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Dissertations / Theses on the topic 'Copper – Spectra'

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1

Gharavi-Naeini, Jafar. "Doping and temperature dependence of the Raman spectra lanthanum strontium copper oxide." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape9/PQDD_0028/NQ51865.pdf.

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2

Pyrka, Gloria Jean. "Electrochemical and structural studies of one-dimensional copper charge transfer complexes." Diss., The University of Arizona, 1988. http://hdl.handle.net/10150/184493.

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The electrochemistry of solid electrodes of charge transfer complexes of tetracyanoquinodimethane (TCNQ) and copper complexes with nitrogen containing chelates, such and dipyridylamine (dpaH), bipyridyl (bpy) and 1,10-dimethyl-2,9-phenanthroline (dmp), has been investigated with cyclic voltammetry. Pressed pellet electrodes of these complexes exhibit a broad electrochemically stable region. The oxidative and reductive breakdown reactions involve solid state reactions into the bulk electrode. These materials also act as electron mediators for glucose oxidation in glucose oxidase modified electr
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3

SWANSON, DALE DORSETT. "ELECTROCHEMICAL AND SPECTROSCOPIC STUDIES OF THIOETHER COORDINATION COMPLEXES (CYCLIC VOLTAMMETRY, OCTAHEDRAL LOW-SPIN METALS, BLUE COPPER PROTEINS, ELECTRON PARAMAGNETIC RESONANCE)." Diss., The University of Arizona, 1985. http://hdl.handle.net/10150/188102.

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The bis 1,4,7-trithiacyclononane (1,4,7-TTCN) complexes of iron, cobalt, nickel and copper are reported in this work. Their properties have been examined using computer-controlled electrochemical and spectroscopic techniques. These TTCN complexes form readily, are unusually symmetrical and support electron transfer reactions at the metal center. The cobalt(II) complex is octahedral, low spin and symmetrical. Four oxidation states of cobalt-TTCN complex are observed; two one-electron transfer processes are reversible. Copper (II) bis 1,4,7-TTCN is unusually symmetrical evidenced by both solid p
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4

張啓亮 and Kai-leung Cheung. "Syntheses and luminescence studies of di- and polynuclear gold(1) and copper(1) complexes, design strategies towards metalloreceptors andmixed-metal complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31242996.

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5

Koenig, Karen Marie. "True absorption of selenium in dairy cows : stable isotope tracer methodology and effect of dietary copper." Thesis, University of British Columbia, 1988. http://hdl.handle.net/2429/27972.

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Gas chromatography mass spectrometry (GCMS) and inductively coupled plasma mass spectrometry (ICPMS) were evaluated for the measurement of selenium (Se) and Se stable isotope ratios. GCMS and ICPMS were found to be accurate for quantitative Se analysis in biological matrices by isotope dilution using Se-78 and Se-76 as internal standards, respectively. A higher precision was obtained for ICPMS than GCMS enabling a smaller quantity of the tracer to be administered to subjects in labelling experiments. The isotopes of choice for metabolic tracers were Se-76 when sample analysis was by GCMS and S
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6

Brown, Jared C. "UV Visible Spectra Analysis of High Temperature Water Gas Shift Catalysts Made from Iron, Lanthanum, Copper, and Chromium Oxides." BYU ScholarsArchive, 2012. https://scholarsarchive.byu.edu/etd/3222.

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Hydrogen is a vital component in several different chemical reactions as well as a potential fuel source for the future. The water gas shift (WGS) reaction converts CO and water to hydrogen and CO2. The objective of this work is to first, characterize the potential benefits of the addition of lanthanum oxide (lanthana) to the iron-chromium-copper (Fe-Cr-Cu) oxide catalysts industrially used in high temperature water gas shift processes, and second, analyze these catalysts using in-situ UV-Visible spectroscopy. The benefits of each component in the catalyst are discussed as well as potential be
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7

Goswami, Arindom. "Fundamental Studies of Copper Corrosion in Interconnect Fabrication Process and Spectroscopic Investigation of Low-k Structures." Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc822794/.

