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Journal articles on the topic 'Cyclic hydrocarbons'

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Published: 4 June 2021
Last updated: 1 February 2022

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1

Perkins, Robert R. "Stereochemistry of cyclic hydrocarbons." Journal of Chemical Education 65, no. 10 (1988): 860. http://dx.doi.org/10.1021/ed065p860.

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2

MORI, Takaaki. "Toxicity of chlorinated cyclic hydrocarbons." Okayama Igakkai Zasshi (Journal of Okayama Medical Association) 98, no. 9-10 (1986): 809–18. http://dx.doi.org/10.4044/joma1947.98.9-10_809.

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3

Himmerich, M., P. G. J. van Dongen та R. M. Noack. "Cyclic hydrocarbons: nanoscopic (π)-SQUIDs?" European Physical Journal B 51, № 1 (2006): 5–15. http://dx.doi.org/10.1140/epjb/e2006-00184-y.

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4

Oliva-Enrich, Josep M., Ibon Alkorta, and José Elguero. "Hybrid Boron-Carbon Chemistry." Molecules 25, no. 21 (2020): 5026. http://dx.doi.org/10.3390/molecules25215026.

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The recently proved one-to-one structural equivalence between a conjugated hydrocarbon CnHm and the corresponding borane BnHm+n is applied here to hybrid systems, where each C=C double bond in the hydrocarbon is consecutively substituted by planar B(H2)B moieties from diborane(6). Quantum chemical computations with the B3LYP/cc-pVTZ method show that the structural equivalences are maintained along the substitutions, even for non-planar systems. We use as benchmark aromatic and antiaromatic (poly)cyclic conjugated hydrocarbons: cyclobutadiene, benzene, cyclooctatetraene, pentalene, benzocyclobutadiene, naphthalene and azulene. The transformation of these conjugated hydrocarbons to the corresponding boranes is analyzed from the viewpoint of geometry and electronic structure.
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5

Грицук, I. Gritsuk, Амерханова, et al. "HEAT STORAGE MATERIALS BASED ON BINUCLEAR AROMATIC HYDROCARBONS." Alternative energy sources in the transport-technological complex: problems and prospects of rational use of 2, no. 1 (2015): 22–26. http://dx.doi.org/10.12737/13829.

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By cyclic and differential thermal analysis were studied conditions that reduce melt overcooling in a number of aromatic hydrocarbons such as diphenyl, diphenylethane, diphenylmethane, diphenylbenzols, naphthalene, and their mixtures. Based on experimental outcomes some practical conclusions were made for effective application of that substances as heat-accumulating materials. First of all, the thermal cycle, including melting and crystallization, is reasonable to carry outwith soft heating near the melting point for specified hydrocarbons. Secondly, it was concluded from the phase diagram analysis of hydrocarbon mixtures, that more effective will be using of alloys of eutectic composition (without thermal cycling limitation).
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6

Wu, Zhilin, Jan Lifka, and Bernd Ondruschka. "Aquasonolysis of selected cyclic C6H hydrocarbons." Ultrasonics Sonochemistry 11, no. 3-4 (2004): 187–90. http://dx.doi.org/10.1016/j.ultsonch.2004.01.028.

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7

Perez, Nancy, Thomas Heine, Robert Barthel, et al. "Planar Tetracoordinate Carbons in Cyclic Hydrocarbons." Organic Letters 7, no. 8 (2005): 1509–12. http://dx.doi.org/10.1021/ol050170m.

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8

HERRMANN, W. A. "ChemInform Abstract: Cyclic Hydrocarbons from Diazoalkanes." ChemInform 28, no. 50 (2010): no. http://dx.doi.org/10.1002/chin.199750317.

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9

Ichikawa, Hiroshi, and Ken Sakata. "Aromaticity/antiaromaticity in cyclic conjugated hydrocarbons." International Journal of Quantum Chemistry 87, no. 3 (2002): 135–44. http://dx.doi.org/10.1002/qua.10088.

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10

Byakov, Vsevolod, and Sergey V. Stepanov. "Towards the Positronium and Radiolytic Hydrogen Formation Mechanisms in Liquid Hydrocarbons." Materials Science Forum 733 (November 2012): 19–23. http://dx.doi.org/10.4028/www.scientific.net/msf.733.19.

