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Journal articles on the topic 'Cumyl peroxide'

Author: Grafiati
Published: 5 June 2025
Last updated: 2 August 2025

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1

Przybysz-Romatowska, Marta, Mateusz Barczewski, Szymon Mania, Agnieszka Tercjak, Józef Haponiuk, and Krzysztof Formela. "Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides." Materials 14, no. 15 (2021): 4205. http://dx.doi.org/10.3390/ma14154205.

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Reactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA via liquid organic peroxides (OP) including 0.5 wt.% of tert-butyl cumyl peroxide (BU), 2,5-dimethyl-2,5-di-(tert-butylperoxy)-hexane (HX), and tert-butyl peroxybenzoa
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2

Muratoglu, O. K., M. D. Asik, C. M. Nepple, et al. "DI-CUMYL PEROXIDE CROSSLINKED UHMWPE/VITAMIN-E BLEND FOR TOTAL JOINT REPLACEMENT IMPLANTS." Orthopaedic Proceedings 105-B, SUPP_12 (2023): 70. http://dx.doi.org/10.1302/1358-992x.2023.12.070.

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Majority of ultra-high molecular weight polyethylene (UHMWPE) medical devices used in total joint arthroplasty are crosslinked using gamma radiation to improve wear resistance. Alternative methods of crosslinking are urgently needed to replace gamma radiation due to rapid decline in its supply. Peroxide crosslinking is a candidate method with widespread industrial applications. Oxidative stability and biocompatibility, which are critical requirements for medical device applications, can be achieved using vitamin-E as an additive and by removing peroxide by-products through high temperature mel
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3

Wiśniewska, Paulina, Łukasz Zedler, Mariusz Marć, Marek Klein, Józef Haponiuk, and Krzysztof Formela. "Ground Tire Rubber Modified by Elastomers via Low-Temperature Extrusion Process: Physico-Mechanical Properties and Volatile Organic Emission Assessment." Polymers 14, no. 3 (2022): 546. http://dx.doi.org/10.3390/polym14030546.

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In this paper, low-temperature extrusion of ground tire rubber was performed as a pro-ecological waste tires recycling method. During this process, ground tire rubber was modified with constant content of dicumyl peroxide and a variable amount of elastomer (in the range: 2.5–15 phr). During the studies, three types of elastomers were used: styrene-butadiene rubber, styrene-ethylene/butylene-styrene grafted with maleic anhydride and ethylene-octene copolymer. Energy consumption measurements, curing characteristics, physico-mechanical properties and volatile organic compounds emitted from modifi
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4

Akbаrov, N., and J. Aliyev. "STUDY OF THE ANTIOXIDATIVE PROPERTIES OF SOME N-ALKYLAMINE SUBSTITUTE EPITIO COMPOUNDS." Scientific heritage, no. 126 (December 8, 2023): 7–11. https://doi.org/10.5281/zenodo.10299348.

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Continuing research for more effective multifunctional additives to petroleum products and in order to determine the relationship between the structure of synthesized compounds and their antioxidant activity as additives to lubricating oils, in this article we tried to study the antioxidant properties of some N-alkylamino-substituted epithio compounds - 1,2- epitio-3-N-alkylaminopropanes (alkylamino-substituted thiierans) in model reactions with cumyl peroxide radicals and cumene hydroperoxide (CHP). The analysis of the conducted studies makes it possible to predict that the alkylamino-substit
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5

Pavlovskii, Yu P., N. S. Kachurina, S. I. Gerasimchuk, and Yu Ya Van-Chin-Syan. "Thermochemical properties of tert-butyl and cumyl derivatives of peroxide compounds." Russian Journal of Physical Chemistry A 87, no. 8 (2013): 1253–58. http://dx.doi.org/10.1134/s003602441307025x.

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6

Marco, E., S. Cuartielles, J. A. Peña, and J. Santamaria. "Simulation of the decomposition of di-cumyl peroxide in an ARSST unit." Thermochimica Acta 362, no. 1-2 (2000): 49–58. http://dx.doi.org/10.1016/s0040-6031(00)00587-6.

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7

Farzaliyeva, A. E., I. A. Rzayeva, A. M. Magarramov, and I. G. Mammadov. "Study of N,S,O-containing compounds as inhibitors of hydrocarbon oxidation." Azerbaijan Oil Industry, no. 03 (March 2024): 40–44. http://dx.doi.org/10.37474/0365-8554/2024-03-40-44.

