Dissertations / Theses on the topic 'Continual mixer'
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Černý, Jan. "Dvoušnekový mísič kontinuální." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2021. http://www.nusl.cz/ntk/nusl-442867.
Full textČerný, Jan. "Dvoušnekový mísič kontinuální." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2020. http://www.nusl.cz/ntk/nusl-433469.
Full textPelka, Tomáš. "Šnekový mísič kontinuální." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2011. http://www.nusl.cz/ntk/nusl-229978.
Full textNancib, Ayacha. "Production d'acide lactique par Lactobacillus casei subsp. rhamnosus sur jus de datte : cinétique et optimisation en cultures discontinues, semi-continues et continues." Thesis, Vandoeuvre-les-Nancy, INPL, 2007. http://www.theses.fr/2007INPL074N/document.
Full textThe aim of this work was to develop an efficient process of lactic acid production by Lactobacillus casei subsp. rhamnosus on date juice In a first part, the batch cultures were realized to carry out the nutritional requirement of the strain. These studies allowed us to describe the effects of carbon substrates, nitrogen substrates and vitamins on the lactic acid production. We showed that ammonium sulphate is a satisfying economic alternative and we have determined feasibility of minimizing the addition of the yeast extract by the partial use of yeast extract combined with the ammonium sulphate plus the addition of vitamins of the group B. Pure and mixed cultures of Lactobacillus casei and Lactococcus lactis were carried out. The mixed system gives better results concerning the lactic acid production and the use of the sugars compared with those obtained in pure cultures of Lactobacillus casei or Lactococcus lactis. The effect of pure sugars (glucose and fructose) and mixed sugars (glucose/fructose) on the lactic acid production was studied. The lactic acid production is more important on mixed sugars than on pure sugars what explains the performances of fermentation on date juice. In a second part, a mode of fed batch operations was defined to improve the performances of the fermentation. The two factors influencing the process are the feeding rate and the concentration of the feeding medium. In a third part, kinetic study in continuous culture was developed. We studied the influence of dilution rate on growth, substrate utilization and lactic acid production. The productivity of the continuous process was considerably increased in comparison with the batch process. Finally, a tentative model has been established for the fermentation process. The corresponding model, although not perfect, is apparently able to simulate growth rate, substrates uptake and lactic acid production in batch culture
Oualha, Khaled. "Étude expérimentale et numérique de l'hydrodynamique de l’écoulement dans un réacteur continu." Thesis, Sorbonne Paris Cité, 2017. http://www.theses.fr/2017USPCD082/document.
Full textDuring this Phd work, on the hydrodynamics of flow in a continuous reactor, where the properties of the elaborated nanomaterials depend on the morphological and structural characteristics of the colloidal solution out coming from the reactor, we first optimized the conditions of use of the latter (Re ≈ 6000), as well as the geometry of the T-mixer in order to improve the quality of the micro-mixing. Then, experimental measurements allowed us to verify that the condition of Damköhler is respected (Da ≤ 1). Finally, this result has been validated numerically. Beyond this Re critical value (Re * ≈ 8000), we have highlighted the phenomenon of cavitations in the T-mixer. This phenomenon has been studied experimentally, by SLS measurements, and numerically by CFD simulation. The results obtained by these two approaches are in agreement. Finally, DLS measurements were made to study and characterize cavitations bubbles. These measurements allowed us to evaluate the size of the bubbles as well as their trajectory along the Z axis 121 at the outlet of the T-mixer. This study was followed by numerical simulations of the cavitations and the multiphase model in our flow. Both experimental and numerical studies confirmed that the decrease in the intensity of scattered light measured by SLS along the Z axis is result to the changes of the number and the size of bubbles
Dimagiba, Richard Raymond N. "Application of the Boundary Element Method to three-dimensional mixed-mode elastoplastic fracture mechanics." Thesis, University of Sheffield, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310815.
Full textCrawford, Ben. "“FROM SCHOOL OF CRISIS TO DISTINGUISHED”: HOW ONE SCHOOL CONTINUES TO DEFEAT THE ODDS." UKnowledge, 2018. https://uknowledge.uky.edu/stem_etds/9.
Full textMariotti, Giulia. "Mixed-use corrugated skyscraper: progetto di un grattacielo in Dubai con studio di superficie continua ondulata derivata da funzioni periodiche." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amslaurea.unibo.it/8671/.
