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1

Liu, Nianqiao, Ruijia Sun, Liangling Wang, et al. "Unexpected red emission from Cs4PbI6 nanocrystals." Journal of Materials Chemistry A 8, no. 12 (2020): 5952–58. http://dx.doi.org/10.1039/d0ta00211a.

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The red emission of Cs<sub>4</sub>PbI<sub>6</sub> zero-dimensional perovskite is found heterogeneous between individual particles, yet exhibits an enhanced stability towards both anion exchange reaction and photo radiation than CsPbI<sub>3</sub>.
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2

Kondo, S., A. Masaki, T. Saito, and H. Asada. "Fundamental optical absorption of CsPbI3 and Cs4PbI6." Solid State Communications 124, no. 5-6 (2002): 211–14. http://dx.doi.org/10.1016/s0038-1098(02)00432-5.

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3

Bhaumik, Saikat, Annalisa Bruno, and Subodh Mhaisalkar. "Broadband emission from zero-dimensional Cs4PbI6 perovskite nanocrystals." RSC Advances 10, no. 23 (2020): 13431–36. http://dx.doi.org/10.1039/d0ra00467g.

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The broadband white light emission is realized in zero dimensional (OD) Cs<sub>4</sub>PbI<sub>6</sub> nanocrystals at low temperatures. The white light emission originates from recombination of both self-trapped excitons and defect state trapped excitons.
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4

Yunakova, O. N. "Influence of impurities on the absorption spectrum of thin Cs4PbI6 films." Functional materials 21, no. 3 (2014): 313–17. http://dx.doi.org/10.15407/fm21.03.313.

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5

Yunakova, O. N., V. K. Miloslavskii, and E. N. Kovalenko. "Exciton absorption spectrum of thin CsPbI3 and Cs4PbI6 films." Optics and Spectroscopy 112, no. 1 (2012): 91–96. http://dx.doi.org/10.1134/s0030400x12010249.

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6

Babin, V., P. Fabeni, M. Nikl, K. Nitsch, G. P. Pazzi, and S. Zazubovich. "Luminescent CsPbI3 and Cs4PbI6 Aggregates in Annealed CsI:Pb Crystals." physica status solidi (b) 226, no. 2 (2001): 419–28. http://dx.doi.org/10.1002/1521-3951(200108)226:2<419::aid-pssb419>3.0.co;2-c.

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7

Bao, Zhen, Chiao-Yin Hsiu, Mu-Huai Fang, et al. "Formation and Near-Infrared Emission of CsPbI3 Nanoparticles Embedded in Cs4PbI6 Crystals." ACS Applied Materials & Interfaces 13, no. 29 (2021): 34742–51. http://dx.doi.org/10.1021/acsami.1c08920.

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8

Satta, Jessica, Alberto Casu, Daniele Chiriu, Carlo Maria Carbonaro, Luigi Stagi, and Pier Carlo Ricci. "Formation Mechanisms and Phase Stability of Solid-State Grown CsPbI3 Perovskites." Nanomaterials 11, no. 7 (2021): 1823. http://dx.doi.org/10.3390/nano11071823.

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CsPbI3 inorganic perovskite is synthesized by a solvent-free, solid-state reaction, and its structural and optical properties can be deeply investigated using a multi-technique approach. X-ray Diffraction (XRD) and Raman measurements, optical absorption, steady-time and time-resolved luminescence, as well as High-Resolution Transmission Electron Microscopy (HRTEM) imaging, were exploited to understand phase evolution as a function of synthesis time length. Nanoparticles with multiple, well-defined crystalline domains of different crystalline phases were observed, usually surrounded by a thin,
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9

M�ller, Ulrich, Kirsten Bernet, and Rudolf Hoppe. "Korrektur zur Kristallstruktur von ?Cs4PbO3? und die Strukturverwandtschaft zwischen den Modifikationen von Cs4PbO4." Zeitschrift f�r anorganische und allgemeine Chemie 612, no. 6 (1992): 143–48. http://dx.doi.org/10.1002/zaac.19926120124.

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10

Ding, Huafeng, Yansu Shan, Jizhou Wang, et al. "Revealing photoluminescence mechanisms of single CsPbBr3/Cs4PbBr6 core/shell perovskite nanocrystals." RSC Advances 11, no. 48 (2021): 30465–71. http://dx.doi.org/10.1039/d1ra04981j.

