Academic literature on the topic 'Cononsolvency effect'

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Journal articles on the topic "Cononsolvency effect"

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Xiao, Rui, Jin Qian, and Shaoxing Qu. "Modeling Gel Swelling in Binary Solvents: A Thermodynamic Approach to Explaining Cosolvency and Cononsolvency Effects." International Journal of Applied Mechanics 11, no. 05 (2019): 1950050. http://dx.doi.org/10.1142/s1758825119500509.

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If gel swells in binary solvents, two unusual phenomena may appear. Two solvents with relatively low swelling ability may become a good solvent for the polymer with high swelling ability when mixed, which is known as a cosolvency effect. In contrast, a cononsolvency effect indicates polymer is less soluable in solvent mixtures than it is in each of the cosolvents. In this work, we develop a thermodynamic theory to describe the equilibrium swelling behaviors of gels in binary solvents based on the Flory–Huggins lattice model. The model can reproduce both cosolvency and cononsolvency effects, sh
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Pica, Andrea, and Giuseppe Graziano. "On the cononsolvency behaviour of hydrophobic clusters in water–methanol solutions." Physical Chemistry Chemical Physics 20, no. 10 (2018): 7230–35. http://dx.doi.org/10.1039/c7cp07943e.

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Kleinschmidt, Denise, Katja Nothdurft, Mikhail V. Anakhov, et al. "Microgel organocatalysts: modulation of reaction rates at liquid–liquid interfaces." Materials Advances 1, no. 8 (2020): 2983–93. http://dx.doi.org/10.1039/d0ma00407c.

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Responsive colloidal microgel-catalysts were applied to an aldol reaction to study how temperature and the effect of cononsolvency can be used as triggers to modulate reaction rates in homogenous phase and on liquid–liquid interfaces.
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Pica, Andrea, and Giuseppe Graziano. "Hydrostatic pressure effect on PNIPAM cononsolvency in water-methanol solutions." Biophysical Chemistry 231 (December 2017): 34–38. http://dx.doi.org/10.1016/j.bpc.2017.01.001.

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Guettari, Moez, Riadh Gomati, and Abdelhafidh Gharbi. "Effect of Temperature on Cononsolvency of Polyvinylpyrrolidone in Water/Methanol Mixture." Journal of Macromolecular Science, Part B 49, no. 3 (2010): 552–62. http://dx.doi.org/10.1080/00222341003595378.

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Kyriakos, Konstantinos, Martine Philipp, Che-Hung Lin, et al. "Quantifying the Interactions in the Aggregation of Thermoresponsive Polymers: The Effect of Cononsolvency." Macromolecular Rapid Communications 37, no. 5 (2016): 420–25. http://dx.doi.org/10.1002/marc.201500583.

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Wang, Huan, Yingli An, Nan Huang, Rujiang Ma, and Linqi Shi. "Investigation of the cononsolvency effect on micellization behavior of polystyrene-b-poly(N-isopropylacrylamide)." Journal of Colloid and Interface Science 317, no. 2 (2008): 637–42. http://dx.doi.org/10.1016/j.jcis.2007.09.063.

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Richter, Marcel, Melanie Hunnenmörder, and Regine V. Klitzing. "The impact of the cononsolvency effect on poly (N-isopropylacrylamide) based microgels at interfaces." Colloid and Polymer Science 292, no. 10 (2014): 2439–52. http://dx.doi.org/10.1007/s00396-014-3340-7.

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Niebuur, Bart-Jan, Chia-Hsin Ko, Xiaohan Zhang, et al. "Pressure Dependence of the Cononsolvency Effect in Aqueous Poly(N-isopropylacrylamide) Solutions: A SANS Study." Macromolecules 53, no. 10 (2020): 3946–55. http://dx.doi.org/10.1021/acs.macromol.0c00489.

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Pérez-Ramírez, H. A., C. Haro-Pérez, and G. Odriozola. "Effect of Temperature on the Cononsolvency of Poly(N-isopropylacrylamide) (PNIPAM) in Aqueous 1-Propanol." ACS Applied Polymer Materials 1, no. 11 (2019): 2961–72. http://dx.doi.org/10.1021/acsapm.9b00665.

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Dissertations / Theses on the topic "Cononsolvency effect"

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"Solubility tuning using the hydrophobic effect and its derivatives." Tulane University, 2021.

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archives@tulane.edu<br>Solubility is the ability of a molecule to favorably interact with a solvent. While seemingly simple in application many phenomena arise from knife-edge like conditions between solubility and insolubility. Herein, three of these phenomena; co-non-solvency, the hydrophobic effect, and the direct and reverse Hofmeister effects are investigated in detail to parse out a mechanistic view of solubility in each case. The first phenomenon, co-non-solvency, is the insolubility of a thermo-responsive polymer and a mixture of two good cosolvents. Host-guest systems are used to prob
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Yong, Huaisong. "Polymer Phase Separation in Competition Solvents." 2020. https://tud.qucosa.de/id/qucosa%3A74795.

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Cononsolvency occurs if a mixture of two good solvents causes the collapse or demixing of polymers into a polymer-rich phase in a certain range of compositions of these two solvents. The better solvent is usually called cosolvent and another common solvent is called solvent. So far, the phase-transition mechanism behind cononsolvency is still rather controversially debated in literature. In this thesis, I experimentally investigated the cononsolvency effect of poly(N-isopropylacrylamide) (PNiPAAm) brushes with different grafting density in aqueous alcohol mixtures. I have used Vis-spectroscopi
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"Cononsolvency and effects on hydrophobic assembly." Tulane University, 2018.

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acase@tulane.edu<br>Self-assembly driven by the hydrophobic effect is the fascinating phenomenon by which non-polar moieties in aqueous solution form unique structures. Perhaps the best known of these assembly processes is the creation of a micelle in water, where hydrophobic tail groups are forced inward while hydrophilic head groups are attracted to aqueous solvent. Beyond micellization, the hydrophobic effect has a strong effect on supramolecular assemblies where guest and host are driven together through the hydrophobic effect. One such supramolecular host is the deep cavity cavitand Octa-
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