Academic literature on the topic 'Cyanoacetamide'

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Journal articles on the topic "Cyanoacetamide"

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Wang, Kan, Katrina Nguyen, Yijun Huang, and Alexander Dömling. "Cyanoacetamide Multicomponent Reaction (I): Parallel Synthesis Of Cyanoacetamides." Journal of Combinatorial Chemistry 11, no. 5 (2009): 920–27. http://dx.doi.org/10.1021/cc9000778.

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El-Behairy, Mohammed Farrag, Rasha M. Hassan, and Eirik Sundby. "Enantioselective Chromatographic Separation and Lipase Catalyzed Asymmetric Resolution of Biologically Important Chiral Amines." Separations 8, no. 10 (2021): 165. http://dx.doi.org/10.3390/separations8100165.

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Cyanoacetamides are vital synthons in synthetic organic chemistry. However, methods to enantiopure cyanoacetamides have not yet been well explored. In this work, the preparation of cyanoacetamide synthons RS-(1a–4a) or methoxyacetamides RS-(1b–4b) in enantiopure/enriched form was investigated. Compounds S-1, S-2, R-1b, R-1a, andR-2b were prepared in enantiopure form (ee > 99%) while compounds S-4, R-2a, and R-4a were achieved in ee 9%, 80%, and 76%, respectively. Many baselines enantioselective HPLC separations of amines 1–4, their cyanoacetamides (1a–4a), and methoxyacetamides (1b–4b) were
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Zdzienicka, Anna. "2-Cyanoacetamide." Synlett 24, no. 09 (2013): 1162–63. http://dx.doi.org/10.1055/s-0033-1338942.

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Sanz-Novo, M., I. León, J. L. Alonso, A. Largo, and C. Barrientos. "Formation of interstellar cyanoacetamide: a rotational and computational study." Astronomy & Astrophysics 644 (November 24, 2020): A3. http://dx.doi.org/10.1051/0004-6361/202038766.

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Context. Cyanoacetamide is a –CN bearing molecule that is also an amide derivative target molecule in the interstellar medium. Aims. The aim of our investigation is to analyze the feasibility of a plausible formation process of protonated cyanoacetamide under interstellar conditions and to provide direct experimental frequencies of the ground vibrational state of the neutral form in the microwave region in order to enable its eventual identification in the interstellar medium. Methods. We used high-level theoretical computations to study the formation process of protonated cyanoacetamide. Furt
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Kantlehner, Willi, Rüdiger Stieglitz, Hansjörg Lehmann, and Markus Vettel. "Orthoamide und Iminiumsalze, IIIC. Weitere Ergebnisse bei der Umsetzung von Orthoamiden der Alkincarbonsäuren mit CH2- und CH2/NH-aciden Verbindungen." Zeitschrift für Naturforschung B 74, no. 11-12 (2019): 925–38. http://dx.doi.org/10.1515/znb-2019-0078.

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AbstractThe 1,1-bis(dimethylamino)-1,3-butadienes (keten aminals) 11a–l are prepared from orthoamide derivatives of alkyne carbonxylic acids 9b, d, e, i and CH2-acidic compounds 10a–c, f–h, k, o. The C-silylated orthoamide derivative 9c shows an ambivalent behaviour towards CH-acidic compounds. Reactions of 9c with strong CH2-acidic compounds like the nitro alkanes 10m, n and strongly enolized carbonyl compounds as methyl acetoacetate, cyanoacetamide, dibenzoylmethane, 1,3-dimethylbarbituric acid proceed under desilylation to give the ketene aminals 11u–z. In contrast to these reactions, the C
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Prlainovic, Nevena, Dejan Bezbradica, Zorica Knezevic-Jugovic, Dusan Velickovic, and Dusan Mijin. "Enzymatic synthesis of vitamin B6 precursor." Journal of the Serbian Chemical Society 78, no. 10 (2013): 1491–501. http://dx.doi.org/10.2298/jsc130322050p.

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3-Cyano-4-ethoxymethyl-6-methyl-2-pyridone is an important precursor in the synthesis of vitamin B6, obtained in the addition reaction between 2-cyanoacetamide and 1-ethoxy-2,4-pentanedione catalyzed by lipase from Candida rugosa (triacylglycerol ester hydrolases, EC 3.1.1.3). This work shows new experimental data and mathematical modeling of lipase catalyzed synthesis of 3-cyano-4-ethoxymethyl-6-methyl-2-pyridone, starting from 1-ethoxy-2,4-pentanedione and 2-cyanoacetamide. Kinetic measurements were done at 50 oC with enzyme concentration of 1.2 % w/v. Experimental results were fitted with t
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Gandhi, Sham S., and Martin S. Gibson. "Condensation reactions of 1,1-dimorpholinoethene and of 1,1-dipiperidinoethene with carbon acids." Canadian Journal of Chemistry 65, no. 12 (1987): 2717–21. http://dx.doi.org/10.1139/v87-451.

