Academic literature on the topic 'Coordination polymers – Synthesis'

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Journal articles on the topic "Coordination polymers – Synthesis"

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Marchenko, Roman D., Taisiya S. Sukhikh, Alexey A. Ryadun, and Andrei S. Potapov. "Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane." Molecules 26, no. 17 (2021): 5400. http://dx.doi.org/10.3390/molecules26175400.

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Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadm
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Kadir, M. A., and Christopher J. Sumby. "Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor." Solid State Phenomena 273 (April 2018): 134–39. http://dx.doi.org/10.4028/www.scientific.net/ssp.273.134.

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Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourie
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Gorduk, Semih, Hakan Yilmaz, and Omer Andac. "Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities." Macedonian Journal of Chemistry and Chemical Engineering 38, no. 1 (2019): 19. http://dx.doi.org/10.20450/mjcce.2019.1711.

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In this study, two new coordination polymers of Cu(II) and Cd(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole were synthesized. The structures of these coordination polymers were characterized with elemental analysis, infrared spectroscopy, thermal analysis, powder X-ray diffraction, and magnetic susceptibility techniques. According to the results of the thermal analysis, the coordination polymers that contained water molecules decomposed below 100 °C, and the final products for both coordination polymers were the related metal oxides in an oxygen atmosphere. Powder X-ray dif
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SHOOTO, NTAOTE DAVID. "A Convenient Synthesis of Antimony Nanorods using 1,2,4,5-Benzenetetracarboxylic Acid." Asian Journal of Chemistry 31, no. 6 (2019): 1301–4. http://dx.doi.org/10.14233/ajchem.2019.21886.

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1,2,4,5-Benzenetetracarboxylic acid (H4Btec) is an ideal candidate for the synthesis of new coordination polymers compounds because of its four carboxyl groups bridging moieties with antimony ions having distorted coordination configuration. This work reports a new compound of coordination polymer, namely, [Sb2(C4H4O6)2(Btec)(H2O)]n, [(C4H4O6)2 = tartrate and Btec4− = 1,2,4,5-benzenetetracarboxylic anion] has been synthesized under reflux. The physical and chemical properties of coordination polymers; Sb2(C4H4O6)2(Btec)(H2O) was affirmed by scanning electron microscope, Fourier transform infra
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Luisi, Brian S., Kevin D. Rowland, and Brian Moulton. "Coordination polymer gels: synthesis, structure and mechanical properties of amorphous coordination polymers." Chemical Communications, no. 27 (2007): 2802. http://dx.doi.org/10.1039/b703768f.

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Vittal, Jagadese. "Photochemical Reactions of Hydrogen-bonded Coordination Polymers." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C529. http://dx.doi.org/10.1107/s2053273314094704.

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Crystallization is a kinetic phenomenon and the experimental conditions like solvents, concentration, pH, temperature and time have greater influence on the nature of products in the synthesis of coordination network structures. During crystallization, the solvents and ligands bind to the metal ions reversibly and hence, the least soluble polymer will crystallize first, independent of the metal-ligand ratio used in the crystallization. The kinetic products quite often contain solvents bonded to the metal ions. The removal of these coordinated solvents is likely to transform the kinetically for
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Patra, Ranjan, and Israel Goldberg. "A three-dimensional coordination polymer of 3-(3,5-dicarboxybenzyloxy)benzoic acid with zinc." Acta Crystallographica Section C Crystal Structure Communications 69, no. 8 (2013): 819–21. http://dx.doi.org/10.1107/s0108270113017204.

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The synthesis is reported of the tricarboxylic acid 3-(3,5-dicarboxybenzyloxy)benzoic acid (H3L) and the product of its reaction under solvothermal conditions with ZnIIcations, namely poly[[μ6-3-(3,5-dicarboxylatobenzyloxy)benzoato](dimethylformamide)-μ3-hydroxido-dizinc(II)], [Zn2(C16H9O7)(OH)(C3H7NO)]n, the formation of which is associated with complete deprotonation of H3L. Its crystal structure consists of a single-framework coordination polymer of the organicL3−ligand with ZnIIcations in a 1:2 ratio, with additional hydroxide and dimethylformamide (DMF) ligands coordinated to the ZnIIcent
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Kuznetsova, Anastasia, Vladislava Matveevskaya, Dmitry Pavlov, Andrei Yakunenkov, and Andrei Potapov. "Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties." Materials 13, no. 12 (2020): 2699. http://dx.doi.org/10.3390/ma13122699.

