Academic literature on the topic 'Cyclic hydrocarbons'

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Journal articles on the topic "Cyclic hydrocarbons"

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Perkins, Robert R. "Stereochemistry of cyclic hydrocarbons." Journal of Chemical Education 65, no. 10 (1988): 860. http://dx.doi.org/10.1021/ed065p860.

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MORI, Takaaki. "Toxicity of chlorinated cyclic hydrocarbons." Okayama Igakkai Zasshi (Journal of Okayama Medical Association) 98, no. 9-10 (1986): 809–18. http://dx.doi.org/10.4044/joma1947.98.9-10_809.

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Himmerich, M., P. G. J. van Dongen та R. M. Noack. "Cyclic hydrocarbons: nanoscopic (π)-SQUIDs?" European Physical Journal B 51, № 1 (2006): 5–15. http://dx.doi.org/10.1140/epjb/e2006-00184-y.

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Oliva-Enrich, Josep M., Ibon Alkorta, and José Elguero. "Hybrid Boron-Carbon Chemistry." Molecules 25, no. 21 (2020): 5026. http://dx.doi.org/10.3390/molecules25215026.

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The recently proved one-to-one structural equivalence between a conjugated hydrocarbon CnHm and the corresponding borane BnHm+n is applied here to hybrid systems, where each C=C double bond in the hydrocarbon is consecutively substituted by planar B(H2)B moieties from diborane(6). Quantum chemical computations with the B3LYP/cc-pVTZ method show that the structural equivalences are maintained along the substitutions, even for non-planar systems. We use as benchmark aromatic and antiaromatic (poly)cyclic conjugated hydrocarbons: cyclobutadiene, benzene, cyclooctatetraene, pentalene, benzocyclobutadiene, naphthalene and azulene. The transformation of these conjugated hydrocarbons to the corresponding boranes is analyzed from the viewpoint of geometry and electronic structure.
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Грицук, I. Gritsuk, Амерханова, et al. "HEAT STORAGE MATERIALS BASED ON BINUCLEAR AROMATIC HYDROCARBONS." Alternative energy sources in the transport-technological complex: problems and prospects of rational use of 2, no. 1 (2015): 22–26. http://dx.doi.org/10.12737/13829.

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By cyclic and differential thermal analysis were studied conditions that reduce melt overcooling in a number of aromatic hydrocarbons such as diphenyl, diphenylethane, diphenylmethane, diphenylbenzols, naphthalene, and their mixtures. Based on experimental outcomes some practical conclusions were made for effective application of that substances as heat-accumulating materials. First of all, the thermal cycle, including melting and crystallization, is reasonable to carry outwith soft heating near the melting point for specified hydrocarbons. Secondly, it was concluded from the phase diagram analysis of hydrocarbon mixtures, that more effective will be using of alloys of eutectic composition (without thermal cycling limitation).
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Wu, Zhilin, Jan Lifka, and Bernd Ondruschka. "Aquasonolysis of selected cyclic C6H hydrocarbons." Ultrasonics Sonochemistry 11, no. 3-4 (2004): 187–90. http://dx.doi.org/10.1016/j.ultsonch.2004.01.028.

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Perez, Nancy, Thomas Heine, Robert Barthel, et al. "Planar Tetracoordinate Carbons in Cyclic Hydrocarbons." Organic Letters 7, no. 8 (2005): 1509–12. http://dx.doi.org/10.1021/ol050170m.

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HERRMANN, W. A. "ChemInform Abstract: Cyclic Hydrocarbons from Diazoalkanes." ChemInform 28, no. 50 (2010): no. http://dx.doi.org/10.1002/chin.199750317.

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Ichikawa, Hiroshi, and Ken Sakata. "Aromaticity/antiaromaticity in cyclic conjugated hydrocarbons." International Journal of Quantum Chemistry 87, no. 3 (2002): 135–44. http://dx.doi.org/10.1002/qua.10088.

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Byakov, Vsevolod, and Sergey V. Stepanov. "Towards the Positronium and Radiolytic Hydrogen Formation Mechanisms in Liquid Hydrocarbons." Materials Science Forum 733 (November 2012): 19–23. http://dx.doi.org/10.4028/www.scientific.net/msf.733.19.

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Ps and radiolytic hydrogen yields anticorrelate in saturated hydrocarbons when molecular structure changes from a normal to a cyclic form. This fact is explained by much higher mobility of primary radical-cations in cyclic hydrocarbons than in normal ones.
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Dissertations / Theses on the topic "Cyclic hydrocarbons"

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Bagga, Amit. "Femtosecond Laser Mass Spectroscopy of Cyclic Aromatic Hydrocarbons." Thesis, Université d'Ottawa / University of Ottawa, 2018. http://hdl.handle.net/10393/37098.