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In the first part of this dissertation, copper bimetallic corrosion and its inhibition in cleaning processes involved in interconnect fabrication is explored. In microelectronics fabrication, post chemical mechanical polishing (CMP) cleaning is required to remove organic contaminants and particles left on copper interconnects after the CMP process. Use of cleaning solutions, however, causes serious reliability issues due to corrosion and recession of the interconnects. In this study, different azole compounds are explored and pyrazole is found out to be a potentially superior Cu corrosion inhi
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8

Unsworth, Paul. "Spectroscopic studies of metal alloys and semiconductor interfaces." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343647.

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9

Carew, Alexander Jon. "Fundamental studies into the catalytic properties of metal-oxide supported gold and copper nanoparticles." Thesis, University of Liverpool, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367710.

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10

Kariapper, Mohamed Sirajudeen. "X-ray standing wave studies of surface adsorption structures." Thesis, University of Warwick, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.365232.

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11

Essex, Sarah Jane. "Spectral intensities in planar copper(II) complexes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239622.

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12

Barnes, Martin Paul. "The electronic spectrum of copper dichloride." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282333.

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13

Yu, Kyle Kai-Hung. "Interfacial Electrochemistry of Copper and Spectro-Electrochemical Characterization of Oxygen Reduction Reaction." Thesis, University of North Texas, 2011. https://digital.library.unt.edu/ark:/67531/metadc103416/.

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The first part of this dissertation highlights the contents of the electrochemical characterization of Cu and its electroplating on Ru-based substrates. The growth of Ru native oxide does diminish the efficiency of Cu plating on Ru surface. However, the electrochemical formed irreversible Ru hydrate dioxide (RuOxHy) shows better coverage of Cu UPD. The conductive Ru oxides are directly plateable liner materials as potential diffusion barriers for the IC fabrication. The part II of this dissertation demonstrates the development of a new rapid corrosion screening methodology for effective charac
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14

Guillet, Stéphane. "Etude des propriétés électroniques des interfaces Ag/Si(100) et Cu/Si(100)." Grenoble 1, 1993. http://www.theses.fr/1993GRE10065.

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Les premiers stades de la formation des interfaces ag/si(100) et cu/si(100) a temperature ambiante ont ete etudies in situ par reflectivite differentielle (1. 5 ev-5. 0 ev) associee a des techniques classiques de surface: photoemission uv (ups), spectroscopie auger (aes) et diffraction d'electrons lents (del). Pour des depots plus importants (quelques dizaines a quelques centaines d'angstroms), des etudes ex situ de la reflectivite dans l'infra-rouge (0. 025 ev-1 ev) et de la conductivite electrique (entre 4k et 300k) sont egalement presentees. Un reflectometre differentiel, construit pour ces
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15

Nyo, Mi Swe Pisamai Kulkanjanatorn. "Spectral characteristics of ethambutol-copper (II) ion complex and its application for quantitative analysis /." Abstract, 2007. http://mulinet3.li.mahidol.ac.th/thesis/2550/cd405/4837396.pdf.

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16

Lamprecht, Emmanuel. "Thermal, spectroscopic and x-ray diffraction studies of copper(II) 1,2,4,5-Benzenetetracarboxylates and copper(II) oxalate a study of metal-organic frameworks." Thesis, Rhodes University, 2008. http://hdl.handle.net/10962/d1005054.

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Novel and known metal organic frameworks with copper(II), sodium and 1,2,4,5-benzenetetracarboxylate were prepared by ambient precipitation, solvothermal and gel-synthesis methods, and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, infrared spectroscopy, differential scanning calorimetry, and thermogravimetry with FTIR evolved-gas analysis. Some of these complexes were investigated for guest inclusion properties with water (the original guest species), methanol, ethanol and pyridine. The gel-synthesis products were the most interesting. The novel threedimensional
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17

Sanderson, Douglas Grant. "An investigation of the relationship between the structure and function of the blue copper electron transport protein plastocyanin using thin-layer, steady-state spectroelectro-chemistry /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487262513407884.

