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1

Xu, Bin, Yan-Yan Zhang, Wen-Long Liu, and Xiao-Ya Hu. "Hexaaquanickel(II) bis{[N-(2-hydroxybenzylidene)alanylglycinato]cuprate(II)} dodecahydrate." Acta Crystallographica Section E Structure Reports Online 62, no. 7 (2006): m1508—m1509. http://dx.doi.org/10.1107/s1600536806021179.

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The crystal structure of the title compound, [Ni(H2O)6][Cu(C12H11N2O4)]2·12H2O, consists of CuII complex anions, NiII complex cations and solvent water molecules. The CuII ion is located on a general position and coordinated by a Schiff base ligand with a square-planar CuN2O2 geometry. The NiII ion is located on an inversion center and coordinated by six water molecules in an octahedral geometry.
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2

Li, Hongdao, Jiao Lu, Jing Xie, Pei Jing, and Licun Li. "Two-Dimensional Nitronyl Nitroxide–Cu Networks Based on Multi-Dentate Nitronyl Nitroxides: Structures and Magnetic Properties." Magnetochemistry 7, no. 5 (2021): 73. http://dx.doi.org/10.3390/magnetochemistry7050073.

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Two multi-dentate nitronyl nitroxide radicals, namely, bisNITPhPy ([5-(4-pyridyl)-1,3-bis(1′-oxyl-3′-oxido-4′,4′,5′,5′-tetramethyl-4,5-hydro-1H-imidazol-2-yl)]benzene) and NIT-3Py-5-4Py (2-{3-[5-(4-pyridyl)]pyridyl}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide), were assembled with CuII ions to obtain two-dimensional heterospin 2p–3d coordination polymers [Cu7(hfac)14(bisNITPhPy)2]n (1) and [Cu2(hfac)4(NIT-3Py-5-4Py)]n (2) (hfac: hexafluoroacetylacetonate). In both compounds, the bisNITPhPy and NIT-3Py-5-3Py radicals acted as pentadentate and tetradentate ligands, respectively, to connect wit
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3

Montiel, Enrique, Julian Cruz, Narayanan Jayanthi, Sylvain Bernés, and Thangarasu Pandiyan. "Structural Changes in CuII Complexes of Potential Octadentate Ligands by Coordination with Carboxylate/Carboxylic Acid: DFT, TD-DFT, and Experimental Studies." Australian Journal of Chemistry 63, no. 6 (2010): 965. http://dx.doi.org/10.1071/ch09555.

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The structural and spectroscopic studies of N,N,N′,N′,N′-pentakis-(benzimidazol-2-yl-methyl)diethylenetriamine (L1) and N,N,N′,N′-tetrakis-(benzimidazol-2-yl-methyl)-N′-(carboxylmethyl)diethylenetriamine (L2H) and [CuL1]2+, [CuL2H]2+, and [CuL2]+ were carried out by density functional theory (DFT) and time-dependant (TD)-DFT techniques. The results show that a geometrical change occurs when carboxylate/carboxylic acid coordinates with the metal ion. For example, the ligand L2H forms an octahedral geometry with CuII and in the structure, four nitrogens (N3, N13, N44, N47) are equatorially coord
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4

D., K. Singh, Gupta R., and Singh Anuradha. "A new chelating resin selective for CuII and HgII." Journal of Indian Chemical Society Vol. 83, Aug 2006 (2006): 830–31. https://doi.org/10.5281/zenodo.5827822.

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Analytical Research Laboratory, Department of Chemistry, H. B. Technological Institute, Kanpllr-208 002, Uttar Pradesh. India <em>E-mail </em>: dhruvksl23@rediffmail.com <em>Manuscript received 29 November 2005. revised 8 May 2006, accepted 11 May 2006</em> A chelating resin based on catechol-formaldehyde copolymer containing &#39;oxime&#39; functional group has beensynthesized. Mercurv(II) and copper(II) were separated in presence of other metal ions with this resin.
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5

Goleva, Kateryna, Dina Naumova, Anna Pavlishchuk, Anthony W. Addison та Matthias Zeller. "Crystal structure of bis(pivaloylhydroxamato-κ2 O,O′)copper(II)". Acta Crystallographica Section E Crystallographic Communications 74, № 9 (2018): 1384–87. http://dx.doi.org/10.1107/s2056989018012227.

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Reaction of copper(II) nitrate with pivaloylhydroxamic acid yielded the title compound, [Cu(pivHA)2] (where pivHA− is pivaloyl hydroxamate, C5H10NO2). The centrosymmetric mononuclear complex consists of a CuII ion, which is located on a center of inversion, with two coordinated pivaloyl hydroxamate monoanions. The CuII ion has a square-planar coordination environment consisting of four O atoms – two carbonyl O atoms and two hydroxamate O atoms from two hydroxamate pivHA− ligands. The pivHA− anions are coordinated to copper(II) in a trans-mode, forming two five-membered O,O′-chelate rings.
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6

Choi, Jong-Ha, Keon Sang Ryoo та Ki-Min Park. "(5,16-Dimethyl-2,6,13,17-tetraazatricyclo[14.4.01,18.07,12]docosane-κ4 N)bis(perchlorato-κO)copper(II)". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2674—m2675. http://dx.doi.org/10.1107/s1600536807048039.