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Cyclic Aromatic molecules are the subject of continued research due to their highly advantageous characteristics which can be exploited in the areas of pharmaceuticals, material science and nano-electronics. While the defining properties and criteria for a molecule to be considered aromatic are very specific and well established, the degree of aromaticity of these molecules and their corresponding ordering remains a source of continued debate. Given that the macroscopic aromatic properties are fundamentally rooted in the underlying electronic structure and molecular dynamics, these properties can be probed in numerous ways. One such method is to exploit the strong laser field as it pertains to non-linear light-matter interaction. More specifically, the study of photoionization, as a direct resultant effect of strong field light-matter interaction, gives us direct insight into electronic and spatial properties as captured via mass spectroscopy. As a strong-field process, photoionization is effective because the variables that influence its results are also the ones that define aromaticity thus a correlation can be postulated. Other strong field advanced techniques to probe aromacity such as High Harmonic Generation (HHG) have already been successful shown by our group to be effective spectroscopic tools. In this way, photoionization provides supporting evidence to enhance the understanding of these novel spectroscopic tools. This thesis demonstrates that photoionization mass spectroscopy can be used as a probe into the aromaticity order of 5-membered cyclic aromatic molecules. Furthermore, the thesis will show that photoionization results correlate with the previously conducted HHG studies in this area thus further supporting these techniques as sensitive spectroscopic tools into aromaticity. The first part of this thesis describes the characterization of aromatic molecules and the corresponding process to obtain photoionization results that can be correlated to aromaticity. In the second part, these results are compared to the theoretical model and HHG demonstrating consistent results. The third and final component of this thesis describes future work, namely two-colour control of photoionization which is intended to provide greater resolution and variation of photoionization spectra thereby providing a more comprehensive and conclusive understanding of the proposed correlation with aromaticity.
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Martin, Caroline M. "Studies of ruthenium and osmium carbonyl clusters with unsaturated cyclic hydrocarbons." Thesis, University of Edinburgh, 1995. http://hdl.handle.net/1842/12583.

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Chapter one contains a brief summary of the cluster-surface analogy, with a structural comparison between metal clusters and the chemisorbed state. Particular emphasis is directed towards the adsorption sites adopted by benzene on the metal surface, and the analogous coordination modes found in cluster compounds. Chapter two describes the synthesis and characterisation of a number of benzene and cyclic C<SUB>6</SUB> alkene containing clusters based on an osmium tetrahedral framework, in which the chemistry is dominated by C-H bond activation reactions. Chapter three deals with the analogous ruthenium chemistry, in which a butterfly arrangement of the four metal atoms seems to predominate. An example of cluster mediated ring contraction and its relevance to surface chemistry is discussed, as is the synthesis of an octaruthenium benzene cluster. The molecular organization of arene cluster complexes in the solid-state is also presented. Chapter four introduces the [2.2]paracyclophane molecule as a new class of π-ligand in organometallic chemistry, and describes the synthesis of a number of ruthenium cluster derivatives, one of which is considered to be a key intermediate in the formation of carbido-atoms in such species. Unique metal polyhedra, and an unusual coordination mode for CO are described. Chapter five gives a detailed account of the reactivity of the triruthenium and hexaruthenium-carbido [2.2]paracyclophane clusters with ligands such as alkynes, phosphines and dienes. Products are discussed which serve as models for the chemisorption of benzene on the metal (111) surface. Chapter six presents the experimental details and spectroscopic and crystallographic data for all compounds synthesised throughout the work described in this thesis.
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Xu, Chen. "Investigation on the thermal decomposition of cyclic hydrocarbons with the shock tube technique." Berlin Logos-Verl, 2009. http://d-nb.info/997892986/04.

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Matsuura, Akira. "Synthesis and Properties of Novel Cyclic π-Conjugated Hydrocarbons with σ-π Interaction". 京都大学 (Kyoto University), 2001. http://hdl.handle.net/2433/150689.

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McMordie, Robert Austin Simms. "Synthetic, mechanistic and stereochemical studies of the primary metabolites of sulphides and cyclic hydrocarbons." Thesis, Queen's University Belfast, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335559.

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Sharma, Divya. "Computational investigation of the photochemistry and spectroscopy of cyclic aromatic hydrocarbons in interstellar ice analogs." Thesis, Heriot-Watt University, 2015. http://hdl.handle.net/10399/2965.