Full textTheron, Félicie. "Conception et mise en œuvre d'un procédé intensifié continu de microencapsulation par polycondensation interfaciale." Thesis, Toulouse, INPT, 2009. http://www.theses.fr/2009INPT045G/document.
Full textThe aim of the present work is to propose a continuous alternative to batch processes classically used to carry out encapsulation by interfacial polycondensation that represent high investment and working costs. Encapsulation by interfacial polycondensation consists in an emulsification step followed by a reactive step. We propose here a process decoupling these two steps using technologies well adapted to hydrodynamic issues of each step. This study is realised on the basis of model system. The emulsification step is carried out in static mixers under turbulent flow. Pressure drop measurements in single-phase flow enable to highlight this flow regime and to establish correlations representing these pressure drops in terms of dimensionless numbers: the Reynolds number and the friction factor. About emulsification we evaluate the influence of different parameters on the operation performances in terms of mean droplets size as a function of energy cost. We compare the performances of three different Sulzer static mixers and correlate results obtained in terms of Sauter mean diameter as a function of Reynolds and Weber numbers. The reactive step has been first carried out is stirred tank in order to study the reaction kinetics and to acquire reaction times necessary to design continuous reactors. Finally this step has been realised using two continuous reactors: the Deanhex reactor (Anxionnaz et al., 2009) and a coiled tube reactor. This last study consists first in validating the continuous process through the conservation of the emulsion size distribution during encapsulation and the conservation of the apparent kinetics. Finally the favourable hydrodynamic conditions presented by continuous reactors offer new ways of intensification to the process. In fact it is possible to increase the microcapsule concentration in the reactor and to work without surfactant to stabilize the emulsion. This continuous process for microcapsules production offers improvements in terms of product quality and working costs compared to traditional batch process used in the industry
Ammarcha, Chawki. "Mélange des poudres en continu : modèles dynamiques et caractérisation des mélanges en ligne." Thesis, Toulouse, INPT, 2010. http://www.theses.fr/2010INPT0138/document.
Full textThe implementation of a continuous mixer in the industry requires detailed studies for a better understanding of this process, with essential aim the development of a control process strategy. The present work reports experimental and modelling results concerning the dynamics of a continuous powder mixer in steady and unsteady states. In particular, we will focus on the transitory phases that are likely to occur : starting, emptying, feeder's feeding, accidental perturbation, etc. We investigate the effect of operating variables, as rotational speed of the stirrer and the inflow rate, on the distribution of particles mass in the mixer and the intermediates flow rates, as well as that of the homogeneity of binary mixtures at the outlet of continuous mixer. A specific experimental protocol, based on image analysis, has been developed for determining mixture quality. The scale of scrutiny can be adjusted and mixture homogeneity can be calculated for this scale in real time. AMarkov chain model is proposed to describe the phenomena observed at both macro-and meso-scales. The model allows to describe the composition of the mixture in different zones of the mixer as well as in the outlet of the vessel, during steady and unsteady regimes and especially at high speed perturbations, whose interest is discussed
Biggers, Mandy Sue. "Elementary teachers' ideas about, planning for, and implementation of learner-directed and teacher-directed inquiry: a mixed methods study." Diss., University of Iowa, 2013. https://ir.uiowa.edu/etd/2438.
Full textCoidakis-Barss, Christina. "INTERPROFESSIONAL TEAMS IN HEALTHCARE: A MIXED-METHODS STUDY." Case Western Reserve University School of Graduate Studies / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=case1428068372.
Full textArenas, Calderon Edward Julián. "Étude de l'élaboration en continu d'émulsions de bitime [i.e.bitume] à taille de gouttes maîtrisée à l'aide de mélangeurs statiques." Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0050/document.
