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Journal articles on the topic 'Copper Antimony Sulfide'

Author: Grafiati

Published: 7 June 2025

Last updated: 2 August 2025

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1

Sarswat, Prashant K., and Michael L. Free. "Enhanced Photoelectrochemical Response from Copper Antimony Zinc Sulfide Thin Films on Transparent Conducting Electrode." International Journal of Photoenergy 2013 (2013): 1–7. http://dx.doi.org/10.1155/2013/154694.

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Copper antimony sulfide (CAS) is a relatively new class of sustainable absorber material, utilizing cost effective and abundant elements. Band gap engineered, modified CAS thin films were synthesized using electrodeposition and elevated temperature sulfurization approach. A testing analog of copper zinc antimony sulfide (CZAS) film-electrolyte interface was created in order to evaluate photoelectrochemical performance of the thin film of absorber materials. Eu3+/Eu2+redox couple was selected for this purpose, based on its relative band offset with copper antimony sulfide. It was observed that

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2

Solozhenkin, Petr M. "Technology of Dry Wastes Processing of Sorption and Solutions of Antimony Chlorides." Transbaikal State University Journal 30, no. 1 (2024): 73–80. http://dx.doi.org/10.21209/2227-9245-2024-30-1-73-80.

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Reducing the loss of valuable components during the processing of complex gold-antimony ores, increasing the extraction of antimony during the flotation of sulfide minerals, is an urgent scientific problem. The aim of the study is to maximize the extraction of gold and antimony from dry sorption waste after gold cyanidation, and to improve the reagent regime of the antimony mineral flotation process. Research objectives are as follows: evaluation of the technology efficiency for processing dry sorption waste; extraction of gold from the cake of acidic leaching of antimony; production of variou

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3

Vinayakumar, V., S. Shaji, D. Avellaneda, J. A. Aguilar-Martínez, and B. Krishnan. "Copper antimony sulfide thin films for visible to near infrared photodetector applications." RSC Advances 8, no. 54 (2018): 31055–65. http://dx.doi.org/10.1039/c8ra05662e.

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4

Wang, Wei, Zheng Xu, Song Tao Huang, et al. "Characteristics Research and Selective Leaching of Anode Slime with High Content of Copper and Stannum." Advanced Materials Research 1010-1012 (August 2014): 1594–97. http://dx.doi.org/10.4028/www.scientific.net/amr.1010-1012.1594.

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The anode slime comes from the process of scrap copper electrolysis which contains high content of copper, stannum and some other metals, such as lead, antimony and precious metals. The result of particle size distribution showed that copper exist in large particle-size parts more than in small ones, while most of stannum concentrate in small particle ones. XRD and MLA were employed to characterize the anode slime. Copper is occurrence in copper sulfide, while stannum is in stannic oxide. Selective leaching by using hydrochloric acid has been conducted based on initial analysis. 97.86% of anti

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5

Zhang, Feng, Keqiang Chen, Xiantao Jiang, et al. "Nonlinear optical absorption and ultrafast carrier dynamics of copper antimony sulfide semiconductor nanocrystals." Journal of Materials Chemistry C 6, no. 33 (2018): 8977–83. http://dx.doi.org/10.1039/c8tc01606b.

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Ternary copper antimony sulfide nanocrystals (CAS NCs), a promising solar cell candidate, have been proposed and investigated from the perspective of nonlinear optical response and ultrafast photoinduced carrier dynamics.

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6

Rylnikova, Marina, Viktor Fedotenko, and Natalia Mitishova. "Influence of structural and textural features of ores and rocks on mine dust explosion hazard during development of pyrite deposits." E3S Web of Conferences 192 (2020): 03017. http://dx.doi.org/10.1051/e3sconf/202019203017.