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Ps and radiolytic hydrogen yields anticorrelate in saturated hydrocarbons when molecular structure changes from a normal to a cyclic form. This fact is explained by much higher mobility of primary radical-cations in cyclic hydrocarbons than in normal ones.
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11

Gao, Hongwei, Richard F. W. Bader, and Fernando Cortés-Guzmán. "Energy additivity in branched and cyclic hydrocarbons." Canadian Journal of Chemistry 87, no. 11 (2009): 1583–92. http://dx.doi.org/10.1139/v09-121.

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This paper considers the degree to which branched hydrocarbons obey a group additivity scheme for energy and population, extending the study of the known experimental and theoretical transferability of the methyl and methylene groups of the linear hydrocarbons. The chemical groups are defined and their properties are determined using the quantum theory of atoms in molecules (QTAIM). The calculations are carried out with a large basis set at the restricted Hartree–Fock and MP2(full) levels of theory. The deviations from additivity, noted for small ring hydrocarbons leading to the definition of strain energy, are also investigated, showing that the QTAIM energies recover the experimental values. The particular delocalization of the electron density over the surface of the cyclopropane ring, responsible for its “homoaromatic” properties, is discussed in some detail. The calculations reported here satisfy the virial theorem as required for the atomic definition of energy. The problems associated with the use of DFT theory arising from its failure to satisfy the virial theorem are discussed with reference to the study of group transferability.
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12

Silverwood, I. P., and J. Armstrong. "Surface diffusion of cyclic hydrocarbons on nickel." Surface Science 674 (August 2018): 13–17. http://dx.doi.org/10.1016/j.susc.2018.03.012.

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13

Pike, Robert D., та Dwight A. Sweigart. "Electrophilic reactivity of coordinated cyclic π-hydrocarbons". Coordination Chemistry Reviews 187, № 1 (1999): 183–222. http://dx.doi.org/10.1016/s0010-8545(98)00231-8.

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14

Sikkema, J., J. A. de Bont, and B. Poolman. "Interactions of cyclic hydrocarbons with biological membranes." Journal of Biological Chemistry 269, no. 11 (1994): 8022–28. http://dx.doi.org/10.1016/s0021-9258(17)37154-5.

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15

Kubátová, Alena, Jana Št’ávová, Wayne S. Seames, et al. "Triacylglyceride Thermal Cracking: Pathways to Cyclic Hydrocarbons." Energy & Fuels 26, no. 1 (2011): 672–85. http://dx.doi.org/10.1021/ef200953d.

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16

Haines, J., and D. F. R. Gilson. "Phase Transitions in Cyclic Hydrocarbons: 1,3-Cycloheptadiene." Molecular Crystals and Liquid Crystals 182, no. 1 (1990): 405–16. http://dx.doi.org/10.1080/00268949008035769.

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17

Hlavathy, Zoltán, and Pál Tétényi. "Uptake of C6 cyclic hydrocarbons on Pt." Vacuum 61, no. 2-4 (2001): 119–22. http://dx.doi.org/10.1016/s0042-207x(00)00466-8.

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18

Perez-Peralta, Nancy, Mario Sanchez, Jesus Martin-Polo, Rafael Islas, Alberto Vela, and Gabriel Merino. "Planar Tetracoordinate Carbons in Cyclic Semisaturated Hydrocarbons." Journal of Organic Chemistry 73, no. 18 (2008): 7037–44. http://dx.doi.org/10.1021/jo800885x.

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19

Bryuske, Ya É. "Chain numbering and encoding of cyclic hydrocarbons." Journal of Structural Chemistry 36, no. 4 (1995): 661–65. http://dx.doi.org/10.1007/bf02578660.

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20

Igarashi, Kei M., and Kensaku Mori. "Spatial Representation of Hydrocarbon Odorants in the Ventrolateral Zones of the Rat Olfactory Bulb." Journal of Neurophysiology 93, no. 2 (2005): 1007–19. http://dx.doi.org/10.1152/jn.00873.2004.

