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Journal articles on the topic 'Copper indium sulfide'

Author: Grafiati
Published: 4 June 2021
Last updated: 9 March 2023

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1

Vadivel, S., K. Srinivasan, and K. R. Murali. "Pulse electrodeposited copper indium sulfide films." Materials Science in Semiconductor Processing 16, no. 3 (June 2013): 765–70. http://dx.doi.org/10.1016/j.mssp.2012.12.024.

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2

Liu, Wenyan, Yu Zhang, Jia Zhao, Yi Feng, Dan Wang, Tieqiang Zhang, Wenzhu Gao, et al. "Photoluminescence of indium-rich copper indium sulfide quantum dots." Journal of Luminescence 162 (June 2015): 191–96. http://dx.doi.org/10.1016/j.jlumin.2015.02.029.

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3

Han, Wei, Luoxin Yi, Nan Zhao, Aiwei Tang, Mingyuan Gao, and Zhiyong Tang. "Synthesis and Shape-Tailoring of Copper Sulfide/Indium Sulfide-Based Nanocrystals." Journal of the American Chemical Society 130, no. 39 (October 2008): 13152–61. http://dx.doi.org/10.1021/ja8046393.

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4

Tablero, C. "Ionization Levels of Doped Copper Indium Sulfide Chalcopyrites." Journal of Physical Chemistry A 116, no. 5 (January 30, 2012): 1390–95. http://dx.doi.org/10.1021/jp209594u.

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5

Morselli, Giacomo, Marco Villa, Andrea Fermi, Kevin Critchley, and Paola Ceroni. "Luminescent copper indium sulfide (CIS) quantum dots for bioimaging applications." Nanoscale Horizons 6, no. 9 (2021): 676–95. http://dx.doi.org/10.1039/d1nh00260k.

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6

Buchmaier, Christine, Thomas Rath, Franz Pirolt, Astrid-Caroline Knall, Petra Kaschnitz, Otto Glatter, Karin Wewerka, et al. "Room temperature synthesis of CuInS2 nanocrystals." RSC Advances 6, no. 108 (2016): 106120–29. http://dx.doi.org/10.1039/c6ra22813e.

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7

Deng, Zheng Bin, Xian Xie, Xiong Tong, Yong Cheng Zhou, Xiao Wang, and Xiang Wen Lv. "Flotation of Indium-Beard Marmatite in the Low Alkali Conditions." Applied Mechanics and Materials 316-317 (April 2013): 846–49. http://dx.doi.org/10.4028/www.scientific.net/amm.316-317.846.

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Flotation of indium-beard marmatite from Mengzi multi-metal sulfide ore in the low alkali conditions was studied. It shows that the mixed reagent X-41 (Main chemical components: Cu≧12%, S≧18%, O≧48%, H≧4.5%) as a new activator in the flotation at pH 9.5 produced a much better beneficiation than the copper sulfate at pH 13. The grade of zinc and indium was increased by 3.39% and 53.52g/t respectively, while the recovers were increased by 4.57% and 3.54%.
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8

Jiao, Mingxia, Xiaodan Huang, Linzheng Ma, Yun Li, Peisen Zhang, Xiaojun Wei, Lihong Jing, Xiliang Luo, Andrey L. Rogach, and Mingyuan Gao. "Biocompatible off-stoichiometric copper indium sulfide quantum dots with tunable near-infrared emission via aqueous based synthesis." Chemical Communications 55, no. 100 (2019): 15053–56. http://dx.doi.org/10.1039/c9cc07674c.

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9

Morselli, Giacomo, Alessandro Gradone, Vittorio Morandi, and Paola Ceroni. "Light-harvesting antennae based on copper indium sulfide (CIS) quantum dots." Nanoscale 14, no. 8 (2022): 3013–19. http://dx.doi.org/10.1039/d2nr00558a.

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10

Han, Shikui, Mingguang Kong, Ying Guo, and Mingtai Wang. "Synthesis of copper indium sulfide nanoparticles by solvothermal method." Materials Letters 63, no. 13-14 (May 2009): 1192–94. http://dx.doi.org/10.1016/j.matlet.2009.02.032.

