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Dissertations / Theses on the topic 'Coordination chemitry'

Author: Grafiati

Published: 8 June 2024

Last updated: 31 July 2025

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1

Hussein, Hiba. "Synthèses de nouveaux ligands carbènes à structures N-hétérocycliques et macro-N-Bis-hétérocycliques symétriques et dissymétriques. Études de leurs propriétés photophysiques, biologiques et de coordination." Electronic Thesis or Diss., Université de Lorraine, 2022. http://www.theses.fr/2022LORR0014.

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L'objectif de ce travail de thèse consiste à préparer de nouvelles molécules photosensibles de type carbènes N-hétérocycliques, ligands ou complexes, dessinées pour répondre aux critères des photosensibilisateurs (PS) (molécules pures, hydrosolubles, biocompatibles, non toxiques, d'efficacité d'absorbance maximale, possédant de bonnes propriétés photophysiques) applicables dans le domaine des matériaux ou/et dans le domaine biomédical tel qu'en photothérapie. L'ambition étant d'optimiser les propriétés spectroscopiques des photosensibilisateurs et d'obtenir une bonne photoactivité. Ce travail

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2

Weis, Philippe [Verfasser], and Ingo [Akademischer Betreuer] Krossing. "Exploring the chemistry of group 15/16 cages with weakly coordinating aluminates – synthesis and coordination chemistry of inorganic cages." Freiburg : Universität, 2019. http://d-nb.info/119056100X/34.

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3

Noack, Cassandra, and n/a. "Studies in Coordination Chemistry." Griffith University. School of Science, 2003. http://www4.gu.edu.au:8080/adt-root/public/adt-QGU20031030.145610.

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The research reported in this thesis was carried out in Brisbane, Australia and Calgary, Canada. The aim of the research conducted in Brisbane was to prepare a series of copper(I) and ruthenium(II) based complexes incorporating a hemilabile phosphine ligand and to determine whether or not these compounds possessed catalytic activity. The history, uses, properties and recent work incorporating hemilabile phosphine ligands is discussed in detail as well as the application of hemilabile ligands to atom transfer radical polymerization (ATRP) and the usefulness of the 'windscreen wiper' action of

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4

Noack, Cassandra. "Studies in Coordination Chemistry." Thesis, Griffith University, 2003. http://hdl.handle.net/10072/366798.

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The research reported in this thesis was carried out in Brisbane, Australia and Calgary, Canada. The aim of the research conducted in Brisbane was to prepare a series of copper(I) and ruthenium(II) based complexes incorporating a hemilabile phosphine ligand and to determine whether or not these compounds possessed catalytic activity. The history, uses, properties and recent work incorporating hemilabile phosphine ligands is discussed in detail as well as the application of hemilabile ligands to atom transfer radical polymerization (ATRP) and the usefulness of the 'windscreen wiper' action of

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5

Keene, Frank Richard. "Aspects of coordination chemistry /." Title page, contents and abstract only, 1998. http://web4.library.adelaide.edu.au/theses/09SD/09sdk26.pdf.

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6

Higginson, Joshua J. "Synthesis and coordination chemistry of ditopic ligands capable of coordinating metal ions and interacting with anions." Thesis, University of Huddersfield, 2015. http://eprints.hud.ac.uk/id/eprint/26444/.

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The aim of this research was to synthesise a series of novel organic multidentate ligands which contain N-donor domains for the coordination of metal ions and amide or amine hydrogen atoms which are capable of interaction with anions. It was envisaged that incorporation of these two binding units would produce a system where the metal ions would control the ability of the ligand to interact with anions or vice versa. Ligand 1 contains a tetradentate N-donor domain formed by a central bipyridine, two thaizole units and two amide units attached in the 4,4’-position of the bipyridine unit. Reacti

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7

Wu, Haiying. "Coordination chemistry of tetraneopentoxyphthalocyaninatocobalt(II)." Thesis, University of British Columbia, 1991. http://hdl.handle.net/2429/29822.

