Academic literature on the topic '[Cp*Ir(bpy-OMe)H]+'

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Journal articles on the topic "[Cp*Ir(bpy-OMe)H]+"

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Talavera, M., J. Bravo, J. Castro, S. García-Fontán, J. M. Hermida-Ramón, and S. Bolaño. "Electronic effects of substituents on the stability of the iridanaphthalene compound [IrCp*{C(OMe)CHC(o-C6H4)(Ph)}(PMe3)]PF6." Dalton Trans. 43, no. 46 (2014): 17366–74. http://dx.doi.org/10.1039/c4dt02744b.

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Niraj, Kumari, and Mishra Lallan. "Reactivity of carboxylato cyclophane with hexafluorobenzene and CuII-2,2' -hi pyridine." Journal of Indian Chemical Society Vol. 88, Aug 2011 (2011): 1241–49. https://doi.org/10.5281/zenodo.5786134.

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Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi-221 005, Uttar Pradesh, India <em>E-mail </em>: lmishrabhu@yahoo.co.in Fax : 91-542-2368127 <em>Manuscript received 03 June 2011, accepted 06 June 2011</em> N,N&#39;,N&#39;&#39;,N&#39;&quot;-Tetrakis(3-earboxy-propionyl)-1,6,20,25-tetraaza[6.1.6.1)paracyclophane, H<sub>4</sub>cp is allowed to react with hexanuorobenzene (hfb) and the binding of H<sub>4</sub>cp with hfb in solution is monitored using spectroscopic techniques (absorption, emission and <sup>1</sup>H NMR). However, a reaction of H4cp with Cu<sup>II</su
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Abramov, P. A., C. Vicent, N. B. Kompankov, J. A. Laricheva, and M. N. Sokolov. "Unique solubility of polyoxoniobate salts in methanol: coordination to cations and POM methylation." RSC Advances 6, no. 24 (2016): 20240–46. http://dx.doi.org/10.1039/c5ra23918d.

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In methanolic solutions of A<sub>4</sub>[{LM′}<sub>2</sub>M<sub>6</sub>O<sub>19</sub>] ({LM′} = {Cp*Rh}<sup>2+</sup>, {Cp*Ir}<sup>2+</sup>, {(C<sub>6</sub>H<sub>6</sub>)Ru}<sup>2+</sup>; M = Nb, Ta; A = Na, K) formation of methoxo complexes [{LM′}<sub>2</sub>M<sub>6</sub>O<sub>19−n</sub>(OMe)n] (n = 1–3) and coordination of CH<sub>3</sub>OH to A<sup>+</sup> take place.
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Deguire, Suzanne, and François Brisse. "The effect of substitution on the conformation in para-substituted ethylene glycol dibenzoate molecules." Canadian Journal of Chemistry 66, no. 10 (1988): 2545–52. http://dx.doi.org/10.1139/v88-399.

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The series of ethylene glycol di-para-X-benzoates, where X = Me, OMe, CN, and NO2, has been studied by infrared spectroscopy and solid state CP/MAS 13C nuclear magnetic resonance. The crystal structures were established for X = Me and OMe. Bond distances, bond angles, and torsion angles were compared to those of related molecules (X = H, Ph, Cl). It was found that the conformation of the CO—O—CH2—CH2—O—CO sequence is either trans-trans-trans or trans-gauche-trans. (trans = t, gauche = g). The CH2—CH2 bond distance ranging from 1.471(2) to 1.499(3) Å is always very short. The O—CH2—CH2 bond ang
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Röllig, Robert, Caroline Emilie Paul, Pierre Rousselot-Pailley, Selin Kara, and Véronique Alphand. "Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and epoxidation: A Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules." Reaction Chemistry & Engineering, 2023. http://dx.doi.org/10.1039/d3re00411b.