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1,1-Dimorpholinoethene and 1,1-dipiperidinoethene condense with such compounds as malononitrile, ethyl cyanoacetate, cyanoacetamide, and diethyl malonate to give the corresponding β,β-disubstituted enamine, a molecule of morpholine or piperidine being eliminated in the process. Similar reactions with acetylacetone and ethyl acetoacetate proceed with loss of the acetyl group to give the β-substituted enamine. 1,1-Dipiperidinoethene and nitromethane give the β-nitroenamine. Secondary processes of either hydrolysis or further Michael addition and elimination are noted in condensations of 1,1-dimo
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NIRMALANANDA, PALIT. "A MODIFICATION OF THE GUARESCHI PYRIDINE SYNTHESIS. PART III." Journal of Indian Chemical Society Vol.26 No.10, Oct. 1949 (2022): 501–3. https://doi.org/10.5281/zenodo.7263393.

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Vala, Ruturajsinh M., Divyang M. Patel, Mayank G. Sharma, and Hitendra M. Patel. "Impact of an aryl bulky group on a one-pot reaction of aldehyde with malononitrile and N-substituted 2-cyanoacetamide." RSC Advances 9, no. 49 (2019): 28886–93. http://dx.doi.org/10.1039/c9ra05975j.

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Ibrahim, N. S., R. M. Mohareb, and H. Z. Shams. "Nitriles in Heterocyclic Synthesis: New Approaches for Synthesis of Some Pyridine Derivatives." Zeitschrift für Naturforschung B 43, no. 10 (1988): 1351–54. http://dx.doi.org/10.1515/znb-1988-1023.

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Abstract A variety of pyridines was prepared from reaction of N-benzylidenecyanoethanoic hydrazide (2) with malononitrile, benzoylacetonitrile, cyanoacetamide and cinnamonitrile derivatives. The reactivity of 2 towards a variety of ketones was studied.
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Dissertations / Theses on the topic "Cyanoacetamide"

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Lourenço, Miguel Cordeiro. "Análise de hidratos de carbono não estruturais em oliveira cv. Cobrançosa." Master's thesis, ISA, 2014. http://hdl.handle.net/10400.5/6978.

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Mestrado em Engenharia Agronómica - Instituto Superior de Agronomia<br>This work was conducted in an olive grove near Santarém and its main objective was the determination of soluble carbohydrates content in roots (R), trunk (T), branches over three years (R+), branches of three years (R3) and branches of two years (R2) in cultivar Cobrançosa to integrate a model of olive growth and development. Samples were taken from six plants randomly chosen, three with high crop load (CA) and three with low crop load (CB) in four time points. Sugars contents were determined by three methods, 2- cyanoaceta
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Moores, Lee C. "Malononitriles and cyanoacetamides containing isoxazoles and isoxazolines." 2011. http://liblink.bsu.edu/uhtbin/catkey/1657737.

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Isoxazoles and isoxazolines have been shown in the literature to be an important scaffold for pharmaceuticals and insecticides, as well as a source of synthetic versatility important to many syntheses. As a substitute for other aromatic rings, isoxazoles are known to change the efficacy of a given compound. Isoxazolines can be used as a precursor to many other functional moieties that may be effected during earlier synthetic steps. There are many routes to the heterocyclic moiety, allowing for their insertion in a wide range of molecules. Our group has previously reported a condensation of ary
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Book chapters on the topic "Cyanoacetamide"

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Spitzner, D. "From -Alkyl-2-cyanoacetamides in the Presence of Phosphoryl Chloride." In Six-Membered Hetarenes with One Nitrogen or Phosphorus Atom. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-015-00463.

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Conference papers on the topic "Cyanoacetamide"

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Dotsenko, Victor, Tatyana Didikina, Elena Chigorina, Darya Lukina, Alexander Bespalov, and Nicolai Aksenov. "N-(Thieno[2,3-b]pyridin-3-yl)cyanoacetamides: synthesis and cyclizations." In The 24th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2020. http://dx.doi.org/10.3390/ecsoc-24-08400.

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