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In the title compound, [Cu(ClO4)2(C20H40N4)], the CuII ion has a tetragonally distorted octahedral environment, with the four N atoms of the macrocyclic ligand in equatorial positions and the O atoms of two perchlorate groups in axial positions. The CuII ion is situated on an inversion centre. The macrocyclic ligand adopts its most stable trans-III conformation. The long axial Cu—O bond is the result of the Jahn–Teller effect. The crystal structure is stabilized by intramolecular hydrogen bonds between secondary N—H and the O atoms of the perchlorate groups.
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7

Wang, Jiao, Guijian Liu, Tanfu Li, Chuncai Zhou, and Cuicui Qi. "Zero-Valent Iron Nanoparticles (NZVI) Supported by Kaolinite for CuII and NiII Ion Removal by Adsorption: Kinetics, Thermodynamics, and Mechanism." Australian Journal of Chemistry 68, no. 8 (2015): 1305. http://dx.doi.org/10.1071/ch14675.

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This research concerns the adsorption of CuII and NiII using zero-valent iron nanoparticles supported by kaolinite (nZVI-Kaolinite). The characterization studies indicated that the surface of kaolinite or the kaolinite fragments were filled with nZVI particles. The kinetics of CuII and NiII adsorption were evaluated for various contact times. The adsorption of CuII and NiII at different initial concentrations was examined by injecting 0.5 g of adsorbent to achieve equilibrium. The adsorption of CuII and NiII was a chemisorption process, which fitted well with the Freundlich and the Temkin isot
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8

Wang, Meixin, Zhaoliang Peng, Changming Zhang, et al. "Effect of Copper Precursors on the Activity and Hydrothermal Stability of CuII−SSZ−13 NH3−SCR Catalysts." Catalysts 9, no. 9 (2019): 781. http://dx.doi.org/10.3390/catal9090781.

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A series of CuII−SSZ−13 catalysts are prepared by in-situ hydrothermal method using different copper precursors (CuII(NO3)2, CuIISO4, CuIICl2) for selective catalytic reduction of NO by NH3 in a simulated diesel vehicle exhaust. The catalysts were characterized by X−ray diffraction (XRD), scanning electron microscope (SEM), X−ray photoelectron spectroscopy (XPS), N2 adsorption-desorption, hydrogen-temperature-programmed reduction (H2−TPR), ammonia temperature-programmed desorption (NH3−TPD), and 27Al and 29Si solid state Nuclear Magnetic Resonance (NMR). The CuII−SSZ−13 catalyst prepared by Cu
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9

Sun, Yin-Xia, Ying-Qi Pan, Xin Xu, and Yang Zhang. "Unprecedented Dinuclear CuII N,O-Donor Complex: Synthesis, Structural Characterization, Fluorescence Property, and Hirshfeld Analysis." Crystals 9, no. 12 (2019): 607. http://dx.doi.org/10.3390/cryst9120607.

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An unprecedented dinuclear CuII complex, [Cu2(L2)2], derived from a salamo-like chelating ligand H2L2, was produced by the cleavage of a newly synthesized, half-salamo-like ligand HL1 (2-[O-(1-ethyloxyamide)]oxime-3,5-dichloro-phenol). This was synthesized and characterized by elemental analyses, IR, UV–Vis and fluorescent spectra, single crystal X-ray diffraction analysis, and Hirshfeld surface analysis. X-ray crystallographic analysis indicated that the two CuII (Cu1 and Cu2) ions bore different (N2O3 and N2O2) coordination environments, the penta-coordinated Cu1 ion possessed a slightly twi
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10

Haketa, Yohei, and Hiromitsu Maeda. "Supramolecular Assemblies of Dipyrrolyldiketone CuII Complexes." Molecules 26, no. 4 (2021): 861. http://dx.doi.org/10.3390/molecules26040861.

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Dipyrrolyldiketones are essential building units of anion-responsive π-electronic molecules and ion-pairing assemblies. Here, we demonstrated that they form complexes with CuII characterized by planar geometries. The solid-state stacking assembled structures, as revealed by single-crystal X-ray analysis, were modulated by the substitution of pyrrole units. The rectangular shapes of the CuII complexes resulted in the formation of mesophases upon introduction of aliphatic chains.
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11

Balikungeri, Antoine. "Acid-Base Properties of 2-Morpholinoethanesulfonic Acid (MES), Complexation Reaction of Cu<sup>II</sup>-MES, and Interaction of Hydrous Manganese Oxide Surface with Cu<sup>II</sup> in MES Buffer." CHIMIA 43, no. 1-2 (1989): 13. https://doi.org/10.2533/chimia.1989.13.

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The acidity constants of 2-morpholinoethanesulfonic acid (MES) have been determined at various ionic strengths; pKa1 = 1.99 and pKa2 = 6.21 at ionic strength I = 0.1 M. The conditional stability constant of CuII-MES complex has been measured by means of a CuII-ion selective electrode: lg cKCu-MES = 1.39 ± 0.07 at pH = 5.57. Furthermore the interaction between CuII and hydrous manganese oxide surface in MES buffer was studied by differential pulse polarography. Conditional stability constants for CuII-MnOx complex (SCu) at three pH values were calculated by two methods: van den Berg-Ružić metho
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12

Stanković, Maja N., Nenad S. Krstić, Ian J. Slipper, et al. "Chemically Modified Lagenaria vulgaris as a Biosorbent for the Removal of CuII from Water." Australian Journal of Chemistry 66, no. 2 (2013): 227. http://dx.doi.org/10.1071/ch12422.

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The ability of a biosorbent based on a chemically modified Lagenaria vulgaris shell for CuII ion removal from aqueous solution was studied in batch conditions. The biosorbent was characterized by Fourier-transform infrared spectroscopy and the effect of relevant parameters such as contact time, pH, biomass dosage, and initial metal ion concentration was evaluated. The sorption process was found to be fast, attaining equilibrium within 40 min, and results were found to be best fitted by a pseudo-second order kinetic model. Experimental data showed that the biosorption is highly pH dependent, an
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13

Van Trieste III, Gerard P., Matthias Zeller та Curtis M. Zaleski. "Synthesis and crystal structure of a pentacopper(II) 12-metallacrown-4: cis-diaquatetrakis(dimethylformamide-κO)manganese(II) tetrakis(μ3-N,2-dioxidobenzene-1-carboximidate)pentacopper(II) dimethylformamide monosolvate". Acta Crystallographica Section E Crystallographic Communications 76, № 5 (2020): 747–51. http://dx.doi.org/10.1107/s2056989020005770.