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In the practice of mining works, sulfide-dust explosions often occur during underground development of pyrite ore deposits: copper-zinc, lead-zinc, copper-nickel, antimony, and others. This makes it necessary to conduct researches aimed at improvement of methods for studying the explosive properties of sulfide dust and development of industrial and environmental safety requirements for mining operations. Currently, there is no generally accepted state-approved regulatory procedure for assessment of sulfide dust explosion hazards during underground mining operations in Russia. Assessment of the

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7

Zeng, Qiang, Yunxiang Di, Chun Huang, et al. "Famatinite Cu3SbS4 nanocrystals as hole transporting material for efficient perovskite solar cells." Journal of Materials Chemistry C 6, no. 30 (2018): 7989–93. http://dx.doi.org/10.1039/c8tc02133c.

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8

Zou, Yu, and Jiang Jiang. "Colloidal synthesis of chalcostibite copper antimony sulfide nanocrystals." Materials Letters 123 (May 2014): 66–69. http://dx.doi.org/10.1016/j.matlet.2014.02.069.

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9

Xu, Dongying, Shuling Shen, Yejun Zhang, Hongwei Gu, and Qiangbin Wang. "Selective Synthesis of Ternary Copper–Antimony Sulfide Nanocrystals." Inorganic Chemistry 52, no. 22 (2013): 12958–62. http://dx.doi.org/10.1021/ic401291a.

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10

Rath, Thomas, Andrew J. MacLachlan, Michael D. Brown, and Saif A. Haque. "Structural, optical and charge generation properties of chalcostibite and tetrahedrite copper antimony sulfide thin films prepared from metal xanthates." Journal of Materials Chemistry A 3, no. 47 (2015): 24155–62. http://dx.doi.org/10.1039/c5ta05777a.

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Chalcostibite and tetrahedrite thin films are prepared from solution on mesoporous TiO<sub>2</sub> layers and photoinduced generation of long-lived charges is detected in these TiO<sub>2</sub>/copper antimony sulfide heterojunctions.

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11

Volodin, Valeriy, Alina Nitsenko, Xeniya Linnik, and Sergey Trebukhov. "Distribution of Rare Elements in Distillation Processing of Polymetallic Matte." Metals 13, no. 12 (2023): 1934. http://dx.doi.org/10.3390/met13121934.

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The results of studies on the distribution of rare elements among the products of distillation processing of polymetallic mattes are present in this article. Schemes of the developed technological equipment for the implementation of the extraction processes of rare elements via the vacuum distillation of mattes are presented. Technological tests were performed with a matte of lead, copper, and antimony plants at 1100–1250 °C and a pressure of up to 700 Pa. It was established that As, Cd, Bi, In, and Ge, by more than 90% in total, are extracted into condensate and dust in the distillation proce

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12

van Embden, Joel, and Yasuhiro Tachibana. "Synthesis and characterisation of famatinite copper antimony sulfide nanocrystals." Journal of Materials Chemistry 22, no. 23 (2012): 11466. http://dx.doi.org/10.1039/c2jm32094k.

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13

Powell, Anthony V., Raquel Paniagua, Paz Vaqueiro, and Ann M. Chippindale. "An Antimony Sulfide with Copper Pillars: [C4H12N2]0.5[CuSb6S10]." Chemistry of Materials 14, no. 3 (2002): 1220–24. http://dx.doi.org/10.1021/cm010751f.

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14

Powell, Anthony V., Sylvain Boissière, and Ann M. Chippindale. "A new mixed-valent copper–antimony sulfide: [H2NCH2CH2NH2]0.5[Cu2SbS3]." Journal of the Chemical Society, Dalton Transactions, no. 22 (2000): 4192–95. http://dx.doi.org/10.1039/b005111j.

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15

Ornelas-Acosta, R. E., S. Shaji, D. Avellaneda, G. A. Castillo, T. K. Das Roy, and B. Krishnan. "Thin films of copper antimony sulfide: A photovoltaic absorber material." Materials Research Bulletin 61 (January 2015): 215–25. http://dx.doi.org/10.1016/j.materresbull.2014.10.027.