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11

Vakalopoulou, Efthymia, Thomas Rath, Fernando Gustavo Warchomicka, Francesco Carraro, Paolo Falcaro, Heinz Amenitsch, and Gregor Trimmel. "Honeycomb-structured copper indium sulfide thin films obtained via a nanosphere colloidal lithography method." Materials Advances 3, no. 6 (2022): 2884–95. http://dx.doi.org/10.1039/d2ma00004k.

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Honeycomb structured copper indium sulfide layers are successfully realized via a nanosphere lithography route employing polystyrene nanosphere array templates and metal xanthates or a nanocrystal ink.
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12

Choi, Hyung Seok, Youngsun Kim, Jae Chul Park, Mi Hwa Oh, Duk Young Jeon, and Yoon Sung Nam. "Highly luminescent, off-stoichiometric CuxInyS2/ZnS quantum dots for near-infrared fluorescence bio-imaging." RSC Advances 5, no. 54 (2015): 43449–55. http://dx.doi.org/10.1039/c5ra06912b.

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13

Witt, Elena, Jürgen Parisi, and Joanna Kolny-Olesiak. "Selective Growth of Gold onto Copper Indium Sulfide Selenide Nanoparticles." Zeitschrift für Naturforschung A 68, no. 5 (May 1, 2013): 398–404. http://dx.doi.org/10.5560/zna.2013-0016.

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Hybrid nanostructures are interesting materials for numerous applications in chemistry, physics, and biology, due to their novel properties and multiple functionalities. Here, we present a synthesis of metal-semiconductor hybrid nanostructures composed of nontoxic I-III-VI semiconductor nanoparticles and gold. Copper indium sulfide selenide (CuInSSe) nanocrystals with zinc blende structure and trigonal pyramidal shape, capped with dodecanethiol, serve as an original semiconductor part of a new hybrid nanostructure. Metallic gold nanocrystals selectively grow onto vertexes of these CuInSSe pyramids. The hybrid nanostructures were studied by transmission electron microscopy, energy dispersive X-ray analysis, X-ray diffraction, and UV-Vis-absorption spectroscopy, which allowed us conclusions about their growth mechanism. Hybrid nanocrystals are generated by replacement of a sacrificial domain in the CuInSSe part. At the same time, small selenium nanocrystals form that stay attached to the remaining CuInSSe/Au particles. Additionally, we compare the synthesis and properties of CuInSSe-based hybrid nanostructures with those of copper indium disulfide (CuInS2). CuInS2/Au nanostructures grow by a different mechanism (surface growth) and do not show any selectivity.
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14

Macdonald, Thomas J., Yatin J. Mange, Melissa Dewi, Aoife McFadden, William M. Skinner, and Thomas Nann. "Cation exchange of aqueous CuInS2 quantum dots." CrystEngComm 16, no. 40 (2014): 9455–60. http://dx.doi.org/10.1039/c4ce00545g.

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Chalcopyrite copper indium disulfide (CIS) QDs have been of recent interest due to their non-toxicity. This article shows a straightforward aqueous cation exchange method to synthesise CIS particles with zinc sulfide coating.
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15

AMANO, Fumiaki, Toshihiro EBINA, and Bunsho OHTANI. "Photoelectrochemical Hydrogen Evolution Using Copper-Indium-Sulfide Nanocrystalline Film Electrodes." Electrochemistry 79, no. 10 (2011): 804–6. http://dx.doi.org/10.5796/electrochemistry.79.804.

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16

Ho, John C. W., Sudip K. Batabyal, Stevin S. Pramana, Jiayi Lum, Viet T. Pham, Dehui Li, Qihua Xiong, Alfred I. Y. Tok, and Lydia H. Wong. "Optical and Electrical Properties of Wurtzite Copper Indium Sulfide Nanoflakes." Materials Express 2, no. 4 (December 1, 2012): 344–50. http://dx.doi.org/10.1166/mex.2012.1091.

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17

Libo, Li, Li Qi, Wang Heng, Yang Xiuchun, Tian Haiyan, Xie Jingchen, and Wang Wentao. "Preparation of Copper Indium Sulfide Film by Electro-Deposition Method." Rare Metal Materials and Engineering 44, no. 6 (June 2015): 1374–78. http://dx.doi.org/10.1016/s1875-5372(15)30092-8.

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18

Wen, Cai, Xiang Weidong, Wang Juanjuan, Wang Xiaoming, Zhong Jiasong, and Liu Lijun. "Biomolecule-assisted synthesis of copper indium sulfide microspheres with nanosheets." Materials Letters 63, no. 28 (November 2009): 2495–98. http://dx.doi.org/10.1016/j.matlet.2009.08.050.