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The thesis work reports developments in the coordination chemistry of tetra-neopentoxyphthalocyaninatocobalt(II) (CoTNPc) complexes. The preparation, characterization, and ligand binding measurements in solution of seven new compounds are described in this thesis. Some additional complexes are studied in situ. Measurement of the equilibrium constants by UV-visible spectroscopy for the 1:1 binding reactions of the axial ligands (L = imidazole, N-methylimidazole, pyridine, 4-picoline, 4-tert-butylpyridine, piperidine, tetrahydrofuran) to CoTNPc in toluene solution allow for an estimation of th

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8

Moore, Charles H. M. "Coordination chemistry of guanidine derivatives." Thesis, University of Nottingham, 1987. http://eprints.nottingham.ac.uk/14354/.

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This thesis describes an investigation of the coordination chemistry of l-cyanoguanidine (cnge), l-carbamoylguanidine (clge) and l-amidino-O-ethylurea (aOeu). Various copper(II) complexes of these analogous molecules were synthesised and characterised using mainly X-ray crystallographic and spectroscopic (infrared and UV-visible) techniques. Only bis (cnge) complexes were observed for copper(II) ions. The monodentate cnge ligands coordinated the copper(II) via their nitrile nitrogen atoms which were located in trans equatorial positions of the copper(II) ions's tetragonally distorted octahedra

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9

Grundy, Joanna. "Bifunctional amidines in coordination chemistry." Thesis, University of Sussex, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.398786.

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10

Mansfield, Natalie Emma. "Phosphaguanidines : coordination chemistry and catalysis." Thesis, University of Sussex, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.435610.

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11

Aucott, Stephen Mark. "Coordination chemistry of aminophosphine ligands." Thesis, Loughborough University, 1999. https://dspace.lboro.ac.uk/2134/34492.

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The reaction of [MCl2(cod)] (M = Pt, Pd) with two equivalents of 2-(diphenylphosphinoamino)pyridine, Ph2PNHpy, in warm acetonitrile led to cationic complexes of the type cis-[MCl(Ph2PNHpy-P,N){Ph2PNHpy-P}][Cl] (M = Pt, Pd) which exhibit broad single 31P{1H} NMR resonances due to their dynamic pyridyl exchange behaviour in solution. A single crystal X-ray diffraction study of the platinum species confirmed the proposed structure and revealed that adjacent complex molecules were held together by hydrogen bonding to the same chloride counter-ion. The bromo- and iodo-cis[MX(Ph2PNHpy-P,N){Ph2PNHpy-

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12

Cevik, Deniz. "Synthesis, purification, and characterization of tetraphosphine ligands." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLX026/document.

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L'évolution récente de la science écologique et durable nécessite des catalyseurs puissants, sophistiquées et dotés de propriétés spécifiques et accordables.Les catalyseurs bimétalliques qui contiennent deux ou plusieurs sites pour l'activation coopérative de substrats réagissant sur des centres métalliques voisins selon certaines conditions. Un certain nombre de squelettes, spécialement conçus pour générer des complexes exclusivement bimétalliques, ont été développés autour d'échafaudages de méthanodibenzodioxocine et de benzofurobenzofurane, y compris un certain nombre de ligands qui agissen

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13

Fleischmann, Martin [Verfasser], and Manfred [Akademischer Betreuer] Scheer. "Oxidation and Coordination Chemistry of En Ligand Complexes under Weakly Coordinating Conditions / Martin Fleischmann ; Betreuer: Manfred Scheer." Regensburg : Universitätsbibliothek Regensburg, 2015. http://d-nb.info/1122354908/34.

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14

Setyawati, Ika Agustin. "Coordination chemistry : basics to bioactive molecules." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0020/NQ46420.pdf.

