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Journal articles on the topic 'Coordination polymers – Synthesis'

Author: Grafiati

Published: 4 June 2021

Last updated: 7 September 2023

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1

Marchenko, Roman D., Taisiya S. Sukhikh, Alexey A. Ryadun, and Andrei S. Potapov. "Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane." Molecules 26, no. 17 (2021): 5400. http://dx.doi.org/10.3390/molecules26175400.

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Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadm

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2

Kadir, M. A., and Christopher J. Sumby. "Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor." Solid State Phenomena 273 (April 2018): 134–39. http://dx.doi.org/10.4028/www.scientific.net/ssp.273.134.

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Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourie

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3

Gorduk, Semih, Hakan Yilmaz, and Omer Andac. "Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities." Macedonian Journal of Chemistry and Chemical Engineering 38, no. 1 (2019): 19. http://dx.doi.org/10.20450/mjcce.2019.1711.

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In this study, two new coordination polymers of Cu(II) and Cd(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole were synthesized. The structures of these coordination polymers were characterized with elemental analysis, infrared spectroscopy, thermal analysis, powder X-ray diffraction, and magnetic susceptibility techniques. According to the results of the thermal analysis, the coordination polymers that contained water molecules decomposed below 100 °C, and the final products for both coordination polymers were the related metal oxides in an oxygen atmosphere. Powder X-ray dif

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4

SHOOTO, NTAOTE DAVID. "A Convenient Synthesis of Antimony Nanorods using 1,2,4,5-Benzenetetracarboxylic Acid." Asian Journal of Chemistry 31, no. 6 (2019): 1301–4. http://dx.doi.org/10.14233/ajchem.2019.21886.

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1,2,4,5-Benzenetetracarboxylic acid (H4Btec) is an ideal candidate for the synthesis of new coordination polymers compounds because of its four carboxyl groups bridging moieties with antimony ions having distorted coordination configuration. This work reports a new compound of coordination polymer, namely, [Sb2(C4H4O6)2(Btec)(H2O)]n, [(C4H4O6)2 = tartrate and Btec4− = 1,2,4,5-benzenetetracarboxylic anion] has been synthesized under reflux. The physical and chemical properties of coordination polymers; Sb2(C4H4O6)2(Btec)(H2O) was affirmed by scanning electron microscope, Fourier transform infra

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5

Luisi, Brian S., Kevin D. Rowland, and Brian Moulton. "Coordination polymer gels: synthesis, structure and mechanical properties of amorphous coordination polymers." Chemical Communications, no. 27 (2007): 2802. http://dx.doi.org/10.1039/b703768f.

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6

Vittal, Jagadese. "Photochemical Reactions of Hydrogen-bonded Coordination Polymers." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C529. http://dx.doi.org/10.1107/s2053273314094704.

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Crystallization is a kinetic phenomenon and the experimental conditions like solvents, concentration, pH, temperature and time have greater influence on the nature of products in the synthesis of coordination network structures. During crystallization, the solvents and ligands bind to the metal ions reversibly and hence, the least soluble polymer will crystallize first, independent of the metal-ligand ratio used in the crystallization. The kinetic products quite often contain solvents bonded to the metal ions. The removal of these coordinated solvents is likely to transform the kinetically for

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7

Patra, Ranjan, and Israel Goldberg. "A three-dimensional coordination polymer of 3-(3,5-dicarboxybenzyloxy)benzoic acid with zinc." Acta Crystallographica Section C Crystal Structure Communications 69, no. 8 (2013): 819–21. http://dx.doi.org/10.1107/s0108270113017204.