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The glomerular sheet of the olfactory bulb (OB) forms odorant receptor maps that are parceled into zones. We previously reported the molecular receptive range (MRR) property of individual glomeruli in the dorsal zone (zone 1) of the OB and showed that polar functional groups play a major role in activating glomeruli in this zone. However, the MRR property of glomeruli in zones 2–4 is not well understood yet. Using the method of intrinsic signal imaging, we recorded odorant-induced glomerular activity from the ventrolateral surface (zones 2–4) of rat OB. While hydrocarbon odorants that lack polar functional groups activate only a few glomeruli in zone 1, we found that a series of hydrocarbon odorants consistently activated many glomeruli in the ventrolateral surface. The hydrocarbon-responsive glomeruli were grouped into two clusters; glomeruli in one cluster (cluster H) responded to benzene-family hydrocarbons but not to cyclic terpene hydrocarbons. Glomeruli in the other cluster (cluster I) responded to both classes of hydrocarbons. Detailed analyses of MRR properties of individual glomeruli using hydrocarbon odorants and polar-functional-group-containing odorants showed that the common and characteristic molecular features effective in activating glomeruli in the clusters H and I are the hydrocarbon skeleton. These results suggest that ORs represented by glomeruli in these clusters recognize primarily the hydrocarbon skeleton of odorants, and thus imply a systematic difference in the manner of recognizing odorant molecular features between ORs in zone 1 and ORs in zones 2–4.
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21

Schmitz, Heiko, Roland Faller, and Florian Müller-Plathe. "Molecular Mobility in Cyclic Hydrocarbons: A Simulation Study." Journal of Physical Chemistry B 103, no. 44 (1999): 9731–37. http://dx.doi.org/10.1021/jp990761s.

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22

Bethke, Sabine, Stefan Brand, Bj�rn Treptow, and Rolf Gleiter. "Strained hydrocarbons from cyclic diynes?preparation and reactivity." Journal of Physical Organic Chemistry 15, no. 8 (2002): 484–89. http://dx.doi.org/10.1002/poc.500.

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23

Gutman, Ivan, Vesna Ivanov-Petrović, and Jerry R. Dias. "Cyclic Conjugation in Total Resonant Sextet Benzenoid Hydrocarbons." Polycyclic Aromatic Compounds 18, no. 2 (2000): 221–29. http://dx.doi.org/10.1080/10406630008028147.

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24

Luo, Wen-zhi, Guang-hui Chen, Song-tao Xiao, Qiang Wang, Ze-kun Huang, and Ling-yu Wang. "The enzyme-like catalytic hydrogen abstraction reaction mechanisms of cyclic hydrocarbons with magnesium-diluted Fe-MOF-74." RSC Advances 9, no. 41 (2019): 23622–32. http://dx.doi.org/10.1039/c9ra04495g.

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25

Disnar, J. R., and Y. Héroux. "Dégradation et lessivage des hydrocarbures de la formation ordovicienne de Thumb Mountain encaissant le gîte Zn–Pb de Polaris (Territoires du Nord-Ouest, Canada)." Canadian Journal of Earth Sciences 32, no. 7 (1995): 1017–34. http://dx.doi.org/10.1139/e95-084.

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Carbonate rocks of the Ordovician Thumb Mountain Formation, host to the Zn–Pb Polaris deposit, contain hydrocarbons that show types of alteration classically attributed to biodegradation and water washing. The hydrocarbons of the upper part of this formation and of the overlying Irene Bay Formation indicate alterations due to water washing only. The hydrocarbons of the impermeable shales of the overlying Cape Phillips Formation display indices of only higher thermal maturity than the underlying units. Contrary to classical concepts of hydrocarbon biodegradation, n-alkanes, cyclohexylalkanes, even isoprenoids and perhaps also steranes seem to have been degraded simultaneously and not successively in this sequence. This alteration process is mainly responsible for a log-linear decrease of the amounts of n-alkanes and cyclohexylalkanes with increasing depth. The severe and uniform alteration of aromatic hydrocarbons throughout the interval, which is opposite to the progressive alteration of associated n-alkanes, can be attributed solely to water washing. This conclusion necessitates a reconsideration of previous interpretations attributing the loss of short-side chain substituted polyaromatic compounds to microbial activity. Hopanes, tri-and tetra–cyclic terpanes as well as aromatic steroids and hopanoids seem to have been unaffected by the alteration phenomena. The increase in the degree of alteration of the hydrocarbons with increasing depth implies that the responsible migrating fluid circulated per ascensum.
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26