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15

Amantia, David. "Coordination chemistry of chelate-tethered nucleobases." Thesis, University of Newcastle Upon Tyne, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.417527.

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16

Thompsett, Andrew Robert. "The coordination chemistry of unusual alkynes." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302650.

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17

Wilson, Thomas Charles. "Coordination chemistry of the pentacyanocyclopentadienide anion." Thesis, University of Cambridge, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.708033.

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18

Balaraman, Lakshmi. "COORDINATION CHEMISTRY OF N,N’- AZODOXIDES." Cleveland State University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=csu1556986156564604.

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19

Farkas, Ildiko. "Coordination Chemistry of Actinide and Lanthanide Ions." Doctoral thesis, KTH, Chemistry, 2001. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3236.

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20

Mjos, Katja Dralle. "Coordination chemistry of antimicrobial and anticancer agents." Thesis, University of British Columbia, 2015. http://hdl.handle.net/2429/54682.

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The World Health Organization has named the resistance of microbes to known antimicrobial drugs as an increasingly serious threat to global public health. Isolates of the ESKAPE pathogens (E. faecium, S. aureus, K. pneumonia, A. baumanii, P. aeruginosa, and Enterobacter species) are responsible for many nosocomial infections each year that require complicated, and therefore expensive, medical treatment, often leading to death in immune-compromised patients. Over the past 50 years, (fluoro-)quinolone antimicrobial agents have been widely used in the clinic as broad-spectrum antibiotics, but lat

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21

Sishta, Chand. "The coordination chemistry of ruthenium porphyrin complexes." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/30790.

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This thesis work reports developments in the coordination chemistry of ruthenium porphyrin complexes, both in terms of the synthesis and chemistry of new compounds, as well as the study of the solution chemistry of some previously reported complexes. The synthesis, characterization and chemistry of ten new Ru(porp) coordination complexes in the oxidation states Ru[superscript]Ⅲ and Ru[superscript]Ⅳ containing halide (Br, CI) and other axial ligands (pyridine, CH₃CN, NH₃ and SbF₆) are described in this thesis. Some additional ten Ru(porp) complexes have been studied in situ. Measurement of the

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22

Farkas, Ildikó. "Coordination chemistry of actinide and lanthanide ions /." Stockholm, 2001. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3236.

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23

Al-Rasbi, Nawal K. "The coordination chemistry of new multidentate ligands." Thesis, University of Sheffield, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.489370.

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The content of this thesis is concerned with two distinctly independent areas of research: (i) the synthesis and coordination chemistry of new multidentate ligands and investigate their emission properties; (ii) the synthesis and study of new poly(pyrazol-1-yl)borate and Pt(II) based ligands and their lanthanide complexes.

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24

Schleep, Mario [Verfasser], and Ingo [Akademischer Betreuer] Krossing. "Molecular and coordination chemistry of Tin(II)." Freiburg : Universität, 2017. http://d-nb.info/1143602927/34.

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25

Metcalfe, John Edwin. "Studies in nickel and manganese coordination chemistry." Thesis, Queen's University Belfast, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263502.

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26

Bishop, P. T. "The coordination chemistry of sterically hindered theolates." Thesis, University of Essex, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381248.

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27

Champness, Neil Robert. "Studies in ruthenium and osmium coordination chemistry." Thesis, University of Southampton, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239648.

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28

Orchard, Simon David. "Synthesis and coordination chemistry of telluroether ligands." Thesis, University of Southampton, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326303.

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29

Mistry, Rakesh. "Synthesis and coordination chemistry of carboranyl phosphines." Thesis, University of Bristol, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442207.

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30

Khalaf, Majid Shannon. "Coordination chemistry of bicyclic guanidines and guanidinates." Thesis, University of Sussex, 2011. http://sro.sussex.ac.uk/id/eprint/7347/.