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The synthesis is reported of the tricarboxylic acid 3-(3,5-dicarboxybenzyloxy)benzoic acid (H3L) and the product of its reaction under solvothermal conditions with ZnIIcations, namely poly[[μ6-3-(3,5-dicarboxylatobenzyloxy)benzoato](dimethylformamide)-μ3-hydroxido-dizinc(II)], [Zn2(C16H9O7)(OH)(C3H7NO)]n, the formation of which is associated with complete deprotonation of H3L. Its crystal structure consists of a single-framework coordination polymer of the organicL3−ligand with ZnIIcations in a 1:2 ratio, with additional hydroxide and dimethylformamide (DMF) ligands coordinated to the ZnIIcent

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8

Kuznetsova, Anastasia, Vladislava Matveevskaya, Dmitry Pavlov, Andrei Yakunenkov, and Andrei Potapov. "Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties." Materials 13, no. 12 (2020): 2699. http://dx.doi.org/10.3390/ma13122699.

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Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-m

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9

Engelhardt, LM, PC Healy, JD Kildea, and AH White. "Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLVII. Vinylpyridine Derivatives of Copper(I) Halides: Synthesis and Conformational Systematics." Australian Journal of Chemistry 42, no. 1 (1989): 185. http://dx.doi.org/10.1071/ch9890185.

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The syntheses and systematic single-crystal X-ray structural characterization of 1 : 1 copper halide ( CuX )/ligand (L) adducts, CuX.L [X= Cl, Br, I; L= 2-vinylpyridine (2-vpy) and 4- vinylpyridine (4-vpy)], are recorded. For X = Cl, Br; L = 2-vpy, the solid state structures are linear polymers, the basic unit of which is an NCuX2CuN dimer , with the fourth coordination site of each copper linked to adjacent units by coordination of the vinyl group. For X= C1, Br; L = 4-vpy, a linear polymeric NCuX/NCuX infinite spine in one dimension is cross-linked from successive copper/ligand groups altern

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10

Trofimova, Olesya Y., Arina V. Maleeva, Kseniya V. Arsenyeva, Anastasiya V. Klimashevskaya, Il’ya A. Yakushev, and Alexandr V. Piskunov. "Glycols in the Synthesis of Zinc-Anilato Coordination Polymers." Crystals 12, no. 3 (2022): 370. http://dx.doi.org/10.3390/cryst12030370.

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We report the synthesis, structural investigation, and thermal behavior for three zinc-based 1D-coordination polymers with 3,6-di-tert-butyl-2,5-dihydroxy-p-benzoquinone, which were synthesized in the presence of different glycols. The interaction of zinc nitrate with glycols, followed by using the resulting solution in solvothermal synthesis with the anilate ligand in DMF, makes it possible to obtain linear polymer structures with 1,2-ethylene or 1,2-propylene glycols coordinated to the metal. The reaction involving 1,3-propylene glycol under similar conditions gives a crystal structure that

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11

Kuwamura, Naoto, and Takumi Konno. "Heterometallic coordination polymers as heterogeneous electrocatalysts." Inorganic Chemistry Frontiers 8, no. 10 (2021): 2634–49. http://dx.doi.org/10.1039/d1qi00112d.

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Heterometallic coordination polymers have been rapidly developed as heterogeneous electrocatalysts. This review highlights the synthesis strategies of these polymers and the relationships between structures and electrocatalytic performances.

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12

Lewis, Reece W., Nino Malic, Kei Saito, Neil R. Cameron, and Richard A. Evans. "Linear Coordination Polymer Synthesis from Bis‐Catechol Functionalized RAFT Polymers." Macromolecular Rapid Communications 41, no. 18 (2020): 2000366. http://dx.doi.org/10.1002/marc.202000366.

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13

Liu, Guo-Cheng, Zhi-Chao Guo, Xiu-Li Wang, Yun Qu, Song Yang, and Hong-Yan Lin. "Tuning 1-D Pb(II) Coordination Polymers by Flexible and Semirigid Dicarboxylates: Synthesis, Structure and Properties." Zeitschrift für Naturforschung B 67, no. 3 (2012): 185–91. http://dx.doi.org/10.1515/znb-2012-0301.