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The title compound, [Mn(C3H7NO)4(H2O)2][Cu5(C7H4NO3)4]·C3H7NO or cis-[Mn(H2O)2(DMF)4]{Cu[12-MCCu(II)N(shi)-4]}·DMF, where MC is metallacrown, shi3− is salicylhydroximate, and DMF is N,N-dimethylformamide, crystallizes in the monoclinic space group P21/n. Two crystallographically independent metallacrown anions are present in the structure, and both anions exhibit minor main molecule disorder by an approximate (non-crystallographic) 180° rotation with occupancy ratios of 0.9010 (9) to 0.0990 (9) for one anion and 0.9497 (8) to 0.0503 (8) for the other. Each pentacopper(II) metallacrown contains
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14

Xie, Sida, Paul V. Bernhardt, Lawrence R. Gahan, and Craig M. Williams. "Contemplating 1,2,4-Thiadiazole-Inspired Cyclic Peptide Mimics: A Computational Investigation." Australian Journal of Chemistry 72, no. 11 (2019): 894. http://dx.doi.org/10.1071/ch19248.

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Marine derived cyclic peptides have inspired chemists for decades as the cavitand architecture can be compared with macrocyclic ligands, and hence easily conceived as mediators of metal-ion transport. Lissoclinamide 5 and ascidiacyclamide are two such cyclic peptides that have received much attention both for their metal ion complexation properties and biological activity; the metal ion binding properties of mimics of these two systems have been reported. Reported herein is a computational study aimed at evaluating the stability, and potential for copper(ii) ion binding by lissoclinamide 5 mim
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15

Thangavel, Kavipriya, Matthias Mendt, Bikash Garai, et al. "Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy." AIP Advances 13, no. 1 (2023): 015019. http://dx.doi.org/10.1063/9.0000532.

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EPR measurements at X- (9.5 GHz), Q- (34 GHz) and W-band (94 GHz) on paddlewheel (PW) type post-synthetic metal exchanged DUT-49(M,M): M- Zn, Mn, Cu MOFs are here reported (DUT–Dresden University of Technology). Temperature-dependent X-band measurements are recorded from T = 7 K to T = 170 K on monometallic DUT-49(Cu), DUT-49(Mn), and bimetallic DUT-49(Cu0.7Zn0.3), DUT-49(Cu0.5Mn0.5) MOFs. In the case of the CuII - CuII dimers in DUT-49(Cu), an isotropic exchange coupling of the metal ions (2 J = −240(11) cm−1) determined from the EPR intensity of the S = 1 spin state of the CuII–CuII dimers u
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16

Liu, Yang, Yong-Lan Feng та Dai-Zhi Kuang. "Triaqua-1κO,2κ2 O-bis(2,2′-bipyridine)-1κ2 N,N′;2κ2 N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2 O 1:O 4-dicopper(II) nitrate monohydrate". Acta Crystallographica Section E Structure Reports Online 68, № 6 (2012): m746—m747. http://dx.doi.org/10.1107/s1600536812019848.

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In the binuclear title compound, [Cu2(C8H4O4)Cl(C10H8N2)2(H2O)3]NO3·H2O, the two crystallographically independent CuII ions have similar coordination environments. One of the CuII ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine molecule, one carboxylate O atom from a terephthalate ligand and one O atom from a water molecule. The other CuII ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of
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17

Denisova, T. I., and D. I. Shvetz. "Modified Organosilica Adsorbents with Bactericidal Properties." Adsorption Science & Technology 20, no. 3 (2002): 285–93. http://dx.doi.org/10.1260/026361702760254469.

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The method of mathematical planning of experiments has been used to determine the optimal conditions for the formation of a two-component organosilica with various compositions modified by metal ions (CuII, ZnII) sorbed from their water–ammonia solutions. Through this method, modified forms of silico-polymethylsiloxanes (SG-PMS) containing 1–30 mg/g CuII ion [SG-PMS(Cu)] and 3–40 mg/g ZnII ion [SG-PMS(Zn)] were synthesized and their adsorption/structural characteristics established. The sorptive capacity of the organosilica sorbents and their modified forms towards pathogenic microflora ( E. c
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18

Wu, Hui-Lu, Xing-Ke Ma, Wei-Bing Lv, Peng Liu, and Ji-Gang Liu. "(4-Hydroxycinnamato)[tris(N-methylbenzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide hemisolvate." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (2007): m783—m784. http://dx.doi.org/10.1107/s1600536807006605.

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19

Mirzaei, Masoud, Hossein Eshtiagh-Hosseini, Azam Hassanpoor, and Victor Barba. "X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine." Journal of the Serbian Chemical Society 77, no. 1 (2012): 67–73. http://dx.doi.org/10.2298/jsc101115153m.

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The new 1D-coordination polymer of CuII ion, {(2- apymH)2[Cu(pyzdc)2] .6H2O}n, (2-apym = 2-aminopyrimidine, pyzdcH2 = 1,4- pyrazine-2,3-dicarboxylic acid), was synthesized based on proton transfer mechanism and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. The coordination polymer consists of infinite anionic chains of [Cu(pyzdc)2]2- anion bridged crossing double chain running along a-axis and discrete (2-apymH)+ fragment. The CuII ion is located on inversion centre in the basal plane of an elongated octahedron and two oxygen atoms from adjac
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20

Sulakshana, Bharti, Choudhary M., P. Rawat Sampat, et al. "Synthetic approach, characterization, superoxide dismutase and antimicrobial activities of imidazolate-bridged CuII-CuII, CuII-NiII and CuII-ZnII binuclear complexes with amino acid derived Schiff bases." Journal of Indian Chemical Society 93, Aug 2016 (2016): 953–64. https://doi.org/10.5281/zenodo.5594776.