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16

Ramasamy, Karthik, Hunter Sims, William H. Butler, and Arunava Gupta. "Mono-, Few-, and Multiple Layers of Copper Antimony Sulfide (CuSbS2): A Ternary Layered Sulfide." Journal of the American Chemical Society 136, no. 4 (2014): 1587–98. http://dx.doi.org/10.1021/ja411748g.

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17

McNulty, Brian A., Simon M. Jowitt, and Ivan Belousov. "THE IMPORTANCE OF GEOLOGY IN ASSESSING BY- AND COPRODUCT METAL SUPPLY POTENTIAL; A CASE STUDY OF ANTIMONY, BISMUTH, SELENIUM, AND TELLURIUM WITHIN THE COPPER PRODUCTION STREAM." Economic Geology 117, no. 6 (2022): 1367–85. http://dx.doi.org/10.5382/econgeo.4919.

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Abstract The ongoing global transition to low- and zero-CO2 energy generation and transport will require more raw materials and metals than ever produced before in human history to develop the necessary infrastructure for solar and wind power generation, electric power grid distribution, and electric vehicle componentry, including batteries. In addition to numerous critical elements, this transition will also require increased production of a range of other metals. This includes copper, with increased production of this metal providing the minerals industry with enhanced opportunities to secur

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18

Cho, Ara, Shahara Banu, Kihwan Kim, et al. "Selective thin film synthesis of copper-antimony-sulfide using hybrid ink." Solar Energy 145 (March 2017): 42–51. http://dx.doi.org/10.1016/j.solener.2016.12.048.

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19

Suehiro, Satoshi, Keisuke Horita, Masayoshi Yuasa, et al. "Synthesis of Copper–Antimony-Sulfide Nanocrystals for Solution-Processed Solar Cells." Inorganic Chemistry 54, no. 16 (2015): 7840–45. http://dx.doi.org/10.1021/acs.inorgchem.5b00858.

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20

Ramos Aquino, Jose Agustin, Dorian Leonardo Rodriguez Vela, Sadasivan Shaji, David Avellaneda Avellaneda, and Bindu Krishnan. "Spray pyrolysed thin films of copper antimony sulfide as photovoltaic absorber." physica status solidi (c) 13, no. 1 (2015): 24–29. http://dx.doi.org/10.1002/pssc.201510102.

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21

Powell, Anthony V., Raquel Paniagua, Paz Vaqueiro, and Ann M. Chippindale. "ChemInform Abstract: An Antimony Sulfide with Copper Pillars: [C4H12N2]0.5 [CuSb6S10]." ChemInform 33, no. 23 (2010): no. http://dx.doi.org/10.1002/chin.200223021.

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22

Oráč, Dušan, Martina Laubertová, František Molnár, Jakub Klimko, Vladimír Marcinov, and Jana Pirošková. "Thermodynamic Study Proposal of Processing By-Product Containing Au, Ag, Cu and Fe Sulfides from Antimony Ore Treatment." Processes 13, no. 3 (2025): 842. https://doi.org/10.3390/pr13030842.

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A possible thermodynamic study of processing Cu (Ag, Au) and Fe sulfide concentrate as a by-product after the processing of tetrahedrite concentrate, applying pyrometallurgical and hydrometallurgical methods, was studied. The sample of sulfide concentrate, 34.7 wt. % Cu, 21.4% Fe, 12 g/t Au, and 7.317 g/t Ag was contained. Analytical technique AAS was used to analyze the sample before conducting a thermodynamic study of the leaching of sulfide concentrate by applying Pourbaix Eh–pH diagrams. The outcome of this thermodynamic research will provide essential data to support recent hydrometallurg

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23

Ishaq, Muhammad, Hui Deng, Umar Farooq, et al. "Efficient Copper‐Doped Antimony Sulfide Thin‐Film Solar Cells via Coevaporation Method." Solar RRL 3, no. 12 (2019): 1900305. http://dx.doi.org/10.1002/solr.201900305.

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24

Liu, Ziliang, Yizhe Tong, Xingmin He, and Longyi Chen. "Study on Optimization of Deep Purification Process Design of Zinc Oxygen Pressure Acid Leaching Solution." Journal of Physics: Conference Series 2738, no. 1 (2024): 012013. http://dx.doi.org/10.1088/1742-6596/2738/1/012013.