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This thesis describes the photochemistry and ultraviolet (UV) spectroscopy of cyclic aromatic hydrocarbons such as benzene and naphthalene, along with small water clusters and crystalline water ice clusters. Firstly, benzene and naphthalene interactions with small water hexamer (W6) clusters, and then benzene interactions with crystalline water ice clusters are investigated. This thesis primarily focuses on the applications of a range of computational chemistry techniques to investigate and characterize excited states of these complex systems, which are generated following one-photon absorption. Benzene and naphthalene, as prototypical polycyclic aromatic hydrocarbons (PAHs), and water and crystalline ice clusters, taken as representative of interstellar ices, could also be considered as useful model systems to replicate polycyclic aromatic hydrocarbons (PAHs) in interstellar ices, and to study their behaviour under UV processing. From coupled cluster (CC) benchmark studies on small water clusters up to water the pentamer, it is shown that that highly correlated linear-response coupled cluster methods such as CCSD and CC3 are important to consider while studying electronic excitations, as electron correlation effects play an important role in such systems, with double excitations playing a dominant role. However, triple excitations contributions calculated are negligible with CCSD and CC3 methods converging monotonically to similar results. The aggregation effect on water at CCSD level has shown a blue shift of ~ 0.7 eV in the central water molecule of water pentamer (C2v) relative to water monomer (C2v), and is in good agreement with the experimental blue shift of ~ 1 eV in condensed phase. For both benzene- and naphthalene-bound water W6 clusters, we have calculated interesting features of benzene- and naphthalene-mediated electronic excitations of the water W6 cluster at wavelengths where photon absorption cross section of water is negligible i.e., above 170 nm. These excitations were originally absent in the isolated water W6 cluster. Similar features are calculated for benzene-bound crystalline ice clusters, which also illustrate the effect of cyclic aromatic hydrocarbons on electronic excitations of ice clusters, and are also observed experimentally. The brightest π → π* electronic transition of benzene and naphthalene is calculated to be red-shifted in wavelength and occurs with lower intensities after interacting with the water W6 and ice clusters. The degeneracy of this transition is also slightly broken in benzene. We have observed new electronic transition features such as charge transfer (CT), and locally diffuse Rydberg type excitation in these complexes. We have found a good performance of hybrid DFT functionals i.e. M06-2X and CAM-B3LYP in calculating vertical excitation energies of these complexes using time dependent density functional theory (TD-DFT). Further, diffusion studies of the deuterium (D) atom have shown the importance of surface morphology in generating different potential sites and hopping characteristics of the D atom on crystalline and amorphous ice surfaces. D2 formation is found to be efficient on the amorphous ice surface, with longer residence times of the D atom indicating a possibility of the deuterium atom getting trapped in such sites. There is then a further possibility of the diffusing D atom to recombine with the trapped D atom to form a D2 molecule. However, such D atom trapping is a rare possibility on crystalline surface, as hopping is fast and thus the recombination process is not efficient on crystalline ice surface.
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Ihm, Hyeran. "Thermal activation and intermediates of six-membered cyclic hydrocarbons and alkyl nitrites on Pt(111) and Cu(100) /." Digital version accessible at:, 2000. http://wwwlib.umi.com/cr/utexas/main.

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Barthel, Robert. "Growth of unsaturated, cyclic, and polycyclic aromatic hydrocarbons: Reactions under the conditions of the interstellar medium." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2009. http://nbn-resolving.de/urn:nbn:de:bsz:14-ds-1238024025498-21465.

