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Journal articles on the topic 'Crotyl alcohol'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Krishnamoorthy, Guna Sekar, та Seplapatty Kalimuthu Periyasamy. "Oxidation of α,β-Unsaturated Alcohols by Quinaldinium Fluorochromate". International Letters of Chemistry, Physics and Astronomy 5 (вересень 2013): 8–19. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.5.8.

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The kinetics of oxidation of α,β-unsaturated alcohols (allyl alcohol, Crotyl alcohol, Cinnamyl alcohol) by quinaldinium fluorochromate has been studied in aqueous acid medium at 313 K. α,β-unsaturated alcohols were converted to the corresponding acrolein, crotonaldehyde and cinnamaldehyde. The reaction is first order each in oxidant, substrate and H+. The decrease in dielectric constant of the medium increases the rate of the reaction. Increase in ionic strength by the addition of sodium perchlorate has no effect on the rate constant. There is no polymerization with acrylonitrile. The reaction

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2

Krishnamoorthy, Guna Sekar, та Seplapatty Kalimuthu Periyasamy. "Oxidation of α,β-Unsaturated Alcohols by Quinaldinium Fluorochromate". International Letters of Chemistry, Physics and Astronomy 5 (19 грудня 2012): 8–19. http://dx.doi.org/10.56431/p-91l939.

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The kinetics of oxidation of α,β-unsaturated alcohols (allyl alcohol, Crotyl alcohol, Cinnamyl alcohol) by quinaldinium fluorochromate has been studied in aqueous acid medium at 313 K. α,β-unsaturated alcohols were converted to the corresponding acrolein, crotonaldehyde and cinnamaldehyde. The reaction is first order each in oxidant, substrate and H+. The decrease in dielectric constant of the medium increases the rate of the reaction. Increase in ionic strength by the addition of sodium perchlorate has no effect on the rate constant. There is no polymerization with acrylonitrile. The reaction

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3

Ying, Xiangxian, Yifang Wang, Bin Xiong та ін. "Characterization of an Allylic/Benzyl Alcohol Dehydrogenase from Yokenella sp. Strain WZY002, an Organism Potentially Useful for the Synthesis of α,β-Unsaturated Alcohols from Allylic Aldehydes and Ketones". Applied and Environmental Microbiology 80, № 8 (2014): 2399–409. http://dx.doi.org/10.1128/aem.03980-13.

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ABSTRACTA novel whole-cell biocatalyst with high allylic alcohol-oxidizing activities was screened and identified asYokenellasp. WZY002, which chemoselectively reduced the C=O bond of allylic aldehydes/ketones to the corresponding α,β-unsaturated alcohols at 30°C and pH 8.0. The strain also had the capacity of stereoselectively reducing aromatic ketones to (S)-enantioselective alcohols. The enzyme responsible for the predominant allylic/benzyl alcohol dehydrogenase activity was purified to homogeneity and designated YsADH (alcohol dehydrogenase fromYokenellasp.), which had a calculated subunit

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4

Meyer, F. K., J. G. Drewett, and R. M. Carlson. "The Crotyl Alcohol Dianion: Addition Reactions." Synthetic Communications 16, no. 3 (1986): 261–65. http://dx.doi.org/10.1080/00397918608076308.

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5

N., D. VALECHHA, and K. PANDEY A. "Kinetics of Oxidation of Allyl, Crotyl and Cinnamic Alcohols by Selenium Dioxide." Journal of Indian Chemical Society Vol. 63, Jul 1986 (1986): 670–73. https://doi.org/10.5281/zenodo.6272753.

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Chemistry Department, Government Science College, Rewa-486 001 Chemistry Department, Government College, Shandol-484 001 <em>Manuscript received 2 July 1984, revised 3 March 1986, accepted 7 June 1986</em> The kinetics of oxidation of allyl, crotyl and cinnamic alcohols by selenium dioxide in 80%<em> </em>(v/v)<em> </em>acetic acid - water mixture have been investigated. The reaction is first order with respect to both alcohols and selenium dioxide. The reactions are catalysed by a strong acid. Primary salt effect is negligible. The reaction rate increases with increase in the percentage

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6

Chivers, Brandon A., and Robert W. J. Scott. "Selective oxidation of crotyl alcohol by AuxPd bimetallic pseudo-single-atom catalysts." Catalysis Science & Technology 10, no. 22 (2020): 7706–18. http://dx.doi.org/10.1039/d0cy01387k.

