Academic literature on the topic 'Cross-coupling reactions'

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Journal articles on the topic "Cross-coupling reactions"

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Pires, Marina, Sara Purificação, A. Santos, and M. Marques. "The Role of PEG on Pd- and Cu-Catalyzed Cross-Coupling Reactions." Synthesis 49, no. 11 (2017): 2337–50. http://dx.doi.org/10.1055/s-0036-1589498.

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Carbon–carbon and carbon–heteroatom coupling reactions are among the most important transformations in organic synthesis as they enable complex structures to be formed from readily available compounds under different routes and conditions. Several metal-catalyzed cross-coupling reactions have been developed creating many efficient methods accessible for the direct formation of new bonds between differently hybridized carbon atoms.During the last decade, much effort has been devoted towards improvement of the sustainability of these reactions, such as catalyst recovery and atom efficiency. Poly
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Kumar, Anil, Saurav Kumar, Jyoti Jyoti, Deepak Gupta, and Gajendra Singh. "A Decade of Exploration of Transition-Metal-Catalyzed Cross-Coupling Reactions: An Overview." SynOpen 07, no. 04 (2023): 580–614. http://dx.doi.org/10.1055/s-0040-1720096.

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AbstractDuring the previous couple of decades, transition-metal (Fe, Co, Cu, Ni, Ru, Rh, Pd, Ag, Au) catalyzed inter- and intramolecular coupling reactions have attracted huge attention for the construction of C–C and C–heteroatom (like C–N, C–P, C–O, C–S, etc.) bonds to synthesize a diverse range of polymers, fine chemicals, and agrochemicals (mainly fungicides, herbicides, and insecticides), as well as biologically and pharmaceutically important organic molecules. Furthermore, the employment of lower cost and easily available metals such as first-row transition-metal salts or metal complexes
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Daley, Ryan A., and Joseph J. Topczewski. "Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism." Synthesis 52, no. 03 (2019): 365–77. http://dx.doi.org/10.1055/s-0039-1690769.

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Palladium-catalyzed cross-couplings and related reactions have enabled many transformations essential to the synthesis of pharmaceuticals, agrochemicals, and organic materials. A related family of reactions that have received less attention are decarboxylative functionalization reactions. These reactions replace the preformed organometallic precursor (e.g., boronic acid or organostannane) with inexpensive and readily available carboxylic acids for many palladium-catalyzed reactions. This review focuses on catalyzed reactions where the elementary decarboxylation step is thought to occur at a pa
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Koóš, Peter, Martin Markovič, Pavol Lopatka, and Tibor Gracza. "Recent Applications of Continuous Flow in Homogeneous Palladium Catalysis." Synthesis 52, no. 23 (2020): 3511–29. http://dx.doi.org/10.1055/s-0040-1707212.

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Considerable advances have been made using continuous flow chemistry as an enabling tool in organic synthesis. Consequently, the number of articles reporting continuous flow methods has increased significantly in recent years. This review covers the progress achieved in homogeneous palladium catalysis using continuous flow conditions over the last five years, including C–C/C–N cross-coupling reactions, carbonylations and reductive/oxidative transformations.1 Introduction2 C–C Cross-Coupling Reactions3 C–N Coupling Reactions4 Carbonylation Reactions5 Miscellaneous Reactions6 Key to Schematic Sy
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Akkarasamiyo, Sunisa, Somsak Ruchirawat, Poonsaksi Ploypradith та Joseph S. M. Samec. "Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols". Synthesis 52, № 05 (2020): 645–59. http://dx.doi.org/10.1055/s-0039-1690740.

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The Suzuki–Miyaura reaction is one of the most powerful tools for the formation of carbon–carbon bonds in organic synthesis. The utilization of alcohols in this powerful reaction is a challenging task. This short review covers progress in the transition-metal-catalyzed Suzuki­–Miyaura-type cross-coupling reaction of π-activated alcohol, such as aryl, benzylic, allylic, propargylic and allenic alcohols, between 2000 and June 2019.1 Introduction2 Suzuki–Miyaura Cross-Coupling Reactions of Aryl Alcohols2.1 One-Pot Reactions with Pre-activation of the C–O Bond2.1.1 Palladium Catalysis2.1.2 Nickel
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Bolm, Carsten. "Cross-Coupling Reactions." Journal of Organic Chemistry 77, no. 12 (2012): 5221–23. http://dx.doi.org/10.1021/jo301069c.

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Bolm, Carsten. "Cross-Coupling Reactions." Organic Letters 14, no. 12 (2012): 2925–28. http://dx.doi.org/10.1021/ol301436v.