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18

Lambert, Alexander S. "Application of UV-Vis Spectroscopy to the Monitoring, Characterization and Analysis of Chemical Equilibria of Copper Etching Baths." Thesis, University of North Texas, 2017. https://digital.library.unt.edu/ark:/67531/metadc1011880/.

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The continuously increasing demand for innovation in the miniaturization of microelectronics has driven the need for ever more precise fabrication strategies for device packaging, especially for printed circuit boards (PCBs). Subtractive copper etching is a fundamental step in the fabrication process, requiring very precise control of etch rate and etch factor. Changes in the etching chemical equilibrium have significant effects on etching behavior, and CuCl2 / HCl etching baths are typically monitored with several parameters including oxidation-reduction potential, conductivity, and specific
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19

Khan, Mustayeen Ahmed. "Stabilite, spectres electroniques et structures des halogenocuprates en milieu protique." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13059.

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Etude des complexes de cu(ii) dans les solvants protiques l'eau, le methanol et l'acide acetique. On caracterise 4 complexes successsifs; calcul de leurs constantes de stabilite. Etude de l'effet du solvant sur les spectres electroniques
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20

Kartouni, Abdelkarim. "Caractérisation analytique des premiers stades de l'oxydation du cuivre par méthodes non destructives." Rouen, 1993. http://www.theses.fr/1993ROUES059.

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L'association des méthodes optiques permet d'identifier les différentes espèces présentes dans les couches d'oxydes développées sur le cuivre depuis des épaisseurs de quelques nanomètres jusqu'à plusieurs micromètres. Les oxydes suivants: l'oxyde précurseur de Cu2O, de formule CuxO, Cu2O, Cu3O2 et CuO ont été caractérisés en spectroscopie UV-Vis-PIR en réflexion diffuse. Les défauts dans les oxydes cuivreux peuvent être identifiés par la spectroscopie de photoluminescence. Les premiers stades de l'oxydation du cuivre font intervenir un processus rapide suivant les réactions: 2Cu+1/2 O2Cu2O-3Cu
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21

Lucato, Leandro Tavares. "Análise comparativa entre as imagens convencionais de ressonância magnética do encéfalo e a espectroscopia de prótons na doença de Wilson." Universidade de São Paulo, 2003. http://www.teses.usp.br/teses/disponiveis/5/5151/tde-17092014-094357/.

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A doença de Wilson (DW) é rara, de herança autossômica recessiva, com prevalência estimada de 1 em 30.000 nascidos vivos, causada por distúrbio no metabolismo do cobre, com sede no fígado e que causa acúmulo do metal primeiramente no hepatócito e secundariamente em outros tecidos (encéfalo, córnea, rins e outros). Os objetivos deste trabalho foram: comparar os achados da espectroscopia de prótons por ressonância magnética (ERM) dos pacientes com DW aos do grupo controle em três localizações (núcleos da base, substância branca frontal e córtex parieto-occipital); correlacionar o grau de acometi
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22

MANAR, ABDELKRIM. "Dynamique des proprietes optiques nonlineaires du chlorure de cuivre au voisinage des resonances electroniques." Université Louis Pasteur (Strasbourg) (1971-2008), 1989. http://www.theses.fr/1989STR13054.

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L'etude des populations des quasiparticules (excitons, polaritons, etc. ), des durees de vie de leurs etats fondamentals et excites est faite par mesures de transmission induite et de gain a l'aide d'une technique "pompe et sonde". L'elargissement asymetrique de la raie d'absorption excitonique est explique par les collisions elastiques entre excitons. Les variations de l'indice de refraction sont expliquees par la dynamique des polaritons de type photonique
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23

Xiao, Lan. "Etude physico-chimique de la complexation de divers ions metalliques (cu**(2+), ni**(2+) et co**(2+)) avec des dipeptides l-l contenant des chaines laterales non-coordinantes." Paris 7, 1988. http://www.theses.fr/1988PA077170.