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7

Lee, Adam F., Zhipeng Chang, Peter Ellis, Simon F. J. Hackett, and Karen Wilson. "Selective Oxidation of Crotyl Alcohol over Pd(111)." Journal of Physical Chemistry C 111, no. 51 (2007): 18844–47. http://dx.doi.org/10.1021/jp709944c.

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8

Chien, Chen-Yie, and Georg Schade. "A rotating disc study of crotyl alcohol reduction." Electrochimica Acta 33, no. 1 (1988): 59–62. http://dx.doi.org/10.1016/0013-4686(88)80032-x.

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9

Cormier, Morgan, Florian Hernvann, and Michaël De Paolis. "Synthetic study toward tridachiapyrone B." Beilstein Journal of Organic Chemistry 18 (December 19, 2022): 1741–48. http://dx.doi.org/10.3762/bjoc.18.183.

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A convergent approach to the skeleton of tridachiapyrone B is described taking advantage of the desymmetrization of α,α’-dimethoxy-γ-pyrone leading to α-crotyl-α’-methoxy-γ-pyrone in one step. To construct the quaternary carbon of the 2,5-cyclohexadienone of the target, a strategy based on the Robinson-type annulation of an aldehyde derived from α-crotyl-α’-methoxy-γ-pyrone was applied. The grafting of the simplified target’s side chain was demonstrated through an oxidative anionic oxy-Cope rearrangement of the tertiary alcohol arising from the 1,2-addition of a 1,3-dimethylallyl reagent to 2,

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10

Ozawa, Tomohiro, Lingyiming Yu, Yasuhiro Yamada, and Satoshi Sato. "Isomerization of Crotyl Alcohol Catalyzed by V2O5-modified Silica." Chemistry Letters 50, no. 9 (2021): 1635–38. http://dx.doi.org/10.1246/cl.210290.

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11

Arévalo, M. C., J. L. Rodríguez, A. M. Castro-Luna, and E. Pastor. "Adsorption, oxidation and reduction of crotyl alcohol on platinum." Electrochimica Acta 51, no. 25 (2006): 5365–75. http://dx.doi.org/10.1016/j.electacta.2006.02.007.

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12

Xie, Guan Qun, Yan Hui Dai, Xi Jing Liu, Meng Fei Luo, and Xiao Nian Li. "Effect of Ce³⁺/Ce⁴⁺ Couple on Selective Hydrogenation of Crotonaldehyde over Pt/CeO₂ Catalyst." Advanced Materials Research 233-235 (May 2011): 1592–96. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.1592.

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By pretreatment of Pt/CeO2catalysts with high temperature reduction and subsequent low temperature reoxidation, the concentration of Ce3+species in the Pt/CeO2catalysts could be adjusted, while at the same time the Pt particle size remained constant. Thus the pure effect of Ce3+/Ce4+couples on the selective hydrogenation of crotonaldehdye could be explored. The investigation provided direct proofs supporting that Ce3+species favors the crotyl alcohol selectivity.

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13

Balcha, Tesfalidet, Jonathan R. Strobl, Candace Fowler, Priyabrat Dash, and Robert W. J. Scott. "Selective Aerobic Oxidation of Crotyl Alcohol Using AuPd Core-Shell Nanoparticles." ACS Catalysis 1, no. 5 (2011): 425–36. http://dx.doi.org/10.1021/cs200040a.

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14

Caminati, Walther, Claudio Paolucci, and Biagio Velino. "Microwave spectrum and torsional potential energy surfaces of cis-crotyl alcohol." Journal of Molecular Spectroscopy 137, no. 2 (1989): 362–72. http://dx.doi.org/10.1016/0022-2852(89)90179-3.