Ostrowski, Sławomir, and Jan Cz Dobrowolski. "What does the HOMA index really measure?" RSC Adv. 4, no. 83 (2014): 44158–61. http://dx.doi.org/10.1039/c4ra06652a.

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27

Langler, Richard F. "A Hückel-Level Kinetic-Stability-Based Approach to Aromaticity: Cyclic Even Alternant Hydrocarbons." Australian Journal of Chemistry 61, no. 1 (2008): 16. http://dx.doi.org/10.1071/ch07216.

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A graph-theoretical procedure is described that relates Hückel-level expectations for the kinetic stabilities of even, alternant hydrocarbons to their Lewis structures. New parameters Ac and T are developed. A universal kinetic-stability-based standard is proposed for classifying alternant hydrocarbons as aromatic, non-aromatic, or anti-aromatic.
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28

Bohl, E., B. Mignolet, J. O. Johansson, F. Remacle, and E. E. B. Campbell. "Low-lying, Rydberg states of polycyclic aromatic hydrocarbons (PAHs) and cyclic alkanes." Physical Chemistry Chemical Physics 19, no. 35 (2017): 24090–99. http://dx.doi.org/10.1039/c7cp03913a.

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29

Wu, Zhilin, Jan Lifka, and Bernd Ondruschka. "Benzene formation during aquasonolysis of selected cyclic C6H hydrocarbons." Ultrasonics Sonochemistry 12, no. 1-2 (2005): 133–36. http://dx.doi.org/10.1016/j.ultsonch.2004.05.015.

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30

DeWitt, Merrick J., and Robert J. Levis. "Near‐infrared femtosecond photoionization/dissociation of cyclic aromatic hydrocarbons." Journal of Chemical Physics 102, no. 21 (1995): 8670–73. http://dx.doi.org/10.1063/1.468969.

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31

Owczarek, Iwona, and Krystyna Blazej. "Recommended Critical Temperatures. Part II. Aromatic and Cyclic Hydrocarbons." Journal of Physical and Chemical Reference Data 33, no. 2 (2004): 541–48. http://dx.doi.org/10.1063/1.1647147.

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32

Janeček, Jiří, Hartmut Krienke, and Georg Schmeer. "Interfacial Properties of Cyclic Hydrocarbons: A Monte Carlo Study." Journal of Physical Chemistry B 110, no. 13 (2006): 6916–23. http://dx.doi.org/10.1021/jp055558d.

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33

Khalitova, L. R., S. A. Grabovskiy, A. V. Antipin, L. V. Spirikhin, and N. N. Kabal’nova. "Products of ozone oxidation of some saturated cyclic hydrocarbons." Russian Journal of Organic Chemistry 51, no. 12 (2015): 1710–16. http://dx.doi.org/10.1134/s1070428015120076.

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34

Oltedal, V. M., K. J. Børve, L. J. Sæthre, T. D. Thomas, J. D. Bozek, and E. Kukk. "Carbon 1s photoelectron spectroscopy of six-membered cyclic hydrocarbons." Phys. Chem. Chem. Phys. 6, no. 17 (2004): 4254–59. http://dx.doi.org/10.1039/b405109b.

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35

Langler, Richard F. "Anticipating π-Bond Dispositions in Cyclic, Even, Classical Hydrocarbons". Australian Journal of Chemistry 64, № 3 (2011): 324. http://dx.doi.org/10.1071/ch10384.