Full textThis work focuses on the continuous emulsification process (using SMX static mixers) of bitumen for concentrated and highly concentrated emulsions. This work uses an approach that integrates the process, the physic-chemical formulation and composition parameters, with the main objective of controlling the drop size of the emulsions. It was shown that the emulsification carried out at high bitumen concentrations and high temperatures favours the production of emulsions with very small droplets sizes (mean diameter ? 1 mm). This is in contrast with emulsification process in batch mode, in the same concentration and temperature conditions. These results demonstrate the competition between energy and physic-chemical formulation aspects. It was also revealed that when continuous emulsification is carried out at 90 % wt. of bitumen, droplet sizes are not a function of the energy provided and, hence, the emulsification process is controlled by the formulation parameters. Morphological analyzes, coupled with kinetics of emulsification obtained by in-situ monitoring of the viscosity, allowed the description of the mechanisms occurring during the emulsification at high internal phase ratio. It was possible to identify two principal steps in the mechanism: a catastrophic phase inversion followed by a droplet reduction by agitation, the largest size reduction being achieved thanks to the effects of shear and elongation in the static mixer. An inline process viscosity measurement methodology was developed. This methodology, based on a Poiseuille analogy, allows the evaluation of the rheological behavior of a fluid through flow rate and pressure drop measurements
de, Cabo Portugal Sebastian. "Non Visuals : Material exploration of non-visual interaction design." Thesis, Umeå universitet, Designhögskolan vid Umeå universitet, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-182466.
Full textDi, Patrizio Nicolas. "Précipitation continue de produits minéraux : étude de l'influence des conditions de mélange à la précipitation sur les caractéristiques d'oxydes mixtes de cérium et de zirconium." Thesis, Paris, ENMP, 2015. http://www.theses.fr/2015ENMP0001/document.
Full textAn automated experimental set-up with rapid mixers is used to study the influence of mixing conditions on the co-precipitation of cerium-zirconium mixed oxides. The intensity of mixing is controlled by the inlet flowrates of the reacting solutions. An engulfment model is used to estimate a mixing time from the measurement of a segregation index by the Villermaux-Dushman reaction system. Three geometries of Hartridge Roughton mixers are compared. Mixing performance is better when a separate mixing chamber upstream of a narrower outlet pipe is present. A better mixing decreases the maximal reducibility temperature of the material and increases the crystal strains of the particles calcined at 1100 °C. This is probably due to a better homogenization of the particles content. The important incorporation of nitrates in the particle at the outlet of the mixers shows precipitation occurs while the mixing process is not finished. This experimental result was confirmed by numerical simulation and an estimation of sursaturations during the mixing process
Doussau, de Bazignan Adélaïde. "Essais cliniques de recherche de dose en oncologie : d'un schéma d'essai permettant l'inclusion continue à l’utilisation des données longitudinales de toxicité." Thesis, Paris 11, 2014. http://www.theses.fr/2014PA11T013/document.
Full textPhase I dose-finding trials aim at identifying the maximum tolerated dose (MTD). The “3+3” design requires an interruption of enrolment while the evaluation of the previous three patients is pending. In pediatric oncology, investigators proposed the Rolling 6 design to allow for a more continuous enrollment. In a simulation study, we showed that an adaptive dose-finding design, with dose allocation guided by a statistical model not only minimizes accrual suspension as with the rolling 6, and but also led to identify more frequently the MTD. However, the performance of these designs in terms of correct identification of the MTD is limited by the binomial variability of the main outcome: the occurrence of dose-limiting toxicity over the first cycle of treatment. We have then proposed a new adaptive design using repeated ordinal data of toxicities experienced during all the cycles of treatment. We aim at identifying the dose associated with a specified tolerable probability of severe toxicity per cycle. The outcome was expressed as the worst toxicity experienced, in three categories (severe / moderate / no toxicity), repeated at each treatment cycle. It was modeled through a proportional odds mixed model. This model enables to seek for cumulated toxicity with time, and to increase the ability to identify the targeted dose, with no increased risk of toxicity, and without delaying study completion. We also compared this ordinal model to a more parsimonious logistic mixed model.Because of their applicability and efficiency, those models for longitudinal data should be more often used in phase I dose-finding trials
Mariano, André Augusto. "Mixed Simulations and Design of a Wideband Continuous-Time Bandpass Delta-Sigma Converter Dedicated to Software Dfined Radio Applications." Thesis, Bordeaux 1, 2008. http://www.theses.fr/2008BOR13644/document.