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Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-m
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Engelhardt, LM, PC Healy, JD Kildea, and AH White. "Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLVII. Vinylpyridine Derivatives of Copper(I) Halides: Synthesis and Conformational Systematics." Australian Journal of Chemistry 42, no. 1 (1989): 185. http://dx.doi.org/10.1071/ch9890185.

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The syntheses and systematic single-crystal X-ray structural characterization of 1 : 1 copper halide ( CuX )/ligand (L) adducts, CuX.L [X= Cl, Br, I; L= 2-vinylpyridine (2-vpy) and 4- vinylpyridine (4-vpy)], are recorded. For X = Cl, Br; L = 2-vpy, the solid state structures are linear polymers, the basic unit of which is an NCuX2CuN dimer , with the fourth coordination site of each copper linked to adjacent units by coordination of the vinyl group. For X= C1, Br; L = 4-vpy, a linear polymeric NCuX/NCuX infinite spine in one dimension is cross-linked from successive copper/ligand groups altern
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Trofimova, Olesya Y., Arina V. Maleeva, Kseniya V. Arsenyeva, Anastasiya V. Klimashevskaya, Il’ya A. Yakushev, and Alexandr V. Piskunov. "Glycols in the Synthesis of Zinc-Anilato Coordination Polymers." Crystals 12, no. 3 (2022): 370. http://dx.doi.org/10.3390/cryst12030370.

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We report the synthesis, structural investigation, and thermal behavior for three zinc-based 1D-coordination polymers with 3,6-di-tert-butyl-2,5-dihydroxy-p-benzoquinone, which were synthesized in the presence of different glycols. The interaction of zinc nitrate with glycols, followed by using the resulting solution in solvothermal synthesis with the anilate ligand in DMF, makes it possible to obtain linear polymer structures with 1,2-ethylene or 1,2-propylene glycols coordinated to the metal. The reaction involving 1,3-propylene glycol under similar conditions gives a crystal structure that
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Dissertations / Theses on the topic "Coordination polymers – Synthesis"

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Maclaren, Jana K. [Verfasser], and Christoph [Akademischer Betreuer] Janiak. "Synthesis and charactarization of chiral coordination polymers = Synthese und Charakterisierung von chiralen koordinations Polymeren." Freiburg : Universität, 2012. http://d-nb.info/1123468699/34.

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Gorlamari, Kranthikkumarreddy. "Synthesis and self-assembly of coordination lipid polymers." To access this resource online via ProQuest Dissertations and Theses @ UTEP, 2008. http://0-proquest.umi.com.lib.utep.edu/login?COPT=REJTPTU0YmImSU5UPTAmVkVSPTI=&clientId=2515.

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CABRAS, VALENTINA. "Green Synthesis Approach to Coordination Polymers by Mechanochemistry." Doctoral thesis, Università degli Studi di Cagliari, 2017. http://hdl.handle.net/11584/249603.

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The field of Metal-Organic Frameworks, also known with the abbreviation MOFs, has been subjected to an accelerated growth in the last 15 years. The process of mixing quickly available metal precursors with organic ligands—many of which are commercially available—to produce a wide range of frameworks, is capturing the interest of chemists and materials scientists worldwide. There is an important link between MOF chemistry and fields of inorganic and coordination chemistry, there is also a conceptual link into the field of materials chemistry that has evolved applications ranging from catalysis
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GARAU, FEDERICA. "DESIGN, SYNTHESIS AND CHARACTERISATION OF POLYFUNCTIONAL COORDINATION POLYMERS." Doctoral thesis, Università degli studi di Padova, 2010. http://hdl.handle.net/11577/3427373.