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15

Sharma, Priyamvada, Riya Sailani, Anita Meena, and Chandra Lata Khandelwal. "A kinetic and mechanistic study of the osmium(VIII)-catalysed oxidation of crotyl alcohol by hexacyanoferrate(III) in aqueous Alkaline medium." Journal of Chemical Research 44, no. 5-6 (2020): 295–300. http://dx.doi.org/10.1177/1747519819900622.

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The kinetics and mechanism of the osmium(VIII)-catalysed oxidation of crotyl alcohol by hexacyanoferrate(III) in aqueous alkaline medium is studied. The role of the osmium(VIII) catalyst is delineated to account for the experimental observations. A plausible reaction mechanism is suggested. Activation parameters such as the energy and entropy of activation are evaluated by employing the Eyring equation and are found to be 36.833 kJ mol−1 and −141.518 J K−1 mol−1, respectively.

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16

Rethinam, A. J., and C. J. Kennedy. "Indirect electrooxidation of crotyl and cinnamyl alcohol using a Ni(OH)2electrode." Journal of Applied Electrochemistry 34, no. 4 (2004): 371–74. http://dx.doi.org/10.1023/b:jach.0000016625.59112.da.

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17

Caminati, Walther, B. Velino, and Adolfo C. Fantoni. "High resolution microwave spectrum and torsional potential energy surfaces oftrans-crotyl alcohol." Molecular Physics 61, no. 5 (1987): 1269–82. http://dx.doi.org/10.1080/00268978700101781.

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18

Davies, Lucinda J., Paul McMorn, Donald Bethell та ін. "Oxidation of crotyl alcohol using Ti-β and Ti-MCM-41 catalysts". Journal of Molecular Catalysis A: Chemical 165, № 1-2 (2001): 243–47. http://dx.doi.org/10.1016/s1381-1169(00)00430-1.

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19

Nagase, Yoshinori, Hideaki Muramatu, and Takuzi Sato. "Selective Hydrogenation of Crotonaldehyde to Crotyl Alcohol on Ag-MnO2/Al2O3·5AlPO4Catalysts." Chemistry Letters 17, no. 10 (1988): 1695–98. http://dx.doi.org/10.1246/cl.1988.1695.

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20

Bailie, Jillian E., and Graham J. Hutchings. "Promotion by sulfur of gold catalysts for crotyl alcohol formation from crotonaldehyde hydrogenation." Chemical Communications, no. 21 (1999): 2151–52. http://dx.doi.org/10.1039/a906538e.

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21

Şahın, M., and S. Bılgıç. "The effect of crotyl alcohol on the corrosion of austenitic chromium–nickel steel." Applied Surface Science 147, no. 1-4 (1999): 27–32. http://dx.doi.org/10.1016/s0169-4332(98)00374-2.

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22

Ting, Louisa Rui Lin, Yujie Peng, and Boon Siang Yeo. "Mechanistic Insights into the Selective Electroreduction of Crotonaldehyde to Crotyl Alcohol and 1‐Butanol." ChemSusChem 14, no. 14 (2021): 2963–71. http://dx.doi.org/10.1002/cssc.202100513.

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23

Lee, Adam F., James N. Naughton, Zhi Liu, and Karen Wilson. "High-Pressure XPS of Crotyl Alcohol Selective Oxidation over Metallic and Oxidized Pd(111)." ACS Catalysis 2, no. 11 (2012): 2235–41. http://dx.doi.org/10.1021/cs300450y.

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24

Sreelatha, Gantla, Mulakaluri Prasada Rao, Bangalore Sethuram, and Tangeda Navaneeth Rao. "Kinetics and mechanism of oxidation of allyl, crotyl and cinnamyl alcohol by chromium(V)." Transition Metal Chemistry 15, no. 1 (1990): 31–33. http://dx.doi.org/10.1007/bf01032227.

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25

Lochař, Václav, and Lucie Smoláková. "Selective oxidation of crotyl alcohol and crotonaldehyde on V2O5/MgO: In situ FTIR study." Reaction Kinetics and Catalysis Letters 96, no. 1 (2009): 117–23. http://dx.doi.org/10.1007/s11144-009-5402-2.