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CsPbBr3/Cs4PbBr6 core/shell perovskite NCs were prepared with a cubic shape. The core CsPbBr3 are coated by a Cs4PbBr6 shell. The XRD, absorption spectra and PLE spectra were different from the simple mixtures of CsPbBr3 and Cs4PbBr6 in bulk.
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11

Děcká, Kateřina, Adéla Suchá, Jan Král, et al. "On the Role of Cs4PbBr6 Phase in the Luminescence Performance of Bright CsPbBr3 Nanocrystals." Nanomaterials 11, no. 8 (2021): 1935. http://dx.doi.org/10.3390/nano11081935.

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CsPbBr3 nanocrystals have been identified as a highly promising material for various optoelectronic applications. However, they tend to coexist with Cs4PbBr6 phase when the reaction conditions are not controlled carefully. It is therefore imperative to understand how the presence of this phase affects the luminescence performance of CsPbBr3 nanocrystals. We synthesized a mixed CsPbBr3-Cs4PbBr6 sample, and compared its photo- and radioluminescence properties, including timing characteristics, to the performance of pure CsPbBr3 nanocrystals. The possibility of energy transfer between the two pha
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12

MUELLER, U., K. BERNET, and R. HOPPE. "ChemInform Abstract: Correction of the Crystal Structure of “Cs4PbO3” and the Structural Relationship Between the Modifications of Cs4PbO4." ChemInform 23, no. 36 (2010): no. http://dx.doi.org/10.1002/chin.199236006.

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13

Rao, Longshi, Xinrui Ding, Xuewei Du, et al. "Ultrasonication-assisted synthesis of CsPbBr3 and Cs4PbBr6 perovskite nanocrystals and their reversible transformation." Beilstein Journal of Nanotechnology 10 (March 6, 2019): 666–76. http://dx.doi.org/10.3762/bjnano.10.66.

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We demonstrate an ultrasonication-assisted synthesis without polar solvent of CsPbBr3 and Cs4PbBr6 perovskite nanocrystals (PNCs) and their reversible transformation. The as-prepared CsPbBr3 PNCs and Cs4PbBr6 PNCs exhibit different optical properties that depend on their morphology, size, and structure. The photoluminescence (PL) emission and quantum yield (QY) of the CsPbBr3 PNCs can be tuned by changing the ultrasound power, radiation time, and the height of the vibrating spear. The optimized CsPbBr3 PNCs show a good stability and high PL QY of up to 85%. In addition, the phase transformatio
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14

La Porta, Felipe A., and Sofia Masi. "Solvent-Mediated Structural Evolution Mechanism from Cs4PbBr6 to CsPbBr3 Crystals." Nanomanufacturing 1, no. 2 (2021): 67–74. http://dx.doi.org/10.3390/nanomanufacturing1020007.

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The study of the solvent-mediated structural evolution mechanism of the Cs4PbBr6 powders prepared using the solvothermal method is presented. The Cs4PbBr6 powders with a rhombohedral structure and an intense green emission (i.e., mainly due to the presence of complex defect states in the forbidden gap), which is stable in its solid-state form, but a distinct behavior is observed in different dispersions, easily detectable when irradiated with ultraviolet (UV) light. Depending on the polarity of the solvent, a change in the emission color from green to red is observed, easily detectable when ir
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15

Li, Zongtao, Cunjiang Song, Longshi Rao, et al. "Synthesis of Highly Photoluminescent All-Inorganic CsPbX3 Nanocrystals via Interfacial Anion Exchange Reactions." Nanomaterials 9, no. 9 (2019): 1296. http://dx.doi.org/10.3390/nano9091296.

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All-inorganic cesium lead halide perovskite CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) have attracted significant attention owing to their fascinating electronic and optical properties. However, researchers still face challenges to achieve highly stable and photoluminescent CsPbX3 NCs at room temperature by the direct-synthesis method. Herein, we synthesize CsPbX3 NCs by a facile and environmentally friendly method, which uses an aqueous solution of metal halides to react with Cs4PbBr6 NCs via interfacial anion exchange reactions and without applying any pretreatment. This method produces monod
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16

Jia, Chao, Hui Li, Xianwei Meng, and Hongbo Li. "CsPbX3/Cs4PbX6 core/shell perovskite nanocrystals." Chemical Communications 54, no. 49 (2018): 6300–6303. http://dx.doi.org/10.1039/c8cc02802h.