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Stabilite des complexes en fonction de l'interaction des chaines laterales du dipeptide et le solvant. Mesures potentiometriques calorimetriques, caracterisation spectrometrique et structure moleculaire
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24

Edel, André. "Photochimie d'un complexe du cuivre (i) : etude dynamique et structurale par rmn de catenands et catenates." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13016.

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L'etude des proprietes photo-physiques et -chimiques du complexe cu(diphenylphenan)::(2)**(+) conduit au premier exemple d'un complexe de cu (i) realisant la photoreduction de l'eau sous irradiation en lumiere visible. Etude rmn de cu (cat-30)**(+) et cu (cat-27)**(+) montrant qu'ils presentent des proprietes topographiques identiques
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25

Faulmann, Christophe. "Conducteurs derives de metaux de transition : complexes moleculaires, polymeres, oxydes de cuivre." Toulouse 3, 1988. http://www.theses.fr/1988TOU30160.

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26

Bouet, Gilles. "Etude structurale et analytique de complexes d'halogénures d'éléments 3D : mx::(2) (M = co,ni,cu; X = cl,br) et de diverses aldoximes furanniques." Angers, 1987. http://www.theses.fr/1987ANGE0009.

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Vingt-quatre nouveaux complexes d'halogénures de métaux 3 D : mx::(2) (m = co,ni,cu; x = cl,br) sont préparés et caractérisés. Leurs structures sont déterminées par diffraction des rayons X pour deux des composés et, à partir de celles-ci, pour l'ensemble des complexes grâce à la spectroscopie infrarouge et à la spectroscopie électronique. Le calcul des constantes de stabilité et des paramètres thermodynamiques correspondants par titrimétrie thermométrique est décrit.
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27

Petit, Jérôme. "Nouveaux outils en sciences de l'environnement: géochimie isotopique du Cu-Zn et spéciation des éléments en trace métalliques par titrage acidimétrique :développement et applications aux phases particulaires de l'estuaire de l'Escaut, aux émissions atmosphériques et aux sols contaminés d'Angleur/Prayon." Doctoral thesis, Universite Libre de Bruxelles, 2009. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/210231.

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Les potentiels de nouveaux moyens d’investigation en sciences de l’environnement, tel que la géochimie des isotopes stables du Cu et du Zn et l’étude de la spéciation des éléments en trace métalliques (ETM) par titrage acidimétrique sont évalués dans le cadre de trois cas d’études, faisant intervenir des matériaux de matrices et de concentrations en ETM variables. Afin de mettre en évidence de très subtiles variations des compositions isotopiques du Cu et du Zn dans les matériaux particulaires variablement pollués, une attention particulière à été voué à la mise au point des méthodes de sépara
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28

Aabid, Sami El. "Méthode basée modèle pour le diagnostic de l'état de santé d'une pile à combustible PEMFC en vue de sa maintenance." Thesis, Toulouse, INPT, 2020. http://www.theses.fr/2020INPT0011.

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Les piles à combustible se positionnent aujourd’hui comme une alternative technologique séduisante face aux solutions classiquement utilisées pour le stockage d’énergie. De par leur rendement de conversion en énergie électrique et leur haute densité énergétique, les grands acteurs du secteur aéronautique en voient une solution intéressante pour réduire l’impact environnemental des avions. C’est dans cette optique que s’inscrit la présente thèse, visant à contribuer au développement de méthodologies destinées au suivi de l’état de santé d’une pile à combustible à membrane échangeuse de protons
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29

LUN, LEE I., and 李宜倫. "Collisionally Activated Decomposition spectra of Amino Acid-Copper Ion Complex." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/66638171850739843472.