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26

MIURA, Hiroshi, Kazuyuki ICHIOKA, Masao SAITO, Joji WATANABE, and Tsuneo MATSUDA. "Synthesis of Crotyl Alcohol by the Selective Hydrogenation of Crotonaldehyde over Alumina-supported Bimetallic Catalysts." NIPPON KAGAKU KAISHI, no. 5 (1994): 487–89. http://dx.doi.org/10.1246/nikkashi.1994.487.

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27

Yu, Lingyiming, Enggah Kurniawan, Tomohiro Ozawa, Hirokazu Kobayashi, Yasuhiro Yamada, and Satoshi Sato. "Catalytic dehydration of crotyl alcohol into 1,3-butadiene over silica-supported metal oxides: Mechanistic features." Molecular Catalysis 537 (February 2023): 112939. http://dx.doi.org/10.1016/j.mcat.2023.112939.

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28

Dorn, Viviana, Emilio Lorenzo Martínez, and Gabriel Radivoy. "Applications of Computational and NMR Methodologies to the Study of Homoallylic Alcohols Diastereomers." Proceedings 9, no. 1 (2018): 12. http://dx.doi.org/10.3390/ecsoc-22-05782.

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Through reducing the system InCl3-Li-DTBB(cat.) in THF at room temperature and in the absence of any additives or anti-caking ligand, we have synthesized indium nanoparticles (InNPs) of about 4 nm. The catalyst was employed in the allylation of carbonyl compounds, giving excellent yields of the corresponding homoallylic alcohols. We have established that the reaction products come from a γ-coupling via a six members cyclic transition state, type Zimmerman–Traxler. Relative to the selectivity, the allylation with crotyl bromide of ortho substituted benzaldehydes (e.g., o-NO2, o-OMe, o-Cl, o-CF3

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29

SEGAWA, Atsushi, Tatsuya ICHIJO, Nobuhiro KIMURA, Keisuke TSURUTA, Naohiro YOSHIDA, and Masaki OKAMOTO. "1,3-Butadiene Production by Crotyl Alcohol Dehydration over Solid Acids and Catalyst Deactivation by Water Adsorption." Journal of the Japan Petroleum Institute 63, no. 2 (2020): 70–78. http://dx.doi.org/10.1627/jpi.63.70.

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30

Tamura, Masazumi, Kensuke Tokonami, Yoshinao Nakagawa, and Keiichi Tomishige. "Selective Hydrogenation of Crotonaldehyde to Crotyl Alcohol over Metal Oxide Modified Ir Catalysts and Mechanistic Insight." ACS Catalysis 6, no. 6 (2016): 3600–3609. http://dx.doi.org/10.1021/acscatal.6b00400.

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31

Tamura, Masazumi, Kensuke Tokonami, Yoshinao Nakagawa, and Keiichi Tomishige. "Effective NbOx-Modified Ir/SiO2 Catalyst for Selective Gas-Phase Hydrogenation of Crotonaldehyde to Crotyl Alcohol." ACS Sustainable Chemistry & Engineering 5, no. 5 (2017): 3685–97. http://dx.doi.org/10.1021/acssuschemeng.6b03060.

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32

Quadrelli, Paolo, Serena Carosso, Misal Memeo, Bruna Bovio, Elena Valletta, and Beatrice Macchi. "N,O-Nucleosides from Ene Reaction of (Nitrosocarbonyl)mesitylene with Crotyl Alcohol: Selectivity, Scope, and Limitations." Synthesis 49, no. 09 (2017): 1972–82. http://dx.doi.org/10.1055/s-0036-1588695.

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33

Lee, Adam F., Simon F. J. Hackett, Graham J. Hutchings, Silvano Lizzit, James Naughton, and Karen Wilson. "In situ X-ray studies of crotyl alcohol selective oxidation over Au/Pd(111) surface alloys." Catalysis Today 145, no. 3-4 (2009): 251–57. http://dx.doi.org/10.1016/j.cattod.2008.10.034.