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A [5:5] ligand based on the bicyclic guanidine 1,4,6-triazabicyclo[3.3.0]oct-4-ene [Htbo] has been synthesised. Two of these tbo units have been linked via a carbon bridgehead to form a novel bidentate ligand. Based on the knowledge that the electronic properties and specific steric interactions at a metal can lead to new insights into the relationship between crystal structure and ligand activity, the synthesised compounds have been investigated as polydentate ligands on the assumption that that they could be used to precisely control coordination environment. The corresponding [6:6] system w

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31

Tatchell, Thomas. "Coordination chemistry of pendant aniline aza-macrocycles." Thesis, Cardiff University, 2005. http://orca.cf.ac.uk/56099/.

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The selective functionalisation of triazamacrocycles is investigated herein, with the focus on 1, 4, 7-triazacyclononane (tacn) The ligands tris (5-fluoro, 2- aminophenyl) 1, 4, 7-triazacyclononane (L1), tris (4-fluoro, 2-aminophenyl) 1,4, 7- triazacyclononane (L") and tris (3-fluoro, 2-ammophenyl) 1, 4, 7-triazacyclononane (L ) were studied. X-Ray crystal data was obtained for (L,)M (C104)2.x:MeCN where M=Mn,,/FeII/Ni"/CuII/Znn/CdII/Hgn, (L2)M (C104)2 xMeCN where M=Mn1I/Fe,I/NiII/CuII/ZnII/Cdn and (L3)M (C104)2 xMeCN where M=Mn,1/NiI,/Cun/Zn,I/Cd,,/Pb11 complexes. The (L,)Cu (C104)2 complex e

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32

Cullen, William M. "Host-guest chemistry of polyhedral coordination cages." Thesis, University of Sheffield, 2015. http://etheses.whiterose.ac.uk/11545/.

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Chapter 1 – Introduction Chapter 2 – Synthesis, characterisation and manipulation of a three component self-assembled system Chapter 3 – Development and utilisation of a fluorescence displacement assay for guest screening Chapter 4 – Prediction of guest binding using molecular docking Chapter 5 – The use of pH changes to control guest binding in water Chapter 6 – Highly efficient catalysis of the Kemp Elimination in the cage cavity.

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33

Benson, Callum Giles Maxwell. "Synthesis and coordination chemistry of functionalised phosphazanes." Thesis, University of Cambridge, 2016. https://www.repository.cam.ac.uk/handle/1810/264415.

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This thesis focuses on the chemistry of novel phosphazane species derived from the chloro-phosphazanes [ClP(μ-NR)]$_2$ and their use as ligands and building blocks for macrocyclic compounds. The introduction (Chapter 1) surveys previous literature in the area, which is pertinent to the new studies. One of the most important issues is the various ways in which dimeric phosph(III)azanes can be employed as precursors for new ligands and in the design of new types of inorganic macrocycles. In Chapter 2 the synthesis of new chloro-dimers of the type [ClP(μ-NR)]$_2$ is described, which are the prima

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34

Hannon, Michael John. "Metal ion control in oligopyridine coordination chemistry." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272558.

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35

Clifton, Jamie. "Phosphinothiophene ligands : coordination chemistry, catalysis, and polymerisation." Thesis, University of Bristol, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.687601.

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36

Van, Veelen Arjen. "Uranium coordination chemistry in Mg-rich systems." Thesis, University of Manchester, 2014. https://www.research.manchester.ac.uk/portal/en/theses/uranium-coordination-chemistry-in-mgrich-systems(707b1576-699c-4f0a-b945-7482cfb7f51f).html.

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In the UK, large quantities of intermediate level waste pose complex radiological remediation challenges. Chemical understanding of uranium in these Mg-rich sludges is vital. Previous studies have examined uranium uptake by calcium carbonate minerals (calcite and aragonite) under conditions pertinent to both natural and anthropogenically perturbed systems. However, research on uranyl uptake by magnesium-rich minerals such as magnesite [MgCO3], brucite [Mg(OH)2], nesquehonite [MgCO3·3H2O] and hydromagnesite-[Mg5(CO3)4(OH)2·4H2O] has not, to the best of our knowledge, been previously conducted.