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Abstract According to the characteristics of high impurity content and complex composition of oxygen pressure leaching (OPL) solution of zinc sulfide concentrate, combined with the quality requirements of large plate electrowinning and automatic plate stripping, the advanced purification process of solution was designed. Through the deep purification process consisting of neutralization indium precipitation and low iron purification, high temperature antimony salt nickel and cobalt removal, copper slag chlorine removal, low temperature zinc powder replacement copper and cadmium removal, fine p

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25

Adewoyin, Adeyinka D. "Absorber layer optimisation of copper antimony sulfide thin film photovoltaics using numerical simulation." Superlattices and Microstructures 158 (October 2021): 107029. http://dx.doi.org/10.1016/j.spmi.2021.107029.

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26

Swathi, S., R. Yuvakkumar, P. Senthil Kumar, G. Ravi, and Dhayalan Velauthapillai. "Polyvinylpyrrolidone-assisted novel copper antimony sulfide nanorods for highly efficient hydrogen evolution reaction." Fuel 314 (April 2022): 123096. http://dx.doi.org/10.1016/j.fuel.2021.123096.

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27

Bella, M., C. Rivero, S. Blayac, H. Basti, M. C. Record, and P. Boulet. "Oleylamine-assisted solvothermal synthesis of copper antimony sulfide nanocrystals: Morphology and phase control." Materials Research Bulletin 90 (June 2017): 188–94. http://dx.doi.org/10.1016/j.materresbull.2017.02.036.

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28

Devi, Chandni, and Rajesh Mehra. "Device simulation of lead-free MASnI3 solar cell with CuSbS2 (copper antimony sulfide)." Journal of Materials Science 54, no. 7 (2019): 5615–24. http://dx.doi.org/10.1007/s10853-018-03265-y.

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29

Štrbac, Nada, Miroslav Sokić, Aleksandra Mitovski, et al. "Investigation of Bi2S3 oxidation process at elevated temperatures in the air atmosphere." Tehnika 75, no. 6 (2020): 587–93. http://dx.doi.org/10.5937/tehnika2005587s.

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Bismuth (III) sulfide has been widely researched in recent years due to its application, but little emphasis has been placed on research regarding its behavior at elevated temperatures. This is of great importance, considering that bismuth, in the form of Bi2S3, is found in copper sulfide concentrates and is considered one of the most harmful components, along with lead, arsenic and antimony. The removal of these substances is one of the basic tasks in the processes of pyrometallurgical extraction of copper, in order to obtain a high purity metal. In order to better understand the behavior of

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30

Sun, Guilin, Guochun Dong, Sufen Tao, Yunjin Xia, and Chao Chen. "Effect of Sulfur on Antimony-Induced High-Temperature Ductility Deterioration of C-Mn Steel." Metals 13, no. 1 (2023): 130. http://dx.doi.org/10.3390/met13010130.

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The recycling of steel scrap is becoming more and more developed to save resources and protect the environment. However, impurities such as antimony in steel scrap cannot be economically and effectively removed, resulting in an inevitable accumulation of impurities. Once the impurity concentration exceeds a certain limit, they will have a great impact on the ductility deterioration and hot shortness of steel. It has been shown that sulfide can inhibit the precipitation of residual elements, such as copper at grain boundaries, in steel. The effect of sulfur on the thermoplasticity of antimony-c

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31

Hu, Ping, Yulian Dong, Guowei Yang, et al. "Hollow CuSbSy Coated by Nitrogen-Doped Carbon as Anode Electrode for High-Performance Potassium-Ion Storage." Batteries 9, no. 5 (2023): 238. http://dx.doi.org/10.3390/batteries9050238.