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The research group where I performed my PhD researches is interested in the synthesis and characterisation of Coordination Polymers (CPs). CPs are infinite systems built up with metal ions (connectors) and organic ligands (linkers) as main elementary units, connected via coordination bonds and other weak interactions [Robin & Fromm, Coord. Chem. Rev., 2006, 250, 2127]. One of the interests in building CPs is the creation of new tuneable functional materials, since CPs are promising materials for applications in gas storage, anion exchange, catalysis, conductivity, luminescence, chirality, magn
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Portolés, Gil Núria. "Green synthesis of coordination polymers using supercritical carbon dioxide." Doctoral thesis, Universitat Autònoma de Barcelona, 2019. http://hdl.handle.net/10803/669382.

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Recentment l’interès per la investigació en polímers de coordinació (CPs) i en xarxes metal·lorgàniques (MOFs) ha crescut degut al potencial d’aquests materials per nombroses aplicacions com per exemple, l’alliberació controlada de fàrmacs, la catàlisi i l’emmagatzematge i la separació de gasos. Generalment aquests materials són sintetitzats utilitzant dissolvents orgànics tòxics i altes temperatures. Per aquest motiu, és necessari desenvolupar rutes sintètiques més sostenibles per accelerar l'expansió industrial d'aquests productes. L’objectiu principal del treball és sintetitzar CPs utilitza
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Dobrawa, Rainer Anton. "Synthesis and characterization of terpyridine-based fluorescent coordination polymers." Doctoral thesis, [S.l.] : [s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=973411813.

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Haja, Mohideen Mohamed Infas. "Novel metal organic frameworks : synthesis, characterisation and functions." Thesis, University of St Andrews, 2011. http://hdl.handle.net/10023/1892.

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The synthesis and properties of novel Metal Organic Frameworks were investigated and reported in this thesis. Thirteen new materials have been synthesized and their properties have been discussed with nine of the structures being solved. The most interesting and useful MOF among the thirteen materials is STAM-1, a copper-based Metal Organic Framework in which the starting linker (Benzene-1,3,5-tricarboxylic acid) undergoes selective in situ monoesterification during the synthesis. The monoesterified BTC can be recovered easily from the MOF, opening up MOF synthesis as a “protection” tool for u
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Kim, Chi Won. "Synthesis of Porous Coordination Polymers for Controlled Nitric Oxide Release." 京都大学 (Kyoto University), 2016. http://hdl.handle.net/2433/204585.

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Lin, Zhuojia. "Hydrothermal synthesis of metal coordination polymers using mixed pyridine-carboxylate ligands /." View abstract or full-text, 2005. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202005%20LIN.

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Aríñez, Soriano Javier. "Design and Synthesis of Submicron Diagnostic Systems Based on Coordination Polymers." Doctoral thesis, Universitat Autònoma de Barcelona, 2016. http://hdl.handle.net/10803/399333.

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Books on the topic "Coordination polymers – Synthesis"

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Design and construction of coordination polymers. Wiley, 2009.

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K, Bregg Robert, ed. Current topics in polymer research. Nova Science Publishers, 2005.

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Walder, Anthony J. Synthesis of novel ion exchange/coordination resins and the mechanistic study of ion exchange/redox dual mechanism bifunctional polymers with their application in metal ion recovery. UMI Dissertation Services, 1989.

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Organometallic and Coordination Clusters and Polymers: Syntheses And Applications Symposium (2004 London, Ont.). Organometallic and coordination clusters and polymers: Syntheses and applications : London, Ontario, Canada, May 29-June 1, 2004. Edited by Abd-El-Aziz Alaa S and Harvey Pierre Dominique 1960-. Wiley-VCH, 2004.

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(Editor), Alaa S. Abd-El-Aziz, and Pierre D. Harvey (Editor), eds. Organometallic and Coordination Clusters and Polymers: Synthesis and Applications (Macromolecular Symposia). Wiley-VCH, 2005.

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Book chapters on the topic "Coordination polymers – Synthesis"

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Costantino, Ferdinando, Andrea Ienco, and Marco Taddei. "The Influence of Non-covalent Interactions in the Structure and Dimensionality of Hybrid Compounds and Coordination Polymers." In Non-covalent Interactions in the Synthesis and Design of New Compounds. John Wiley & Sons, Inc, 2016. http://dx.doi.org/10.1002/9781119113874.ch9.