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The article is devoted to research on the study of synthesized N,S,O-containing organic compounds as inhibitors of hydrocarbon oxidation. The antioxidant properties of these compounds were studied using the kinetic method and using isopropylbenzene (cumene) as a model hydrocarbon. The study of cumene autoxidation in the presence of these compounds showed that all of them have sufficiently high antioxidant properties. To evaluate the ability of these compounds to terminate the oxidation chains by reaction with peroxide radicals, the oxidation of cumene initiated by azodiisobutyronitrile in the
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8

Gojayeva, S. S., N. M. Nazarov, S. S. Babayev, et al. "Synthesis of Some Heterotic Cycle Azolidines." Herald of Azerbaijan Engineering Academy 15, no. 4 (2023): 52–59. https://doi.org/10.52171/2076-0515_2023_15_04_52_59.

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In this article 2-thio-4-oxothiazolidine, 2-thio-4-oxo-5-methylthiazolidine, thiozolidinone2,4, 2-thiogidantone, which are highly reactive as a result of three-component condensated in thepresence of various catalysts, provide ample opportunities for the synthesis of other nitrogenousheterocyclic compounds. Different thiozalidindions (tions) are synthesized. To assess theantioxidant properties of the synthesized compounds, the kinetics of their reactions withcumylperoxide radicals and cumylhydroperoxide are studied. The reaction of the studiedcompounds with cumyl peroxide radicals is studied o
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9

Zhulin, V. M., O. B. Rudakov, and V. L. Antonovskii. "Calculation of activation volumes of thermal conversions of trimethylsilyl(cumyl) peroxide by the spline approximation method." Kinetics and Catalysis 45, no. 6 (2004): 788–93. http://dx.doi.org/10.1007/s10975-005-0034-7.

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10

Liu, HanShuang, KaiJun Wang, XiaoYan Cao, JiaXin Su, and Zhenggui Gu. "A new highly active La2O3–CuO–MgO catalyst for the synthesis of cumyl peroxide by catalytic oxidation." RSC Advances 11, no. 21 (2021): 12532–42. http://dx.doi.org/10.1039/d1ra00176k.

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11

Zhulin, V. M., O. B. Rudakov, A. V. Ganyushkin, and V. A. Yablokov. "Effect of high pressure on the activation parameters of thermal transformations of trimethylsilyl(cumyl) peroxide in the liquid phase." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 35, no. 10 (1986): 2013–18. http://dx.doi.org/10.1007/bf00957513.

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12

Panda, Atanu, Subhasish Mahapatra, Achu Govind K.R., and Rames C. Panda. "Employing economic model predictive control for improving efficiency of the batch reactor carrying out decomposition of the Di-Cumyl-Peroxide." Journal of the Taiwan Institute of Chemical Engineers 167 (February 2025): 105864. https://doi.org/10.1016/j.jtice.2024.105864.

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13

Oyama, Ryoko, and Manabu Abe. "Reactivity and Product Analysis of a Pair of Cumyloxyl and tert-Butoxyl Radicals Generated in Photolysis of tert-Butyl Cumyl Peroxide." Journal of Organic Chemistry 85, no. 13 (2020): 8627–38. http://dx.doi.org/10.1021/acs.joc.0c01016.

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14

Mashima, Tsuyoshi, Koji Oohora, and Takashi Hayashi. "Substitution of an amino acid residue axially coordinating to the heme molecule in hexameric tyrosine-coordinated hemoprotein to enhance peroxidase activity." Journal of Porphyrins and Phthalocyanines 21, no. 12 (2017): 824–31. http://dx.doi.org/10.1142/s1088424617500936.

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To convert an originally tyrosine-coordinated heme to histidine-coordinated heme in hexameric tyrosine-coordinated hemoprotein, HTHP, Tyr45, a residue coordinating to the heme cofactor, and Arg25 located in the distal site are replaced with Phe45 and His25, respectively in each of the subunits of the protein. The obtained HTHP mutant (HTHP[Formula: see text] was characterized by SDS-PAGE, ESI-TOF MS, dynamic light scattering measurements and size exclusion chromatography. These analyses indicate that HTHP[Formula: see text] maintains its stable hexameric structure with the altered ligation of
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15

Muratoglu, Orhun K., Mehmet D. Asik, Cecilia M. Nepple, et al. "Di‐cumyl peroxide cross‐linked UHMWPE/vitamin‐E blend for total joint arthroplasty implants." Journal of Orthopaedic Research, August 25, 2023. http://dx.doi.org/10.1002/jor.25679.

