Academic literature on the topic 'Copper(II)-carboxylate complexes'

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Journal articles on the topic "Copper(II)-carboxylate complexes"

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N., KUMAR, L. KALSOTRA B., and RENU SACHAR (Miss). "2,4,6-Trimethylpyridine Complexes of Copper(II)carboxylates." Journal of Indian Chemical Society Vol. 62, Feb 1985 (1985): 100–102. https://doi.org/10.5281/zenodo.6302622.

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Department of Chemistry, University of Jammu, Jammu-180 001 <em>Manuscript received 5 December 1983, revised 28 May 1984, accepted 18 January 1985</em> A series of adducts of copper(II)carboxylates of general formula. [Cu(O<sub>2</sub>CR)<sub>2</sub>&nbsp;(2,4,6-Me<sub>3</sub>Py)<sub>n</sub>]&nbsp;(where R =C<sub>6</sub>H<sub>5,</sub>&nbsp;CH<sub>3</sub>C<sub>4</sub>H<sub>4&nbsp;</sub>,CIC<sub>o</sub>.H<sub>4</sub>,&nbsp;ClCH<sub>2</sub>, CI<sub>2</sub>&nbsp;CH ; and n=1 or 2) have been synthesised. Magnetic and spectral studies reveal that 1 : 1 adducts are binuclear carboxylate bridged speci
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Hankel née Reinhold, Katharina, Fabian Burzlaff, Björn B. Beele, and Fabian Mohr. "Silver(I) and Copper(I) Complexes of Dicarboxylic Acid Derivatives: Synthesis, Characterization and Thermal Studies." Inorganics 12, no. 5 (2024): 140. http://dx.doi.org/10.3390/inorganics12050140.

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A family of silver(I) and copper(I) complexes containing carboxylate ligands were prepared from the corresponding carboxylic acids and Ag2O. The compounds were characterized by various spectroscopic methods and X-ray diffraction. In the solid state, the silver(I) salts are coordination polymers based on dinuclear silver species with bridging carboxylate ligands. The reaction of these silver salts with Ph3P gives four-coordinate, tetrahedral bis(phosphine) complexes. Analogous copper(I) bis(phosphine) compounds were prepared by the reduction of copper(II) carboxylates with Ph3P. Decomposition t
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Piani, Robin, Björn B. Beele, Jörg Rust, Christian W. Lehmann, and Fabian Mohr. "Coinage Metal Complexes Containing Perfluorinated Carboxylates." Chemistry 5, no. 2 (2023): 813–33. http://dx.doi.org/10.3390/chemistry5020058.

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A variety of coinage-metal complexes containing perfluorinated carboxylate ligands, together with their structures and thermal behavior, are reported. The silver(I) salts were accessible from the direct reaction of Ag2O with the acids in toluene. Their gold(I) phosphine counterparts formed in high yields by transmetallation using the silver(I) salts. Some structurally unique, mixed-metal (Au,Ag) complexes formed upon combining solutions of the silver(I) salts with the gold(I) phosphine carboxylates. The reduction of dinuclear copper(II) compounds containing perfluorinated carboxylates with tri
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Karthikeyan, Ammasai, Packianathan Thomas Muthiah, and Franc Perdih. "Supramolecular architectures in CoIIand CuIIcomplexes with thiophene-2-carboxylate and 2-amino-4,6-dimethoxypyrimidine ligands." Acta Crystallographica Section C Structural Chemistry 72, no. 5 (2016): 442–50. http://dx.doi.org/10.1107/s2053229616006148.

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The coordination chemistry of mixed-ligand complexes continues to be an active area of research since these compounds have a wide range of applications. Many coordination polymers and metal–organic framworks are emerging as novel functional materials. Aminopyrimidine and its derivatives are flexible ligands with versatile binding and coordination modes which have been proven to be useful in the construction of organic–inorganic hybrid materials and coordination polymers. Thiophenecarboxylic acid, its derivatives and their complexes exhibit pharmacological properties. Cobalt(II) and copper(II)
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Lacko, Michal, Peter Papp, Iwona B. Szymańska, Edward Szłyk, and Štefan Matejčík. "Electron interaction with copper(II) carboxylate compounds." Beilstein Journal of Nanotechnology 9 (February 1, 2018): 384–98. http://dx.doi.org/10.3762/bjnano.9.38.