Full textWireless front-end receivers of last generation mobile devices operate at least two frequency translations before I/Q demodulation. Frequency translation increases the system complexity, introducing several problems associated with the mixers (dynamic range limitation, noise injection from the local oscillator, etc.). Herein, the position of the analog-to-digital interface in the receiver chain can play an important role. Moving the analog-to-digital converter (ADC) as near as possible to the antenna, permits to simplify the overall system design and to alleviate requirements associated with analog functions (filters, mixers). These currently requirements have led to a great effort in designing improved architectures as Continuous-Time Delta-Sigma ADCs. The behavioural modeling this converter, although the circuit design of the main blocks has been the subject of this thesis. The use of an advanced design methodology, allowing the mixed simulation at different levels of abstraction, allows to validate both the circuit design and the overall system conversion. Using a multi-feedback architecture associated with a multi-bit quantizer, the continuous-time Bandpass Delta-Sigma converter achieves a SNR of about 76 dB in a wide band of 20MHz
Wium, Anna-Marie. "The development of a support programme for foundation phase teachers to facilitate listening and language for numeracy." Thesis, University of Pretoria, 2010. http://hdl.handle.net/2263/24685.
Full textThesis (DPhil)--University of Pretoria, 2010.
Speech-Language Pathology and Audiology
unrestricted
McKay, Ian Ross. "Assessing orientations to cultural difference of the faculty of a university foundation programme in the Gulf Cooperation Council : a mixed-methods approach informed by the Intercultural Development Continuum and using the Intercultural Development Inventory." Thesis, University of Exeter, 2013. http://hdl.handle.net/10871/13781.
Full textHessel, Gianna. "The impact of participation in ERASMUS study abroad in the UK on students' overall English language proficiency, self-efficacy, English use anxiety and self-motivation to continue learning English : a mixed-methods investigation." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:7ae490c6-2303-4889-ae67-df3deb5eb870.
Full textO'Carroll, Veronica. "Practice mentors' attitudes and perspectives of interprofessional working, and interprofessional practice learning for students : a mixed-methods case study." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/10482.
Full textBreteau, Jean-Marc. "Etude de materiaux dopes ni**(2+) et co**(2+) pour laser accordable a fonctionnement continu dans le proche infrarouge." Paris 6, 1986. http://www.theses.fr/1986PA066357.
Full textSeydou, Hassane Ramatou. "Contribution au développement des techniques ensemblistes pour l’estimation de l’état et des entrées des systèmes à temps continu : application à la détection de défauts." Thesis, Bordeaux 1, 2012. http://www.theses.fr/2012BOR14669/document.
Full textThis thesis deals with the problem of a dynamical system observation and the estimation of its characteristic variables; the latter point constitutes the core element in many engineering science fields. The final aim is to build a general framework for integrity control and fault detection of such systems within a bounded error context. The developments offered herein make use of parity relations, sliding mode differentiators, interval observers and constraint satisfaction problems. Input reconstruction techniques are developed for a general class of nonlinear continuous-time systems. Domains are reconstructed for the input values which are consistent with the measurements using interval analysis and constraint satisfaction techniques. It is shown that time-varying or invariant coordinate changes may relax the applicability conditions (stability/cooperativity) of the interval observer design methods. Sliding mode differentiators were also used to enhance interval observer accuracy. The proposed approaches are illustrated through computer simulations and they have been applied to aircraft servo loop control surface for robust and early detection of abnormal positions
Coons, Marc P. L. "Solvent Effects for Vertical Ionization Processes in Liquid Water and at the Liquid-Vapor Interface." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1503014629752161.
Full textCao, Trong Son. "Modélisation de l’endommagement ductile sous trajets de chargement complexes." Thesis, Paris, ENMP, 2013. http://www.theses.fr/2013ENMP0038/document.