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As a potential anode material for potassium-ion batteries (PIBs), bimetallic sulfides are favored by researchers for their high specific capacity, low cost, and long cycle life. However, the non-ideal diffusion rate and poor cycle stability pose significant challenges in practical applications. In this work, bimetallic sulfide CuSbSy@C with a yolk-shell structure was synthesized by in situ precipitation and carbonization. When CuSbSy is applied in the anode of PIBs, it can provide the desired capacity and reduce the volume expansion of the compound through the synergistic effect between copper

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32

Dosmukhamedov, N. K., E. E. Zholdasbay, A. A. Argyn, Yu B. Icheva, and M. B. Kurmanseitov. "Enlarged tests on the processing of copper-lead mattes obtained after reductive smelting of balanced feed charge." Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources 337, no. 2 (2025): 75–84. https://doi.org/10.31643/2026/6445.19.

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The paper examines the behavior of copper, lead, zinc and arsenic during the oxidative blowing of intermediate copper-lead matte, which represents the second stage of the general technology for processing balanced raw materials for copper and lead production. The optimal parameters for the oxidative blowing of intermediate matte have been established: the time of blowing the melt with oxygen is 20 min; the oxygen consumption is 1.4 times higher than its consumption from the stoichiometrically required amount for the oxidation of zinc and iron sulfide; the temperature is 1250 °C. High indicator

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33

Hota, Poulami, Arijit Kapuria, Saptasree Bose, Dilip K. Maiti, and Shyamal K. Saha. "The role of lone-pair electrons on electrocatalytic activity of copper antimony sulfide nanostructures." Materials Chemistry and Physics 291 (November 2022): 126676. http://dx.doi.org/10.1016/j.matchemphys.2022.126676.

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34

Kishore Kumar, Y. B., S. Guru Prasad, A. S. Swapna Smitha, et al. "Effect of carrier gas on copper antimony sulfide thin films by spray pyrolytic approach." Chalcogenide Letters 21, no. 9 (2024): 719–27. http://dx.doi.org/10.15251/cl.2024.219.719.

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This study explores the ternary compound semiconductor as a potential absorber layer for third-generation solar cells. CuSbS2, a promising candidate for thin film absorber layers, is fabricated using a simple spray pyrolysis method. The research specifically investigates the influence of two different carrier gases during the fabrication process. X-ray diffraction as well as Raman studies confirm that the films exhibit a chalcostibite structure. Notably, films fabricated with nitrogen as the carrier gas demonstrate enhanced crystallinity, accompanied by reduced microstrain and dislocation dens

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35

Kumar, B. Hemanth, S. Shaji, and M. C. Santhosh Kumar. "Effect of substrate temperature on properties of co-evaporated copper antimony sulfide thin films." Thin Solid Films 697 (March 2020): 137838. http://dx.doi.org/10.1016/j.tsf.2020.137838.

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36

Sribenjawan, Janthima, Duanghatai Raknual, Veeramol Vailikhit, Nareerat Kitisripanya, and Auttasit Tubtimtae. "Facile synthesis of copper-antimony-sulfide nanostructures on WO3 electrodes: Investigation of electrochemical performance." Materials Letters 245 (June 2019): 126–29. http://dx.doi.org/10.1016/j.matlet.2019.02.120.

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37

Blanco-Vino, Walter, Gerardo Zamora, and Javier I. Ordóñez. "Selective Removal of Arsenic and Antimony from Pb-Ag Sulfide Concentrates by Alkaline Leaching: Thermodynamic and Kinetic Studies." Mining 4, no. 2 (2024): 284–301. http://dx.doi.org/10.3390/mining4020017.

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Arsenic and antimony are impurities that reduce the economic value of concentrates due to the environmental problems they cause. The removal of these impurities by hydrometallurgical means has been highly studied for sulfide copper concentrates using different leaching agents in an alkaline medium (NaClO, H2O2, NaOH, Na2S, NaHS, and S). For a lead–silver concentrate consisting of galena, sphalerite, and pyrite, it was possible to selectively reduce the arsenic content from 1.10% to 0.55% and antimony from 2.41 to 1.04% through the digestion-leaching technique that uses elemental sulfur as a le

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38

Khanchuk, A. I., V. P. Molchanov, and D. V. Androsov. "THE FIRST INFORMATION ABOUT THE GOLD-COPPER MINERALIZATION OF THE KONTORSKOYE ORE OPENING (ARIADNE INTRUSION OF ULTRABASITES, PRIMORYE)." Доклады Российской академии наук. Науки о Земле 511, no. 1 (2023): 5–11. http://dx.doi.org/10.31857/s268673972260240x.

