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Journal articles on the topic 'Cononsolvency'

Author: Grafiati

Published: 4 June 2021

Last updated: 5 February 2022

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1

Xiao, Rui, Jin Qian, and Shaoxing Qu. "Modeling Gel Swelling in Binary Solvents: A Thermodynamic Approach to Explaining Cosolvency and Cononsolvency Effects." International Journal of Applied Mechanics 11, no. 05 (June 2019): 1950050. http://dx.doi.org/10.1142/s1758825119500509.

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If gel swells in binary solvents, two unusual phenomena may appear. Two solvents with relatively low swelling ability may become a good solvent for the polymer with high swelling ability when mixed, which is known as a cosolvency effect. In contrast, a cononsolvency effect indicates polymer is less soluable in solvent mixtures than it is in each of the cosolvents. In this work, we develop a thermodynamic theory to describe the equilibrium swelling behaviors of gels in binary solvents based on the Flory–Huggins lattice model. The model can reproduce both cosolvency and cononsolvency effects, showing that these effects are caused by the preferential absorption of the solvent by polymer together with solvent–solvent interactions. The model is also applied to describe experimentally observed cosolvency and cononsolvency effects in the literature, which shows an acceptable agreement.

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2

Wang, Jian, Nian Wang, Biaolan Liu, Jia Bai, Pei Gong, Geying Ru, and Jiwen Feng. "Preferential adsorption of the additive is not a prerequisite for cononsolvency in water-rich mixtures." Physical Chemistry Chemical Physics 19, no. 44 (2017): 30097–106. http://dx.doi.org/10.1039/c7cp04384h.

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3

Mochizuki, Kenji, and Kenichiro Koga. "Cononsolvency behavior of hydrophobes in water + methanol mixtures." Physical Chemistry Chemical Physics 18, no. 24 (2016): 16188–95. http://dx.doi.org/10.1039/c6cp01496h.

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4

Bharadwaj, Swaminath, and Nico F. A. van der Vegt. "Does Preferential Adsorption Drive Cononsolvency?" Macromolecules 52, no. 11 (May 23, 2019): 4131–38. http://dx.doi.org/10.1021/acs.macromol.9b00575.

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5

Pica, Andrea, and Giuseppe Graziano. "On the cononsolvency behaviour of hydrophobic clusters in water–methanol solutions." Physical Chemistry Chemical Physics 20, no. 10 (2018): 7230–35. http://dx.doi.org/10.1039/c7cp07943e.

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6

Pica, Andrea, and Giuseppe Graziano. "An alternative explanation of the cononsolvency of poly(N-isopropylacrylamide) in water–methanol solutions." Physical Chemistry Chemical Physics 18, no. 36 (2016): 25601–8. http://dx.doi.org/10.1039/c6cp04753j.

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7

Lucht, Niklas, Steffen Eggers, and Volker Abetz. "Cononsolvency in the ‘drunken’ state: the thermoresponsiveness of a new acrylamide copolymer in water–alcohol mixtures." Polymer Chemistry 8, no. 7 (2017): 1196–205. http://dx.doi.org/10.1039/c6py01751g.

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8

Nothdurft, Katja, David H. Müller, Thorsten Brands, André Bardow, and Walter Richtering. "Enrichment of methanol inside pNIPAM gels in the cononsolvency-induced collapse." Physical Chemistry Chemical Physics 21, no. 41 (2019): 22811–18. http://dx.doi.org/10.1039/c9cp04383g.

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9

Zhang, Xiangyu, Jing Zong, and Dong Meng. "A unified understanding of the cononsolvency of polymers in binary solvent mixtures." Soft Matter 16, no. 33 (2020): 7789–96. http://dx.doi.org/10.1039/d0sm00811g.

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10

Kleinschmidt, Denise, Katja Nothdurft, Mikhail V. Anakhov, Anna A. Meyer, Matthias Mork, Rustam A. Gumerov, Igor I. Potemkin, Walter Richtering, and Andrij Pich. "Microgel organocatalysts: modulation of reaction rates at liquid–liquid interfaces." Materials Advances 1, no. 8 (2020): 2983–93. http://dx.doi.org/10.1039/d0ma00407c.