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Taking advantage of the unique properties of two-component flavo-monooxygenases and the ability of [Cp*Ir(bpy-OMe)H]+ to transfer hydrides to reduce flavins, we extended the scope of this pH- and oxygen-robust iridium(III)-complex...
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Fernández, Sergio, Eric A. Assaf, Shahbaz Ahmad, et al. "Room‐Temperature Formate Ester Transfer Hydrogenation Enables an Electrochemical/Thermal Organometallic Cascade for Methanol Synthesis from CO2." Angewandte Chemie, November 21, 2024. http://dx.doi.org/10.1002/ange.202416061.

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The reduction of CO2 to synthetic fuels is a valuable strategy for energy storage. However, the formation of energy‐dense liquid fuels such as methanol remains rare, particularly under low‐temperature and ‐pressure conditions that can be coupled to renewable electricity sources via electrochemistry. Here, a multicatalyst system pairing an electrocatalyst with a thermal organometallic catalyst is introduced, which enables the reduction of CO2 to methanol at ambient temperature and pressure. The cascade methanol synthesis proceeds via CO2 reduction to formate by electrocatalyst [Cp*Ir(bpy)Cl]+ (
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Fernández, Sergio, Eric A. Assaf, Shahbaz Ahmad, et al. "Room‐Temperature Formate Ester Transfer Hydrogenation Enables an Electrochemical/Thermal Organometallic Cascade for Methanol Synthesis from CO2." Angewandte Chemie International Edition, November 21, 2024. http://dx.doi.org/10.1002/anie.202416061.

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The reduction of CO2 to synthetic fuels is a valuable strategy for energy storage. However, the formation of energy‐dense liquid fuels such as methanol remains rare, particularly under low‐temperature and ‐pressure conditions that can be coupled to renewable electricity sources via electrochemistry. Here, a multicatalyst system pairing an electrocatalyst with a thermal organometallic catalyst is introduced, which enables the reduction of CO2 to methanol at ambient temperature and pressure. The cascade methanol synthesis proceeds via CO2 reduction to formate by electrocatalyst [Cp*Ir(bpy)Cl]+ (
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Cattaneo, Mauricio, Elisabeth Gallmeier, Pedro O. Abate, Brandon Mercado, and James Mayer. "Tunning Energetics of 2e⁻/2H+ PCET Properties with Model Ru‐bisamido Complexes." Chemistry – A European Journal, July 12, 2024. http://dx.doi.org/10.1002/chem.202401308.

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Most redox processes that break/form bonds involve net 2e− changes, and many are coupled to protons. Yet most proton‐coupled electron transfer (PCET) studies focus on 1e–/1H+ reactions. Reported here is a family of molecular models that undergo tunable 2e–/2H+ redox changes. Complexes [(X2bpy)RuII(en*)2](PF6)2 and [(X2bpy)RuIV(en*‐H)2](PF6)2 have been synthesized with bpy = 2,2’‐bipyridine with 4,4’‐subtitutions X = ‐NMe2, ‐OMe, ‐Me, ‐H, ‐CF3; and en* = 2,3‐dimethyl‐2,3‐butanediamine. They have been characterized by IR, UV‐vis, and NMR spectroscopies, XRD, electrochemistry, mass spectrometry,
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Dissertations / Theses on the topic "[Cp*Ir(bpy-OMe)H]+"

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Röllig, Robert. "Chemical hydride transfer for flavin dependent monooxygenases of two-component systems." Electronic Thesis or Diss., Aix-Marseille, 2021. http://www.theses.fr/2021AIXM0436.

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Le terme monooxygénases flavoprotéiques (flavoprotein monooxygenases FPMO) recouvre aussi bien des flavoenzymes formées d’une seule composante que de deux. L'indépendance fonctionnelle de la partie oxygénase de la 2,5-dicétocamphane 1,2-monooxygénase I (2,5-DKCMO), une Baeyer-Villiger monooxygénase de type II, FMN dépendante, de sa contrepartie réductase, ainsi que le mécanisme de transfert de la flavine par libre diffusion, ont été étudiés dans des réactions sans réductase mais où des analogues biomimétiques synthétiques de nicotinamide (NCB) ont été utilisés pour réduire le FMN. L'équilibre
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