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Two new one-dimensional (1-D) Pb(II) coordination polymers, namely, [Pb(3-pdip)(L1)]·H2O (1) and [Pb(3-pdip)(L2)] (2) [L1H2 = 1,6-hexanedioic acid, L2H2 = homophthalic acid, 3-pdip = 2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline] have been obtained from hydrothermal reactions of Pb(II) nitrate with the phenanthroline derivative and the two dicarboxylic acids. Single-crystal X-ray diffraction analysis reveals that compound 1 is a staircase-like double-chain coordination polymer constructed from binuclear [Pb2N4O8] subunits and pairs of [L1]2− anions. Compound 2 is a linear coordination polymer

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14

Ewert, Ernest, Izabela Pospieszna-Markiewicz, Martyna Szymańska, et al. "New N4-Donor Ligands as Supramolecular Guests for DNA and RNA: Synthesis, Structural Characterization, In Silico, Spectrophotometric and Antimicrobial Studies." Molecules 28, no. 1 (2023): 400. http://dx.doi.org/10.3390/molecules28010400.

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The present work reports the synthesis of new N4-donor compounds carrying p-xylyl spacers in their structure. Different Schiff base aliphatic N-donors were obtained synthetically and subsequently evaluated for their ability to interact with two models of nucleic acids: calf-thymus DNA (CT-DNA) and the RNA from yeast Saccharomyces cerevisiae (herein simply indicated as RNA). In more detail, by condensing p-xylylenediamine and a series of aldehydes, we obtained the following Schiff base ligands: 2-thiazolecarboxaldehyde (L1), pyridine-2-carboxaldehyde (L2), 5-methylisoxazole-3-carboxaldehyde (L3

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15

Li, Xiangyu, Lishuai Zong, Weijie Li, Yibo Wang, Jinyan Wang, and Xigao Jian. "Synthesis and Characterization of Schiff Base Polymers via Metal Coordination and Its Application in Infrared Stealth Coating." Polymers 14, no. 21 (2022): 4563. http://dx.doi.org/10.3390/polym14214563.

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In order to reduce the infrared emissivity to meet the requirements of modern warfare for infrared stealth materials, we prepared the polymers containing Schiff base moieties using polyetheramine and 2,6-pyridinedicarboxaldehyde by solution polycondensation and coordinated with Ni2+, Cu2+, and Sm3+ ions to prepare organic coatings. The structure and the thermal and mechanical properties of the coatings were studied in detail. Meanwhile, the effect of the conductivity change of coordination polymers on infrared emissivity was studied systematically. The results showed the polymer coordinated wi

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16

Shao, Zhi-Chao, Xiang-Ru Meng, and Hong-Wei Hou. "Two new CdII and ZnII coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid: synthesis, crystal structure and characterization." Acta Crystallographica Section C Structural Chemistry 75, no. 8 (2019): 1065–72. http://dx.doi.org/10.1107/s2053229619009227.

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Aminobenzoic acid derivatives are widely used in the preparation of new coordination polymers since they contain O-atom donors, as well as N-atom donors, and have a rich variety of coordination modes which can lead to polymers with intriguing structures and interesting properties. Two new coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid (H3abtc), namely, poly[(μ3-1-amino-5-carboxybenzene-3,4-dicarboxylato)diaquacadmium(II)], [Cd(C9H5NO6)(H2O)2] n , (I), and poly[[bis(μ5-1-aminobenzene-3,4,5-tricarboxylato)triaquatrizinc(II)] dihydrate], {[Zn3(C9H4NO6)2(H2O)3]·2H2O} n

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17

Kim, Cho Rong, Takashi Uemura, and Susumu Kitagawa. "Inorganic nanoparticles in porous coordination polymers." Chemical Society Reviews 45, no. 14 (2016): 3828–45. http://dx.doi.org/10.1039/c5cs00940e.

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18

Satyanarayana, S., and R. L. Elsenbaumer. "Novel heterocyclic coordination polymers: synthesis and characterization." Synthetic Metals 102, no. 1-3 (1999): 1470–71. http://dx.doi.org/10.1016/s0379-6779(98)00545-1.