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Responsive colloidal microgel-catalysts were applied to an aldol reaction to study how temperature and the effect of cononsolvency can be used as triggers to modulate reaction rates in homogenous phase and on liquid–liquid interfaces.

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11

Pica, Andrea, and Giuseppe Graziano. "Comment on “Relating side chain organization of PNIPAm with its conformation in aqueous methanol” by D. Mukherji, M. Wagner, M. D. Watson, S. Winzen, T. E. de Oliveira, C. M. Marques and K. Kremer, Soft Matter, 2016, 12, 7995." Soft Matter 13, no. 42 (2017): 7698–700. http://dx.doi.org/10.1039/c7sm01065f.

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We try to clarify some issues that were raised by an article that appeared in Soft Matter, 2016, 12, 7995. PNIPAM cononsolvency is not due to the bridging mechanism of MeOH molecules; it is caused by geometric-energetic frustration.

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12

Dalgicdir, Cahit, Francisco Rodríguez-Ropero, and Nico F. A. van der Vegt. "Computational Calorimetry of PNIPAM Cononsolvency in Water/Methanol Mixtures." Journal of Physical Chemistry B 121, no. 32 (August 7, 2017): 7741–48. http://dx.doi.org/10.1021/acs.jpcb.7b05960.

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13

Backes, Sebastian, Patrick Krause, Weronika Tabaka, Marcus U. Witt, and Regine von Klitzing. "Combined Cononsolvency and Temperature Effects on Adsorbed PNIPAM Microgels." Langmuir 33, no. 50 (December 5, 2017): 14269–77. http://dx.doi.org/10.1021/acs.langmuir.7b02903.

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14

Mills, Carolyn E., Erika Ding, and Bradley D. Olsen. "Cononsolvency of Elastin-like Polypeptides in Water/Alcohol Solutions." Biomacromolecules 20, no. 6 (May 22, 2019): 2167–73. http://dx.doi.org/10.1021/acs.biomac.8b01644.

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15

Schild, Howard G., M. Muthukumar, and David A. Tirrell. "Cononsolvency in mixed aqueous solutions of poly(N-isopropylacrylamide)." Macromolecules 24, no. 4 (July 1991): 948–52. http://dx.doi.org/10.1021/ma00004a022.

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16

Heppner, Ian N., Molla R. Islam, and Michael J. Serpe. "Unexpected Cononsolvency Behavior of Poly (N-isopropylacrylamide)-Based Microgels." Macromolecular Rapid Communications 34, no. 21 (September 23, 2013): 1708–13. http://dx.doi.org/10.1002/marc.201300626.

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17

Maccarrone, Simona, Christine Scherzinger, Olaf Holderer, Peter Lindner, Melissa Sharp, Walter Richtering, and Dieter Richter. "Cononsolvency Effects on the Structure and Dynamics of Microgels." Macromolecules 47, no. 17 (August 20, 2014): 5982–88. http://dx.doi.org/10.1021/ma500954t.

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18

Qiu, Xiao Xia, Jie Sun, Shu Jie Tong, Shi Jia Wang, Li Yuan Wu, Fang Yuan Cheng, and Hai Ning Lv. "Cononsolvency Phenomena of Poly(N-Isopropylacrylamide) in Mixed Solvents at Different Temperatures." Advanced Materials Research 332-334 (September 2011): 1752–55. http://dx.doi.org/10.4028/www.scientific.net/amr.332-334.1752.

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N-isopropylacrylamide was synthesized in a mixture of DMF and THF ( 7:3 in volume ratio) and characterized by FT-IR. The behavior of poly(N-isopropylacrylamide) chain was studied by spectrometer in mixtures of water with DMF and THF. Cononsolvency phenomena were found to be temperature-dependent, as demixing occurred upon increasing temperature. A significant shrinkage of polymer chains and deswelling of polymer gels, followed by phase separation, were observed for high water fractions.

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19

LÃ³pez-LeÃ³n, Teresa, Delfina Bastos-GonzÃ¡lez, Juan Luis Ortega-Vinuesa, and Abdelhamid ElaÃ¯ssari. "Salt Effects in the Cononsolvency of Poly(N-isopropylacrylamide) Microgels." ChemPhysChem 11, no. 1 (January 18, 2010): 188–94. http://dx.doi.org/10.1002/cphc.200900491.

