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Journal articles on the topic 'Cononsolvency effect'

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1

Xiao, Rui, Jin Qian, and Shaoxing Qu. "Modeling Gel Swelling in Binary Solvents: A Thermodynamic Approach to Explaining Cosolvency and Cononsolvency Effects." International Journal of Applied Mechanics 11, no. 05 (2019): 1950050. http://dx.doi.org/10.1142/s1758825119500509.

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If gel swells in binary solvents, two unusual phenomena may appear. Two solvents with relatively low swelling ability may become a good solvent for the polymer with high swelling ability when mixed, which is known as a cosolvency effect. In contrast, a cononsolvency effect indicates polymer is less soluable in solvent mixtures than it is in each of the cosolvents. In this work, we develop a thermodynamic theory to describe the equilibrium swelling behaviors of gels in binary solvents based on the Flory–Huggins lattice model. The model can reproduce both cosolvency and cononsolvency effects, sh
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2

Pica, Andrea, and Giuseppe Graziano. "On the cononsolvency behaviour of hydrophobic clusters in water–methanol solutions." Physical Chemistry Chemical Physics 20, no. 10 (2018): 7230–35. http://dx.doi.org/10.1039/c7cp07943e.

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3

Kleinschmidt, Denise, Katja Nothdurft, Mikhail V. Anakhov, et al. "Microgel organocatalysts: modulation of reaction rates at liquid–liquid interfaces." Materials Advances 1, no. 8 (2020): 2983–93. http://dx.doi.org/10.1039/d0ma00407c.

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Responsive colloidal microgel-catalysts were applied to an aldol reaction to study how temperature and the effect of cononsolvency can be used as triggers to modulate reaction rates in homogenous phase and on liquid–liquid interfaces.
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4

Pica, Andrea, and Giuseppe Graziano. "Hydrostatic pressure effect on PNIPAM cononsolvency in water-methanol solutions." Biophysical Chemistry 231 (December 2017): 34–38. http://dx.doi.org/10.1016/j.bpc.2017.01.001.

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5

Guettari, Moez, Riadh Gomati, and Abdelhafidh Gharbi. "Effect of Temperature on Cononsolvency of Polyvinylpyrrolidone in Water/Methanol Mixture." Journal of Macromolecular Science, Part B 49, no. 3 (2010): 552–62. http://dx.doi.org/10.1080/00222341003595378.

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6

Kyriakos, Konstantinos, Martine Philipp, Che-Hung Lin, et al. "Quantifying the Interactions in the Aggregation of Thermoresponsive Polymers: The Effect of Cononsolvency." Macromolecular Rapid Communications 37, no. 5 (2016): 420–25. http://dx.doi.org/10.1002/marc.201500583.

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7

Wang, Huan, Yingli An, Nan Huang, Rujiang Ma, and Linqi Shi. "Investigation of the cononsolvency effect on micellization behavior of polystyrene-b-poly(N-isopropylacrylamide)." Journal of Colloid and Interface Science 317, no. 2 (2008): 637–42. http://dx.doi.org/10.1016/j.jcis.2007.09.063.

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8

Richter, Marcel, Melanie Hunnenmörder, and Regine V. Klitzing. "The impact of the cononsolvency effect on poly (N-isopropylacrylamide) based microgels at interfaces." Colloid and Polymer Science 292, no. 10 (2014): 2439–52. http://dx.doi.org/10.1007/s00396-014-3340-7.

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9

Niebuur, Bart-Jan, Chia-Hsin Ko, Xiaohan Zhang, et al. "Pressure Dependence of the Cononsolvency Effect in Aqueous Poly(N-isopropylacrylamide) Solutions: A SANS Study." Macromolecules 53, no. 10 (2020): 3946–55. http://dx.doi.org/10.1021/acs.macromol.0c00489.

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10

Pérez-Ramírez, H. A., C. Haro-Pérez, and G. Odriozola. "Effect of Temperature on the Cononsolvency of Poly(N-isopropylacrylamide) (PNIPAM) in Aqueous 1-Propanol." ACS Applied Polymer Materials 1, no. 11 (2019): 2961–72. http://dx.doi.org/10.1021/acsapm.9b00665.

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11

Xun, Weiwei, and Walter Richtering. "Dilution leading to viscosity increase based on the cononsolvency effect of temperature-sensitive microgel suspensions." Colloids and Surfaces A: Physicochemical and Engineering Aspects 484 (November 2015): 377–85. http://dx.doi.org/10.1016/j.colsurfa.2015.08.014.

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12

Yong, Huaisong, Bastien Molcrette, Marcel Sperling, Fabien Montel, and Jens-Uwe Sommer. "Regulating the Translocation of DNA through Poly(N-isopropylacrylamide)-Decorated Switchable Nanopores by Cononsolvency Effect." Macromolecules 54, no. 9 (2021): 4432–42. http://dx.doi.org/10.1021/acs.macromol.1c00215.

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13

Matsuguchi, Masanobu, and Shinnosuke Fujii. "HCl Gas Sensor Coating Based on Poly(N-isopropylacrylamide) Nanoparticles Prepared from Water-Methanol Binary Solvent." Sensors 18, no. 10 (2018): 3283. http://dx.doi.org/10.3390/s18103283.