Full textThe present PhD thesis aims at a better understanding and modeling of ductile damage mechanisms during cold forming processes, with wire drawing, rolling and cold pilgering as examples. In addition, special attention is paid to implemented damage models parameters identification methodology. All three approaches of ductile damage were investigated: uncoupled phenomenological fracture criteria; coupled phenomenological models; micromechanical model. These models have been implemented in Forge®, which required adaptation of algorithms to its mixed velocity-pressure formulation and to its finite element (P1+/P1). Parallel to the numerical work, various mechanical tests on three different materials (high carbon steel, stainless steel and zirconium alloy) were carried out for work hardening, and damage models parameters identification. In situ X-ray micro-tomography tensile tests have also been exploited for the identification of ductile damage mechanisms (nucleation, growth and coalescence) as well as the identification of micromechanical model. Finally, we carried out comparative studies of these models on our three abovementioned forming processes and materials. Regarding wire drawing and rolling of stainless steel, good agreement between numerical simulations and experimental results was found. For high carbon perlitic steel ultimate wire drawing, the GTN micro-mechanical model has given the best result, both qualitatively and quantitatively. Moreover, the comparison of the different models on different processes (wire rolling on high carbon steel, cold pilgering on zirconium alloy) highlights on the one hand the important role of the third deviatoric stress invariant in damage localization for shear-dominated forming processes. It shows on the other hand that the identification process itself should be based on microstructure measurements to provide accurate results in forming application
Hardy, Emmanuel. "Etude et développement d'un amplificateur audio de classe D intégré haute performance et basse consommation." Thesis, Aix-Marseille, 2013. http://www.theses.fr/2013AIXM4722/document.
Full textMost current embedded devices, such as smartphones, GPS or portable consoles, feature one speaker or more, those speakers being driven by an integrated audio amplifier. This type of amplifier must meet four specifications: an adequate audio quality, to be immune to system disturbances, low power consumption and the smallest silicon area. This work takes its origin from the creation of Primachip in May 2009 by Christian Dufaza and Hassan Ihs. The aim of this startup was to develop and sell an innovative audio class-D amplifier for mobile market: the digital class-D concept. A partnership with the IM2NP laboratory was decided to propose a PhD topic under CIFRE contract (PhD in an industrial environment), in order to study and improve the amplifier architecture. Its originality is in the partial feedback concept which applies to a loop made of a digital ΔΣ modulator driving the power stage, with an analogue-to-digital converter (ADC) in the feedback path. It makes it possible to achieve stability while offering an outstanding power supply rejection. An integrated prototype of the class-D amplifier was designed, fabricated and evaluated. A new continuous-time ΔΣ ADC has been added to enable the digital class-D loop to achieve performances superior or equal to state of the art. The circuit measurement results were encouraging, although not ideal. The analysis of the prototype errors was performed. The conclusions should allow the design of an integrated audio amplifier making the best of the digital class-D architecture
Morice, Erwan. "Fissuration dans les matériaux quasi-fragiles : approche numérique et expérimentale pour la détermination d'un modèle incrémental à variables condensées." Phd thesis, École normale supérieure de Cachan - ENS Cachan, 2014. http://tel.archives-ouvertes.fr/tel-01048626.
Full textExcoffier, Mathilde. "Chance-Constrained Programming Approaches for Staffing and Shift-Scheduling Problems with Uncertain Forecasts : application to Call Centers." Thesis, Paris 11, 2015. http://www.theses.fr/2015PA112244/document.
Full textThe staffing and shift-scheduling problems in call centers consist in deciding how many agents handling the calls should be assigned to work during a given period in order to reach the required Quality of Service and minimize the costs. These problems are subject to a growing interest, both for their interesting theoritical formulation and their possible applicative effects. This thesis aims at proposing chance-constrained approaches considering uncertainty on demand forecasts.First, this thesis proposes a model solving the problems in one step through a joint chance-constrained stochastic program, providing a cost-reducing solution. A continuous-based approach leading to an easily-tractable optimization program is formulated with random variables following continuous distributions, a new continuous relation between arrival rates and theoritical real agent numbers and constraint linearizations. The global risk level is dynamically shared among the periods during the optimization process, providing reduced-cost solution. The resulting solutions respect the targeted risk level while reducing the cost compared to other approaches.Moreover, this model is extended so that it provides a better representation of real situations. First, the queuing system model is improved and consider the limited patience of customers. Second, another formulation of uncertainty is proposed so that the period correlation is considered.Finally, another uncertainty representation is proposed. The distributionally robust approach provides a formulation while assuming that the correct probability distribution is unknown and belongs to a set of possible distributions defined by given mean and variance. The problem is formulated with a joint chance constraint. The risk at each period is a decision variable to be optimized. A deterministic equivalent problem is proposed. An easily-tractable mixed-integer linear formulation is obtained through piecewise linearizations
Nduwayo, Placide. "Formulations mathématiques et algorithmes pour le problème d'affectation des quais du cross-dock." Thesis, Valenciennes, Université Polytechnique Hauts-de-France, 2020. http://www.theses.fr/2020UPHF0013.