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Hydrocarbons, in particular polycyclic aromatic hydrocarbons (PAHs), have been long discussed to be carriers of interstellar infrared (IR) emission and ultraviolet (UV) absorption features. Yet, their origin in dense phases of the interstellar medium (ISM), such as molecular clouds, remains unclear. In this work, growth mechanisms based on ion-molecule reactions between cationic PAHs/hydrocarbons and methyne (CH) were investigated. The reaction type and the precursor were derived and selected from known chemical and physical properties of the ISM. These chemical reactions were characterised by calculating branching ratios (based on cross sections) and capture rate coefficients, minimum reaction paths, reaction enthalpies, thermal equilibrium constants, and microcanonic isomerisation and radiative deactivation rate coefficients. In order to cope with the variety of reaction parameters, a hierarchic workflow scheme was set up. First, the reaction potential energy surface was sampled by molecular dynamics simulations. Then, minimum energy paths of the most probable reaction channels were investigated. Finally, molecular and kinetic properties of stationary points were calculated. The quantum chemical level of theory was increased at each step from DFTB (tight-binding density-functional), to DFT, and finally to post-Hartree-Fock methods. Results on CH based hydrocarbon growth showed the transition from non-cyclic hydrocarbons to cyclic and aromatic structures and from cyclic to polycyclic aromatic hydrocarbons. Additionally, the reactive collisions between hydrocarbons and CH were found to produce sufficient energy for isomerisation and fragmentation processes even at ultra low temperatures. In all, the results indicate that methyne might be a proper precursor for the formation of large interstellar PAHs<br>Kohlenwasserstoffe, insbesondere polyzyklische Kohlenwasserstoffe (engl. PAHs), werden seit einigen Jahren als Mitverursacher interstellar IR-Emissions- und UV-Absorptionsbanden angesehen und diskutiert. Dabei ist die Herkunft dieser Moleküle in den dichten Phasen des interstellaren Mediums (ISM) aber noch nicht aufgeklärt. In dieser Arbeit wurden daher die Bildungsmechanismen, welche auf Ion-Molekül-Reaktionen zwischen kationischen PAHs und Kohlenwasserstoffen und dem Molekül CH beruhen, untersucht. Sowohl der Reaktionstyp als auch der Präkursor wurden anhand von bekannten physikalischen und chemischen Eigenschaften des ISM abgeleitet und ausgewählt. Die Analyse der chemischen Reaktionen basierte auf Berechnungen zur Produktzusammensetzung und Einfangsratenkoeffizienten (welche wiederum aus berechneten Reaktionsquerschnitten hervorgingen) Minimumenergiepfade (MEP), Reaktionsenthalpien, thermische Gleichgewichtskonstanten und mikrokanonische Isomerisierungs- und Strahlungsdeaktivierungs-Ratenkoeffizienten. Um der Vielzahl an Reaktionsparameter gerecht zu werden, wurden die Berechnungsmethoden entsprechend eines hierarischen Fließschemas kombiniert. Hierzu wurden zuerst durch Molekulardynamik-Simulationen die Reaktionspotentialenergieflächen abgerastert. Auf der nächsten Stufe wurden statistisch bedeutsame Reaktionskanäle bezüglich ihrer Minimumenergiepfade untersucht. Den Abschluss bildete die Berechnung molekularer und kinetischer Charakteristika stationärer Punkte auf einem MEP. Entsprechend dieses Schemas wurde die quantenchemische Genauigkeit auf jeder Stufe von approximativer DFT über DFT zu post-Hartree-Fock verändert. Die Ergebnisse des CH-basierten Kohlenwasserstoffwachstums zeigten einen Übergang von nichtzyklischen zu zyklischen and aromatischen Strukturen, sowie von zyklischen zu polyzyklischen Kohlenwasserstoffen. Außerdem zeigte sich, dass reaktive Kollisionen zwischen Kohlenwasserstoffen und CH auch bei Tiefsttemperaturen immer ausreichend Energie für Isomerisierungs- und Fragmentationsprozesse liefert. Die Ergebnisse dieser Arbeit lassen den Schluss zu, dass CH ein geeigneter Präkursor für die Bildung großer interstellarer PAH ist
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Barthel, Robert. "Growth of unsaturated, cyclic, and polycyclic aromatic hydrocarbons: Reactions under the conditions of the interstellar medium." Doctoral thesis, Technische Universität Dresden, 2008. https://tud.qucosa.de/id/qucosa%3A23589.