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In the present study we have performed electron collision experiments with copper carboxylate complexes: [Cu2(t-BuNH2)2(µ-O2CC2F5)4], [Cu2(s-BuNH2)2(µ-O2CC2F5)4], [Cu2(EtNH2)2(µ-O2CC2F5)4], and [Cu2(µ-O2CC2F5)4]. Mass spectrometry was used to identify the fragmentation pattern of the coordination compounds produced in crossed electron – molecular beam experiments and to measure the dependence of ion yields of positive and negative ions on the electron energy. The dissociation pattern of positive ions contains a sequential loss of both the carboxylate ligands and/or the amine ligands from the c
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Szymańska, Iwona B., Katarzyna Madajska, Aleksandra Butrymowicz, and Magdalena Barwiołek. "Copper(II) Perfluorinated Carboxylate Complexes with Small Aliphatic Amines as Universal Precursors for Nanomaterial Fabrication." Materials 14, no. 23 (2021): 7451. http://dx.doi.org/10.3390/ma14237451.

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Copper(II) carboxylate compounds with ethylamine and isopropylamine of the general formula [Cu2(RNH2)2(µ-O2CRf)4], where R = Et, iPr, and Rf = CnF2n+1, n = 1–6, were characterised in the condensed and gas phases by electron impact mass spectrometry (EI MS), IR spectroscopy, and thermal analysis. A mass spectra analysis confirmed the presence of metallated species in the gas phase. Among the observed fragments, the pseudomolecular ions [Cu2(RNH2)2(µ-O2CRf)3]+ were found, which suggests the dimeric structure of the studied complexes with axially N-coordinated ethyl- or isopropylamine molecules a
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Krasnikova, Natalia, Sergey Krasnikov, Elizaveta Bolshakova, Polina Koroleva, Anna Nametkina, and Vladimir Yasonov. "Synthesis and characteristics of four new copper(II) carboxylate complexes with adamantane fragment." From Chemistry Towards Technology Step-By-Step 5, no. 1 (2024): 145–53. http://dx.doi.org/10.52957/2782-1900-2024-5-1-145-153.

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The paper considers the results of synthesis, elemental analysis, and spectroscopic methods (IR, UV-vis) of four new copper(II) complexes with anions of 1-adamantanecarboxylic acid, 4-(1-adamantyl)benzoic acid and their L-valine derivatives as ligands. Based on the obtained spectral data, the authors assumed the biyaderic structure of these complexes with bidentate coordination of carboxylate ligands of the type [Cu2+2(RCOO-)4(H2O)2], with RCOO-as carboxylate ligands. The synthesised compounds are of interest as low toxic potential therapeutic agents with anti-inflammatory and anti-cancer acti
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Lawrance, GA, BW Skelton, AH White, and EN Wilkes. "Tetraazacycloalkanes With Pendant Carboxylates. Copper(II)-Directed Syntheses and Crystal Structure of (Ethyl 1,5,9,13-tetraazabicyclo[11.2.2]heptadecane-7-carboxylate)copper(II) Perchlorate." Australian Journal of Chemistry 44, no. 11 (1991): 1511. http://dx.doi.org/10.1071/ch9911511.

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Reaction of copper(II) complexes of the tetraamines H2N-(CH2)n-NH-(CH2)m-NH-(CH2)n-NH2 (n, m=5, 6), N,N′- bis (3-aminopropyl)-1,4-diazacyclohexane and ethane-1,2-diamine with formaldehyde and diethyl malonate in methanolic base produces macrocycles where initially new -NH-CH2-C( COOEt )2-CH2-NH-links are built by joining the cis-disposed primary amines in the precursor complexes. Under the basic conditions of the reaction, the macrocyclic product may be isolated not simply with gem ethoxycarbonyl groups, but as the carboxy ethoxycarbonyl, or even with a single carboxy pendant or its ester foll
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Ahmed Redayan, Muayed, Ziad Tariq Ibrahim, and Ghalib E. atyi. "Synthesis and Characterization of Copper (II ), Zinc (II ),Cobalt (II) and Nickel (II) complexes Derived from2-Hydroxy-1-naphthaldehyde and DL- glycyl-DL- glycin." AL-QADISIYAH MEDICAL JOURNAL 13, no. 23 (2018): 202–7. http://dx.doi.org/10.28922/qmj.2017.13.23.202-207.