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17

De Matteis, Fabio, Francesco Vitale, Simone Privitera, et al. "Optical Characterization of Cesium Lead Bromide Perovskites." Crystals 9, no. 6 (2019): 280. http://dx.doi.org/10.3390/cryst9060280.

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CsPbBr3 and Cs4PbBr6 perovskite powders have been synthesized through a relatively simple low-temperature and low-cost method. Nanocrystalline films have also been deposited from solutions with four different molar compositions of binary salt precursors. Optical absorption, emission and excitation spectra have been performed in the UV-visible spectral range while X-ray diffraction (XRD) has been recorded to characterize the nanocrystal morphology for the different molar compositions. A preferential orientation of crystallites along the (024) crystalline plane has been observed as a function of
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18

Yunakova, O. N. "Exciton absorption spectrum of Cs4PbCl6 thin films." Functional materials 22, no. 2 (2015): 175–80. http://dx.doi.org/10.15407/fm22.02.175.

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19

Billstrand, Brian, Kaifu Bian, Casey Karler, Dongmei Ye, Austin Hwang, and Hongyou Fan. "Solution Based Synthesis of Cs4PbBr6 Perovskite Particles with High Luminescence and Stability." MRS Advances 3, no. 45-46 (2018): 2825–31. http://dx.doi.org/10.1557/adv.2018.308.

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ABSTRACTLow dimensional lead halide perovskite particles are of tremendous interest due to their size-tunable band gaps, low exciton binding energy, high absorption coefficients, outstanding quantum and photovoltaic efficiencies. Herein we report a new solution-based synthesis of stabilized Cs4PbBr6 perovskite particles with high luminescence. This method requires only mild conditions and produces colloidal particles that are ideal for highly efficient solution-based device fabrications. The synthesized microstructures not only display outstanding luminescence quantum yield but also long term
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20

Zhang, Yuhai, Makhsud I. Saidaminov, Ibrahim Dursun, et al. "Zero-Dimensional Cs4PbBr6 Perovskite Nanocrystals." Journal of Physical Chemistry Letters 8, no. 5 (2017): 961–65. http://dx.doi.org/10.1021/acs.jpclett.7b00105.

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21

Kondo, S., K. Amaya, S. Higuchi, T. Saito, H. Asada, and M. Ishikane. "Fundamental optical absorption of Cs4PbCl6." Solid State Communications 120, no. 4 (2001): 141–44. http://dx.doi.org/10.1016/s0038-1098(01)00363-5.

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22

Kondo, S., K. Amaya, and T. Saito. "Localized optical absorption in Cs4PbBr6." Journal of Physics: Condensed Matter 14, no. 8 (2002): 2093–99. http://dx.doi.org/10.1088/0953-8984/14/8/334.

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23

Zhang, Lei, and Xiaoxue Zhang. "Aggregation of molecular halide perovskite Cs4PbX6: A first-principles investigation." Chemical Physics Letters 732 (October 2019): 136653. http://dx.doi.org/10.1016/j.cplett.2019.136653.

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24

Yuan, Ye, Qing Yao, Jie Zhang, et al. "Negative photoconductivity in Cs4PbBr6 single crystal." Physical Chemistry Chemical Physics 22, no. 25 (2020): 14276–83. http://dx.doi.org/10.1039/d0cp02004d.

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Negative photoconductivity is firstly observed in large size Cs<sub>4</sub>PbBr<sub>6</sub> single crystal that grown from Cs-rich solution. The Br vacancy and free excitons are responsible for this novel phenomena.
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25

Bae, Hyeongyu, Dongcheol Park, Eunsang Lee, Hohjai Lee, and Kang Taek Lee. "Re-cyclic photophysics in perovskite Cs4PbBr6." Applied Physics Letters 119, no. 1 (2021): 011101. http://dx.doi.org/10.1063/5.0053583.

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26

Al-Asbahi, Bandar Ali, Saif M. H. Qaid, and Abdullah S. Aldwayyan. "Effect of Donor-Acceptor Concentration Ratios on Non-Radiative Energy Transfer in Zero-Dimensional Cs4PbBr6 Perovskite/MEH-PPV Nanocomposite Thin Films." Polymers 12, no. 2 (2020): 444. http://dx.doi.org/10.3390/polym12020444.