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Hydrocarbons, in particular polycyclic aromatic hydrocarbons (PAHs), have been long discussed to be carriers of interstellar infrared (IR) emission and ultraviolet (UV) absorption features. Yet, their origin in dense phases of the interstellar medium (ISM), such as molecular clouds, remains unclear. In this work, growth mechanisms based on ion-molecule reactions between cationic PAHs/hydrocarbons and methyne (CH) were investigated. The reaction type and the precursor were derived and selected from known chemical and physical properties of the ISM. These chemical reactions were characterised by calculating branching ratios (based on cross sections) and capture rate coefficients, minimum reaction paths, reaction enthalpies, thermal equilibrium constants, and microcanonic isomerisation and radiative deactivation rate coefficients. In order to cope with the variety of reaction parameters, a hierarchic workflow scheme was set up. First, the reaction potential energy surface was sampled by molecular dynamics simulations. Then, minimum energy paths of the most probable reaction channels were investigated. Finally, molecular and kinetic properties of stationary points were calculated. The quantum chemical level of theory was increased at each step from DFTB (tight-binding density-functional), to DFT, and finally to post-Hartree-Fock methods. Results on CH based hydrocarbon growth showed the transition from non-cyclic hydrocarbons to cyclic and aromatic structures and from cyclic to polycyclic aromatic hydrocarbons. Additionally, the reactive collisions between hydrocarbons and CH were found to produce sufficient energy for isomerisation and fragmentation processes even at ultra low temperatures. In all, the results indicate that methyne might be a proper precursor for the formation of large interstellar PAHs.<br>Kohlenwasserstoffe, insbesondere polyzyklische Kohlenwasserstoffe (engl. PAHs), werden seit einigen Jahren als Mitverursacher interstellar IR-Emissions- und UV-Absorptionsbanden angesehen und diskutiert. Dabei ist die Herkunft dieser Moleküle in den dichten Phasen des interstellaren Mediums (ISM) aber noch nicht aufgeklärt. In dieser Arbeit wurden daher die Bildungsmechanismen, welche auf Ion-Molekül-Reaktionen zwischen kationischen PAHs und Kohlenwasserstoffen und dem Molekül CH beruhen, untersucht. Sowohl der Reaktionstyp als auch der Präkursor wurden anhand von bekannten physikalischen und chemischen Eigenschaften des ISM abgeleitet und ausgewählt. Die Analyse der chemischen Reaktionen basierte auf Berechnungen zur Produktzusammensetzung und Einfangsratenkoeffizienten (welche wiederum aus berechneten Reaktionsquerschnitten hervorgingen) Minimumenergiepfade (MEP), Reaktionsenthalpien, thermische Gleichgewichtskonstanten und mikrokanonische Isomerisierungs- und Strahlungsdeaktivierungs-Ratenkoeffizienten. Um der Vielzahl an Reaktionsparameter gerecht zu werden, wurden die Berechnungsmethoden entsprechend eines hierarischen Fließschemas kombiniert. Hierzu wurden zuerst durch Molekulardynamik-Simulationen die Reaktionspotentialenergieflächen abgerastert. Auf der nächsten Stufe wurden statistisch bedeutsame Reaktionskanäle bezüglich ihrer Minimumenergiepfade untersucht. Den Abschluss bildete die Berechnung molekularer und kinetischer Charakteristika stationärer Punkte auf einem MEP. Entsprechend dieses Schemas wurde die quantenchemische Genauigkeit auf jeder Stufe von approximativer DFT über DFT zu post-Hartree-Fock verändert. Die Ergebnisse des CH-basierten Kohlenwasserstoffwachstums zeigten einen Übergang von nichtzyklischen zu zyklischen and aromatischen Strukturen, sowie von zyklischen zu polyzyklischen Kohlenwasserstoffen. Außerdem zeigte sich, dass reaktive Kollisionen zwischen Kohlenwasserstoffen und CH auch bei Tiefsttemperaturen immer ausreichend Energie für Isomerisierungs- und Fragmentationsprozesse liefert. Die Ergebnisse dieser Arbeit lassen den Schluss zu, dass CH ein geeigneter Präkursor für die Bildung großer interstellarer PAH ist.
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Forsberg, Björn. "Classical over-the-barrier model for ionization of poly-cyclic aromatic hydrocarbons in keV-collisions with atomic ions." Thesis, Stockholms universitet, Fysikum, 2011. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-60168.

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We are developing a novel classical over-the barrier model for electron transfer from an in nitely thin conducting disc to a point charge projectile to model multiple electron capture in e.g. keV collisions of atomic ions with poly-cyclic aromatic hydrocarbons (PAHs). In its nal form, the present model will incorporate the polarization of the PAH molecules due to the active electron and the point charge projectile at a general angle of incidence. This will drastically improve the description of the potential barrier in comparisons with simpler versions of the model where the nite size and polarizability of the target molecule is neglected or treated in an averaged fashion. In this work we arrive at expressions for the electrostatic potential energy barrier experienced by the active electron in the two spatial orientations where the point charge projectile is located along the normal symmetry axis and in the tangent plane of the disc. Applied to coronene (C24H12) such barriers compare better with high level density functional theory (DFT) calculations than with the results from the simpler versions of the classical over-the-barrier models for atomic and spherical cluster targets. These results thus strongly supports the conducting disc approximation of PAHs. Finally we discuss the nal steps in the model development and possible extensions of the model to include less symmetric elliptical discs or spherical caps.
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Books on the topic "Cyclic hydrocarbons"

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Parker, Philip M. The World Market for Cyclic Hydrocarbons: A 2007 Global Trade Perspective. ICON Group International, Inc., 2006.

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Parker, Philip M. The 2007 Import and Export Market for Cyclic Hydrocarbons in China. ICON Group International, Inc., 2006.

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Parker, Philip M. The 2007 Import and Export Market for Cyclic Hydrocarbons in India. ICON Group International, Inc., 2006.

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Parker, Philip M. The 2007 Import and Export Market for Cyclic Hydrocarbons in United States. ICON Group International, Inc., 2006.

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Relative lifetimes of MAPLUB® greases for space applications. National Aeronautics and Space Administration, Glenn Research Center, 2002.

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Parker, Philip M. The 2007-2012 World Outlook for Distilling Coal Tars and Manufacturing Cyclic Crudes, Cyclic Intermediates, and Hydrocarbons from Refined Petroleum or Natural Gas Excluding Petrochemicals. ICON Group International, Inc., 2006.