Full textCross-docking is a strategy originally introduced to optimize operations inside a warehouseas part of the optimization of the Supply Chain. Like traditional warehouses, productsare collected from numerous freight yards such that suppliers, factories, manufactures,etc., usingtrucks, and are moved towards processing centers named cross-docks. At cross-dock yard, productsfirst get unloaded on inbound dock doors. Afterwards, they are sorted according to theirdestinations and are immediately transferred, using handling devices, to appropriate outbounddock doors to be sometimes consolidated with other products of the same destination and arereloaded into shipping trucks. Unlike traditional warehouse where storage period of productsis indefinite, for cross-dock, goods are unloaded and reloaded the same day without waiting intemporary storage area or can wait less than one day. In this PhD thesis, we study an NP-hardoptimization problem raised by cross-dock referred to “Cross-dock Door Assignment Problem(CDAP)”. The CDAP consists in assignment of incoming and outgoing trucks to inbound andoutbound dock doors of cross-dock, respectively. The goal is to minimize the total transportationcost inside the cross-dock. The standard quadratic formulation of the CDAP includes theGeneralized Assignment Problem as subproblem. In this dissertation, we perform an extensivecross-docking literature review. Then, we carry out a broad analysis of the standard quadraticformulation as well as the standard linearization of the CDAP. From this in-deph study, wepropose several new non standard Mixed Integer Linear Programming models for the CDAP. Todetect the best linear model among those we propose and those existing, we compare the performanceof these models on instances proposed in the literature. We next propose a LagrangianRelaxation approach to produce the best new lower bounds to optimal solution value. This LagrangianRelaxation is applied to the model that produces the best LP relaxation bounds. TheLagrangian dual is solved using a subgradient algorithm. According to the experiments it seemsthat large-scale instances cannot be solved with an exact method in reasonable running times andmemory requirements. Thus, we propose and implement two heuristics based on “ProbabilisticTabu Search” to operate efficiently with larger instances of the CDAP. To assess the effectivenessof these proposed heuristics, we compare their performance, first between them and thenwith recent heuristics in the literature. The results demonstrate the efficiency of the proposedapproaches on data sets from the literature
Sienkiewicz, Magdalena. "Méthodologie de localisation des défauts soft dans les circuits intégrés mixtes et analogiques par stimulation par faisceau laser : analyse de résultats des techniques dynamiques paramétriques." Thesis, Bordeaux 1, 2010. http://www.theses.fr/2010BOR14028/document.
Full textThis thesis deals with Soft failure localization in the analog and mixed mode Integrated Circuits (ICs) by means of Dynamic Laser Stimulation techniques (DLS). The results obtained using these techniques are very complex to analyze in the case of analog and mixed ICs. In this work we develop a methodology which facilitates the analysis of the laser mapping. This methodology consists on combining the experimental results (laser mapping) with the electrical simulations of laser stimulation impact on the device. The influence of photoelectric and thermal phenomena on the IC (transistor level) has been modeled and simulated. The methodology has been validated primarily on test structures before being used on complex Freescale ICs existing in commerce
LeBlanc, Graham. "Design and simulation of a control continuum for tetherless underwater vehicles." 2011. http://hdl.handle.net/10222/14176.
Full textBhat, Pradeep Prabodha. "The dynamics of filaments of complex liquids analyzed by continuum and mixed continuum-stochastic methods." Thesis, 2007. http://hdl.handle.net/1911/20576.
Full textCiucci, Francesco. "Continuum Modeling of Mixed Conductors: A Study of Ceria." Thesis, 2009. https://thesis.library.caltech.edu/5273/1/thesis.pdf.
Full textIn this thesis we have derived a new way to analyze the impedance response of mixed conducting materials for use in solid oxide fuel cells (SOFCs), with the main focus on anodic materials, in particular cerium oxides.
First we have analyzed the impact of mixed conductivity coupled to electrocatalytic behavior in the linear time-independent domain for a thick ceria sample. We have derived that, for a promising fuel cell material, Samarium Doped Ceria, chemical reactions are the determining component of the polarization resistance.
As a second step we have extended the previous model to the time-dependent case, where we focused on single harmonic excitation, the impedance spectroscopy conditions. We extended the model to the case where some input diffusivities are spatially nonuniform. For instance we considered the case where diffusivities change significantly in the vicinity of the electrocatalytic region.