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A new technique, which employs π-bond placement coefficients, is presented. That technique, in conjunction with a few parameters that are readily available from traditional Hückel theory, permits one to systematically anticipate π-bond placements for optimized lowest-lying singlet states. One may then foresee the relative magnitudes of calculated ΔHf values for selected sets of structural isomers. Structural predictions are compared with parameterization method 3 (PM3) calculations, density functional theory calculations and experimental results. Reasonable expectations for the most stable structure narrow the choice of molecules that may then be scrutinized by more exact computations or by experiment.
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36

Ezdin, B. S., A. E. Zarvin, A. S. Yaskin, V. V. Kalyada, and S. A. Konovalov. "Fast Cyclic Compression Installation for Conversion of Light Hydrocarbons." Chemical and Petroleum Engineering 52, no. 1-2 (2016): 26–28. http://dx.doi.org/10.1007/s10556-016-0141-5.

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37

Promkotra, Sarunya. "Phase Equilibria of Condensate and Natural Gas." Advanced Materials Research 746 (August 2013): 529–32. http://dx.doi.org/10.4028/www.scientific.net/amr.746.529.

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Condensate and natural gas from a gas field in the northeast of Thailand are examined for their physical and chemical properties, and phase behaviors referring to phase equilibria. The physical properties of condensate are analyzed based on API gravity, density, Reid vapor pressure, true vapor pressure, pressure and temperature, viscosity and specific energy. Chemical components of natural gas are grouped depending on the amount of organic hydrocarbons which are methane, light hydrocarbons, heavy hydrocarbons, aromatic and cyclic compounds and non-hydrocarbon contents in the mole per cent of 97.15, 1.16, 0.22, 0.019 and 1.50, respectively. Pristane and phytane ratio is 1.73 which refers to an oxidizing environment during the deposition of the petroleum reservoir. Phase behavior of condensate is found only one phase, liquid phase at 15°C and 101.327 kPa, which indicates the critical temperature of 592.13 K and the critical pressure of 2,372.96 kPa. However, natural gas can be separated in two phases, vapor and liquid phases. The results show that the cricondentherm and cricondenbar of natural gas are 326.36 K and 1,295.28 kPa, respectively. These results can be useful for controlling and managing condensate and natural gas.
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38

Dobrovolná, Zuzana, and Libor Červený. "Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst." Collection of Czechoslovak Chemical Communications 62, no. 9 (1997): 1497–502. http://dx.doi.org/10.1135/cccc19971497.

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Competitive hydrogenation of alkenes (cyclohexene, hex-1-ene, hept-1-ene, oct-1-ene) and dienes (octa-1,7-diene, cyclohexa-1,3-diene) was carried out by catalytic hydrogen transfer from ammonium formate on palladium in methanol. The adsorptivity and reactivity of the hydrocarbons decreased in the series: cyclic diene > linear diene > linear 1-alkene > cyclic alkene.
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39

Shafer, Wilson, Muthu Gnanamani, Uschi Graham, et al. "Fischer–Tropsch: Product Selectivity–The Fingerprint of Synthetic Fuels." Catalysts 9, no. 3 (2019): 259. http://dx.doi.org/10.3390/catal9030259.

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The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a wide range (C1–C70+) of hydrocarbons, primarily straight-chained paraffins. Additional hydrocarbon products, which can also be a majority, are linear olefins, specifically: 1-olefin, trans-2-olefin, and cis-2-olefin. Minor hydrocarbon products can include isomerized hydrocarbons, predominantly methyl-branched paraffin, cyclic hydrocarbons mainly derived from high-temperature FTS and internal olefins. Combined, these products provide 80–95% of the total products (excluding CO2) generated from syngas. A vast number of different oxygenated species, such as aldehydes, ketones, acids, and alcohols, are also embedded in this product range. These materials can be used to probe the FTS mechanism or to produce alternative chemicals. The purpose of this article is to compare the product selectivity over several FTS catalysts. Discussions center on typical product selectivity of commonly used catalysts, as well as some uncommon formulations that display selectivity anomalies. Reaction tests were conducted while using an isothermal continuously stirred tank reactor. Carbon mole percentages of CO that are converted to specific materials for Co, Fe, and Ru catalysts vary, but they depend on support type (especially with cobalt and ruthenium) and promoters (especially with iron). All three active metals produced linear alcohols as the major oxygenated product. In addition, only iron produced significant selectivities to acids, aldehydes, and ketones. Iron catalysts consistently produced the most isomerized products of the catalysts that were tested. Not only does product selectivity provide a fingerprint of the catalyst formulation, but it also points to a viable proposed mechanistic route.
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40

Zhang, Hongda, Pravas Deria, Omar K. Farha, Joseph T. Hupp, and Randall Q. Snurr. "A thermodynamic tank model for studying the effect of higher hydrocarbons on natural gas storage in metal–organic frameworks." Energy Environ. Sci. 8, no. 5 (2015): 1501–10. http://dx.doi.org/10.1039/c5ee00808e.