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Composite materials with different concentration ratios of a hybrid of zero-dimensional (0-D) Cs4PbBr6 perovskite, which acts as a donor (D), and poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), which acts as an acceptor (A), were successfully prepared via a solution blending method prior to being deposited onto glass substrates by a spin-coating technique. The influence of acceptor content on the structural, optical, and energy transfer properties of the donor was investigated. The perovskite nanocrystals formed thin films without any chemical interactions within a matrix
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27

Zhang, Jing, Li Wang, Wenwen Liu, et al. "Synthesis of Au or Pt@Perovskite Nanocrystals via Interfacial Photoreduction." Catalysts 11, no. 2 (2021): 174. http://dx.doi.org/10.3390/catal11020174.

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The surface modification of perovskite nanocrystals (NCs) (i.e., their decoration with noble metals) holds great promise with respect to the tailoring of their properties but has remained a challenge because perovskite NCs are extremely sensitive to water and alcohols. In this study, Au or Pt@CsPbBr3 NCs were successfully synthesized by photoreduction at the water/hexane interface. First, Cs4PbBr6 NCs were synthesized through the hot-injection method. Then, Cs4PbBr6 was transformed into CsPbBr3 and subjected to noble metal modification, both at the interface. The synthesized CsPbBr3 NCs exhibi
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28

Bhaumik, Saikat. "Exciton Relaxation Dynamics in Perovskite Cs4PbBr6 Nanocrystals." ACS Omega 5, no. 35 (2020): 22299–304. http://dx.doi.org/10.1021/acsomega.0c02655.

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29

Wang, Liangling, Hong Liu, Yuhai Zhang, and Omar F. Mohammed. "Photoluminescence Origin of Zero-Dimensional Cs4PbBr6 Perovskite." ACS Energy Letters 5, no. 1 (2019): 87–99. http://dx.doi.org/10.1021/acsenergylett.9b02275.

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30

Nikl, M., E. Mihokova, K. Nitsch, et al. "Photoluminescence of Cs4PbBr6 crystals and thin films." Chemical Physics Letters 306, no. 5-6 (1999): 280–84. http://dx.doi.org/10.1016/s0009-2614(99)00477-7.

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31

Li, Yanxiu, He Huang, Yuan Xiong, Stephen V. Kershaw, and Andrey L. Rogach. "Reversible transformation between CsPbBr3 and Cs4PbBr6 nanocrystals." CrystEngComm 20, no. 34 (2018): 4900–4904. http://dx.doi.org/10.1039/c8ce00911b.

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32

Velázquez, Matias, Alban Ferrier, Stanislas Péchev, et al. "Luminescence properties of Pr3+-doped Cs4PbBr6 single crystals." Physics Procedia 2, no. 2 (2009): 407–9. http://dx.doi.org/10.1016/j.phpro.2009.07.025.

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33

de Weerd, Chris, Junhao Lin, Leyre Gomez, Yasufumi Fujiwara, Kazutomo Suenaga, and Tom Gregorkiewicz. "Hybridization of Single Nanocrystals of Cs4PbBr6 and CsPbBr3." Journal of Physical Chemistry C 121, no. 35 (2017): 19490–96. http://dx.doi.org/10.1021/acs.jpcc.7b05752.

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34

Bao, Zhen, Yu-Jui Tseng, Wenwu You, et al. "Efficient Luminescence from CsPbBr3 Nanoparticles Embedded in Cs4PbBr6." Journal of Physical Chemistry Letters 11, no. 18 (2020): 7637–42. http://dx.doi.org/10.1021/acs.jpclett.0c02321.

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35

Cha, Ji-Hyun, Jae Hoon Han, Wenping Yin, et al. "Photoresponse of CsPbBr3 and Cs4PbBr6 Perovskite Single Crystals." Journal of Physical Chemistry Letters 8, no. 3 (2017): 565–70. http://dx.doi.org/10.1021/acs.jpclett.6b02763.

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36

Saidaminov, Makhsud I., Jawaher Almutlaq, Smritakshi Sarmah, et al. "Pure Cs4PbBr6: Highly Luminescent Zero-Dimensional Perovskite Solids." ACS Energy Letters 1, no. 4 (2016): 840–45. http://dx.doi.org/10.1021/acsenergylett.6b00396.

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37

Zhang, Yuhai, Lutfan Sinatra, Erkki Alarousu, et al. "Ligand-Free Nanocrystals of Highly Emissive Cs4PbBr6 Perovskite." Journal of Physical Chemistry C 122, no. 11 (2018): 6493–98. http://dx.doi.org/10.1021/acs.jpcc.8b01735.