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20

Pica, Andrea, and Giuseppe Graziano. "Hydrostatic pressure effect on PNIPAM cononsolvency in water-methanol solutions." Biophysical Chemistry 231 (December 2017): 34–38. http://dx.doi.org/10.1016/j.bpc.2017.01.001.

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21

Yong, Huaisong, Sebastian Rauch, Klaus-Jochen Eichhorn, Petra Uhlmann, Andreas Fery, and Jens-Uwe Sommer. "Cononsolvency Transition of Polymer Brushes: A Combined Experimental and Theoretical Study." Materials 11, no. 6 (June 11, 2018): 991. http://dx.doi.org/10.3390/ma11060991.

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22

Saltzman, Alexander, Hayden Houser, Mae Langrehr, and Henry S. Ashbaugh. "Nonpolar solute cononsolvency in ethanol/water mixtures – Connections to solvent structure." Journal of Molecular Liquids 298 (January 2020): 111944. http://dx.doi.org/10.1016/j.molliq.2019.111944.

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23

Dalgicdir, Cahit, Francisco Rodríguez-Ropero, and Nico F. A. van der Vegt. "Correction to “Computational Calorimetry of PNIPAM Cononsolvency in Water/Methanol Mixtures”." Journal of Physical Chemistry B 123, no. 4 (January 17, 2019): 955. http://dx.doi.org/10.1021/acs.jpcb.9b00306.

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24

Zuo, Taisen, Changli Ma, Guisheng Jiao, Zehua Han, Shiyan Xiao, Haojun Liang, Liang Hong, et al. "Water/Cosolvent Attraction Induced Phase Separation: A Molecular Picture of Cononsolvency." Macromolecules 52, no. 2 (January 4, 2019): 457–64. http://dx.doi.org/10.1021/acs.macromol.8b02196.

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25

Guettari, Moez, Riadh Gomati, and Abdelhafidh Gharbi. "Effect of Temperature on Cononsolvency of Polyvinylpyrrolidone in Water/Methanol Mixture." Journal of Macromolecular Science, Part B 49, no. 3 (April 27, 2010): 552–62. http://dx.doi.org/10.1080/00222341003595378.

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26

Scherzinger, C., O. Holderer, D. Richter, and W. Richtering. "Polymer dynamics in responsive microgels: influence of cononsolvency and microgel architecture." Physical Chemistry Chemical Physics 14, no. 8 (2012): 2762. http://dx.doi.org/10.1039/c2cp23328b.

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27

Hao, Jinkun, He Cheng, Paul Butler, Li Zhang, and Charles C. Han. "Origin of cononsolvency, based on the structure of tetrahydrofuran-water mixture." Journal of Chemical Physics 132, no. 15 (April 21, 2010): 154902. http://dx.doi.org/10.1063/1.3381177.

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28

Chen, Xueqian, Wei Feng, Xia Han, and Honglai Liu. "Possible Way to Study Cononsolvency in Confinement: A Lattice Density Functional Theory Approach." Langmuir 33, no. 42 (September 27, 2017): 11446–56. http://dx.doi.org/10.1021/acs.langmuir.7b03134.

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29

Yang, Man, and Kongshuang Zhao. "Cononsolvency of poly(N-isopropylacrylamide) in methanol aqueous solution-insight by dielectric spectroscopy." Journal of Polymer Science Part B: Polymer Physics 55, no. 16 (June 4, 2017): 1227–34. http://dx.doi.org/10.1002/polb.24377.

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30

Chen, Jean-Hong, Hsiu-Hsiu Chen, Ying-Xun Chang, Pei-Ying Chuang, and Po-Da Hong. "Effects of cononsolvency on preferential adsorption phenomenon in poly(N-isopropylacrylamide) ternary solutions." Journal of Applied Polymer Science 107, no. 4 (2007): 2732–42. http://dx.doi.org/10.1002/app.27359.