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19

Zhao, Yonggang, Kunhao Li, and Jing Li. "Review. Solvothermal Synthesis of Multifunctional Coordination Polymers." Zeitschrift für Naturforschung B 65, no. 8 (2010): 976–98. http://dx.doi.org/10.1515/znb-2010-0804.

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This review focuses primarily on the past 10 years of our development of multifunctional coordination polymers with 1D, 2D and 3D structures employing low-temperature and cost-effective hydrothermal and solvothermal methods. The effects of the experimental conditions and parameters on the crystal formation and phase separation, including temperature and pressure, reaction pH, solvent and composition, are discussed. Our studies have shown that a variety of different types of network structures may be rationally designed and synthesized by deliberate selection and construction of metal building

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20

Lin, Wenbin, William J Rieter, and Kathryn M L. Taylor. "Modular Synthesis of Functional Nanoscale Coordination Polymers." Angewandte Chemie International Edition 48, no. 4 (2009): 650–58. http://dx.doi.org/10.1002/anie.200803387.

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21

Huo, Jiaxiong. "Advanced coordination polymer materials for drug delivery systems." Applied and Computational Engineering 7, no. 1 (2023): 202–7. http://dx.doi.org/10.54254/2755-2721/7/20230446.

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Coordination polymers demonstrated outstanding performance and ability in drug delivery resulting from their porosity and combinatory structure of non-metal and metal. Previous research has made considerable efforts on different aspects of coordination polymers, including synthesises, modifications and pre-clinical studies. Furthermore, among those coordination polymers, metal organic frameworks turn out to be the one that performs best. Therefore, recent researches are more and more inclined to using MOFs as drug delivery systems. This literature review will talk about the current synthesis m

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22

Mautner, Franz A., Patricia V. Jantscher, Roland C. Fischer, et al. "Coordination Polymers in Dicyanamido-Cadmium(II) with Diverse Network Dimensionalities." Crystals 11, no. 2 (2021): 181. http://dx.doi.org/10.3390/cryst11020181.

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The synthesis and structural characterization of six dicyanamido-cadmium(II) complexes are reported: catena-[Cd(μ1,3-dca)(μ1,5-dca)(3-ampy)] (1), catena-[Cd3(μ1,3,5-dca)2(μ1,5-dca)4(pyNO)2(H2O)2] (2), catena-{Cd(H2O)2(μ1,5-dca)2](2,6-lut-NO)} (3), catena-[Cd(Me2en)(μ1,5-dca)2] (4), catena-[Cd(Me4en)(μ1,5-dca)2] (5), and [Cd(1,8-damnp)2(dca)2] (6), where dca = dicyanamide anion, 3-ampy = 3-aminopyridine, pyNO = pyridine-N-oxide, 2,6-lut-NO = 2,6-lutidine-N-oxide, Me2en = N,N-dimethyl-ethylenediamine, Me4en = N,N,N′,N′-tetramethyl-ethylenediamine, and 1,8-damnp = 1,8-diaminonaphthaline. The coor

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23

Uemura, Takashi, Tetsuya Kaseda, and Susumu Kitagawa. "Controlled Synthesis of Anisotropic Polymer Particles Templated by Porous Coordination Polymers." Chemistry of Materials 25, no. 18 (2013): 3772–76. http://dx.doi.org/10.1021/cm4025843.

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24

Gong, Wei, Kunkun Zheng, and Peijun Ji. "Platinum deposited on cerium coordination polymer for catalytic oxidation of hydroxymethylfurfural producing 2,5-furandicarboxylic acid." RSC Advances 7, no. 55 (2017): 34776–82. http://dx.doi.org/10.1039/c7ra05427k.

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25

Dadashi, Jaber, Mohammad Khaleghian, Younes Hanifehpour, Babak Mirtamizdoust, and Sang Woo Joo. "Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation." Nanomaterials 12, no. 13 (2022): 2257. http://dx.doi.org/10.3390/nano12132257.