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37

Youfu, Katsuyuki. "Coordination chemistry and reactivities of expanded porphyrins." 京都大学 (Kyoto University), 2006. http://hdl.handle.net/2433/144223.

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38

Clayton, Hayley J. "Synthesis and coordination chemistry of ligands for supramolecular chemistry and sensing applications." Thesis, University of Huddersfield, 2008. http://eprints.hud.ac.uk/id/eprint/6954/.

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A series of multidentate N-donor ligands have been synthesised all containing pyridyl and pyridyl/thiazole units and their coordination behaviour is described. The ligands are classified into four types; i) terpyridine containing pyridyl/thiazole ligands (L1-3); ii) pyridyl/thiazole ligands containing a 3,3′-disubstituted bipyridine core. (L4-8); iii) 2,2′-bipyridine containing a crown ether moiety (L9-11); and iv) a 2,2′- bipyridine derived ligand containing a urea functional group in the 3,3′-positions (L12). Chapter II describes terpyridyl/pyridyl/thiazole ligands: - the synthesis of (L1-3)

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39

Fischbach, Urs Christian. "Rigid phosphane-olefin ligands : synthesis and coordination chemistry /." Zürich : ETH, 2006. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=16733.

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40

Uppal, Baljinder S. "'Click' chemistry in coordination and supramolecular chemical applications." Thesis, University of Huddersfield, 2012. http://eprints.hud.ac.uk/id/eprint/18043/.

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The term “click chemistry” was first coined by Sharpless and co-workers in 2001 and encompasses a range of high yielding organic coupling reactions which are rapid, highly selective and proceed with good functional group tolerance. Furthermore the reaction conditions are mild and require minimal workup and product purification. The most prominent example of these reactions is the copper catalysed alkyne/azide cycloaddition (CuAAC) for the formation of 1,4- disubstituted-1,2,3-triazoles. CuACC has been utilised in a variety of chemical disciplines including organic synthesis, the modification o

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41

Szymczak, Nathaniel Kolnik. "Coordination chemistry of dihydrogen and dihydrogen hydrogen-bonding /." view abstract or download file of text, 2007. http://proquest.umi.com/pqdweb?did=1400962351&sid=1&Fmt=2&clientId=11238&RQT=309&VName=PQD.

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Thesis (Ph. D.)--University of Oregon, 2007.<br>Typescript. Includes vita and abstract. Includes bibliographical references (leaves 307-324). Also available for download via the World Wide Web; free to University of Oregon users.

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42

Babecki, Ryszard. "Aspects of the coordination chemistry of betaketophosphoryl compounds." Thesis, Staffordshire University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.278915.

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43

White, David James. "The coordination chemistry of some multidentate thioether ligands." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239238.

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44

Rawle, Simon Charles. "The coordination chemistry of some multidentate thioether ligands." Thesis, University of Oxford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.329963.

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45

Lippolis, Vito. "Studies on the coordination chemistry of macrocyclic ligands." Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311755.

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46

Baysal, Akin. "Coordination chemistry of molecules derived from 1,10-diazaphenanthrene." Thesis, University of Kent, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.362310.

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47

Martin, Nicola Catherine. "Supramolecular coordination chemistry of mellitic and pyromellitic acids." Thesis, University of Newcastle Upon Tyne, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.412650.

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48

Russo, Luca. "Supramolecular coordination chemistry of isophthalic and trimellitic acids." Thesis, University of Newcastle Upon Tyne, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.427315.

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49

Oldroyd, Richard Duncan. "The coordination chemistry of periodate and tellurate ligands." Thesis, University of Southampton, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240580.

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50

Akpan, C. A. "Coordination chemistry of phospha-allenes and phospha-alkenes." Thesis, University of Sussex, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375131.

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