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Staubitz, Anne, Melanie Walther, Waldemar Kipke, Sven Schultzke, and Souvik Ghosh. "Modification of Azobenzenes by Cross-Coupling Reactions." Synthesis 53, no. 07 (2021): 1213–28. http://dx.doi.org/10.1055/s-0040-1705999.

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AbstractAzobenzenes are among the most extensively used molecular switches for many different applications. The need to tailor them to the required task often requires further functionalization. Cross-coupling reactions are ideally suited for late-stage modifications. This review provides an overview of recent developments in the modification of azobenzene and its derivatives by cross-coupling reactions.1 Introduction2 Azobenzenes as Formally Electrophilic Components2.1 Palladium Catalysis2.2 Nickel Catalysis2.3 Copper Catalysis2.4 Cobalt Catalysis3 Azobenzenes as Formally Nucleophilic Compone
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Kubota, Koji, and Hajime Ito. "Mechanochemical Cross-Coupling Reactions." Trends in Chemistry 2, no. 12 (2020): 1066–81. http://dx.doi.org/10.1016/j.trechm.2020.09.006.

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Tobrman, Tomáš. "Vinyl Esters and Vinyl Sulfonates as Green Alternatives to Vinyl Bromide for the Synthesis of Monosubstituted Alkenes via Transition-Metal-Catalyzed Reactions." Chemistry 5, no. 4 (2023): 2288–321. http://dx.doi.org/10.3390/chemistry5040153.

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This review summarizes the applications of vinyl sulfonate and vinyl acetate as green alternatives for vinyl bromide in cross-coupling reactions. In the first part, the preparation of vinyl sulfonates and their cross-coupling reactions are briefly discussed. Then, a brief review of vinyl acetate cross-coupling reactions, including cyclization reactions, the Fujiware–Moritani reaction, and transvinylation reactions are described.
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Dissertations / Theses on the topic "Cross-coupling reactions"

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Arismendi, Romero Graciela. "Paladium catalized cross-coupling reactions." Revista de Química, 2012. http://repositorio.pucp.edu.pe/index/handle/123456789/101014.

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El premio Nobel en Química de este año ha sido otorgado a los investigadores Richard Heck (EE.UU.), Ei-ichi Negishi (EE.UU.) y Akira Suzuki (Japón), por sus valiosos aportesen el desarrollo de un tipo específico de reacciones para la formación de enlaces C-C: “Reacciones de acoplamientocruzado catalizadas por paladio”. La creciente demanda de nuevas sustancias para el desarrollo de medicamentos, materiales y/o compuestos biológicamente activos ha hecho de este descubrimiento una importante herramienta para los químicos, dándoles la capacidad de atender estas necesidades con la creación de molé
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Moriwaki, Yuya. "Cross-Coupling Reactions in Flow Microreactor Systems." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/200446.

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Adams, Kirsty. "Metal catalysed cross-coupling reactions of heterocycles." Thesis, University of Huddersfield, 2013. http://eprints.hud.ac.uk/id/eprint/20889/.

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This report describes two methodology studies dedicated towards development of metal catalysed crosscoupling reactions in the synthesis of novel heterocyclic compounds. Firstly, a Heck-Mizoroki arylation reaction is reported for the direct functionalisation of tetrahydropyridines, towards the synthesis of kainoid analogues. Kainoids are a group of non-proteinogenic pyrrolidine dicarboxylic acids, which have attracted considerable interest because of their potent biological activity, including insecticidal, anthelmintic and neuroexcitatory properties. The ideal synthesis of kainoids would allow
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Black, Daniel. "Imines in copper-catalyzed cross-coupling reactions." Thesis, McGill University, 2006. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=102960.

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The purpose of this study was to develop new catalytic methods to mediate carbon-carbon bond forming reactions with imines under mild conditions and in a general manner. We found that copper catalysts were compatible in cross-coupling of a range of mild organometallic reagents, providing simple, efficient routes to alpha-substituted amides and amines.<br>Chapter 2 of this thesis describes a new copper-catalyzed multicomponent synthesis of alpha-substituted amides. This reaction was developed based upon previous work in this laboratory, which showed that palladium catalysts were competent in St
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Hall, Mark Andrew. "Iron-catalysed cross-coupling and reduction reactions." Thesis, University of Bristol, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.551314.