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The current study aims to explain recent developments in the synthesis of Pb(II)-azido metal-organic coordination polymers. Coordination polymers are defined as hybrid materials encompassing metal-ion-based, organic linkers, vertices, and ligands, serving to link the vertices to 1D, 2D, or 3D periodic configurations. The coordination polymers have many applications and potential properties in many research fields, primarily dependent on particular host–guest interactions. Metal coordination polymers (CPs) and complexes have fascinating structural topologies. Therefore, they have found numerous

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26

Ghosh, Pritam, Additi Roychowdhury, Montserrat Corbella, et al. "Designed synthesis of CO2-promoted copper(ii) coordination polymers: synthesis, structural and spectroscopic characterization, and studies of versatile functional properties." Dalton Trans. 43, no. 36 (2014): 13500–13508. http://dx.doi.org/10.1039/c4dt00183d.

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27

Saalfrank, Rolf W., Oliver Struck, Matthew G. Davidson, and Ronald Snaith. "Coordination Polymers, IX[1] Synthesis and Crystal Structure of a 1D-Sodium Coordination Polymer: [NaL4(PMDETA)]∞." Chemische Berichte 127, no. 12 (1994): 2489–92. http://dx.doi.org/10.1002/cber.19941271220.

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28

Diana, Eliano, Giuliana Gervasio, Emanuele Priola, and Elisabetta Bonometti. "A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)]n[Ag(SCN)(CN)]n." CrystEngComm 16, no. 43 (2014): 10040–45. http://dx.doi.org/10.1039/c4ce01424c.

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29

Lu, L., W. P. Wu, A. Q. Ma, B. Xie, and Y. Wu. "Synthesis, structural, and luminescence of two coordination polymers." Russian Journal of Coordination Chemistry 41, no. 9 (2015): 573–78. http://dx.doi.org/10.1134/s1070328415080035.

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30

Nakayama, Mitsuki, Takuya Kanetomo, and Masaya Enomoto. "Dithiooxalato-bridged Nickel Coordination Polymers: Synthesis and Structures." Chemistry Letters 49, no. 9 (2020): 1050–52. http://dx.doi.org/10.1246/cl.200243.

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31

Imoto, Hiroaki, Yasuhiro Morisaki, and Yoshiki Chujo. "Synthesis and coordination behaviors of P-stereogenic polymers." Chemical Communications 46, no. 40 (2010): 7542. http://dx.doi.org/10.1039/c0cc03120h.

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Li, Feng, Taohai Li, Xiaoju Li, Xing Li, Yuling Wang, and Rong Cao. "Synthesis of Chiral Coordination Polymers by Spontaneous Resolution." Crystal Growth & Design 6, no. 6 (2006): 1458–62. http://dx.doi.org/10.1021/cg0600905.

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33

Yang, E., Hong-Yan Li, Zi-Sheng Liu, and Qi-Dan Ling. "Urothermal synthesis of two photoluminescent cadmium coordination polymers." Inorganic Chemistry Communications 30 (April 2013): 152–55. http://dx.doi.org/10.1016/j.inoche.2013.01.030.

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Sushrutha, S. R., Raghunandan Hota, and Srinivasan Natarajan. "Adenine-Based Coordination Polymers: Synthesis, Structure, and Properties." European Journal of Inorganic Chemistry 2016, no. 18 (2016): 2962–74. http://dx.doi.org/10.1002/ejic.201600111.

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Abourahma, Heba, Gregory J. McManus, Brian Moulton, Rosa D. Bailey Walsh, and Michael J. Zaworotko. "Design, synthesis and structural diversity in coordination polymers." Macromolecular Symposia 196, no. 1 (2003): 213–27. http://dx.doi.org/10.1002/masy.200390162.

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36

Deville, Claire, Henrik S. Jeppesen, Vickie McKee, and Nina Lock. "Anion and solvent controlled growth of crystalline and amorphous zinc(ii) coordination polymers and a molecular complex." Dalton Transactions 50, no. 11 (2021): 3979–89. http://dx.doi.org/10.1039/d0dt04190d.