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38

Gan, Zhixing, Fei Zheng, Wenxin Mao, et al. "The optical properties of Cs4PbBr6–CsPbBr3 perovskite composites." Nanoscale 11, no. 31 (2019): 14676–83. http://dx.doi.org/10.1039/c9nr04787e.

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39

Su, Sijing, Jialin Shen, Haochen Sun, et al. "Shape-controlled synthesis of Ag/Cs4PbBr6 Janus nanoparticles." Nanotechnology 32, no. 7 (2020): 075601. http://dx.doi.org/10.1088/1361-6528/abb905.

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40

Peng, Xiaogai, Jin Chen, Fengchao Wang, Canyun Zhang, and Bobo Yang. "One-pot synthesis of CsPbBr3/Cs4PbBr6 perovskite composite." Optik 208 (April 2020): 164579. http://dx.doi.org/10.1016/j.ijleo.2020.164579.

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41

Nikl, M., E. Mihokova, and K. Nitsch. "Photoluminescence & decay kinetics of Cs4PbCl6 single crystals." Solid State Communications 84, no. 12 (1992): 1089–92. http://dx.doi.org/10.1016/0038-1098(92)90691-2.

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42

De Bastiani, Michele, Ibrahim Dursun, Yuhai Zhang, et al. "Inside Perovskites: Quantum Luminescence from Bulk Cs4PbBr6 Single Crystals." Chemistry of Materials 29, no. 17 (2017): 7108–13. http://dx.doi.org/10.1021/acs.chemmater.7b02415.

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43

Yin, Jun, Yuhai Zhang, Annalisa Bruno, et al. "Intrinsic Lead Ion Emissions in Zero-Dimensional Cs4PbBr6 Nanocrystals." ACS Energy Letters 2, no. 12 (2017): 2805–11. http://dx.doi.org/10.1021/acsenergylett.7b01026.

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44

Cha, Ji-Hyun, Hyun-Jong Lee, Sun Ha Kim, et al. "Superparamagnetism of Green Emissive Cs4PbBr6 Zero-Dimensional Perovskite Crystals." ACS Energy Letters 5, no. 7 (2020): 2208–16. http://dx.doi.org/10.1021/acsenergylett.0c00964.

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45

Hui, Juan, Yingnan Jiang, Ömür Ö. Gökçinar, et al. "Unveiling the Two-Step Formation Pathway of Cs4PbBr6 Nanocrystals." Chemistry of Materials 32, no. 11 (2020): 4574–83. http://dx.doi.org/10.1021/acs.chemmater.0c00661.

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46

Kang, Byungkyun, and Koushik Biswas. "Exploring Polaronic, Excitonic Structures and Luminescence in Cs4PbBr6/CsPbBr3." Journal of Physical Chemistry Letters 9, no. 4 (2018): 830–36. http://dx.doi.org/10.1021/acs.jpclett.7b03333.

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47

Jung, Young-Kwang, Joaquín Calbo, Ji-Sang Park, Lucy D. Whalley, Sunghyun Kim, and Aron Walsh. "Intrinsic doping limit and defect-assisted luminescence in Cs4PbBr6." Journal of Materials Chemistry A 7, no. 35 (2019): 20254–61. http://dx.doi.org/10.1039/c9ta06874k.

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48

Zhang, Qiao, and Yadong Yin. "Strong photoluminescence of Cs4PbBr6 crystals: a long mystery story." Science Bulletin 63, no. 9 (2018): 525–26. http://dx.doi.org/10.1016/j.scib.2018.04.015.

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49

Xuan, Tongtong, Sunqi Lou, Junjian Huang, et al. "Monodisperse and brightly luminescent CsPbBr3/Cs4PbBr6 perovskite composite nanocrystals." Nanoscale 10, no. 21 (2018): 9840–44. http://dx.doi.org/10.1039/c8nr01266k.

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50

Yu, Xiaoya, Linzhong Wu, Huicheng Hu, et al. "Cs4PbX6 (X = Cl, Br, I) Nanocrystals: Preparation, Water-Triggered Transformation Behavior, and Anti-Counterfeiting Application." Langmuir 34, no. 35 (2018): 10363–70. http://dx.doi.org/10.1021/acs.langmuir.8b01683.

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