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31

Kyriakos, Konstantinos, Martine Philipp, Che-Hung Lin, Margarita Dyakonova, Natalya Vishnevetskaya, Isabelle Grillo, Alessio Zaccone, et al. "Quantifying the Interactions in the Aggregation of Thermoresponsive Polymers: The Effect of Cononsolvency." Macromolecular Rapid Communications 37, no. 5 (January 18, 2016): 420–25. http://dx.doi.org/10.1002/marc.201500583.

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32

Dudowicz, Jacek, Karl F. Freed, and Jack F. Douglas. "Communication: Cosolvency and cononsolvency explained in terms of a Flory-Huggins type theory." Journal of Chemical Physics 143, no. 13 (October 7, 2015): 131101. http://dx.doi.org/10.1063/1.4932061.

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33

Scherzinger, Christine, Annett Schwarz, André Bardow, Kai Leonhard, and Walter Richtering. "Cononsolvency of poly-N-isopropyl acrylamide (PNIPAM): Microgels versus linear chains and macrogels." Current Opinion in Colloid & Interface Science 19, no. 2 (April 2014): 84–94. http://dx.doi.org/10.1016/j.cocis.2014.03.011.

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34

Matsuguchi, Masanobu, and Shinnosuke Fujii. "HCl Gas Sensor Coating Based on Poly(N-isopropylacrylamide) Nanoparticles Prepared from Water-Methanol Binary Solvent." Sensors 18, no. 10 (September 29, 2018): 3283. http://dx.doi.org/10.3390/s18103283.

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Poly(N-isopropylacrylamide) (PNIPAM) nanoparticles formed in water-methanol binary solvent were successfully deposited on a resonator surface at room temperature by exploiting the cononsolvency effect on the phase transition of PNIPAM aqueous solutions. Scanning electron microscopic observation revealed that the nanoparticles were secondary and made up of agglomerated primary spherical particles of about 10-nm diameter, buried in the film. The magnitude of the sensor response toward HCl gas was larger than that of the nanoparticle sensor prepared from pure water solvent, and the sensitivity to 1 ppm of HCl of sensor-coated nanoparticles based on the present method was 3.3 Hz/ppm. The recovery of the sensors was less than 90% at first cycle measurement, but had improved to almost 100% at the third cycle.

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35

Mochizuki, Kenji, Shannon R. Pattenaude, and Dor Ben-Amotz. "Influence of Cononsolvency on the Aggregation of Tertiary Butyl Alcohol in Methanol–Water Mixtures." Journal of the American Chemical Society 138, no. 29 (July 14, 2016): 9045–48. http://dx.doi.org/10.1021/jacs.6b04914.

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36

Osaka, Noboru, and Mitsuhiro Shibayama. "Pressure Effects on Cononsolvency Behavior of Poly(N-isopropylacrylamide) in Water/DMSO Mixed Solvents." Macromolecules 45, no. 4 (February 10, 2012): 2171–74. http://dx.doi.org/10.1021/ma2027116.

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37

Wang, Huan, Yingli An, Nan Huang, Rujiang Ma, and Linqi Shi. "Investigation of the cononsolvency effect on micellization behavior of polystyrene-b-poly(N-isopropylacrylamide)." Journal of Colloid and Interface Science 317, no. 2 (January 2008): 637–42. http://dx.doi.org/10.1016/j.jcis.2007.09.063.

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38

Richter, Marcel, Melanie Hunnenmörder, and Regine V. Klitzing. "The impact of the cononsolvency effect on poly (N-isopropylacrylamide) based microgels at interfaces." Colloid and Polymer Science 292, no. 10 (August 19, 2014): 2439–52. http://dx.doi.org/10.1007/s00396-014-3340-7.

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39

Wang, Jing-Hong, Rui Chen, Zi-Qing Zhao, Jie Shen, He Yang, Yan Luo, Gao-Jian Chen, Hong Chen, and John L. Brash. "Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency." Chinese Journal of Polymer Science 39, no. 7 (March 23, 2021): 856–64. http://dx.doi.org/10.1007/s10118-021-2541-z.

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40

Geiger, Christina, Julija Reitenbach, Lucas P. Kreuzer, Tobias Widmann, Peixi Wang, Robert Cubitt, Cristiane Henschel, André Laschewsky, Christine M. Papadakis, and Peter Müller-Buschbaum. "PMMA-b-PNIPAM Thin Films Display Cononsolvency-Driven Response in Mixed Water/Methanol Vapors." Macromolecules 54, no. 7 (April 2, 2021): 3517–30. http://dx.doi.org/10.1021/acs.macromol.1c00021.