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Werner, Julia, Tomče Runčevski, Robert Dinnebier, Stefan G. Ebbinghaus, Stefan Suckert, and Christian Näther. "Thiocyanato Coordination Polymers with Isomeric Coordination Networks - Synthesis, Structures, and Magnetic Properties." European Journal of Inorganic Chemistry 2015, no. 20 (2015): 3236–45. http://dx.doi.org/10.1002/ejic.201500473.

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Werner, Julia, Tomče Runčevski, Robert Dinnebier, Stefan G. Ebbinghaus, Stefan Suckert, and Christian Näther. "Thiocyanato Coordination Polymers with Isomeric Coordination Networks - Synthesis, Structures, and Magnetic Properties." European Journal of Inorganic Chemistry 2015, no. 20 (2015): 3214. http://dx.doi.org/10.1002/ejic.201500712.

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Geagea, Elie, Judicael Jeannoutot, Louise Morgenthaler, Simon Lamare, Frank Palmino, and Frédéric Chérioux. "On-Surface Synthesis of Ligands to Elaborate Coordination Polymers on an Au(111) Surface." Nanomaterials 11, no. 8 (2021): 2102. http://dx.doi.org/10.3390/nano11082102.

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On-surface metal-organic polymers have emerged as a class of promising 2D materials. Here, we propose a new strategy to obtain coordination polymers by transforming supramolecular networks into coordination polymers by surface-assisted cyclo-dehydrogenation of organic building blocks. All nanostructures are fully characterized by using scanning tunneling microscopy under ultra-high vacuum on a gold surface. We demonstrated that the balance between molecule-molecule interaction and molecule-substrate interaction can be drastically modified by a strong modification of the geometry of the molecul

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40

He, Zi-Wei, Chang-Jie Liu, Wei-Dong Li, Shuai-Shuai Han, and Shui-Sheng Chen. "Two Interpenetrated Zn(II) Coordination Polymers: Synthesis, Topological Structures, and Property." Crystals 9, no. 11 (2019): 601. http://dx.doi.org/10.3390/cryst9110601.

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Two interpenetrated coordination polymers (CPs) {[Zn1(L)(NO2pbda)]n[Zn2(L)(NO2pbda)]n} (1) and [Zn(L)(Brpbda)]n (2) were prepared by reactions of zinc sulfate heptahydrate with N-donor ligands of 1,4-di(1H-imidazol-4-yl)benzene (L) and auxiliary carboxylic acids of nitroterephthalic acid (H2NO2pbda) and 2,5-dibromoterephthalic acid (H2Brpbda), respectively. The structures of the CPs were characterized by Fourier-Transform Infrared (IR) spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The coordination polymer 1 has two different (4, 4) sql 2D layer structures based on the

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41

Khunur, Mohammad Misbah, and Yuniar Ponco Prananto. "Synthesis and Structure of 2D Cobalt(II)-tartrate Hydrate Coordination Polymers Crystallised from Aqueous Solution." Bulletin of Chemical Reaction Engineering & Catalysis 13, no. 2 (2018): 213. http://dx.doi.org/10.9767/bcrec.13.2.1342.213-219.

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Cobalt(II)-tartrate hydrate coordination polymer is successfully crystallisedfrom aqueous solution at room temperature. Unlike previous methods, diammonium tartrate was used and reacted directly with an aqueous solution of cobalt(II). Single crystal X-ray and ATR-IR analyses were performed toward the synthesized crystal. The crystal structure displaysa (6,3) 2D sheet which then grow into a 3D hydrogen-bonded network. Tetra- and hexa-dentate dianionic tartaric ligands are observed in the crystal structure, in which the hexadentate ligand connects four different cobalt centres. This method is co

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42

Gao, Wen-Yang, Gerard Pierre Van Trieste III, and David C. Powers. "Synthesis of atomically precise single-crystalline Ru2-based coordination polymers." Dalton Transactions 49, no. 45 (2020): 16077–81. http://dx.doi.org/10.1039/d0dt02233k.