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Copper (II ) , Zinc (II ) , Cobalt (II) and Nickel (II ) complexes with the Schiff base derived from 2-Hydroxy-1-naphthaldehyde and DL-glycine -DL-glycine were synthesized.These compounds have been characterized by elemental analysis , conductivity measurement, IR and UV-Vis.The molar conductance measurement indicate that the complexes are 1:1 non-electrolytes. The IR data demonstrate the tetradentate binding of the ligand .The COO- stretching bands in the IR spectra suggest that carboxylate acts as a monodentate group when binding with metal . The bonding sites are the carboxylate oxygen , im
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Sirajuddin, Muhammad, Changaiz Ahmad, Hizbuallah Khan, Imdad Ullahkhan, Muhammad Tariq, and Nazif Ullah. "Synthesis, spectroscopic characterization, biological screening and POM analysis of potentially bioactive copper(II) carboxylate complexes." Bulletin of the Chemical Society of Ethiopia 36, no. 1 (2022): 57–71. http://dx.doi.org/10.4314/bcse.v36i1.6.

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ABSTRACT. Here we are reporting the synthesis, characterization of four novel copper(II) complexes with carboxylate ligand and their evaluation for biological applications. The complexes have general formulas C22H18CuN4O12, C32H26CuN6O12, C27H23CuN5O12 and C34H26CuN6O12. The synthesized complexes were characterized by FT-IR and elemental analyses carried out through EDX. The deprotonation of the carboxylate ligand, 4-(2-methoxy-5-nitrophenylamino)-4-oxobut-2-enoic acid, was observed in FT-IR spectrum, indicating that complexation happens via the carboxylate moiety's oxygen. In complexes 1 and
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Dissertations / Theses on the topic "Copper(II)-carboxylate complexes"

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LeCloux, Daniel D. (Daniel David) 1970. "Synthesis and reactivity of copper(I) and iron(II) carboxylate-bridged dimetallic complexes." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/50411.

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Motreff-Zeisser, Artur. "Modification de surfaces de téflon et de SiO2 par adsorption de complexes de cuivre(II)- carboxylates perfluorés." Thesis, Bordeaux 1, 2010. http://www.theses.fr/2010BOR14087/document.

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Le développement de méthodologies permettant de fonctionnaliser aisément les surfaces est un domaine en plein essor. Nous avons synthétisé et caractérisé de nouveaux complexes de cuivre(II)-carboxylates hautement fluorophiles qui ont été utilisés pour modifier des surfaces. Ces complexes possèdent à l'état solide une très grande affinité pour l'eau, l'hydratation induisant un changement radical des propriétés magnétiques du solide. Ces complexes fluorophiles s'adsorbent très fortement sur le Téflon ou sur le verre pour conduire à des surfaces hydrophiles et coordinantes. En utilisant la chimie
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Ireland, David Rey. "Copper(II) and Ruthenium(II) Complexes from Polydentate Ligands." University of Dayton / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1523008522727672.

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Essex, Sarah Jane. "Spectral intensities in planar copper(II) complexes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239622.

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Zhang, Yousheng. "Polynuclear magnetic complexes of manganese(II), cobalt(II), nickel(II) and copper(II)." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape2/PQDD_0014/NQ52856.pdf.

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Quinlan, D. J. "Hydrogen bonding in N-ligated copper(II) complexes." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262983.

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Gouany, Frady. "Design and synthesis of novel chiral dirhodium(II) carboxylate complexes for asymmetric cyclopropanation reactions." Doctoral thesis, importedStudentThesis, 2015. https://researchprofiles.canberra.edu.au/en/studentTheses/5bf54ed4-a642-4cda-9e01-fe1876fd800e.

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Crowder, Janell M. "Homo- and Heterometallic Bis(Pentafluorobenzoyl)Methanide Complexes of Copper(II) and Cobalt(II)." Thesis, State University of New York at Albany, 2017. http://pqdtopen.proquest.com/#viewpdf?dispub=10680674.

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<p> &beta;-Diketones are well known to form metal complexes with practically every known metal and metalloid. Metal complexes of fluorinated &beta;-diketones generally exhibit increased volatility and thermal stability compared to the non-fluorinated analogues, and thus are used extensively in various chemical vapor deposition (CVD) processes for the deposition of metal, simple or mixed metal oxides, and fluorine-doped metal oxide thin films. Furthermore, the electron-withdrawing nature of the fluorinated ligand enhances the Lewis acidity of a coordinatively unsaturated metal center which faci
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Jamadar, Abeda. "Copper(II) and Zinc(II) complexes of aroyl hydrazones as potential antitubercular agents." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/3099/.