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19

Rath, Thomas, Verena Kaltenhauser, Wernfried Haas, Angelika Reichmann, Ferdinand Hofer, and Gregor Trimmel. "Solution-processed small molecule/copper indium sulfide hybrid solar cells." Solar Energy Materials and Solar Cells 114 (July 2013): 38–42. http://dx.doi.org/10.1016/j.solmat.2013.02.024.

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20

Lim, Hui Min, Jia Yi Tan, Sudip K. Batabyal, Shlomo Magdassi, Subodh G. Mhaisalkar, and Lydia H. Wong. "Photoactive Nanocrystals by Low-Temperature Welding of Copper Sulfide Nanoparticles and Indium Sulfide Nanosheets." ChemSusChem 7, no. 12 (August 21, 2014): 3290–94. http://dx.doi.org/10.1002/cssc.201402333.

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21

Perner, Verena, Thomas Rath, Franz Pirolt, Otto Glatter, Karin Wewerka, Ilse Letofsky-Papst, Peter Zach, Mathias Hobisch, Birgit Kunert, and Gregor Trimmel. "Hot injection synthesis of CuInS2 nanocrystals using metal xanthates and their application in hybrid solar cells." New Journal of Chemistry 43, no. 1 (2019): 356–63. http://dx.doi.org/10.1039/c8nj04823a.

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Copper indium sulfide nanocrystals with sizes of 3–4 nm were synthesized from metal xanthates in a hot injection reaction. After ligand exchange, their performance as acceptors in polymer/nanocrystal hybrid solar cells was evaluated.
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22

Raevskaya, Alexandra, Oksana Rosovik, Andriy Kozytskiy, Oleksandr Stroyuk, Volodymyr Dzhagan, and Dietrich R. T. Zahn. "Non-stoichiometric Cu–In–S@ZnS nanoparticles produced in aqueous solutions as light harvesters for liquid-junction photoelectrochemical solar cells." RSC Advances 6, no. 102 (2016): 100145–57. http://dx.doi.org/10.1039/c6ra18313a.

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A direct “green” aqueous synthesis of mercapto acetate-stabilized copper indium sulfide (CIS) nanoparticles (NPs) and core/shell CIS@ZnS NPs of a varied composition under ambient conditions and a temperature lower than 100 °C is reported.
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23

Vermang, Bart, Aniket Mule, Nikhil Gampa, Sylvester Sahayaraj, Samaneh Ranjbar, Guy Brammertz, Marc Meuris, and Jef Poortmans. "Progress in Cleaning and Wet Processing for Kesterite Thin Film Solar Cells." Solid State Phenomena 255 (September 2016): 348–53. http://dx.doi.org/10.4028/www.scientific.net/ssp.255.348.

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Copper indium gallium selenide/sulfide (CIGS) and copper zinc tin selenide/sulfide (CZTS) are two thin film photovoltaic materials with many similar properties. Therefore, three new processing steps – which are well-known to be beneficial for CIGS solar cell processing – are developed, optimized and implemented in CZTS solar cells. For all these novel processing steps an increase in minority carrier lifetime and cell conversion efficiency is measured, as compared to standard CZTS processing. The scientific explanation of these effects is very similar to its CIGS equivalent: the incorporation of alkali metals, ammonium sulfide surface cleaning, and Al2O3 surface passivation leads to electrical enhancement of the CZTS bulk, front surface and reduced front interface recombination, respectively.
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24

Lian, Zong-Juan, Tian-Yang Lin, Cai-Xia Yao, Yi-Long Su, Sheng-Hua Liao, and Sheng-Mei Wu. "Staphylococcus aureus strains exposed to copper indium sulfide quantum dots exhibit increased tolerance to penicillin G, tetracycline and ciprofloxacin." New Journal of Chemistry 44, no. 16 (2020): 6533–42. http://dx.doi.org/10.1039/c9nj05748j.