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Department of Chemistry, National Institute of Technology, Patna-800 005, Bihar, India <em>E-mail </em>: mukesh@nitp.ac.in Department of Chemistry, Govt. V. P.G. College, Maihar-485 771, Madhya Pradesh, India Department of Chemistry, Govt. S. G. S. P.G. College, Sidhi-486 661, Madhya Pradesh, India Department of Zoology, Govt. U.G. College, Amarpatan-485 775, Madhya Pradesh, India Department of Chemistry, MRSC, University of Coimbra, Coimbra Portugal <em>Manuscript received online 18 March 2016, accepted 28 March 2016</em> Synthetic and characterization of several imidazolato-bridged binuclear
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21

Du, Zi-Yi, Yong-Rong Xie та He-Rui Wen. "Poly[aqua(μ2-4,4′-bipyridyl-κ2 N:N′)(μ2-3-phosphonatobenzenesulfonato-κ2 O:O′)copper(II)]". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2766—m2767. http://dx.doi.org/10.1107/s1600536807050763.

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The title polymer, [Cu(C6H5O6PS)(C10H8N2)(H2O)] n , was synthesized by a hydrothermal method. The CuII ion is five-coordinated by one phosphonate O atom, one sulfonate O atom, two N atoms of the bipyridyl ligand and one water molecule. The coordination geometry around the metal centre can be described as slightly distorted square-pyramidal. The CuII ions are connected by bidentate bridging phosphonato-benzenesulfonate ligands, forming one-dimensional helical chains along [010], which are further bridged by bidentate 4,4′-bipyridyl ligands, generating a two-dimensional layered crystal structure
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22

Cristóvão, Beata, Dariusz Osypiuk, and Barbara Mirosław. "The Crystal Structure and Physicochemical Properties of New Complexes Containing a CuII-LnIII-CuII Core." Crystals 14, no. 2 (2024): 189. http://dx.doi.org/10.3390/cryst14020189.

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Three new cationic complexes, [Cu4Tb2(H2L)4(NO3)4(H2O)3](NO3)2·5.5H2O·2MeOH (1), [Cu4Ho2(H2L)4(NO3)4(H2O)3](NO3)2·7.5H2O (2), and [Cu4Er2(H2 L)4(NO3)4(H2O)3](NO3)2·7H2O·3MeOH (3), were synthesized and studied using elemental and TG/DTG/DSC analyses, single-crystal X-ray diffraction, and magnetic measurements. The structure analysis showed that 1–3 crystallize as (NO3)-bridged compounds and that the lanthanide(III) ion acts as a joint connecting two [CuH2L] coordination units. In each heterotrinuclear unit, an asymmetry in the degree of planarity of the bridging CuO2Ln fragments is observed. Th
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23

Malinowska, Katarzyna, and Roman Modranka. "Dichlorido[(3,5-dimethyl-1H-pyrazol-1-yl)methane]copper(II)." Acta Crystallographica Section E Structure Reports Online 63, no. 11 (2007): m2782. http://dx.doi.org/10.1107/s1600536807048878.

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The title compound, [CuCl2(C11H16N4)], is isostructural with the previously characterized ZnII analogous complex. The CuII ion is four-coordinate in a CuCl2N2 distorted tetrahedral geometry. In the crystal structure, weak C—H...Cl interactions are observed.
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24

Chu, Xin, and Kou-Lin Zhang. "Preparation and characterization of two new CuII supramolecular coordination polymers incorporating sulfobenzoate and flexible heterocyclic ligands." Acta Crystallographica Section C Structural Chemistry 73, no. 12 (2017): 1087–97. http://dx.doi.org/10.1107/s2053229617014899.

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The assembly of CuII with the multifunctional ligand 2-amino-4-sulfobenzoic acid (H2asba) in the presence of the auxiliary flexible ligands 1,4-bis(triazol-1-ylmethyl)benzene (bbtz) and 1,4-bis(imidazol-1-ylmethyl)benzene (bix) under ambient conditions resulted in two new supramolecular coordination polymers, namely poly[[(3-amino-4-carboxybenzenesulfonato-κO)aquabis[μ2-1,4-bis(triazol-1-ylmethyl)benzene-κ2 N 4:N 4′]copper(II)] 3-amino-4-carboxybenzenesulfonate tetrahydrate], {[Cu(C7H6NO5S)(C12H12N6)2(H2O)](C7H6NO5S)·4H2O} n , (1), and poly[[bis(μ2-2-amino-4-sulfonatobenzoato-κ3 O 1:N,O 1′)tet
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25

Glaser, Thorsten, Maik Heidemeier, Erich Krickemeyer, and Hartmut Bögge. "Synthesis and Structural Characterization of a Monofunctionalized Phloroglucin-Derivative: A Precursor for Heterotrinuclear meta-Phenylene Bridged Complexes." Zeitschrift für Naturforschung B 61, no. 6 (2006): 753–57. http://dx.doi.org/10.1515/znb-2006-0616.