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The 2006-2011 World Outlook for Manufacturing Acyclic, Aliphatic, or Cyclic Aromatic Hydrocarbons Made from Refined Petroleum or Liquid Hydrocarbons Such ... Styrene, Xylene, Ethyl Benzene, and Cumene. Icon Group International, Inc., 2005.

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Parker, Philip M. The 2007-2012 World Outlook for Manufacturing Acyclic, Aliphatic, or Cyclic Aromatic Hydrocarbons Made from Refined Petroleum or Liquid Hydrocarbons Such ... Styrene, Xylene, Ethyl Benzene, and Cumene. ICON Group International, Inc., 2006.

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Paulson, CAJ. Greenhouse Gas Control Technologies. Edited by RA Durie, DJ Williams, AY Smith, and P. McMullan. CSIRO Publishing, 2001. http://dx.doi.org/10.1071/9780643105027.

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The control of greenhouse gas emissions continues to be a major global problem. It is inter-disciplinary, both in substance and approach, and covers technical, political and economic issues involving governments, industry and the scientific community.&#x0D; These proceedings contain 220 papers presented at the 5th International Conference on Greenhouse Gas Control Technologies (GHGT-5) held in August 2000 at Cairns, Queensland, Australia.&#x0D; The papers cover the capture of carbon dioxide, geological storage of carbon dioxide, ocean storage of carbon dioxide, storage of carbon dioxide with enhanced hydrocarbon recovery, utilisation of carbon dioxide, other greenhouse gases, fuel cells, alternative energy carriers, energy efficiency, life cycle assessments and energy modelling, economics, international and national policy, trading and accounting policy, social and community issues, and reducing emission from industry and power generation.
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Book chapters on the topic "Cyclic hydrocarbons"

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Baev, Alexei K. "Specific Intermolecular Interactions of Nitrogen and Oxygen Containing Cyclic Hydrocarbons." In Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-37472-2_7.

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Löhmannsröben, H. G., and K. Luther. "Intramolecular Kinetics of Vibrationally Excited Singlet and Triplet States in Some Cyclic Hydrocarbons." In Springer Proceedings in Physics. Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-642-47541-2_38.

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Barfield, Michael. "Ab Initio IGLO Studies of the Conformational Dependence of the γ-Effect in the 13C NMR Spectra of Cyclic Hydrocarbons." In Nuclear Magnetic Shieldings and Molecular Structure. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1652-7_27.

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Bižić-Ionescu, Mina, Danny Ionescu, Marco Günthel, Kam W. Tang, and Hans-Peter Grossart. "Oxic Methane Cycling: New Evidence for Methane Formation in Oxic Lake Water." In Biogenesis of Hydrocarbons. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-53114-4_10-1.

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Bižić-Ionescu, Mina, Danny Ionescu, Marco Günthel, Kam W. Tang, and Hans-Peter Grossart. "Oxic Methane Cycling: New Evidence for Methane Formation in Oxic Lake Water." In Biogenesis of Hydrocarbons. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-78108-2_10.

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Konstantinova, M., and N. Koprinarov. "Cyclic Hydrocarbon Decomposition to Carbon Nanoparticles via Spark Discharge." In Carbon Nanomaterials in Clean Energy Hydrogen Systems - II. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-94-007-0899-0_9.

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Mørk, Atle, Ashton F. Embry, and Wolfgang Weitschat. "Triassic transgressive-regressive cycles in the Sverdrup Basin, Svalbard and the Barents Shelf." In Correlation in Hydrocarbon Exploration. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-1149-9_11.

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Sahonero-Canavesi, Diana X., Isabel M. López-Lara, and Otto Geiger. "Membrane Lipid Degradation and Lipid Cycles in Microbes." In Aerobic Utilization of Hydrocarbons, Oils and Lipids. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-39782-5_38-1.

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Sahonero-Canavesi, Diana X., Isabel M. López-Lara, and Otto Geiger. "Membrane Lipid Degradation and Lipid Cycles in Microbes." In Aerobic Utilization of Hydrocarbons, Oils, and Lipids. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-50418-6_38.

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Whiticar, Michael J. "The Biogeochemical Methane Cycle." In Hydrocarbons, Oils and Lipids: Diversity, Origin, Chemistry and Fate. Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-319-90569-3_5.

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Conference papers on the topic "Cyclic hydrocarbons"

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Wang, J. L., Q. Liu, W. Feng, W. Che, and J. Q. Li. "The study of poly cyclic aromatic hydrocarbons pollution characteristics in Changhe River." In 3rd International Conference on Contemporary Problems in Architecture and Construction. IET, 2011. http://dx.doi.org/10.1049/cp.2011.1243.