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Copper indium sulfide, CuInS2 (CIS), semiconductor nanocrystals have the qualities of low toxicity, high absorption coefficient and near-infrared luminescence, and thus have attracted increasing attention due to their wide prospective applications in various fields.
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25

Ghorpade, Uma V., Mahesh P. Suryawanshi, Seung Wook Shin, Chang Woo Hong, Inyoung Kim, Jong H. Moon, Jae Ho Yun, Jin Hyeok Kim, and Sanjay S. Kolekar. "Wurtzite CZTS nanocrystals and phase evolution to kesterite thin film for solar energy harvesting." Physical Chemistry Chemical Physics 17, no. 30 (2015): 19777–88. http://dx.doi.org/10.1039/c5cp02007g.

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A quaternary indium- and gallium-free kesterite (KS)-based compound, copper zinc tin sulfide (Cu2ZnSnS4, CZTS), has received significant attention for its potential applications in low cost and sustainable solar cells.
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26

Le Tulzo, Harold, Nathanaelle Schneider, and Frédérique Donsanti. "In Situ Microgravimetric Study of Ion Exchanges in the Ternary Cu-In-S System Prepared by Atomic Layer Deposition." Materials 13, no. 3 (February 1, 2020): 645. http://dx.doi.org/10.3390/ma13030645.

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Reaction mechanisms during the growth of multinary compounds by atomic layer deposition can be complex, especially for sulfide materials. For instance, the deposition of copper indium disulfide (CuInS2) shows a non-direct correlation between the cycle ratio, the growth per cycle of each binary growth cycles, i.e., CuxS and In2S3, and the film composition. This evidences side reactions that compete with the direct Atomic Layer Deposition (ALD) growth reactions and makes the deposition of large films very challenging. To develop a robust upscalable recipe, it is essential to understand the chemical surface reactions. In this study, reaction mechanisms in the Cu-In-S ternary system were investigated in-situ by using a quartz crystal microbalance system to monitor mass variations. Pure binary indium sulfide (In2S3) and copper sulfide (CuxS) thin film depositions on Al2O3 substrate were first studied. Then, precursors were transported to react on CuxS and In2S3 substrates. In this paper, gas-phase ion exchanges are discussed based on the recorded mass variations. A cation exchange between the copper precursor and the In2S3 is highlighted, and a solution to reduce it by controlling the thickness deposited for each stack of binary materials during the CuInS2 deposition is finally proposed.
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27

Harvie, Andrew J., Matthew Booth, Ruth L. Chantry, Nicole Hondow, Demie M. Kepaptsoglou, Quentin M. Ramasse, Stephen D. Evans, and Kevin Critchley. "Observation of compositional domains within individual copper indium sulfide quantum dots." Nanoscale 8, no. 36 (2016): 16157–61. http://dx.doi.org/10.1039/c6nr03269a.

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28

Lisensky, George, Ross McFarland-Porter, Weltha Paquin, and Kangying Liu. "Synthesis and Analysis of Zinc Copper Indium Sulfide Quantum Dot Nanoparticles." Journal of Chemical Education 97, no. 3 (January 22, 2020): 806–12. http://dx.doi.org/10.1021/acs.jchemed.9b00642.

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29

Park, Jae Chul, and Yoon Sung Nam. "Controlling surface defects of non-stoichiometric copper-indium-sulfide quantum dots." Journal of Colloid and Interface Science 460 (December 2015): 173–80. http://dx.doi.org/10.1016/j.jcis.2015.08.037.

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30

Rath, Thomas, Michael Edler, Wernfried Haas, Achim Fischereder, Stefan Moscher, Alexander Schenk, Roman Trattnig, et al. "A Direct Route Towards Polymer/Copper Indium Sulfide Nanocomposite Solar Cells." Advanced Energy Materials 1, no. 6 (October 6, 2011): 1046–50. http://dx.doi.org/10.1002/aenm.201100442.

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31

Sukhomlinov, Dmitry, Lassi Klemettinen, Hugh O’Brien, Pekka Taskinen, and Ari Jokilaakso. "Behavior of Ga, In, Sn, and Te in Copper Matte Smelting." Metallurgical and Materials Transactions B 50, no. 6 (September 23, 2019): 2723–32. http://dx.doi.org/10.1007/s11663-019-01693-y.