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Within the Sikhote-Alin orogenic belt, a new promising type of mineral resources has been identified – complex ores and placers spatially and genetically related to Late Mesozoic ultramafic intrusions. An example of this is the Ariadne massif of ultramafic rocks, in the center of which there is a manifestation of gold-titanium mineralization, and in the exocontact – gold-antimony. The main features of the mineralogy and geochemistry of gold-copper formations in its near-intrusive zone are determined. To reconstruct the conditions for the formation of these ores, the isotopic composition of sul

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39

Barros, Kayo Santana, Vicente Schaeffer Vielmo, Belén Garrido Moreno, Gabriel Riveros, Gerardo Cifuentes, and Andréa Moura Bernardes. "Chemical Composition Data of the Main Stages of Copper Production from Sulfide Minerals in Chile: A Review to Assist Circular Economy Studies." Minerals 12, no. 2 (2022): 250. http://dx.doi.org/10.3390/min12020250.

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The mining industry has faced significant challenges to maintaining copper production technically, economically, and environmentally viable. Some of the major limitations that must be overcome in the coming years are the copper ore grade decline due to its intense exploitation, the increasing requirements for environmental protection, and the need to expand and construct new tailings dams. Furthermore, the risk of a supply crisis of critical metals, such as antimony and bismuth, has prompted efforts to increase their extraction from secondary resources in copper production. Therefore, improvin

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40

Ramasamy, Karthik, Benjamin Tien, P. S. Archana, and Arunava Gupta. "Copper antimony sulfide (CuSbS2) mesocrystals: A potential counter electrode material for dye-sensitized solar cells." Materials Letters 124 (June 2014): 227–30. http://dx.doi.org/10.1016/j.matlet.2014.03.046.

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41

Ramasamy, Karthik, Hunter Sims, William H. Butler, and Arunava Gupta. "Selective Nanocrystal Synthesis and Calculated Electronic Structure of All Four Phases of Copper–Antimony–Sulfide." Chemistry of Materials 26, no. 9 (2014): 2891–99. http://dx.doi.org/10.1021/cm5005642.

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42

Shapouri, Samaneh, Elnaz Irani, Payam Rajabi Kalvani, et al. "Substrate-Dependent Characteristics of CuSbS2 Solar Absorber Layers Grown by Spray Pyrolysis." Coatings 15, no. 6 (2025): 683. https://doi.org/10.3390/coatings15060683.

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Copper antimony sulfide (CuSbS2) is an affordable and eco-friendly solar absorber with an optimal bandgap and high absorption coefficient, and it stands out as a promising candidate for thin-film solar cells. This study investigates the effects of indium tin oxide (ITO), fluorine-doped tin oxide (FTO), and glass substrates on the microstructural, morphological, and optical properties of CuSbS2 (CAS) layers synthesized via spray pyrolysis. X-ray Diffraction (XRD) and Raman spectroscopy analyses revealed that CAS phases formed on ITO and FTO substrates exhibited a phase composition without addit

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43

Shaybekov, R. I., B. A. Makeev, N. N. Kononkova, S. I. Isaenko, and E. M. Tropnikov. "Palladium tellurides and bismuthtellurides in sulfide copper-nickel ores of the Savabeisky ore occurrence (Nenets Autonomous District, Russsia)." LITHOSPHERE (Russia) 21, no. 4 (2021): 574–94. http://dx.doi.org/10.24930/1681-9004-2021-21-4-574-594.