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As part of our synthetic efforts for new triplesalen derivatives, we reacted 2,4,6-triacetyl- 1,3,5-trihydroxybenzene (1) with excess Cu(ClO4)2 · 6H2O, imidazole, and ethylenediamine. However, not the triple ketimine derivative was formed but the mononuclear CuII complex [LCuII(ImH)]ClO4 · 0.5EtOH · 0.5H2O (HL = 6-(1-(2-aminoethylimino)ethyl)-2,4-diacetyl-1,3,5-trihydroxybenzene) with only one ketimine function. This complex forms a one-dimensional coordination polymer in the solid state through the apical binding of a keto-oxygen atom of one cation to the CuII ion of a neighboring cation. Mag
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26

Toscano, Rubén A., Sergio Martínez-Vargas та Jesús Valdés-Martínez. "Bis(4′-phenyl-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)copper(II) bis(tetrafluoroborate)". Acta Crystallographica Section E Structure Reports Online 62, № 4 (2006): m846—m848. http://dx.doi.org/10.1107/s1600536806009664.

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The 4-phenylterpyridine ligand coordinates to the CuII ion in the title compound, [Cu(C21H15N3)2](BF4)2, as an N,N′,N′′-terdentate meridional ligand. The geometry of the Cu atom in the cation is octahedral. The BF4 − anions are disordered.
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27

You, Zhong-Lu, Jia Wang, and Xiao Han. "[N,N-Diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]dithiocyanatocopper(II)." Acta Crystallographica Section E Structure Reports Online 62, no. 4 (2006): m860—m861. http://dx.doi.org/10.1107/s1600536806010506.

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The title compound, [Cu(NCS)2(C12H19N3)], is a mononuclear copper(II) complex. The CuII ion is five-coordinated in a square-pyramidal configuration by three N atoms of the Schiff base ligand, and by two terminal N atoms from two thiocyanate anions.
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28

Qiu, Xiao-Yang. "Azido{1-[(2-diethylaminoethylimino)methyl]naphthalato}copper(II)." Acta Crystallographica Section E Structure Reports Online 62, no. 4 (2006): m849—m850. http://dx.doi.org/10.1107/s1600536806010087.

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The title compound, [Cu(C17H21N2O)(N3)], is a mononuclear copper(II) complex. The central CuII ion is four-coordinated by one O and two N atoms of the Schiff base ligand, and by one N atom of an azide anion, forming a distorted square-planar coordination geometry.
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29

Zhu, Qi-Yong, Yi-Jun Wei, and Feng-Wu Wang. "Azido{1-[2-(dimethylamino)ethyliminomethyl]naphthalenolato}copper(II)." Acta Crystallographica Section E Structure Reports Online 62, no. 5 (2006): m983—m985. http://dx.doi.org/10.1107/s1600536806010555.

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In the title mononuclear copper(II) complex, [Cu(C15H17N2O)N3], the CuII ion is four-coordinate in a square-planar geometry defined by the imine and amine N atoms, the naphthalenolate O atom of the Schiff base and a terminal N atom of the azide anion.
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30

Powell, Kipton J., Paul L. Brown, Robert H. Byrne, et al. "Chemical speciation of environmentally significant metals with inorganic ligands Part 2: The Cu2+-OH-, Cl-, CO32-, SO42-, and PO43- systems (IUPAC Technical Report)." Pure and Applied Chemistry 79, no. 5 (2007): 895–950. http://dx.doi.org/10.1351/pac200779050895.

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Complex formation between CuII and the common environmental ligands Cl-, OH-, CO32-, SO42-, and PO43- can have a significant effect on CuII speciation in natural waters with low concentrations of organic matter. Copper(II) complexes are labile, so the CuII distribution amongst these inorganic ligands can be estimated by numerical modeling if reliable values for the relevant stability (formation) constants are available. This paper provides a critical review of such constants and related thermodynamic data. It recommends values of log10βp,q,r° valid at Im = 0 mol kg-1 and 25 °C (298.15 K), alon
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31

Tempesta, Jésio D., Fábio Faria Paiva, Leonildo A. Ferreira, et al. "Metallacrown of CeIIICuII5: Synthesis, Structural Characterization and Insights for Nanoparticles." Magnetochemistry 10, no. 12 (2024): 96. https://doi.org/10.3390/magnetochemistry10120096.

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The heterobimetallic 15-MC-5 metallacrown of formula [CeCu5(5mpzHA)5(NO3)(H2O)7]·2NO3·7H2O, designated MC-Ce, was synthesized using 5-methyl-2-pyrazinehydroxamic acid (5mpzHA) as a linker, reacting with CeIII and CuII salts under mild conditions. Single-crystal X-ray diffraction analysis reveals a crown-like [Cu5Ce(5mpzHA)5] core, characteristic of a 15-MC-5 system, with five CuII atoms at the rim of the crown and the CeIII ion occupying the dome of the crown, with water molecules, oxygen atoms and one nitrate anion filling the nine-coordination sphere around the CeIII ion, which exhibits a di
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32

Minoru, Matsuno, Noor Shabana, Numata Takashi, Haraguchi Tomoyuki, Akitsu Takashiro, and Hara Michikazu. "Synthesis and structural characterization of new [CuII-TiO2 ] composites from CuII-salen as precursors." Journal of Indian Chemical Society Vol. 94, Oct 2017 (2017): 1089–98. https://doi.org/10.5281/zenodo.5636668.

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Department of Chemistry, Tokyo University of Science, Shinjuku-ku, Tokyo, Japan <em>E-mail</em> : akitsu@rs.kagu.tus.ac.jp Department of Chemistry, Aligarh Muslim University, Aligarh-202 002, Uttar Pradesh, India Institute of Innovative Research, Tokyo Institute of Technology, Yokohama, Kanagawa, Japan <em>Manuscript received 03 August 2017, accepted 02 September 2017</em> Five salen type copper(II) complexes [CuL<sup>1</sup> ] (1), [CuL<sup>2</sup> ] (2), [CuL<sup>3</sup> ] (3), [CuL<sup>4</sup> ] (4) and [CuL<sup>5</sup> ] (5) and their composites with TiO<sub>2</sub> , [CuL<sup>1</sup> -TiO
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33

Hou, Han-Na. "{1-[2-(Methylamino)ethyliminomethyl]naphthalen-2-olato}thiocyanatocopper(II)." Acta Crystallographica Section E Structure Reports Online 62, no. 7 (2006): m1533—m1534. http://dx.doi.org/10.1107/s1600536806021544.