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34

Valueva, S. V., M. E. Vylegzhanina, K. A. Mitusova, et al. "Silver-Containing Nanodispersions Based on the Water-Soluble Copolymer of N-Vinylpyrrolidone with Sodium N-Crotyl-4-aminosalicylate and Crotyl Alcohol: Synthesis and Spectroscopic, Structural, and Morphological Characteristics." Russian Journal of Applied Chemistry 94, no. 3 (2021): 294–302. http://dx.doi.org/10.1134/s1070427221030046.

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35

Wang, D., F. Ammari, R. Touroude, D. S. Su, and R. Schlögl. "Promotion effect in Pt–ZnO catalysts for selective hydrogenation of crotonaldehyde to crotyl alcohol: A structural investigation." Catalysis Today 147, no. 3-4 (2009): 224–30. http://dx.doi.org/10.1016/j.cattod.2008.10.018.

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36

Davies, Lucinda J., Paul McMorn, Donald Bethell, et al. "Epoxidation of Crotyl Alcohol Using Ti-Containing Heterogeneous Catalysts: Comments on the Loss of Ti by Leaching." Journal of Catalysis 198, no. 2 (2001): 319–27. http://dx.doi.org/10.1006/jcat.2000.3139.

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37

Sharma, Priyamvada, Riya Sailani, Anita Meena, and C. L. Khandelwal. "Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium." International Journal of Chemical Kinetics 50, no. 5 (2018): 335–42. http://dx.doi.org/10.1002/kin.21162.

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38

MIURA, H., M. SAITO, J. WATANABE, K. ICHIOKA, and T. MATSUDA. "ChemInform Abstract: Synthesis of Crotyl Alcohol by the Selective Hydrogenation of Crotonaldehyde Over Alumina-Supported Bimetallic Catalysts." ChemInform 25, no. 38 (2010): no. http://dx.doi.org/10.1002/chin.199438105.

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39

Jia, Aiping, Hantao Peng, Yunshang Zhang, et al. "The Roles of Precursor-Induced Metal–Support Interaction on the Selective Hydrogenation of Crotonaldehyde over Ir/TiO2 Catalysts." Catalysts 11, no. 10 (2021): 1216. http://dx.doi.org/10.3390/catal11101216.

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Various supported Ir/TiO2 catalysts were prepared using different Ir precursors (i.e., H2IrCl6, (NH4)2IrCl6 and Ir(acac)3) and tested for vapor phase selective hydrogenation of crotonaldehyde. The choice of Ir precursor significantly altered the Ir-TiOx interaction in the catalyst, which thus had essential influences on the geometric and electronic properties of the Ir species, reducibility, and surface acidity, and, consequently, their reaction behaviors. The Ir/TiO2-N catalyst using (NH4)2IrCl6 as the precursor gave the highest initial reaction rates and turnover frequencies of crotyl alcoho

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40

Delgado, Blanco, Vesna Krstic, Pesquera Gonzalez, and González Martinez. "Modified clays, PILC’s, applied in catalysis." Chemical Industry 65, no. 1 (2011): 37–42. http://dx.doi.org/10.2298/hemind100906066d.

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In this work, the capability of new materials PILC?s synthesized from montmorillonite as support for catalysts based on Rh or Sn promoted Rh has been studied. Rh based catalysts were synthesized by hydrogen reduction at atmospheric pressure for a cationic organo-metallic rhodium complex. The influence of the supports in the incorporation of the active phase has been studied. The catalysts have been tested in the hydrogenation of crotonaldehyde in the vapor phase at atmospheric pressure, analyzing the effect of some working parameters in the formation of the reaction products, namely the temper

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41

INOUE, Hiroshi, Takeshi ITO, and Chiaki IWAKURA. "Control of Product Distribution in the Hydrogenation of Crotonaldehyde, Butyraldehyde and Crotyl Alcohol Using the Successive Hydrogenation System." Electrochemistry 69, no. 9 (2001): 699–701. http://dx.doi.org/10.5796/electrochemistry.69.699.