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Research subject. The Savabeisky sulfide copper-nickel ore occurrence, located in the central part of the Khengur (Central Pay-Khoy) gabbro-dolerite complex of the Pay-Khoy, within the Yugorsky Peninsula, located in the Far North-East of the European part of Russia, in the Arkhangelsk region, between the Barents and Kara Seas.Materials and methods. Samples of copper-nickel ores with noble metal mineralization were studied. Palladium tellurides and bismuthtellurides were characterized using optical and scanning electron microscopy, electron backscatter diffraction (EBSD), X-ray structural analy

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44

Zhang, Yu, Jianhua Tian, Kejian Jiang, Jinhua Huang, Huijia Wang, and Yanlin Song. "In situ gas-solid reaction for fabrication of copper antimony sulfide thin film as photovoltaic absorber." Materials Letters 209 (December 2017): 23–26. http://dx.doi.org/10.1016/j.matlet.2017.07.106.

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45

Askarova, Gulzhan, Mels Shautenov, and Kulzhamal Nogaeva. "Flotation enrichment of resistant gold ores." E3S Web of Conferences 168 (2020): 00005. http://dx.doi.org/10.1051/e3sconf/202016800005.

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Ores of the Vasilkovsky deposit include arsenopyrite, pyrite, pyrrhotite, marcasite, gold, chalcopyrite, sphalerite, galena, faded ore (tennantite)S, bismuthine, native bismuth, lellingite, molybdenite, cubanite, bornite, antimonite, relict minerals, magnetite, apatite and apatite chromite, sericite, chlorite, potassium feldspar, tourmaline), quartz, carbonates (siderite, ankerite, calcite), fluorite, barite. Arsenopyrite is the main ore mineral. It contains the bulk of gold, as well as impurities - copper, cobalt, nickel, bismuth, zirconium, titanium, lead, zinc, antimony, silver, molybdenum.

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46

Shaji, S., V. Vinayakumar, B. Krishnan, et al. "Copper antimony sulfide nanoparticles by pulsed laser ablation in liquid and their thin film for photovoltaic application." Applied Surface Science 476 (May 2019): 94–106. http://dx.doi.org/10.1016/j.apsusc.2019.01.072.

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47

Krishnan, B., S. Shaji, and R. Ernesto Ornelas. "Progress in development of copper antimony sulfide thin films as an alternative material for solar energy harvesting." Journal of Materials Science: Materials in Electronics 26, no. 7 (2015): 4770–81. http://dx.doi.org/10.1007/s10854-015-3092-2.

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48

Ramasamy, Karthik, Hunter Sims, William H. Butler, and Arunava Gupta. "ChemInform Abstract: Selective Nanocrystal Synthesis and Calculated Electronic Structure of All Four Phases of Copper-Antimony-Sulfide." ChemInform 45, no. 29 (2014): no. http://dx.doi.org/10.1002/chin.201429028.

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49

Kvyatkovskiy, S. A., S. M. Kozhakhmetov, A. S. Semenova, M. A. Dyussebekova, and A. A. Shakhalov. "Hydrothermal treatment of sinters containing thiosalts of non-ferrous metals." Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources 335, no. 4 (2024): 42–49. http://dx.doi.org/10.31643/2025/6445.38.

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Abstract:

Preliminary experiments have shown that the solution to the environmental problem of recycling copper-electrolyte smelting slags is by sulfidization followed by leaching and subsequent separation of selenium, tellurium, arsenic, and antimony from the solution. The first operation of this technology, which provides high selectivity, is sintering. The results obtained indicate the formation of metal thiosalts during sintering in the presence of sodium sulfate and carbonate and a reducing agent at a temperature of 800 0C. An increase in temperature leads to the melting of individual components of

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50

Chen, Keqiang, Jing Zhou, Wen Chen, Qiao Chen, Peng Zhou, and Yueli Liu. "A green synthesis route for the phase and size tunability of copper antimony sulfide nanocrystals with high yield." Nanoscale 8, no. 9 (2016): 5146–52. http://dx.doi.org/10.1039/c5nr09097k.

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