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The title compound, [Cu(C14H15N2O)(NCS)], is a mononuclear copper(II) complex, with two molecules in the asymmetric unit. The CuII ion is coordinated by one O and two N atoms of a Schiff base ligand, and by one N atom of a thiocyanate anion, forming a square-planar geometry.
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34

Potočňák, Ivan, Oleksandr Bukrynov, Andrii Kliuikov, et al. "A CuII complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties." Acta Crystallographica Section C Structural Chemistry 74, no. 5 (2018): 584–89. http://dx.doi.org/10.1107/s2053229618005697.

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The complex (2,2′-biquinoline-κ2 N,N′)(carbamoylcyanonitrosomethanide-κ2 N,O)chloridocopper(II) acetonitrile monosolvate, [Cu(C3H2N3O2)Cl(C18H12N2)]·CH3CN or [Cu(ccnm)Cl(biq)]·acn (acn is acetonitrile, biq is 2,2′-biquinoline and ccnm is carbamoylcyanonitrosomethanide), (I), was prepared as a result of nucleophilic addition of water to the dicyanonitrosomethanide ion in the presence of CuII and biq. IR spectroscopy confirmed the presence of ccnm, biq and acn in (I). The solid-state structure consists of the neutral complex containing ccnm and biq ligands, coordinated to the CuII atom in a bide
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35

Ouellette, Wayne, and Jon Zubieta. "Aqua[2,6-bis(pyridin-2-yl)pyridin-4-ol]sulfatocopper(II) dihydrate." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (2007): m908—m909. http://dx.doi.org/10.1107/s1600536807008914.

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The CuII ion of the title complex, [Cu(SO4)(C15H11N3O)(H2O)]·2H2O, exhibits a square-pyramidal coordination geometry, defined by the three N-atom donors of a 2,6-bis(pyridin-2-yl)pyridin-4-ol ligand and an O atom of a sulfate group in the basal plane, and by an aqua ligand in the apical position.
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36

Elmali, Ayhan, and Yalçın Elerman. "Magnetic Properties and Crystal Structure of a CuIIGdIII Heterodinuclear Schiff Base Complex." Zeitschrift für Naturforschung B 59, no. 5 (2004): 535–40. http://dx.doi.org/10.1515/znb-2004-0508.

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Abstract The crystal structure and the magnetic properties of a heterodinuclear complex, [LCu(Me2CO)Gd(NO3)3]2 (L=N,N’-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) are reported: [(C19H20N2O4)Cu(C3H6O)Gd(NO3)3]2, triclinic, space group P1, with a = 12.118.3(9), b = 13.562(3), c = 9.391(3) Å , α = 93.03(3), β = 107.65(2), γ = 73.07(2)°, V = 1406.0(7) Å3, Z = 1. The crystal structure consists of two independent binuclear CuIIGdIII complexes and two non-coordinating acetone molecules in the asymmetric unit. The central region of the complexs is occupied by CuII and GdIII ions which are
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37

Tak, Aijaz Ahmad, Farukh Arjmand, and Sartaj Tabassum. "Synthesis of New Five Coordinated Copper(II) and Nickel(II) Complexes of L-Valine and Kinetic Study of Copper(II) with Calf Thymus DNA." Metal-Based Drugs 9, no. 1-2 (2002): 81–90. http://dx.doi.org/10.1155/mbd.2002.81.

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Five coordinated novel complexes of CuII and NiII have been synthesized from benzil and 1,3- diaminopropane-CuII/NiII complex and characterized by elemental analysis, i.r., n.m.r., e.p.r, molar conductance and u.v-vis, spectroscopy. The complexes are ionic in nature and exhibit pentaeoordinated geometry around the metal ion. The reaction kinetics of C25H36N5O2CuCl with calf thymus DNA was studied by u.v-vis, spectroscopy in aqueous medium. The complex after interaction with calf thymus DNA shows shift in the absorption spectrum and hypochromicity indicating an intercalative binding mode. The K
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38

Dodds, Christopher A., and Alan R. Kennedy. "Formation of a nonanuclear copper(II) cluster with 3,5-dimethylpyrazolate starting from an NHC complex of copper(I) chloride." Acta Crystallographica Section E Crystallographic Communications 76, no. 9 (2020): 1486–90. http://dx.doi.org/10.1107/s2056989020011275.

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The complete nonanuclear cluster in bis[1,3-bis(2,6-dimethylphenyl)imidazolium] di-μ-chlorido-tetrachloridooctakis(μ-3,5-dimethylpyrazolato)hexa-μ3-hydroxido-nonacopper(II) chloroform disolvate, [HIXy]2[Cu9(μ-pz*)8(μ3-OH)6(μ2-Cl)2Cl4]·2CHCl3 or (C19H21N2)2[Cu9(C5H7N2)8Cl6(OH)6]·2CHCl3, where pz* is the 3,5-dimethylpyrazolyl anion, C5H7N2 −, and HIXy is the 1,3-bis(2,6-dimethylphenyl)imidazolium cation, C19H21N2 +, is generated by a crystallographic centre of symmetry with a square-planar CuII ion bound to four μ3-OH ions lying on the inversion centre. Of the four remaining unique CuII atoms, t
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39

Bai, Dekui, Xiaofang Wang, Dongxia Huo, Quanhong Ying, Ni Wang, and Baixue Xia. "Coprecipitation Preparation of Cu/Zn/Al-Hydrotalcite-Like Compound for Copper Removal from Electroplating Wastewater." Journal of Chemistry 2019 (January 2, 2019): 1–9. http://dx.doi.org/10.1155/2019/5347920.