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41

Lebedev, Yuri A. "Microwave Discharges in Liquid Hydrocarbons: Physical and Chemical Characterization." Polymers 13, no. 11 (2021): 1678. http://dx.doi.org/10.3390/polym13111678.

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Microwave discharges in dielectric liquids are a relatively new area of plasma physics and plasma application. This review cumulates results on microwave discharges in wide classes of liquid hydrocarbons (alkanes, cyclic and aromatic hydrocarbons). Methods of microwave plasma generation, composition of gas products and characteristics of solid carbonaceous products are described. Physical and chemical characteristics of discharge are analyzed on the basis of plasma diagnostics and 0D, 1D and 2D simulation.
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42

Bakke, Jan M., Morten Lundquist, U. Pedersen, P. Bödstrup Rasmussen, and S. O. Lawesson. "The RuO4 Oxidation of Cyclic Saturated Hydrocarbons. Formation of Alcohols." Acta Chemica Scandinavica 40b (1986): 430–33. http://dx.doi.org/10.3891/acta.chem.scand.40b-0430.

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43

Wu, Zhilin, Jan Lifka, and Bernd Ondruschka. "Sonochemical reaction of selected cyclic C6H hydrocarbons in organic solvents." Ultrasonics Sonochemistry 12, no. 1-2 (2005): 127–31. http://dx.doi.org/10.1016/j.ultsonch.2004.05.014.

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44

St. Pierre, R. J., E. L. Chronister, Li Song, and M. A. El-Sayed. "Reactivity of gas-phase niobium clusters toward several cyclic hydrocarbons." Journal of Physical Chemistry 91, no. 18 (1987): 4648–51. http://dx.doi.org/10.1021/j100302a002.

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45

Karwasz, G. P., D. Pliszka, R. S. Brusa, and C. Perazzolli. "Low Energy Cross-Sections for Positron Interactions with Cyclic Hydrocarbons." Acta Physica Polonica A 107, no. 4 (2005): 666–72. http://dx.doi.org/10.12693/aphyspola.107.666.

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46

Makowska, Anna, Anna Hryniewicka, and Jerzy Szydłowski. "Miscibility behavior of trihexyl(tetradecyl)phosphonium tetrafluoroborate with cyclic hydrocarbons." Fluid Phase Equilibria 372 (June 2014): 21–25. http://dx.doi.org/10.1016/j.fluid.2014.03.020.

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47

Červeny, L., P. Kluson, and I. Paseka. "Transformations of cyclic C6 unsaturated hydrocarbons on a palladium catalyst." Reaction Kinetics & Catalysis Letters 43, no. 2 (1991): 533–37. http://dx.doi.org/10.1007/bf02064724.

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48

Dzhemilev, U. M., A. G. Ibragimov, E. V. Gribanova, and L. M. Khalilov. "Direct metallation of cyclic conjugated hydrocarbons by highly reactive magnesium." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 37, no. 2 (1988): 347–49. http://dx.doi.org/10.1007/bf00957442.

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49

Matteoli, Enrico, Luciano Lepori, and Andrea Spanedda. "Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25�C." Journal of Solution Chemistry 23, no. 5 (1994): 619–38. http://dx.doi.org/10.1007/bf00972749.

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50

Çelikler, Dilek, Sibel Demir Kaçan, and Nisa Yenikalaycı. "Nomenclature of Cyclic and Aromatic Hydrocarbons by Educational Games: OrgChemGame." International Journal of Progressive Education 17, no. 4 (2021): 297–307. http://dx.doi.org/10.29329/ijpe.2021.366.18.

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