preserving the zeolite structure. Special attention was paid to the characterization of the strength and accessibility of the acid sites. The catalysts were tested in the isobutane/butene alkylation, a reaction that is typically catalyzed by zeolites but limited by coke deposition. Additionally, glycerol esterification with acetic acid was used as a test reaction due to the required participation
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Kellouai, Wanda, Jean-Louis Barrat, Patrick Judeinstein, Marie Plazanet, and Benoit Coasne. "On De Gennes narrowing of fluids confined at the molecular scale in nanoporous materials." Journal of Chemical Physics 160, no. 2 (2024). http://dx.doi.org/10.1063/5.0186956.

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Beyond well-documented confinement and surface effects arising from the large internal surface and severely confining porosity of nanoporous hosts, the transport of nanoconfined fluids remains puzzling in many aspects. With striking examples such as memory, i.e., non-viscous effects, intermittent dynamics, and surface barriers, the dynamics of fluids in nanoconfinement challenge classical formalisms (e.g., random walk, viscous/advective transport)—especially for molecular pore sizes. In this context, while molecular frameworks such as intermittent Brownian motion, free volume theory, and surfa
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Dissertations / Theses on the topic "Confined Diffusion in Zeolite and BCC solid"

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Nag, Shubhadeep. "Novel and Fundamental Studies of Separation Methods Leading to Very High Degree of Separation of Molecular Mixtures and Related Studies." Thesis, 2021. https://etd.iisc.ac.in/handle/2005/5224.

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Separation of molecular mixtures will often require in chemistry, biology, physics and material science. Existing methods of separation can at best yield a separation factor of 10^4 . They also incur huge expenditure of energy. A new and novel method of separation is proposed in the thesis based on Levitation and Blowtorch effects. This method has been applied for the separation of the four different mixtures, (i) n-pentane-neopentane, (ii) 2,2-dimethyl butane-n-pentane, (iii) n-hexane-neopentane, and (iv) 2,2-dimethyl butane-n-pentane. The results based on Non-Equilibrium Monte Carlo simulati
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Ghorai, Pradip Kumar. "Diffusion Maximum Or Levitation Effect In Porous Solids, Dense Fluids And Polar Liquids And Development Of Hydrocarbon-Zeolite Potential And Related Aspects." Thesis, 2004. https://etd.iisc.ac.in/handle/2005/1350.

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Ghorai, Pradip Kumar. "Diffusion Maximum Or Levitation Effect In Porous Solids, Dense Fluids And Polar Liquids And Development Of Hydrocarbon-Zeolite Potential And Related Aspects." Thesis, 2004. http://etd.iisc.ernet.in/handle/2005/1350.

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