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Cu/Zn/Al-hydrotalcite-like compound (Cu/Zn/Al-HTlc) was prepared by the coprecipitation method with ZnII, AlIII cations solution, and electroplating wastewater containing CuII cation. The preparation conditions of Cu/Zn/Al-HTlc were optimized. The metal ion pollutants removal effect and iodide maximum adsorption capacity of Cu/Zn/Al-HTlc were also studied. The physicochemical properties of the Cu/Zn/Al-HTlc were analyzed by X-ray diffraction, FTIR, SEM, N2 adsorption-desorption isotherms, and TG-DTG. The results showed that Cu/Zn/Al-HTlc should be prepared with the ZnII-AlIII molar ratio of 1.
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40

Butsch, Katharina, Aaron Sandleben, Maryam Heydari Dokoohaki, Amin Reza Zolghadr, and Axel Klein. "Pyridine-2,6-Dicarboxylic Acid Esters (pydicR2) as O,N,O-Pincer Ligands in CuII Complexes." Inorganics 7, no. 4 (2019): 53. http://dx.doi.org/10.3390/inorganics7040053.

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The pyridine-2,6-carboxylic esters pydicR2 with R = Me or Ph form the unprecedented mononuclear CuII complexes [Cu(pydicR2)Cl3]− in one-pot reactions starting from pyridine-2,6-carboxychloride pydicCl2, CuII chloride, and NEt3 in MeOH or PhOH solution under non-aqueous conditions. The triethylammonium salts (HNEt3)[Cu(pydicR2)Cl3] were isolated. The methyl derivative could be crystallized to allow a XRD structure determination. Both structures were optimized using DFT calculations in various surroundings ranging from gas phase and the non-coordinating solvent CH2Cl2 to the weakly coordinating
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41

Jin, Shouwen, та Daqi Wang. "Bis[μ-bis(imidazol-1-yl)methane]bis[aqua(oxalato)copper(II)] dihydrate". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2755—m2756. http://dx.doi.org/10.1107/s1600536807050465.

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The title compound, [Cu2(C2O4)2(C7H8N4)2(H2O)2]·2H2O, features a centrosymmetric dinuclear complex. The CuII ion adopts a square-pyramidal geometry. It is coordinated by two N atoms from two bis(N-imidazolyl)methane molecules as bridging ligands, two O atoms from one oxalate anion in chelating mode and one water molecule. There are several O—H...O hydrogen bonds in the crystal structure.
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42

Elmali, Ayhan, and Yalçin Elerman. "Crystal Structure and Magnetic Properties of a CeIII –CuII Heterodinuclear Complex." Zeitschrift für Naturforschung B 58, no. 7 (2003): 639–43. http://dx.doi.org/10.1515/znb-2003-0706.

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Crystal structure and magnetic properties of a heterodinuclear complex, LCu(Me2CO)Ce(NO3)O3 (L = (N,N’-propylene-bis(3-methoxysalicylideneimine)) are reported. (C19H22N2O4)Cu(C3H6O) Ce(NO3)3, monoclinic, space group P21/c, with a = 9.8295(4), b = 19.049(3), c = 15.668(3) Å , β = 94.873(12)◦, V = 2923.2(7) Å3, Z = 4. The central region of the complex is occupied by CuII and CeIII ions which are bridged by two phenolato oxygen atoms of the ligand. The copper ion adopts a square-based 4+1 coordination made, the equatorial N2O2 donors being afforded by the ligand while the axial position is occupi
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43

Mohammed, Ameen Hadi, Enaam Fadel Mousa, Ameera Hassan Hamed, and Mansor Ahmad. "Synthesis of Multifunctional Polymers Based on Tert-Butyl Acrylamide/Octyl Acrylate as Lubricant Additives and Adsorbents for Copper Ion from Aqueous Solution." Baghdad Science Journal 20, no. 6(Suppl.) (2023): 2467. http://dx.doi.org/10.21123/bsj.2023.9095.

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Two homopolymeric and three copolymeric additives for base oil were synthesized using octyl acrylate (OA) and tert-butyl acrylamide (TBA) monomers. The two additives named P1 and P2 are the homopolymers of TBA and OA, respectively, whereas copolymeric additives named Co1, Co2, and Co3 were synthesized by varying the ratios of TBA:OA as 1:3, 3:1 and 1:1, respectively. The prepared polymers were characterized by Fourier Transform Infrared (FTIR). Based on the solubility of synthesized polymers in base oil and reactivity ratios of TBA/OA copolymer (0.222, 0.434) calculated by Fineman-Ross method,
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44

Cristóvão, Beata, Dariusz Osypiuk, and Agata Bartyzel. "New Heterotrinuclear CuIILnIIICuII (Ln = Ho, Er) Compounds with the Schiff Base: Syntheses, Structural Characterization, Thermal and Magnetic Properties." Materials 15, no. 12 (2022): 4299. http://dx.doi.org/10.3390/ma15124299.