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Iron nanoparticles of size 6-16 nm have been successfully prepared by the reduction of FeCb with 3-pentylmagnesium bromide in the presence of polyethylene glycol. These nanoparticles show excellent activity in the catalytic dehalogenation of a range of alkyl and aryl halides when used at 5 mol% loadings, if an excess of the Grignard is present to ensure the regeneration of the catalyst. Alkyl halides react to give mixtures of alkane, alkene and homocoupled products, with good selectivity of the alkane product being observed. Aryl halides undergo hydrodehalogenation cleanly and do not undergo h
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Zhou, Jianrong (Jianrong Steve). "Cross-coupling reactions of unactivated alkyl halides." Thesis, Massachusetts Institute of Technology, 2005. http://hdl.handle.net/1721.1/33655.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2005.<br>Vita.<br>Includes bibliographical references.<br>My graduate research at MIT has been focused on the development of palladium- or nickel-catalyzed cross-coupling reactions using unactivated alkyl electrophiles (e.g., halides and sulfonates). Although aryl and alkenyl electrophiles have been commonly used in such processes, the utility of alkyl substrates has been underdeveloped, and merits further exploration. We have developed the first palladium-based catalyst that is effective for Negishi couplings of prima
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Hua, Xi Ye. "Expanding the Scope of Coupling Partners in Catalytic Cross-Coupling Reactions." Thesis, Université d'Ottawa / University of Ottawa, 2016. http://hdl.handle.net/10393/35521.

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Carbon-carbon (C-C) bond formation is among the most important processes in organic chemistry. Transition metal catalyzed C-C bond formation is an active research area that shows great potential due to high selectivity and relatively mild conditions. In Chapter 1, a new reaction for direct acylation of aryl halides is discussed. Specifically, the catalytic reaction between aryl halides/pseudohalides and aldehydes is explored. The choice of ligand, base, solvent, temperature, catalyst and substrates are important factors for optimizing this catalytic reaction. The various combinations of all
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García, Melchor Maximiliano. "Theoretical Study on Pd-catalyzed Cross-Coupling Reactions." Doctoral thesis, Universitat Autònoma de Barcelona, 2012. http://hdl.handle.net/10803/96827.

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D’ençà el seu descobriment, fa ja prop de tres dècades, les reaccions d’acoblament creuat C-C catalitzades per Pd han esdevingut una de les transformacions més poderoses dins la química organometàl·lica. De fet, tres dels desenvolupadors de les reaccions d’acoblament més emprades (reaccions de Heck, Suzuki i Negishi) van ésser guardonats l'any 2010 amb el premi Nobel de Química. El mecanisme general de les reaccions d'acoblament creuat C-C consisteix en tres etapes: addició oxidant, transmetal·lació, i eliminació reductiva. La millora d’una reacció comporta el coneixement profund del seu mecan
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Munday, Rachel Hannah. "Vinyldimethylphenylsilanes as latent partners in cross-coupling reactions." Thesis, University of Nottingham, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.430546.

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Zhang, Liang. "Catalytic Conjunctive Cross-Coupling and Catalytic Diboration Reactions." Thesis, Boston College, 2017. http://hdl.handle.net/2345/bc-ir:107561.

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Thesis advisor: James P. Morken<br>This dissertation will present four main projects focused on stereoselective construction of borylated compounds as well as their applications in asymmetric syntheses. The first two projects describe the development of a catalytic conjunctive cross-coupling reaction. By merging three simple starting materials, an organolithium reagent, an organoboronate, and an organic electrophile, a synthetically valuable secondary boronate is furnished by the conjunctive cross-coupling in an efficient and enantioselective fashion. Next, this strategy is expanded to synthes
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Books on the topic "Cross-coupling reactions"

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Miyaura, Norio, ed. Cross-Coupling Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/3-540-45313-x.

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Nishihara, Yasushi, ed. Applied Cross-Coupling Reactions. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32368-3.

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Lei, Aiwen, Wei Shi, Chao Liu, Wei Liu, Hua Zhang, and Chuan He. Oxidative Cross-Coupling Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2016. http://dx.doi.org/10.1002/9783527680986.

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Diederich, François, and Peter J. Stang, eds. Metal-Catalyzed Cross-Coupling Reactions. Wiley-VCH Verlag GmbH, 1998. http://dx.doi.org/10.1002/9783527612222.

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Evano, Gwilherm, and Nicolas Blanchard, eds. Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.

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de, Meijere A., and Diederich François, eds. Metal-catalyzed cross-coupling reactions. 2nd ed. Wiley-VCH, 2004.

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Diederich, François. Metal-catalyzed cross-coupling reactions. Wiley-VCH, 1998.

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N, Diederich François, and Stang P. J, eds. Metal-catalyzed cross-coupling reactions. 2nd ed. Wiley-VCH, 2004.

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Norio, Miyaura, and Buchwald Stephen L, eds. Cross-coupling reactions: A practical guide. Springer, 2002.