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Friščić, Tomislav. "Toward Mechanochemical Synthesis of Metal-Organic Frameworks: From Coordination Polymers and Lattice Inclusion Compounds to Porous Materials." In Metal-Organic Frameworks. John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470606858.ch9.

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Osakada, Kohtaro, and Daisuke Takeuchi. "Coordination Polymerization of Dienes, Allenes, and Methylenecycloalkanes." In Polymer Synthesis. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b13016.

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de Lange, Kim, Jos M. J. Paulusse, Antonius T. M. Marcelis, and Han Zuilhof. "Reversible Coordination Polymers." In Ionic Interactions in Natural and Synthetic Macromolecules. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118165850.ch10.

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Soares, João B. P., and Odilia Pérez. "Coordination Polymerization." In Handbook of Polymer Synthesis, Characterization, and Processing. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118480793.ch5.

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Kaes, Christian, and Mir Wais Hosseini. "Molecular Networks: An Approach to Coordination Polymers." In Supramolecular Engineering of Synthetic Metallic Materials. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-5280-8_4.

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Visseaux, Marc, Thomas Chenal, and Philippe Zinck. "Coordinative Chain Transfer Polymerization and Copolymerization by Means of Rare Earth Organometallic Catalysts for the Synthesis of Tailor-Made Polymers." In Advances in Organometallic Chemistry and Catalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118742952.ch27.

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"Design of Stimuli-responsive Macromolecular Blocks." In Stimuli-Responsive Materials: From Molecules to Nature Mimicking Materials Design. The Royal Society of Chemistry, 2016. http://dx.doi.org/10.1039/bk9781849736565-00018.

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This chapter covers fundamental concepts in polymer synthesis, with the focus on controllable synthesis of stimuli-responsive polymers. The first sections introduce the basic concepts of molecular weight and molecular weight definitions. Various polymer architectures are introduced, with an ultimate goal of being able to synthesize sometimes very challenging synthetic steps. The following polymerizations are discussed: chain and step growth, statistical radical, cationic and anionic, coordination, ring opening, ring-opening metathesis polymerization, and controlled radical polymerization, which is represented by nitroxy-mediated polymerization, atom transfer radical polymerization, and reversible addition-fragmentation chain transfer.
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Tong, M. L., and X. M. Chen. "Synthesis of Coordination Compounds and Coordination Polymers." In Modern Inorganic Synthetic Chemistry. Elsevier, 2017. http://dx.doi.org/10.1016/b978-0-444-63591-4.00008-2.

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Dembaremba, Tendai O., Adeniyi S. Ogunlaja, and Zenixole R. Tshentu. "Coordination Polymers and Polymer Nanofibers for Effective Adsorptive Desulfurization." In Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials. IGI Global, 2021. http://dx.doi.org/10.4018/978-1-7998-8591-7.ch032.

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Desulfurization of fuel oils is an essential process employed in petroleum refineries to reduce the sulfur content to levels mandated for environmental protection. Hydrodesulfurization (HDS), which is currently being employed, is limited in treating refractory organosulfur compounds and only reduces the sulfur content in fuels to a range of 200-500 ppmS. In this chapter, several scientific and technological advances reported in the literature for the desulfurization of fuels are reviewed and discussed. Amongst these techniques, oxidative desulfurization (ODS) and adsorptive desulfurization (ADS) are proposed as additional steps to complement HDS in meeting the mandated ultra-low sulfur levels (10 ppmS). In the ODS technique, refractory organosulfur compounds are oxidized to organosulfones, followed by solvent extraction or adsorption of the organosulfones. The chemistry involved in the development and fabrication of sulfur/sulfone responsive adsorbents is also discussed. The use of molecular imprinted polymers (MIPs) and coordination polymers (CPs) for the selective adsorption of organosulfone compounds (in ODS) and/or organosulfur (in ADS) offers various properties such as imprinting effect, hydrogen bonding, π-π interactions, van der Waals forces, π-complexation, and electrostatic interactions. CPs, in particular metal organic frameworks (MOFs), have been reported to possess suitable features to overcome most of these challenges associated with adsorptive ultra-deep desulfurization when design strategies to achieve good selectivity are strictly followed. Matching the sizes of the cavities to the critical dimensions of the sulfur containing compounds (SCCs), using suitable metal centres which allow for coordinative interaction with the SCCs and using linkers with suitable functionality as to enhance specific interaction (dispersion forces) with the SCCs were considered to be pivotal features to prioritize. The prospects for the use of MIPs and CPs for future industrial applications in desulfurization are envisaged.
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Conference papers on the topic "Coordination polymers – Synthesis"