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There is a continuing need to make new antitubercular drugs due to development of resistance towards present drugs. To do this, series of pyruvate hydrazones (PVAHs) and their respective Cu(II) complexes and Zn(II) complexes were synthesized and fully characterised. Variable temperature NMR studies of PVAHs indicate the presence of E and Z isomers in the solution. Determination of the obtained single crystal X-ray structures reveals that Cu(II) ion binds to PVAH ligand in 1:1 ratio resulting in square pyramidal geometry in most of the Cu(II) complexes, whereas Zn(II) ion binds to two PVAH liga
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Doddridge, Bruce Germein. "Ligand exchange and substitution on five-coordinate complexes of copper (II), nickel (II) and cobalt (II) /." Title page, contents and summary only, 1986. http://web4.library.adelaide.edu.au/theses/09PH/09phd641.pdf.

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Books on the topic "Copper(II)-carboxylate complexes"

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Lindgren, Teppo. Dimeric copper(II) complexes with some 3-amino-1-propanols. Turun yliopisto, 1987.

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Jezierska, Julia. Badanie metodą elektronowego rezonansu paramagnetycznego struktury kompleksów miedzi (II) ze szczególnym uwzględnieniem procesów polimeryzacji i ligandów polimerycznych. Wydawn. Uniwersytetu Wrocławskiego, 1993.

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McLean, Colin Henry. Copper (II) complexes of imidazole - containing ligands. 1986.

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Davis, William Michael. 1. Synthesis, structure and properties of an imidazolate bridged CU(II)-Co(III) complex ; 2. Synthesis, structures and properties of nickel (II) and copper (II) tropocoronand complexes. 1985.

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Book chapters on the topic "Copper(II)-carboxylate complexes"

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Doedens, Robert J. "Structure and Metal-Metal Interactions in Copper(II) Carboxylate Complexes." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166222.ch9.

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Albers, Michel O., Eric Singleton, Janet E. Yates, and Fred B. Mccormick. "Dinuclear Ruthenium(II) Carboxylate Complexes." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132579.ch44.

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Reed, Gregory A., and Cherukury Madhu. "Peroxide Scavenging by Cu(II) Sulfate and Cu(II) (3,5-Diisopropylsalicylate)2." In Biology of Copper Complexes. Humana Press, 1987. http://dx.doi.org/10.1007/978-1-4612-4584-1_22.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mononuclear copper(II) carboxylate complex." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_355.

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Salari, Hamid, Max L. Baker, John B. Barnett, Lee S. F. Soderberg, William M. Willingham, and John R. J. Sorenson. "Radioprotectant Effects of Cu(II)(3,5-DIPS)2." In Biology of Copper Complexes. Humana Press, 1987. http://dx.doi.org/10.1007/978-1-4612-4584-1_33.

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Willingham, William M., and John R. J. Sorenson. "pH-Dependent Superoxide Dismutase-Mimetic Reactivity of Copper(II)Ethylenediaminetetraacetate." In Biology of Copper Complexes. Humana Press, 1987. http://dx.doi.org/10.1007/978-1-4612-4584-1_35.

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Kwik, W. L., K. P. Ang, M. Winkler, D. Spira, and E. I. Solomon. "26. Ternary Complexes of Copper(II)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132524.ch26.

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Basolo, F. "Manganese(II) and Copper(I) Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch188.

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Kasemeier, Scott L., Hamid Salari, and John R. J. Sorenson. "Anticancer Effects of Cu(II)(3,5-Diisopropylsalicylate)2in Mice Inoculated Intramuscularly with Ehrlich Ascites Carcinoma Cells." In Biology of Copper Complexes. Humana Press, 1987. http://dx.doi.org/10.1007/978-1-4612-4584-1_27.

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Torregrosa, Doris, Scott L. Kasemeier, John R. J. Sorenson, and Louis W. Chang. "Effects of Cu(II)(3,5-DIPS)2 on Solid Ehrlich Cell Tumor in Mice: A Pathological Study." In Biology of Copper Complexes. Humana Press, 1987. http://dx.doi.org/10.1007/978-1-4612-4584-1_28.

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Conference papers on the topic "Copper(II)-carboxylate complexes"

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Schock, Michael R., Darren A. Lytle, and Jonathan A. Clement. "Effects of pH, Carbonate, Orthophosphate, and Redox Potential on Cuprosolvency." In CORROSION 1995. NACE International, 1995. https://doi.org/10.5006/c1995-95610.

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Abstract A comprehensive solubility model for copper in drinking water has been developed, that is consistent with available data for copper dissolution and passivation in drinking water systems. Copper solubility (cuprosolvency) is greatly affected by the redox conditions of the systems. The concentration of Cu(I) is dominated by Cu2O(s) or CuOH(s) solid phases, plus soluble aqueous ammonia and chloride complexes. In new piping, the concentration of Cu(II) is mainly governed by Cu(OH)2(s) (cupric hydroxide), rather than CuO(s) (tenorite) or Cu2(OH)2CO3(s)(malachite). Complexation of Cu(II) by
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Tanasković, Slađana, Branka Dražić, and Mirjana Antonijević Nikolić. "Biological activity of new mixed ligand copper(II) complexes." In RAD Conference. RAD Centre, 2022. http://dx.doi.org/10.21175/rad.spr.abstr.book.2022.24.2.