As a third and final step we use to model to capture the two dimensional behavior of mixed conducting thin films, where the electronic motion from one side of the sample to the other is impeded. Such conditions are similar to those encountered in fuel cells where an electrolyte conducting exclusively oxygen ions is placed between the anode and the cathode. The framework developed was also extended to study a popular cathodic material, Lanthanum Manganite.
The model is used to give unprecedented insight in SOFC polarization resistance analysis of mixed conductors. It helps elucidate rigorously rate determining steps and to address the interplay of diffusion with diffusion losses. Electrochemical surface losses dominate for most experimental conditions of Samarium Doped Ceria and they are shown to be strongly dependent on geometry.
Sunyk, Rudolf [Verfasser]. "On aspects of mixed continuum atomistic material modelling / von Rudolf Sunyk." 2004. http://d-nb.info/972145435/34.
Full text(5929553), Ernesto Camarena. "Multiscale Continuum Modeling of Piezoelectric Smart Structures." Thesis, 2019.
Find full textFirst, the Mechanics of Structure Genome (MSG) was extended to provide a rigorous analytical homogenization method. The MFC was idealized to consist of a stack of homogeneous layers where some of the layers were homogenized with existing rules of mixtures. For the analytical model, the electrical behavior caused by the interdigitated electrodes (IDEs) was approximated with uniform poling and uniform electrodes. All other assumptions on the field variables were avoided; thus an exact solution for a stack of homogeneous layers was found with MSG. In doing so, it was proved that in any such multi-layered composite, the in-plane strains and the transverse stresses are equal in each layer and the in-plane electric fields and transverse electric displacement are constant between the electrodes. Using this knowledge, a hybrid rule of mixtures was developed to homogenize the entire MFC layup so as to obtain the complete set of effective device properties. Since various assumptions were avoided and since the property set is now complete, it is expected that greater energy equivalence between reality and the homogenized model has been made possible. The derivation clarified what the electrical behavior of a homogenized solid with internal electrodes should be—an issue that has not been well understood. The behavior was verified by large-scale FE models of an isolated MFC patch.
Increased geometrical fidelity for homogenization was achieved with an FE-based RVE analysis that accounted for finite-thickness effects. The presented theory also rectifies numerous issues in the literature with the use of the periodic boundary conditions. The procedure was first developed without regard to the internal electrodes (ie a homogenization of the active layer). At this level, the boundary conditions were shown to satisfy a piezoelectric macrohomogeneity condition. The methodology was then applied to the full MFC layup, and modifications were implemented so that both types of MFC electrodes would be accounted for. The IDE case considered nonuniform poling and electric fields, but fully poled material was assumed. The inherent challenges associated with these nonuniformities are explored, and a solution is proposed. Based on the homogenization boundary conditions, a dehomogenization procedure was proposed that enables the recovery of local fields. The RVE analysis results for the effective properties revealed that the homogenization procedure yields an unsymmetric constitutive relation; which suggests that the MFC cannot be homogenized as rigorously as expected. Nonetheless, the obtained properties were verified to yield favorable results when compared to a large-scale 3D FE model.
As a final test of the obtained effective properties, large-scale 3D FE models of MFCs acting in a static unimorph configuration were considered. The most critical case to test was the smallest MFC available. Since none of the homogenized models account for the passive MFC regions that surround the piezoelectric fiber array, some of the test models were constructed with and without the passive regions. Studying the deflection of the host substrate revealed that ignoring the passive area in smaller MFCs can overpredict the response by up to 20%. Satisfactory agreement between the homogenized models and a direct numerical simulation were obtained with a larger MFC (about a 5% difference for the tip deflection). Furthermore, the uniform polarization assumption (in the analytical model) for the IDE case was found to be inadequate. Lastly, the recovery of the local fields was found to need improvement.
Negara, Ardiansyah. "Subsurface Flow Modeling in Single and Dual Continuum Anisotropic Porous Media using the Multipoint Flux Approximation Method." Diss., 2015. http://hdl.handle.net/10754/554393.
Full textSchmidt, Hansjörg. "Anisotropic Viscoelasticity at Large Strain Deformations." 2018. https://monarch.qucosa.de/id/qucosa%3A23546.
Full text