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42

Yang, Qiu-Yun, Yuan Zhu, Li Tian, et al. "Preparation and characterization of Au-In/APTMS-SBA-15 catalysts for chemoselective hydrogenation of crotonaldehyde to crotyl alcohol." Applied Catalysis A: General 369, no. 1-2 (2009): 67–76. http://dx.doi.org/10.1016/j.apcata.2009.08.032.

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43

Pei, Yan, Jianqiang Wang, Qiang Fu, et al. "A non-noble amorphous Co–Fe–B catalyst highly selective in liquid phase hydrogenation of crotonaldehyde to crotyl alcohol." New Journal of Chemistry 29, no. 8 (2005): 992. http://dx.doi.org/10.1039/b505701a.

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44

Naughton, James, Andrew Pratt, Charles W. Woffinden, et al. "Metastable De-excitation Spectroscopy and Density Functional Theory Study of the Selective Oxidation of Crotyl Alcohol over Pd(111)." Journal of Physical Chemistry C 115, no. 51 (2011): 25290–97. http://dx.doi.org/10.1021/jp205340z.

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45

Kerton, Owain J., Paul McMorn, Donald Bethell, et al. "Effect of structure of the redox molecular sieve TS-1 on the oxidation of phenol, crotyl alcohol and norbornylene." Physical Chemistry Chemical Physics 7, no. 13 (2005): 2671. http://dx.doi.org/10.1039/b503241e.

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46

Lee, Adam F., Christine V. Ellis, Karen Wilson, and Nicole S. Hondow. "In situ studies of titania-supported Au shell–Pd core nanoparticles for the selective aerobic oxidation of crotyl alcohol." Catalysis Today 157, no. 1-4 (2010): 243–49. http://dx.doi.org/10.1016/j.cattod.2010.04.032.

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47

COLOMA, F., A. SEPULVEDAESCRIBANO, and F. RODRIGUEZREINOSO. "Improvement of the selectivity to crotyl alcohol in the gas-phase hydrogenation of crotonaldehyde over platinum/activated carbon catalysts." Applied Catalysis A: General 123, no. 1 (1995): L1—L5. http://dx.doi.org/10.1016/0926-860x(94)00281-9.

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48

Gaskell, Christine V., Christopher M. A. Parlett, Mark A. Newton, Karen Wilson, and Adam F. Lee. "Redox-Controlled Crotyl Alcohol Selective Oxidation: In Situ Oxidation and Reduction Dynamics of Catalytic Pd Nanoparticles via Synchronous XANES/MS." ACS Catalysis 2, no. 11 (2012): 2242–46. http://dx.doi.org/10.1021/cs300445y.

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49

Fontaine, Frank R., Rachael A. Dunlop, Dennis R. Petersen, and Philip C. Burcham. "Oxidative Bioactivation of Crotyl Alcohol to the Toxic Endogenous Aldehyde Crotonaldehyde: Association of Protein Carbonylation with Toxicity in Mouse Hepatocytes." Chemical Research in Toxicology 15, no. 8 (2002): 1051–58. http://dx.doi.org/10.1021/tx0255119.

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50

GRICE, S. C., W. R. FLAVELL, A. G. THOMAS, et al. "ELECTRONIC STRUCTURE AND REACTIVITY OF TM-DOPED La1-xSrxCoO3 (TM = Ni, Fe) CATALYSTS." Surface Review and Letters 09, no. 01 (2002): 277–83. http://dx.doi.org/10.1142/s0218625x02002191.

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The catalytic properties of LaCoO 3 in the oxidation of organic molecules in aqueous solution are explored as a function of doping with both Sr substitution for La and Fe and Ni substitution for Co. VUV photoemission is used to explore the surface reactivity of the ceramic catalysts in aqueous solution, using H 2 O as a probe molecule. These measurements are complemented by EXAFS and XANES measurements designed to probe the local defect structure and by GC measurements of catalytic activity in the aqueous epoxidation of crotyl alcohol. We relate the observed catalytic activity to the defect st

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