Relevant bibliographies by topics / Cyanides Hydrolysis

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  1. Journal articles

Academic literature on the topic 'Cyanides Hydrolysis'

Author: Grafiati
Published: 4 June 2021
Last updated: 3 February 2022

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Journal articles on the topic "Cyanides Hydrolysis"

1

Hargono, Hargono, Andri Cahyo Kumoro, and Bakti Jos. "Inhibitory Effects of Cyanide on the Activity of Granular Starch Hydrolyzing Enzyme (GSHE) during Hydrolysis of Cassava (Manihot Esculenta Crantz) Starch." Periodica Polytechnica Chemical Engineering 63, no. 1 (2018): 11–17. http://dx.doi.org/10.3311/ppch.12006.

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The kinetics and inhibitory effects of cyanide on the granular starch hydrolyzing enzyme (GSHE) activity during hydrolysis of cassava (Manihot esculenta Crantz) starch at low temperature were studied. The substrates included native cassava starch at various concentrations (100-400 g/L) and native cassava starches with added cyanide at various concentrations (50-150 mg/kg), while the concentration of enzyme was 1.5% (w/w). A decrease in reducing sugar concentration during hydrolysis of cassava starch indicated that the cyanide reduced the enzyme activity. Lineweaver-Burk plot of Michaelis-Mente
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2

Petrov, S. V., and V. F. Petrov. "Hydrolysis of cyanides in aqueous solutions." Russian Journal of Inorganic Chemistry 52, no. 5 (2007): 793–95. http://dx.doi.org/10.1134/s0036023607050245.

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3

Dhillon, Jasvinder, Suneel Chhatre, Rishi Shanker, and N. Shivaraman. "Transformation of aliphatic and aromatic nitriles by a nitrilase from Pseudomonas sp." Canadian Journal of Microbiology 45, no. 10 (1999): 811–15. http://dx.doi.org/10.1139/w99-087.

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A Pseudomonas sp. (S1) isolated from a garden soil possessed a unique nitrilase, which is capable of catalyzing the direct hydrolysis of both potassium and organic cyanides to their corresponding carboxylic acids and ammonia, without the formation of amide as an intermediate. The nitrilase was purified with 4.8% recovery in three steps from a cell extract of the strain. The relative mobility of the homogenous enzyme preparation in SDS and native polyacrylamide gels indicated molecular weight of 41 kDa, approximately. Pseudomonas sp. (S1) utilized all the nitriles as carbon and nitrogen sources
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4

Midler, M., C. M. Bagner, A. S. Wildman, and E. S. Venkataramani. "Destruction of cyanides by alkaline hydrolysis in a pipeline reactor." Environmental Progress 11, no. 4 (1992): 251–55. http://dx.doi.org/10.1002/ep.670110410.

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5

Christoffers, Jens, and David Kieslich. "Cyanide Anions as Nucleophilic Catalysts in Organic Synthesis." Synthesis 53, no. 19 (2021): 3485–96. http://dx.doi.org/10.1055/a-1499-8943.

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AbstractThe nucleophilic addition of a cyanide anion to a carbonyl group is the basis for several cyanide-catalyzed organic reactions, which are summarized in this review. Since cyanide is also a good leaving group, it is an excellent catalyst for transacylation reactions. As an electron-withdrawing group, it also stabilizes a negative charge in its α-position, thus allowing the umpolung of aldehydes to formyl anion equivalents. The two leading examples are the benzoin condensation and the Michael–Stetter reaction furnishing α-hydroxy ketones and 1,4-dicarbonyl compounds, which are both cataly
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6

Taydakov, Ilya V., and Mikhail A. Kiskin. "On the hydrolysis of diethyl 2-(perfluorophenyl)malonate." Beilstein Journal of Organic Chemistry 16 (July 28, 2020): 1863–68. http://dx.doi.org/10.3762/bjoc.16.153.

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Diethyl 2-(perfluorophenyl)malonate was synthesized in 47% isolated yield by the reaction of sodium diethyl malonate and hexafluorobenzene. The resulting compound was considered as a starting material for synthesizing 2-(perfluorophenyl)malonic acid by hydrolysis. It was found that the desired 2-(perfluorophenyl)malonic acid could not be obtained from this ester by hydrolysis, neither under basic nor under acidic conditions. Nevertheless, hydrolysis of the ester with a mixture of HBr and AcOH gave 2-(perfluorophenyl)acetic acid in a good preparative yield of 63%. A significant advantage of thi
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7

Cenčič, Matjaž, Ivan Kobal, and Janvit Golob. "Thermal Hydrolysis of Cyanides in Spent Pot Lining of Aluminium Electrolysis." Chemical Engineering & Technology 21, no. 6 (1998): 523–32. http://dx.doi.org/10.1002/(sici)1521-4125(199806)21:6<523::aid-ceat523>3.0.co;2-p.

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8

Geresh, Shimona, Yakir Giron, Ygal Gilboa, and Robert Glaser. "Electronic substituent effects in the nitrilase-catalyzed hydrolysis of para-substituted benzyl cyanides." Tetrahedron 49, no. 44 (1993): 10099–102. http://dx.doi.org/10.1016/s0040-4020(01)80205-2.

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9

Rudel, Stefan S., Sebastian A. Baer, Patrick Woidy, et al. "Recent advances in the chemistry of uranium halides in anhydrous ammonia." Zeitschrift für Kristallographie - Crystalline Materials 233, no. 12 (2018): 817–44. http://dx.doi.org/10.1515/zkri-2018-2066.

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Abstract This article presents an overview of recent advancements in the field of uranium chemistry, paying special attention to the preparation of starting materials and to the chemistry of uranium halides in liquid ammonia. Where suitable, insights into the chemistry of thorium are also presented. Herein, we report upon the crystal structures of several ammine complexes as well as their deprotonation products. Specific examples of hydrolysis products in liquid ammonia are showcased. Additionally, advancements in the preparation of uranium cyanides are presented.
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10

Khusnutdinov, Ravil, Tatyana Egorova, Leonard Khalilov, Ekaterina Meshcheriakova, and Usein Dzhemilev. "Direct and Stereoselective Iron-Catalyzed Amidation of Binor-S with Alkyl and Aryl Cyanides in Water." Synthesis 50, no. 07 (2018): 1555–59. http://dx.doi.org/10.1055/s-0036-1591881.

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The amidation of heptacyclo[8.4.0.02,12.03,8.04,6.05,9.011,13]tetra­decane (binor-S) with aceto-, propio-, valero-, and benzonitrile was performed in the presence of water and FeCl3·6H2O as catalyst to give the corresponding 10-exo-amidohexacyclo[9.2.1.02,7.03,5.04,8.09,13]tetradecanes. Hydrolysis of 10-exo-acetamidohexacyclo[9.2.1.02,7.03,5.04,8.09,13]tetra­decane with sodium hydroxide in n-butanol afforded 10-exo-aminohexacyclo[9.2.1.02,7.03,5.04,8.09,13]tetradecane in quantitative yield.
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