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Qin, Yan, Yu Xiao, Pu Huang, Yun Zhu, and Ming Yi. "The Research Progress on the Synthesis and Application of Microporous Coordination Polymers." In 2015 International Symposium on Material, Energy and Environment Engineering. Atlantis Press, 2015. http://dx.doi.org/10.2991/ism3e-15.2015.2.

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Bader, Mamoun M., and Phuong-Truc T. Pham. "Synthesis and characterization of some new coordination polymers for third-order nonlinear optical applications." In SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, edited by Manfred Eich and Mark G. Kuzyk. SPIE, 1999. http://dx.doi.org/10.1117/12.368273.

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Wang, Ya-Ning, Shi-Jie Li, and Wen-Dong Song. "Construction of one new coordination polymers based on 5-(pyridin-4-yl)isophthalic acid acid ligands: synthesis, crystal structures and magnetism." In 3rd International Conference on Mechatronics, Robotics and Automation. Atlantis Press, 2015. http://dx.doi.org/10.2991/icmra-15.2015.39.

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Bet, Fernanda, and Joel Dias da Silva. "Biodegradable composites of cassava starch and agro-industrial by-products: a review." In ENSUS2023 - XI Encontro de Sustentabilidade em Projeto. Grupo de Pesquisa Virtuhab/UFSC, 2023. http://dx.doi.org/10.29183/2596-237x.ensus2023.v11.n4.p85-96.

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The environmental concern with the use of synthetic polymers, above all, used in single-use packaging such as expanded polystyrene (EPS), is related to the use of non-renewable resources and, it is accentuated, with the prolonged decomposition time of this material in the environment. Cassava starch, a renewable and biodegradable polymer, offer a partial solution to the problem. Therefore, the objective of this work was to gather publications in natural polymers and to discuss the similarities and differences between these studies. The method of systematic literature review proposed by Confort
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Fuylani, A., M. V. Russo, G. Polzonetti, and M. Cuccu. "/spl pi/-conjugated organometallic polymers based on Pd(II) coordination sites." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835255.

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Ok-Sanz Jung, Young-A Lee, and C. G. Pierpont. "Bistability, low energy electron transter, and photomechanics: diimlne-bridged cobalt semiquinonate-catecholate coordination polymer." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834778.

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Kawata, S., S. Kitagawa, M. Kondo, and M. Katada. "Fabrication of infinite two- and three-dimensional copper coordination polymers of chloranilic acid and its derivatives. crystal structures and magnetic properties." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834727.

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Sadeghzadeh, Homa, and Ali Morsali. "Syntheses and characterization of a new nano-structure lead (II) coordination polymer by sonochemical method." In 2010 International Conference on Enabling Science and Nanotechnology (ESciNano). IEEE, 2010. http://dx.doi.org/10.1109/escinano.2010.5701073.

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Misran, Halina, A. M. Aminuddin, F. A. M. Zini, et al. "Facile Synthesis and Characterizations of MOF-5 Coordination Polymer with Various Metal Linker Ratios for Ammonia Gas Storage." In INTERNATIONAL CONFERENCE ON ADVANCES IN MATERIALS AND PROCESSING TECHNOLOGIES (AMPT2010). AIP, 2011. http://dx.doi.org/10.1063/1.3552454.

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Xiao, Fengping, and Peng Hu. "Synthesis, characterization, magnetic properties of cobalt coordination polymer based on 4,4'-Oxybisbenzoic acid and 1,4-bis(pyrid-4-yl)benzene." In 2017 International Conference on Material Science, Energy and Environmental Engineering (MSEEE 2017). Atlantis Press, 2017. http://dx.doi.org/10.2991/mseee-17.2017.81.

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