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41

Niebuur, Bart-Jan, Chia-Hsin Ko, Xiaohan Zhang, Kora-Lee Claude, Leonardo Chiappisi, Alfons Schulte, and Christine M. Papadakis. "Pressure Dependence of the Cononsolvency Effect in Aqueous Poly(N-isopropylacrylamide) Solutions: A SANS Study." Macromolecules 53, no. 10 (May 5, 2020): 3946–55. http://dx.doi.org/10.1021/acs.macromol.0c00489.

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42

Hofmann, Christian H., Sebastian Grobelny, Mirko Erlkamp, Roland Winter, and Walter Richtering. "Influence of high-pressure on cononsolvency of poly(N-isopropylacrylamide) nanogels in water/methanol mixtures." Polymer 55, no. 8 (April 2014): 2000–2007. http://dx.doi.org/10.1016/j.polymer.2014.03.006.

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43

Scherzinger, C., A. Balaceanu, C. H. Hofmann, A. Schwarz, K. Leonhard, A. Pich, and W. Richtering. "Cononsolvency of mono- and di-alkyl N-substituted poly(acrylamide)s and poly(vinyl caprolactam)." Polymer 62 (April 2015): 50–59. http://dx.doi.org/10.1016/j.polymer.2015.02.007.

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44

Nian, Shifeng, and Lin Pu. "Racemic Fluorescence Probe for Enantiomeric Excess Determination: Application of Cononsolvency of a Polymer in Sensing." Journal of Organic Chemistry 84, no. 2 (December 14, 2018): 909–13. http://dx.doi.org/10.1021/acs.joc.8b02793.

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45

Pérez-Ramírez, H. A., C. Haro-Pérez, and G. Odriozola. "Effect of Temperature on the Cononsolvency of Poly(N-isopropylacrylamide) (PNIPAM) in Aqueous 1-Propanol." ACS Applied Polymer Materials 1, no. 11 (October 17, 2019): 2961–72. http://dx.doi.org/10.1021/acsapm.9b00665.

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46

Xun, Weiwei, and Walter Richtering. "Dilution leading to viscosity increase based on the cononsolvency effect of temperature-sensitive microgel suspensions." Colloids and Surfaces A: Physicochemical and Engineering Aspects 484 (November 2015): 377–85. http://dx.doi.org/10.1016/j.colsurfa.2015.08.014.

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47

Yong, Huaisong, Bastien Molcrette, Marcel Sperling, Fabien Montel, and Jens-Uwe Sommer. "Regulating the Translocation of DNA through Poly(N-isopropylacrylamide)-Decorated Switchable Nanopores by Cononsolvency Effect." Macromolecules 54, no. 9 (April 23, 2021): 4432–42. http://dx.doi.org/10.1021/acs.macromol.1c00215.

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48

Pagonis, Konstantinos, and Georgios Bokias. "Upper critical solution temperature—type cononsolvency of poly(N,N-dimethylacrylamide) in water—organic solvent mixtures." Polymer 45, no. 7 (March 2004): 2149–53. http://dx.doi.org/10.1016/j.polymer.2004.01.063.

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49

Matsuda, Yasuhiro, Motoyasu Kobayashi, Masahiko Annaka, Kazuhiko Ishihara, and Atsushi Takahara. "UCST-Type Cononsolvency Behavior of Poly(2-methacryloxyethyl phosphorylcholine) in the Mixture of Water and Ethanol." Polymer Journal 40, no. 5 (March 26, 2008): 479–83. http://dx.doi.org/10.1295/polymj.pj2008009.

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50

Saunders, Brian R., Helen M. Crowther, and Brian Vincent. "Poly[(methyl methacrylate)-co-(methacrylic acid)] Microgel Particles: Swelling Control Using pH, Cononsolvency, and Osmotic Deswelling." Macromolecules 30, no. 3 (February 1997): 482–87. http://dx.doi.org/10.1021/ma961277f.

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