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New heterotrinuclear complexes with the general formula [Cu2Ln(H2L)(HL)(NO3)2]×MeOH (Ln = Ho (1), Er (2), H4L = N,N′-bis(2,3-dihydroxybenzylidene)-1,3-diaminopropane) were synthesized using compartmental Schiff base ligand in conjugation with auxiliary ligands. The compounds were characterized by elemental analysis, ATR-FTIR spectroscopy, X-ray diffraction, TG, DSC, TG-FTIR and XRD analysis. The N2O4 salen-type ligand coordinates 3d and 4f metal centers via azomethine nitrogen and phenoxo oxygen atoms, respectively, to form heteropolynuclear complexes having CuO2Ln cores. In the crystals 1 and
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45

Elerman, Y., A. Elmali, C. T. Zeyrek, I. Svoboda, and H. Fuess. "Crystal Structure and Magnetic Properties of a New Hetero-Dinuclear CuIIMnII Schiff Base Complex." Zeitschrift für Naturforschung B 58, no. 4 (2003): 271–77. http://dx.doi.org/10.1515/znb-2003-0405.

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Mn[Cu(L)(O2CMe)2] · H2O (L = N,N’-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) was synthesized and the crystal structure determined. (C23H26CuMnN2O8).H2O, monoclinic, space group P21/c, a = 12.017(3), b = 8.217(3), c = 24.786(4) Å , β = 92.10(2)°, V = 2446(1) Å3, Z = 4. The crystal structure consists of ordered dinuclear units with CuII and MnII ions bridged by two oxygen atoms of the Schiff base ligand. The CuII coordination sphere is a slightly distorted square-plane formed by the N2O2 donor set of the Schiff base ligands. The average Cu-O and Cu-N distances are 1.920(1) and 1.957
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46

Vassilyeva, Olga Yu, Elena A. Buvaylo, Vladimir N. Kokozay, Andrii K. Melnyk, and Brian W. Skelton. "Crystal structure and characterization of a new copper(II) chloride dimer with methyl(pyridin-2-ylmethylidene)amine." Acta Crystallographica Section E Crystallographic Communications 76, no. 6 (2020): 790–93. http://dx.doi.org/10.1107/s2056989020005903.

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The new copper(II) complex, namely, di-μ-chlorido-bis{chlorido[methyl(pyridin-2-ylmethylidene)amine-κ2 N,N′]copper(II)}, [Cu2Cl4(C7H8N2)2], (I), with the ligand 2-pyridylmethyl-N-methylimine (L, a product of Schiff base condensation between methylamine and 2-pyridinecarbaldehyde) is built of discrete centrosymmetric dimers. The coordination about the CuII ion can be described as distorted square pyramidal. The base of the pyramid consists of two nitrogen atoms from the bidentate chelate L [Cu—N = 2.0241 (9), 2.0374 (8) Å] and two chlorine atoms [Cu—Cl = 2.2500 (3), 2.2835 (3) Å]. The apical po
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47

Powell, Kipton J., Paul L. Brown, Robert H. Byrne, et al. "Chemical speciation of environmentally significant metals with inorganic ligands. Part 4: The Cd2+ + OH–, Cl–, CO32–, SO42–, and PO43– systems (IUPAC Technical Report)." Pure and Applied Chemistry 83, no. 5 (2011): 1163–214. http://dx.doi.org/10.1351/pac-rep-10-08-09.

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The numerical modeling of CdII speciation amongst the environmental inorganic ligands Cl–, OH–, CO32–, SO42–, and PO43– requires reliable values for the relevant stability (formation) constants. This paper compiles and provides a critical review of these constants and related thermodynamic data. It recommends values of log10βp,q,r° valid at Im = 0 mol kg–1 and 25 °C (298.15 K), along with the equations and empirical reaction ion interaction coefficients, ∆&amp;epsilon; , required to calculate log10βp,q,r values at higher ionic strengths using the Brønsted–Guggenheim–Scatchard specific ion inte
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48

Xiang, Jiang-Feng, Ming Li, Si-Min Wu, Liang-Jie Yuan, and Ju-Tang Sun. "Diaquabis(pyridine-2,3-dicarboxylato)copper(II)." Acta Crystallographica Section E Structure Reports Online 62, no. 5 (2006): m1122—m1123. http://dx.doi.org/10.1107/s1600536806014218.

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The centrosymmetric title copper(II) complex, [Cu(C7H4NO4)2(H2O)2], was synthesized via the hydrothermal method at a mild temperature (353 K). The CuII ion has a distorted octahedral coordination environment, with two N and two O atoms from the pyridine-2,3-dicarboxylate ligands in a common plane and with two water molecules in axial positions. Hydrogen bonds play an important role in the formation of the three-dimensional structure.
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49

Wang, Min, Bo Hu, Xiao-Tao Deng та Cheng-Gang Wang. "μ-Oxalato-κ4 O,O′:O′′,O′′′-bis[chloro(1,10-phenanthroline-κ2 N,N′)copper(II)]". Acta Crystallographica Section E Structure Reports Online 63, № 3 (2007): m710—m711. http://dx.doi.org/10.1107/s1600536807005806.

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In the title dimeric complex, [Cu2(C2O4)Cl2(C12H8N2)2], which lies on a crystallographic inversion center, the CuII ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom. In the crystal structure, pairs of molecules related by π–π stacking interactions are stacked along the c-axis direction
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50

Saliba, R., H. Gauthier, R. Gauthier, and M. Petit-Ramel. "The Use of Eucalyptus Barks for the Adsorption of Heavy Metal Ions and Dyes." Adsorption Science & Technology 20, no. 2 (2002): 119–29. http://dx.doi.org/10.1260/026361702320360540.

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Eucalyptus barks harvested in Lebanon were used for the adsorption of pollutants such as heavy metal ions and dyes. Washing with water or pretreatment with formaldehyde was performed on the bark powder. The adsorption capacity of this material towards CuII, CrIII, CdII and NiII was evaluated in a batch process for various parameters. The results obtained showed that the retention capacity increased with contact time, pH and initial metal ion concentration but decreased with temperature. The adsorption capacities were 2.61, 0.71, 2.24 and 0.75 mmol/g adsorbent for CuII, CrIII, CdII and NiII, re
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