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Abstract The distributions of Ga, In, Sn, and Te between copper-iron mattes and silica-saturated iron silicate slags over a wide range of matte grades 55 to 75 pct Cu were determined at 1300 °C using a gas-phase equilibration-quenching technique and direct phase composition analysis by Electron Probe X-ray Microanalysis and Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry. Alumina from aluminum, a typical minor element of electric and electronic copper scrap, and lime were adopted as slag modifiers for increasing the trace element recoveries. Gallium and tin were distributed predominantly in the slag, indium preferred sulfide matte at low matte grades and slag at high, whereas tellurium strongly favored the sulfide matte in particular in high matte grades. The slag modifiers alumina and lime had a minor impact on the distribution coefficients of gallium and tin, but for indium and tellurium the distribution coefficients were more strongly affected by the basic oxides. The strong tendencies of tin and tellurium to vaporize at the experimental temperature were confirmed.
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32

Zheng, Yaxin, Bahareh Sadeghimakki, Navid M. S. Jahed, and Siva Sivoththaman. "Scalable Non-injection Synthesis of Cd-Free Copper Indium Sulfide/Zinc Sulfide Quantum Dots for Third-Gen Photovoltaic Application." MRS Advances 1, no. 30 (2016): 2193–98. http://dx.doi.org/10.1557/adv.2016.536.

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ABSTRACTCopper Indium Sulfide (CIS)-based quantum dots (QDs) are considered as a safer alternative compared to carcinogenic cadmium- and lead-based QDs. Here, we present a facile, high throughput, and non-injection method of synthesizing CIS-based QDs. The structure, shape, size, and crystalline structure of the synthesized QDs were studied using high resolution transmission electron microscopy (HRTEM). The effects of temperature and compositional dependency on the structure and optical properties of the resulting QDs were investigated using elemental, absorption, photoluminescence (PL), and time-resolved spectroscopic analyses. We observed that a gradient increase of temperature during the core growth, as well as addition of excess indium (In) and zinc (Zn) precursors during core and core/shell synthesis, at low growth temperatures, resulted in QDs with improved PL and lifetime. The large Stokes shift, broad emission spectra, and long-lived emission of the synthesized QDs reveal their potential applicability to third generation photovoltaic and optoelectronic devices.
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33

Mitzi, David B., Oki Gunawan, Teodor K. Todorov, and D. Aaron R. Barkhouse. "Prospects and performance limitations for Cu–Zn–Sn–S–Se photovoltaic technology." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 371, no. 1996 (August 13, 2013): 20110432. http://dx.doi.org/10.1098/rsta.2011.0432.

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While cadmium telluride and copper–indium–gallium–sulfide–selenide (CIGSSe) solar cells have either already surpassed (for CdTe) or reached (for CIGSSe) the 1 GW yr −1 production level, highlighting the promise of these rapidly growing thin-film technologies, reliance on the heavy metal cadmium and scarce elements indium and tellurium has prompted concern about scalability towards the terawatt level. Despite recent advances in structurally related copper–zinc–tin–sulfide–selenide (CZTSSe) absorbers, in which indium from CIGSSe is replaced with more plentiful and lower cost zinc and tin, there is still a sizeable performance gap between the kesterite CZTSSe and the more mature CdTe and CIGSSe technologies. This review will discuss recent progress in the CZTSSe field, especially focusing on a direct comparison with analogous higher performing CIGSSe to probe the performance bottlenecks in Earth-abundant kesterite devices. Key limitations in the current generation of CZTSSe devices include a shortfall in open circuit voltage relative to the absorber band gap and secondarily a high series resistance, which contributes to a lower device fill factor. Understanding and addressing these performance issues should yield closer performance parity between CZTSSe and CdTe/CIGSSe absorbers and hopefully facilitate a successful launch of commercialization for the kesterite-based technology.
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34

Ning, Jiajia, Stephen V. Kershaw, and Andrey L. Rogach. "Shape-Controlled Synthesis of Copper Indium Sulfide Nanostructures: Flowers, Platelets and Spheres." Nanomaterials 9, no. 12 (December 14, 2019): 1779. http://dx.doi.org/10.3390/nano9121779.