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碩士<br>東海大學<br>化學系<br>95<br>Triple-stage quadrupole tandem mass spectrometry and fast ion bombardment technique were applied for study of ion-molecular reaction, the complex formation, and fragmentation pattern of amino acids with metal ions in the gas phase. Results of our collisionally activated dissociation ( CAD ) experiment indicate that amino acids with transition metal ions Cu+ can lose specific neutral molecules ( HCOOH, H2O ) or [Cu]+ fragment ions dissociate the amino acid’s backbones to produce their daughter fragment ions. [A+Cu2Cl]+ can produce [A+Cu]+ and [A+Cu]+- HCOOH fragment
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30

Dumkow, Irene D. "Oxygen-deficient YBa���Cu���O[������x] films investigated by perturbed angular correlation spectroscopy." Thesis, 1997. http://hdl.handle.net/1957/33817.

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31

Ma, Giang N. "XAFS investigation of the local structure of cadmium in Cu(In[subscript 0.7]Ga[subscript 0.3])Se���-based thin films." Thesis, 2004. http://hdl.handle.net/1957/30970.

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We have performed fluorescence extended X-ray absorption fine structure (EXAFS) measurements on the Cd K-edge of partial electrolyte (PE) treated Cu(In[subscript 0.7]Ga[subscript 0.3])Se��� (CIGS) thin film samples using synchrotron X-ray radiation. This data was compared to the EXAFS spectra of CdSe and CdO standards. Cd local structure models were constructed and used for the least square analysis of the spectra. The first model employed implantation of a cadmium atom and a single oxygen atom into the CIGS lattice. Specifically, an oxygen atom was introduced in the tetrahedral bonded Cd-Se l
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32

Chiu, Hsien-Ju, and 邱顯儒. "Spectral and electrochemical characterization of new vanadyl ,copper and zinc porphyrins." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/62931549030355050125.

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碩士<br>國立臺灣大學<br>化學研究所<br>90<br>Abstract We reported synthesis of nonaqueous porphyrins about ZnENP, CuENP with naphthoic ester and ZnHNP, cis-VOHNP and trans-VOHNP with naphthoic acid. The electrochemical properties of porphyrin have been studied by cyclic voltammetry (CV) and spectroelectrochemistry. There are two reversible redox couples in the CV of ZnTMP and ZnENP at oxidation potential. Observation by UV-vis-near IR spectroelectrochemistry indicated that ZnENP was first oxidation to cation radical ,ZnENP+· and that the second oxidation renders rapid intramolecular ch
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33

Otieno, Tom. "Diazine-bridged coordination polymers of copper and nickel : synthesis and thermal, spectral, structural, and magnetic properties." Thesis, 1993. http://hdl.handle.net/2429/2625.

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A large number of coordination compounds of copper(I), copper (II) and nickel (II) have been prepared and characterized by thermal, spectroscopic and X-ray diffraction methods as well as by elemental analysis and magnetic susceptibility measurements. The neutral ligands used in the study were pyrazine (1,4-diazine), pyridazine (1,2-diazine), methylpyrazine, 2,5-dimethylpyrazine, pyridine and 4,4'-bipyridine. Anionic ligands of a range of coordinating abilities were employed. These include cyanate, nitrate, methanesulfonate, hexafluoroarsenate, hexafluorophosphate, chloride and thiocyanate anio
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34

Zeribi, Abderrahim. "Contribution différentielle des variations du nombre de copies aux troubles du spectre autistique et aux traits cognitifs." Thèse, 2018. http://hdl.handle.net/1866/21376.

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35

Moreau, Clara. "Mapping genome-wide neuropsychiatric mutation effects on functional brain connectivity : c opy number variants delineate dimensions contributing to autism and schizophrenia." Thesis, 2020. http://hdl.handle.net/1866/24592.

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Les recherches menées pour comprendre les troubles du spectre autistique (TSA) et la schizophrénie (SZ) ont communément utilisé une approche dite descendante, partant du diagnostic clinique pour investiguer des phénotypes intermédiaires cérébraux ainsi que des variations génétiques associées. Des études transdiagnostiques récentes ont remis en question ces frontières nosologiques, et suggèrent des mécanismes étiologiques imbriqués. L’approche montante propose de composer des groupes de porteurs d’un même variant génétique afin d’investiguer leur contribution aux conditions neuropsychiatriques
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