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Metallopolymerization of kinetically inert Ru<sub>2</sub> metallomonomers via construction of Ag–N bonds provides access to atomically precise single-crystalline Ru<sub>2</sub>-based coordination polymers with varied network topology and primary coordination sphere.

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Manna, Paulami, Bharat Kumar Tripuramallu, Suresh Bommakanti, and Samar K. Das. "Synthesis, characterization and magnetism of metal–organic compounds: role of the positions of the coordinating groups of a meso-flexible ligand in placing anisotropy to exhibit spin-canting behaviour." Dalton Transactions 44, no. 6 (2015): 2852–64. http://dx.doi.org/10.1039/c4dt03468f.

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Zhu, Ziqian, Yufang Tao, Yansong Jiang, et al. "Two scandium coordination polymers: rapid synthesis and catalytic properties." CrystEngComm 21, no. 35 (2019): 5261–68. http://dx.doi.org/10.1039/c9ce00969h.

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Brown, Matthew L., and Daniel B. Leznoff. "Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions." Canadian Journal of Chemistry 98, no. 7 (2020): 365–72. http://dx.doi.org/10.1139/cjc-2020-0031.

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The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A se

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Kadota, Kentaro, Nghia Tuan Duong, Yusuke Nishiyama, Easan Sivaniah, Susumu Kitagawa, and Satoshi Horike. "Borohydride-containing coordination polymers: synthesis, air stability and dehydrogenation." Chemical Science 10, no. 24 (2019): 6193–98. http://dx.doi.org/10.1039/c9sc00731h.

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Saalfrank, Rolf W., Michael Decker, Frank Hampel, Karl Peters, and Hans Georg von Schnering. "Coordination Polymers, 13. Induction of Helicity via Stereogenic Centers: Asymmetric Synthesis of (P)- and (M)-Coordination Polymers." Chemische Berichte 130, no. 9 (1997): 1309–13. http://dx.doi.org/10.1002/cber.19971300921.

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Basinger, Corinne A., Kaitlin Sullivan, Sarah Siemer, Stuart Oehrle, and Keith A. Walters. "Synthesis and Preliminary Characterization of a PPE-Type Polymer Containing Substituted Fullerenes and Transition Metal Ligation Sites." Journal of Chemistry 2015 (2015): 1–11. http://dx.doi.org/10.1155/2015/672654.

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A substituted fullerene was incorporated into a PPE-conjugated polymer repeat unit. This subunit was then polymerized via Sonogashira coupling with other repeat units to create polymeric systems approaching 50 repeat units (based on GPC characterization). Bipyridine ligands were incorporated into some of these repeat units to provide sites for transition metal coordination. Photophysical characterization of the absorption and emission properties of these systems shows excited states located on both the fullerene and aromatic backbone of the polymers that exist in a thermally controlled equilib

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Ienco, Andrea, Giulia Tuci, Annalisa Guerri, and Ferdinando Costantino. "Mechanochemical Access to Elusive Metal Diphosphinate Coordination Polymer." Crystals 9, no. 6 (2019): 283. http://dx.doi.org/10.3390/cryst9060283.

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Several binary metal diphosphinate compounds (ML) have been reported for diphosphinate bonded by a single methylene fragment. In case of longer bridges, binary products are difficult to isolate in crystalline form. Here, using a solvent assisted mechano-chemistry synthesis, we report two new ML crystalline phases, one hydrated and one anhydrous. The hydrated phase is a 2D coordination polymer with an open framework structure. Its network displays a new topology for coordination polymers and metal organic frameworks. The thermal behavior of the two phases has been studied. Finally, the importan

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Chen, Dong, Pengfei Zhang, Qianrong Fang, et al. "Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability." Inorganic Chemistry Frontiers 5, no. 8 (2018): 2018–22. http://dx.doi.org/10.1039/c8qi00471d.

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A simple and versatile strategy is developed for the synthesis of coordination-supported organic polymers(COPs) via coordination between Al<sup>3+</sup> and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation.

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