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Seo, Tamae. Palladium-Catalyzed Mechanochemical Cross-Coupling Reactions. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1991-4.

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Book chapters on the topic "Cross-coupling reactions"

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Terao, Jun, Nobuaki Kambe, Luis A. Sarandeses, et al. "Cross-Coupling Reactions." In Catalysts for Fine Chemical Synthesis, Volume 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470862017.ch7.

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Li, Jie Jack. "Hiyama cross-coupling reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_141.

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Li, Jie Jack. "Kumada cross-coupling reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_171.

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Li, Jie Jack. "Negishi cross-coupling reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_211.

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Li, Jie Jack. "Hiyama cross-coupling reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_134.

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Li, Jie Jack. "Kumada cross-coupling reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_154.

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Li, Jie Jack. "Negishi cross-coupling reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_190.

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Li, Jie Jack. "Hiyama cross-coupling reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_132.

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Li, Jie Jack. "Kumada cross-coupling reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_160.

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Li, Jie Jack. "Negishi cross-coupling reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_200.

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Conference papers on the topic "Cross-coupling reactions"

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Fancy, Saiada Fuadi, Md Ahsan Sabbir, Kingsley Lau, and Dale DeFord. "Extended Connectivity of Zinc Pigments to Provide Enhanced Galvanic Coupling by Partial Replacement with Nano-particles." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-13470.

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Abstract Zinc rich primer coatings (ZRP) have become widely used since the 1980's for corrosion mitigation. The effectiveness of the ZRP coating strongly depends on the pigment volume concentration and bonding to the steel substrate. Beneficial cathodic polarization occurs when the dispersed zinc pigments have continuity with the steel substrate. Carbon nano-particles are being considered in the development of the ZRP coating systems considering its physical, electrical and mechanical properties. Therefore this is of interest to identify the extent of possible corrosion mitigation of a nano-pa
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Čapek, Petr, Miroslav Otmar, Milena Masojídková, and Antonín Holý. "Cross-coupling reactions of 2,6-dichloro-9-deazapurine." In XIIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2002. http://dx.doi.org/10.1135/css200205304.

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Carvalho, Diego B., Camila B. Andrade, Carla R. Z. Miranda, et al. "Synthesis of Thiophene Acetylenes via Sonogashira Cross- Coupling Reactions." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013820103940.

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Gobo, Nicholas R. S., Timothy J. Brocksom, and Kleber T. de Oliveira. "Cross-coupling reactions as a strategy for Naphthalocyanine synthesis." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013911161227.

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Lima, Lucas Welington, and Ataualpa A. C. Braga. "Computational study on the reaction mechanism of Cp*Rh(III)-catalyzed cross-coupling reactions." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020144.

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The reaction mechanism of reaction reported by Onodera et al4 was studied in the M06L/Def2SVP level of theory. Two possible reaction products were characterized, named as product a and product b, where product a that was identified in the experimental study is due to a exergonic reaction and product b due to a endoergonic reaction.
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Levashov, Andrey, Dmitriy Buriy, Valeriy Konshin, and Alexey Andreev (deceased). "Stille-type cross coupling reactions with tetraalkynyl stannanes." In The 20th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-a060.

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Iglesias, Bernardo A., Henrique E. Toma, and Koiti Araki. "Synthesis of poly(pyridyl)porphyrins by Heck and Sonogashira cross-coupling reactions." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0096-1.

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Rúa-Sueiro, Marcos, Paula Munín-Cruz, Sara Bermúdez-Fernández, and José M. Vila. "Palladium Cyclometallated Compounds: Evaluation of Their Catalytic Activity in Cross-Coupling Reactions." In ECCS 2021. MDPI, 2022. http://dx.doi.org/10.3390/eccs2021-11034.

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"Efficient Synthesis of Conjugated 1,3,4-Thiadiazole Derivatives under Suzuki Cross-Coupling Reactions." In 2023 4th International Scientific Conference "Chemical Technology and Engineering". Lviv Polytechnic National University, 2023. http://dx.doi.org/10.23939/cte2023.182.

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Hocek, Michal, and Dana Hocková. "Regioselective cross-coupling reactions in the synthesis of multisubstituted purine bases and nucleosides." In XIIIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2005. http://dx.doi.org/10.1135/css200507213.

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Reports on the topic "Cross-coupling reactions"

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Bedi, Vaibhav, Puja K. Mahajan, and Nitin T. Patil. Gold Catalysis: A New Contender for Cross-Coupling Reactions with Aryl Halides. The Israel Chemical Society, 2023. http://dx.doi.org/10.51167/acm00038.

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