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"The Poly Cyclic Hydrocarbons levels In Some Fishes Tissues Collected From Derna City ( LIBYA) Coast." In International Conference on Chemical, Agricultural and Medical Sciences. International Institute of Chemical, Biological & Environmental Engineering, 2014. http://dx.doi.org/10.15242/iicbe.c514080.

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Grohmann, Jasper, Wolfgang Meier, and Manfred Aigner. "Gas Turbine Model Combustor Emissions of Liquid Single-Component Fuels." In ASME Turbo Expo 2017: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/gt2017-63182.

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Alternative liquid fuels can contain hydrocarbons of different types and chain lengths and the fuel composition has an influence on combustion behavior. In this study, the influence of liquid single-component fuels on exhaust gas emissions of a gas turbine model combustor for swirl-stabilized spray flames was investigated under atmospheric pressure. The nozzle exhibited a dual-swirl geometry and a prefilming airblast atomizer. The spray was characterized by Phase Doppler Anemometry (PDA) and Mie scattering measurements and the flame CH* chemiluminescence was measured. Six single-component hydrocarbons were chosen: three linear alkanes (n-hexane, n-nonane, n-dodecane), one cyclic alkane (cyclohexane), one branched alkane (iso-octane) and one aromatic hydrocarbon (toluene). Kerosene Jet A-1 was used as a technical reference. Results show minor differences in CO emissions and significant differences in NOx emissions of the various fuels at comparable flow conditions and adiabatic flame temperatures. The measurements indicate a correlation between the nitric oxide emissions and the spray quality.
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Idrisov, D. V., S. S. Matveev, S. G. Matveev, N. I. Gurakov, I. V. Chechet, and A. S. Semenikhin. "EXPERIMENTAL AND NUMERICAL STUDY OF COMBUSTION OF AVIATION KEROSENE TS-1 SURROGATES." In 9TH INTERNATIONAL SYMPOSIUM ON NONEQUILIBRIUM PROCESSES, PLASMA, COMBUSTION, AND ATMOSPHERIC PHENOMENA. TORUS PRESS, 2020. http://dx.doi.org/10.30826/nepcap9a-26.

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The article analyzes two types of kerosene surrogates: six-component SU1 and four-component SU2. The characteristics of the both differ from the accepted reference values no more than by 1%. It is revealed that multicomponent surrogates are necessary for reproducing the physicochemical properties of the real aviation kerosene. In addition, various classes of hydrocarbons such as alkanes, cyclic alkanes, and aromatic hydrocarbons should be included in order to meet these properties. Other parameters such as density, H/C ratio, and molar mass impose additional and important constraints on the development of surrogates. Several methods for combined reactor prediction of the concentrations of carcinogenic polycyclic aromatic hydrocarbons (PAHs) in aircraft kerosene combustion chambers have been proposed and investigated.
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Selim, Mohamed Y. E., M. S. Radwan, and H. E. Saleh. "Performance of Dual Fuel Engine Running on Jojoba Oil as Pilot Fuel and CNG or LPG." In ASME/JSME 2007 Thermal Engineering Heat Transfer Summer Conference collocated with the ASME 2007 InterPACK Conference. ASMEDC, 2007. http://dx.doi.org/10.1115/ht2007-32016.

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The use of Jojoba Methyl Ester as a pilot fuel was investigated for almost the first time as a way to improve the performance of dual fuel engine running on natural gas or LPG at part load. The dual fuel engine used was Ricardo E6 variable compression diesel engine and it used either compressed natural gas (CNG) or liquefied petroleum gas (LPG) as the main fuel and Jojoba Methyl Ester as a pilot fuel. Diesel fuel was used as a reference fuel for the dual fuel engine results. During the experimental tests, the following have been measured: engine efficiency in terms of specific fuel consumption, brake power output, combustion noise in terms of maximum pressure rise rate and maximum pressure, exhaust emissions in terms of carbon monoxide and hydrocarbons, knocking limits in terms of maximum torque at onset of knocking, and cyclic data of 100 engine cycle in terms of maximum pressure and its pressure rise rate. The tests examined the following engine parameters: gaseous fuel type, engine speed and load, pilot fuel injection timing, pilot fuel mass and compression ratio. Results showed that using the Jojoba fuel with its improved properties has improved the dual fuel engine performance, reduced the combustion noise, extended knocking limits and reduced the cyclic variability of the combustion.
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Zheng, Ming, Usman Asad, Xiaoye Han, Meiping Wang, and Graham T. Reader. "Hydrocarbon Impacts on Diesel HCCI Engine Cycles." In ASME 2009 Internal Combustion Engine Division Fall Technical Conference. ASMEDC, 2009. http://dx.doi.org/10.1115/icef2009-14012.