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AbstractMajority of ultrahigh molecular weight polyethylene (UHMWPE) medical devices used in total joint arthroplasty are cross‐linked using gamma radiation to improve wear resistance. Alternative methods of cross‐linking are urgently needed to replace gamma radiation due to rapid decline in its supply. Peroxide cross‐linking is a candidate method with widespread industrial applications. Oxidative stability and biocompatibility, which are critical requirements for medical device applications, can be achieved using vitamin‐E as an additive and by removing peroxide by‐products through high‐tempe
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16

Aguilera, Tania, Jesús Pastrán, Ligia Llovera, et al. "C2 and C1‐Symmetric Camphopyrazole Dioxomolybdenum(VI) Complexes catalyze the Epoxidation of Cyclic Olefins." Zeitschrift für anorganische und allgemeine Chemie, September 4, 2023. http://dx.doi.org/10.1002/zaac.202300104.

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AbstractDioxomolybdenum(VI) complexes (1‐6) were prepared in good yields (≥79 %) using enantiopure C2 and C1‐symmetric bidentate N,N‐ligands (L1‐L6) derived from (+)‐camphor. The ligands and complexes were characterized by NMR spectroscopy, IR, and elemental analysis. Single crystal X‐ray diffraction analyses of complexes 3, 4 and 6 confirmed the bidentate coordination modes of ligands L3, L4, and L6 and revealed distorted octahedral coordination geometries around the metal center. Complexes 3 and 6 form conformational isomers depending on the orientation of the substituents of the ligand aryl
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17

Zhang, Ying, Jia Lu, Junjun Wu, and Xueqin Gao. "Exploring the impact of cellulose nanocrystals and annealing treatment on the interlayer bond strength of polylactic acid 3D printed composites." Journal of Applied Polymer Science, November 29, 2023. http://dx.doi.org/10.1002/app.54956.

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AbstractThe extrusion‐based 3D printing process offers advantages, such as high precision, low cost, high speed, simplicity, and the ability to deposit multiple materials simultaneously. However, using 3D printing composite materials with orthogonal anisotropy can limit the interlayer bonding strength of printed parts. In this study, the interlayer tensile strength of 3D‐printed polylactic acid (PLA) was affected by adding 0.5 wt% cellulose nanocrystals (CNC) and 1.2 wt% di‐cumyl peroxide (DCP) to PLA, and annealing at low temperature (373 K, 1 h). The effects of annealing and CNC were determi
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18

Mishra, Arunima, Yuetan Dou, and Hansel M. Fletcher. "Characterization of thioredoxin–thioredoxin reductase system in Filifactor alocis." Molecular Oral Microbiology, October 20, 2024. http://dx.doi.org/10.1111/omi.12486.

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AbstractIntroductionFilifactor alocis is a newly appreciated member of the periodontal community with a strong periodontal disease correlation. Little is known about the survival mechanisms by which F. alocis copes with oxidative stress and establishes the infection within the local inflammatory microenvironment of the periodontal pocket. The aim of this study is to investigate if F. alocis putative peroxiredoxin/AhpC protein FA768 may constitute an alkyl hydroperoxide reductase system utilizing putative thioredoxin reductase protein FA608, and putative thioredoxin/glutaredoxin homolog FA1411/
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19

Shah, Nouman Ali, Adnan Ahmad, Rizwan M. Gul, et al. "Effect of Surface Crosslinking on the Wear and Friction Behavior of Tea Polyphenol Stabilized Ultra-High Molecular Weight Polyethylene for Total Joint Replacements." Materials Research 28 (2025). https://doi.org/10.1590/1980-5373-mr-2024-0618.

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Highly crosslinked ultra-high molecular weight polyethylene (UHMWPE) with vitamin E (VE) as an antioxidant is widely used for joint implants. VE helps resist oxidation but raises concerns about reduced crosslink density and wear performance. This research hypothesized that tea polyphenols (tPPs), such as lipid-soluble epigallocatechin gallate (lsEGCG) and epigallocatechin gallate (EGCG), could prevent the usual decrease in crosslink density caused by VE, thereby enhancing wear performance. The antioxidants were blended with UHMWPE at 0.2 wt% and surface chemically crosslinked using di-cumyl pe
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20

Vardanyan, L. R., S. A. Hayrapetyan, T. V. Vandunts, et al. "ANTIOXIDANT PROPERTIES OF LEAVES OF SOME TREES." CHEMICAL AND ENVIRONMENTAL TECHNOLOGIES, 2023. http://dx.doi.org/10.53297/18293379-2023.2-62.

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The paper presents the results of studies of antioxidant properties of the leaves of the English oak (Quercus robur), Georgian oak (Quercus iberica), white willow (Salix alba) and common sycamore (Lycium barbarum) leaves. It is shown that all the studied extracts have antioxidant properties. The antioxidant capacity of the investigated extracts is studied on the example of the model reaction of the initiated oxidation of cumene. Azo-di-isobutyronitrile (AIBN) was used as a source of a free radical, and chlorobenzene was used as a solvent. The oxidation of the substances is carried out on a man
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