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Joshi, S. K., R. K. Katare, and B. D. Shrivastava. "EXAFS Studies of Some Copper(II) Mixed-Ligand Complexes." In X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP, 2007. http://dx.doi.org/10.1063/1.2644675.

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Berkesi, O., I. Dreveni, J. A. Andor, U. A. Jayasooriya, R. D. Cannon, and J. Mink. "Fourier transform infrared and FT-Raman studies on tetranuclear oxo-centered carboxylate complexes of zinc (II)." In Fourier Transform Spectroscopy: Ninth International Conference, edited by John E. Bertie and Hal Wieser. SPIE, 1994. http://dx.doi.org/10.1117/12.166781.

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Darwish, Abdalla M., Robert R. Copeland, R. Sliz, et al. "Highly polarizable metallic complexes for nonlinear optics copper(II) and nickel(II) complexes of bis(salicylaldiminato) Schiff base." In SPIE's 1996 International Symposium on Optical Science, Engineering, and Instrumentation. SPIE, 1996. http://dx.doi.org/10.1117/12.256169.

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Soldatovic, Tanja, and Enisa Selimovic. "Interaction of Zinc(II) and Copper(II) Terpyridine Complexes with Biomolecules." In 2nd International Electronic Conference on Medicinal Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecmc-2-a001.

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Stevanović, Nevena Lj, Mia Stanković, Tina P. Andrejević, Darko P. Ašanin, Ivana M. Stanojević, and Biljana Đ. Glišić. "DNA AND BSA INTERACTIONS OF COPPER(II) AND ZINC(II) COMPLEXES WITH ANTIFUNGAL AGENT FLUCONAZOLE." In 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.399s.

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Aromatic nitrogen-containing heterocycles (N-heterocycles) have attracted a considerable attention as scaffolds for compounds, which have an application in different pharmacological areas, ranging from vitamins to different antimicrobial and antitumor agents. In this respect, azoles are of special importance as potent and broad-spectrum agents used for the treatment of many invasive fungal infections. In the present study, the interaction of the clinically used antifungal drug fluconazole (fcz) and its copper(II) and zinc(II) complexes, {[CuCl2(fcz)2].5H2O}n (1) and {[ZnCl2(fcz)2]·2C2H5OH}n (2
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Pirjol, Ticuta Negreanu. "POTENTIAL ANTIMICROBIAL AGENTS BASED ON CHLORHEXIDINE COMPLEXES WITH ZINC AND COPPER(II)." In 13th SGEM GeoConference on ECOLOGY, ECONOMICS, EDUCATION AND LEGISLATION. Stef92 Technology, 2013. http://dx.doi.org/10.5593/sgem2013/be5.v1/s20.101.

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Mishra, A., P. Sharma, and P. K. Malviya. "Extended X-ray absorption studies of copper (II) dibenzoyal methane diquinoline complexes." In PROCEEDING OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN APPLIED PHYSICS AND MATERIAL SCIENCE: RAM 2013. AIP, 2013. http://dx.doi.org/10.1063/1.4810720.

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Turomsha, Iveta S., Maxim Y. Gvozdev, Natalia V. Loginova, Galina A. Ksendzova, and Nikolai P. Osipovich. "Synthesis, Characterization and Biological Activity of Hydrazones and Their Copper(II) Complexes." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13576.

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Reports on the topic "Copper(II)-carboxylate complexes"

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Leeladee, Pannee. Cooperative small-molecule activation toward sustainable catalysis. Faculty of Science, Chulalongkorn University, 2018. https://doi.org/10.58837/chula.res.2018.47.

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In this research, a series of copper complexes containing polypyridyl ligands were designed to study the influence from ligands, nuclearity, solvents and secondary coordination on reactivity toward small-molecule activation. This structure-reactivity relationship was used in investigation for oxygen reduction reactions (ORR), and applied in detection of ascorbic acid (AsH₂). Firstly, copper (II) complexes containing polypyridyl derivatives ligands (i.e., Cu(dpa), Cu(adpa) and Cu₂ (addpa)) were synthesized and fully characterized by elemental analysis, mass spectrometry and X-ray crystallograph
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