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Thermal efficiency and NOx emission comparisons are made between the homogeneous charge compression ignition (HCCI) and the conventional diesel cycles on a number of common-rail diesel engine platforms of high compression ratios with conventional diesel fuel and dimethyl ether as a surrogate fuel. The empirical studies have been conducted under independently controlled exhaust gas recirculation (EGR), intake boost, and exhaust backpressure. The energy relevance of the combustible substances such as carbon monoxide and hydrocarbon species in the engine exhaust has been evaluated quantitatively. However, the impact of the hydrocarbons produced during the HCCI cycles on the attainment of ultra low levels of NOx is less understood and it is unclear if the hydrocarbon species are a precursor to the ultra low NOx and also contribute in part to the NOx reduction. Therefore, the chemical impact of the hydrocarbon species on the NOx emission under low temperature combustion cycles has been examined with crank-angle resolved in-cylinder sampling techniques and fast-response emission analyzers. This paper intends to identify the major impacts of the hydrocarbons on the fuel efficiency and emissions of diesel HCCI cycles.
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Revana, Karthik, and Meftun H. Erdogan. "Optimization of Cyclic Steam Stimulation under Uncertainty." In Hydrocarbon Economics and Evaluation Symposium. Society of Petroleum Engineers, 2007. http://dx.doi.org/10.2118/107949-ms.

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Franco, Egberto Gomes, Paulo Lucas Dantas Filho, Carlos Eduardo Rollo Ribeiro, Geraldo Francisco Burani, and Marcelo Linardi. "Proton Exchange Membrane Fuel Cell Catalyst: Synthesis and Characterization." In ASME 2008 6th International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2008. http://dx.doi.org/10.1115/fuelcell2008-65068.

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Fuel cells are a promising technology to deal with energy sustainability, especially for mobility purposes the Proton Exchange Membrane Fuel Cell and hydrogen produced from biomass could be coupled to overcome the amount of CO2 emissions. In order to improve fuel cells performances the search for new electrocatalysts has a great importance in this technology the challenge for a fuel cell catalyst that is less poisoned by CO is one of the most important field in low temperature fuel cell developments that use alcohol and hydrocarbons as primary fuels. In this work PtSm, PtTb, PtDy, PtU, PtRuMo and PtRuDy systems have been synthesized by the colloid method, investigated by the following techniques: X-rays fluorescence analysis (XFA), X-rays powder diffraction (XRD), X-rays photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), cyclic voltammetry (CV) and polarization curves (Exi). The results obtained in this work shows that PtRuMo is the best choice for direct methanol oxidation. For direct ethanol oxidation the higher activity was found in PtRuDy system. PtU system was investigated and showed an interesting behaviour in ethanol oxidation. After two cycles of H2/O2 and ethanol/O2 the catalyst was able to reach the initial figures on hydrogen/oxygen oxidation which means that no degradation of the catalyst was indentified.
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Frenette, C. T., M. Saeedi, and J. L. Henke. "Integrated Economic Model for Evaluation and Optimization of Cyclic Steam Stimulation Projects." In SPE Hydrocarbon Economics and Evaluation Symposium. Society of Petroleum Engineers, 2014. http://dx.doi.org/10.2118/169859-ms.

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Hakeem, Mohannad, James Anderson, Gopichandra Surnilla, and Shuya Shark Yamada. "Characterization and Speciation of Fuel Oil Dilution in Gasoline Direct Injection (DI) Engines." In ASME 2015 Internal Combustion Engine Division Fall Technical Conference. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/icef2015-1072.

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Fuel dilution in oil is a known issue for gasoline direct injection (DI) engines especially in colder climates and for customers with short, lightly-loaded driving cycles. In this work, oil samples were generated using a cold oil fuel accumulation test. Gas chromatography (GC) was used to speciate the hydrocarbons accumulated in the oil and characterize their quantity, type, molecular weight distribution, and volatility. Further testing and analysis was done to characterize the fuel hydrocarbons that evaporate from oil during engine warm-up conditions. The results demonstrate how the wide range of gasoline hydrocarbon volatility leads to different behavior in the accumulation and subsequent evaporation phases. Lastly, a model was created to extend this analysis and estimate the evaporation of hydrocarbons from the oil.
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Reports on the topic "Cyclic hydrocarbons"

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Demuth, O. J., C. J. Bliem, G. L. Mines, and W. D. Swank. Supercritical binary geothermal cycle experiments with mixed-hydrocarbon working fluids and a vertical, in-tube, counterflow condenser. Office of Scientific and Technical Information (OSTI), 1985. http://dx.doi.org/10.2172/6053602.

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Bliem, C. J., and G. L. Mines. Supercritical binary geothermal cycle experiments with mixed-hydrocarbon working fluids and a near-horizontal in-tube condenser. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/6532956.

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