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Colloidal semiconductor nanostructures have been widely investigated for several applications, which rely not only on their size but also on shape control. CuInS2 (often abbreviated as CIS) nanostructures have been considered as candidates for solar energy conversion. In this work, three-dimensional (3D) colloidal CIS nanoflowers and nanospheres and two-dimensional (2D) nanoplatelets were selectively synthesized by changing the amount of a sulfur precursor (tert-dodecanethiol) serving both as a sulfur source and as a co-ligand. Monodisperse CIS nanoflowers (~15 nm) were formed via the aggregation of smaller CIS nanoparticles when the amount of tert-dodecanethiol used in reaction was low enough, which changed towards the formation of larger (70 nm) CIS nanospheres when it significantly increased. Both of these structures crystallized in a chalcopyrite CIS phase. Using an intermediate amount of tert-dodecanethiol, 2D nanoplatelets were obtained, 90 nm in length, 25 nm in width and the thickness of a few nanometers along the a-axis of the wurtzite CIS phase. Based on a series of experiments which employed mixtures of tert-dodecanethiol and 1-dodecanethiol, a ligand-controlled mechanism is proposed to explain the manifold range of the resulting shapes and crystal phases of CIS nanostructures.
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35

Berends, Anne C., Johannes D. Meeldijk, Marijn A. van Huis, and Celso de Mello Donega. "Formation of Colloidal Copper Indium Sulfide Nanosheets by Two-Dimensional Self-Organization." Chemistry of Materials 29, no. 24 (December 14, 2017): 10551–60. http://dx.doi.org/10.1021/acs.chemmater.7b04925.

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36

So, David, and Gerasimos Konstantatos. "Thiol-Free Synthesized Copper Indium Sulfide Nanocrystals as Optoelectronic Quantum Dot Solids." Chemistry of Materials 27, no. 24 (December 11, 2015): 8424–32. http://dx.doi.org/10.1021/acs.chemmater.5b03943.

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37

Zhang, Aiyu, Qian Ma, Mengkai Lu, Guangwei Yu, Yuanyuan Zhou, and Zifeng Qiu. "Copper−Indium Sulfide Hollow Nanospheres Synthesized by a Facile Solution-Chemical Method." Crystal Growth & Design 8, no. 7 (July 2008): 2402–5. http://dx.doi.org/10.1021/cg701257x.

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38

Titus, Jochen, Robert W. Birkmire, Christina Hack, Georg Müller, and Patrick McKeown. "Sulfur incorporation into copper indium diselenide single crystals through annealing in hydrogen sulfide." Journal of Applied Physics 99, no. 4 (February 15, 2006): 043502. http://dx.doi.org/10.1063/1.2162271.

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39

Krylova, Galyna, Halyna Yashan, John G. Hauck, Peter C. Burns, Paul J. McGinn, and Chongzheng Na. "Microwave-Assisted Solution–Liquid–Solid Synthesis of Single-Crystal Copper Indium Sulfide Nanowires." Crystal Growth & Design 15, no. 6 (May 8, 2015): 2859–66. http://dx.doi.org/10.1021/acs.cgd.5b00284.

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40

Nomura, Ryoki, Kouichi Kanaya, and Haruo Matsuda. "Preparation of Copper-Indium-Sulfide Thin Films by Solution Pyrolysis of Organometallic Sources." Chemistry Letters 17, no. 11 (November 5, 1988): 1849–50. http://dx.doi.org/10.1246/cl.1988.1849.

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41

Hollingsworth, Jennifer A., Aloysius F. Hepp, and William E. Buhro. "Spray CVD of Copper Indium Sulfide Films: Control of Microstructure and Crystallographic Orientation." Chemical Vapor Deposition 5, no. 3 (June 1999): 105–8. http://dx.doi.org/10.1002/(sici)1521-3862(199906)5:3<105::aid-cvde105>3.0.co;2-g.

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42

Higashimoto, Shinya, Tsubasa Okada, Taisuke Arase, Masashi Azuma, Mari Yamamoto, and Masanari Takahashi. "High performance of TiO2 based solar cells sensitized with copper-indium sulfide colloids prepared in water: Roles of surface modifications with indium sulfide and zinc sulfide by SILAR methods." Electrochimica Acta 222 (December 2016): 867–74. http://dx.doi.org/10.1016/j.electacta.2016.11.051.

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43

Babu, P. J. S., T. S. Padmanabhan, M. I. Ahamed, and A. Sivaranjani. "Studies on copper indium selenide/Zinc sulphide semiconductor quantum dots for solar cell applications." Chalcogenide Letters 18, no. 11 (November 2021): 701–15. http://dx.doi.org/10.15251/cl.2021.1811.701.