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Poly(N-isopropylacrylamide) (PNIPAM) nanoparticles formed in water-methanol binary solvent were successfully deposited on a resonator surface at room temperature by exploiting the cononsolvency effect on the phase transition of PNIPAM aqueous solutions. Scanning electron microscopic observation revealed that the nanoparticles were secondary and made up of agglomerated primary spherical particles of about 10-nm diameter, buried in the film. The magnitude of the sensor response toward HCl gas was larger than that of the nanoparticle sensor prepared from pure water solvent, and the sensitivity to
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14

Xue, Jinqiao, Wei Bai, Hanyi Duan, et al. "Tetraphenylethene Cross-Linked Thermosensitive Microgels via Acylhydrazone Bonds: Aggregation-Induced Emission in Nanoconfined Environments and the Cononsolvency Effect." Macromolecules 51, no. 15 (2018): 5762–72. http://dx.doi.org/10.1021/acs.macromol.8b01100.

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15

Alenichev, Igor, Zdeňka Sedláková, and Michal Ilavský. "Swelling and mechanical behavior of charged poly(N-isopropylmethacrylamide) and poly(N-isopropylacrylamide) networks in water/ethanol mixtures. Cononsolvency effect." Polymer Bulletin 58, no. 1 (2006): 191–99. http://dx.doi.org/10.1007/s00289-006-0586-3.

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16

Biswas, Chandra Sekhar, Qiao Wang, Bing Du, and Florian J. Stadler. "Testing of the effect of parameters on the cononsolvency of random copolymer gels of N-isopropylacrylamide and N-ethylacrylamide in methanol-water mixed solvents by simple gravimetric method." Polymer Testing 62 (September 2017): 177–88. http://dx.doi.org/10.1016/j.polymertesting.2017.06.028.

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17

Backes, Sebastian, Patrick Krause, Weronika Tabaka, Marcus U. Witt, and Regine von Klitzing. "Combined Cononsolvency and Temperature Effects on Adsorbed PNIPAM Microgels." Langmuir 33, no. 50 (2017): 14269–77. http://dx.doi.org/10.1021/acs.langmuir.7b02903.

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18

Maccarrone, Simona, Christine Scherzinger, Olaf Holderer, et al. "Cononsolvency Effects on the Structure and Dynamics of Microgels." Macromolecules 47, no. 17 (2014): 5982–88. http://dx.doi.org/10.1021/ma500954t.

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19

López-León, Teresa, Delfina Bastos-González, Juan Luis Ortega-Vinuesa, and Abdelhamid Elaïssari. "Salt Effects in the Cononsolvency of Poly(N-isopropylacrylamide) Microgels." ChemPhysChem 11, no. 1 (2010): 188–94. http://dx.doi.org/10.1002/cphc.200900491.

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20

Morales-Moctezuma, Marissa D., and Sebastian G. Spain. "The effects of cononsolvents on the synthesis of responsive particles via polymerisation-induced thermal self-assembly." Polymer Chemistry 12, no. 32 (2021): 4696–706. http://dx.doi.org/10.1039/d1py00396h.

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Responsive nanogels were synthesised via RAFT-mediated polymerisation-induced thermal self-assembly in cononsolvent mixtures of water and ethanol. The solvent mixture affected the particle size, tacticity and thermal properties.
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21

Lang, Xiaolong, Erin X. Xu, Yuan Wei, Lauren N. Walters, and Michael J. A. Hore. "Isomeric and structural effects in polymer cononsolvent systems." Polymer 170 (April 2019): 190–97. http://dx.doi.org/10.1016/j.polymer.2019.03.011.

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22

Chen, Jean-Hong, Hsiu-Hsiu Chen, Ying-Xun Chang, Pei-Ying Chuang, and Po-Da Hong. "Effects of cononsolvency on preferential adsorption phenomenon in poly(N-isopropylacrylamide) ternary solutions." Journal of Applied Polymer Science 107, no. 4 (2007): 2732–42. http://dx.doi.org/10.1002/app.27359.

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23

Osaka, Noboru, and Mitsuhiro Shibayama. "Pressure Effects on Cononsolvency Behavior of Poly(N-isopropylacrylamide) in Water/DMSO Mixed Solvents." Macromolecules 45, no. 4 (2012): 2171–74. http://dx.doi.org/10.1021/ma2027116.

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24

Takahashi, Nobuaki, Toshiji Kanaya, Koji Nishida, and Keisuke Kaji. "Effects of cononsolvency on gelation of poly(vinyl alcohol) in mixed solvents of dimethyl sulfoxide and water." Polymer 44, no. 15 (2003): 4075–78. http://dx.doi.org/10.1016/s0032-3861(03)00390-2.

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25

Wu, Shuwang, Yousif Alsaid, Bowen Yao, et al. "Rapid and scalable fabrication of ultra‐stretchable, anti‐freezing conductive gels by cononsolvency effect." EcoMat 3, no. 2 (2021). http://dx.doi.org/10.1002/eom2.12085.

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26

Ma, Jie, Zheng Jia, and Shaoxing Qu. "A Constitutive Model for Binary-Solvent Gels." Journal of Applied Mechanics 87, no. 8 (2020). http://dx.doi.org/10.1115/1.4047116.

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Abstract A hydrogel is a network of polymeric chains hosting a large amount of the single solvent, namely, water. The high degree of hydration not only endows hydrogels with desired attributes such as superb biocompatibility but it also yields disadvantages, including high volatility and inability to host hydrophobic drugs. The need for enhancing the versatility of hydrogels to meet requirements of diverse applications has led to the fabrication of binary-solvent gels (e.g., gels in aqueous ethanol) with the hope to capitalize on both the merits of water and other organic solvents. In this pap
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