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Despite dedicated efforts to develop efficient quantum dot sensitized (QDS) photovoltaic cells, the efficiency of these cells still lags behind their theoretical value. In order to increase photo conversion efficiency, the extant methods are predominantly focus on modifying the band gaps of quantum dots and optimizing the interfaces of cell components to increase light utilization capacity. In this study, we have designed and investigated QDS solar cells using Copper Indium Selenide (CuInSe2 or simply CIS) as a quantum dot absorber. In order to achieve tunable bandgap, increased photoluminescence, reduced density of surface defect state and higher light-harvesting efficiency, the CuInSe2 is alloying with Zinc sulfide (ZnS) to design Copper Indium Selenide-Zinc sulfide (CISZS) quantum dots. The resulting CISZS sensitizer exhibits improved photoelectric characteristics and greater chemical stability. The performance of the CIS and CISZS solar cells is evaluated individually through Silvaco-Atlas simulation software in terms of measures such as power conversion efficiency, open-circuit voltage (Voc), the density of short-circuit current (Jsc) and fill-factor (FF). The CISZS-based solar cells show an average conversion efficiency of 23.5% (i.e., 4.94% higher than the efficiency of CIS solar cell) with Voc = 0.596V, Jsc = 23.61mA/cm2 and FF = 0.84 under AM 1.5G with a power density of 100mW/cm2 . The achieved power conversion efficiency indicates the greatest performances of the QDS solar cells. These non-toxic photovoltaic devices reveal better optical and electrical properties than toxic lead and cadmium chalcogenide quantum dots absorbers.
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44

Huang, Yun, Xueying Zhan, Kai Xu, Lei Yin, Zhongzhou Cheng, Chao Jiang, Zhenxing Wang, and Jun He. "Highly sensitive photodetectors based on hybrid 2D-0D SnS2-copper indium sulfide quantum dots." Applied Physics Letters 108, no. 1 (January 4, 2016): 013101. http://dx.doi.org/10.1063/1.4939442.

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45

Vasekar, Parag S., Anant H. Jahagirdar, and Neelkanth G. Dhere. "Photovoltaic characterization of Copper–Indium–Gallium Sulfide (CIGS2) solar cells for lower absorber thicknesses." Thin Solid Films 518, no. 7 (January 2010): 1788–90. http://dx.doi.org/10.1016/j.tsf.2009.09.033.

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46

Kays, Joshua C., Alexander M. Saeboe, Reyhaneh Toufanian, Danielle E. Kurant, and Allison M. Dennis. "Shell-Free Copper Indium Sulfide Quantum Dots Induce Toxicity in Vitro and in Vivo." Nano Letters 20, no. 3 (January 30, 2020): 1980–91. http://dx.doi.org/10.1021/acs.nanolett.9b05259.

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47

Aydin, Erkan, Mehmet Sankir, and Nurdan Demirci Sankir. "Conventional and rapid thermal annealing of spray pyrolyzed copper indium gallium sulfide thin films." Journal of Alloys and Compounds 615 (December 2014): 461–68. http://dx.doi.org/10.1016/j.jallcom.2014.06.140.

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48

Guijarro, Néstor, Elena Guillén, Teresa Lana-Villarreal, and Roberto Gómez. "Quantum dot-sensitized solar cells based on directly adsorbed zinc copper indium sulfide colloids." Phys. Chem. Chem. Phys. 16, no. 19 (March 26, 2014): 9115–22. http://dx.doi.org/10.1039/c4cp00294f.

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49

Sakamoto, Masanori, Lihui Chen, Makoto Okano, David M. Tex, Yoshihiko Kanemitsu, and Toshiharu Teranishi. "Photoinduced Carrier Dynamics of Nearly Stoichiometric Oleylamine-Protected Copper Indium Sulfide Nanoparticles and Nanodisks." Journal of Physical Chemistry C 119, no. 20 (January 30, 2015): 11100–11105. http://dx.doi.org/10.1021/jp511864p.

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50

Lim, Hui Min, Jia Yi Tan, Sudip K. Batabyal, Shlomo Magdassi, Subodh G. Mhaisalkar, and Lydia H. Wong. "Inside Back Cover: Photoactive Nanocrystals by Low-Temperature Welding of Copper Sulfide Nanoparticles and Indium Sulfide Nanosheets (ChemSusChem 12/2014)." ChemSusChem 7, no. 12 (November 7, 2014): 3549. http://dx.doi.org/10.1002/cssc.201403101.

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