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Dissertations / Theses on the topic 'Cyclic voltammetry'

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1

Helfrick, John C. "Cyclic square wave voltammetry." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/30681.

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2

Mizzon, Giulia. "Bioelectrochemistry by fluorescent cyclic voltammetry." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:6a1134dd-c24d-4e60-ac83-936a6918131f.

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Understanding the factors influencing the ET characteristics of redox proteins confined at an electrochemical interface is of fundamental importance from both pure (fundamental science) and applied (biosensory) perspectives. This thesis reports on progress made in the emerging field of coupled electrochemical characterization and optical imaging in moving the analysis of redox-active films to molecular scales. More specifically the combination of cyclic voltammetry and wide-field Total Internal Reflection (TIRF) microscopy, here named ‘Fluorescent Cyclic Voltammetry’ (FCV), was applied to moni
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3

Kollipara, Suresh Babu. "Organic Electrochemical Transistors for Fast Scan Cyclic Voltammetry." Thesis, Linköpings universitet, Fysik och elektroteknik, 2013. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-98676.

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The work presented in the thesis is about the evaluation of Organic Electrochemical Transistors (OECTs) for fast scan cyclic voltammetry (FSCV). FSCV is a method which has been used for real time dopamine sensing both in vivo and in vitro. The method is sensitive to noise and could therefore benefit from signal preamplification at the point of sensing, which could be achieved by incorporation of OECTs. In this study the OECTs are based on the conductive polymer poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS). The gate consists of gold microelectrodes of different sizes to
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4

Tichter, Tim [Verfasser]. "Theory of Cyclic Voltammetry at Macroporous Electrodes / Tim Tichter." Berlin : Freie Universität Berlin, 2020. http://d-nb.info/1220288314/34.

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5

Brubaker, Joel Patrick. "A Diffusion Model for Cyclic Voltammetry with Nanostructured Electrode Surfaces." University of Dayton / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1418273596.

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6

Bolinger, Roman Wilhelm. "The deployment of digital simulation tools to verify cyclic voltammetry experiments /." Zürich, 2000. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=13637.

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7

Isaac, Christian James. "Redox active metal complexes : synthesis and DNA binding studies." Thesis, University of Newcastle Upon Tyne, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287813.

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8

Gruden, Roman, Andreas Buchholz, and Olfa Kanoun. "Electrochemical analysis of water and suds by impedance spectroscopy and cyclic voltammetry." Universitätsbibliothek Chemnitz, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-149036.

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Optimum detergent dosage during a washing process depends on water quality, degree of pollution and quantity of laundry. Particularly, water quality is an important factor. Other parameters like carbonate- or non-carbonate hardness and calcium / magnesium (Ca / Mg) ratio in addition to total hardness of water have an impact on the amount of detergent. This work discusses the possibilities realizing a detergent sensor that measures important parameters for the washing process and assess the ideal necessary amount of detergent during the washing process. The approach is to combine impedance spec
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9

Rodriguez-Ibarra, Veronica 1963. "Cyclic voltammetry of mercapto compounds and their reaction products with arsenic species." Thesis, The University of Arizona, 1993. http://hdl.handle.net/10150/278356.

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The electrochemical behavior of L-cysteine, 3-mercaptopropionic acid, dimercaptopropanesulfonic acid and dimercaptosuccinic acid, was examined at a mercury film electrode, gold electrode and platinum electrode. The effect of scan rate, pH and concentration were determined by cyclic voltammetry. The comparison of the cyclic voltammograms, established a great similarity among the monomercapto compounds at different molecular weight and structure and among the dimercapto compounds that were studied. Differences between the behavior of dimercapto and monomercapto compounds were also established. T
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10

Zuurbier, Richard James. "Novel aspects of platinum porphyrin chemistry." Thesis, Brunel University, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307537.

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11

Aherne, Christine M. "Electrochemical and structural properties of some 1,2,3,5 and 1,3,2,4 dithiadiazolylium salts and related compounds." Thesis, Durham University, 1995. http://etheses.dur.ac.uk/5121/.

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This work centres around the electrochemical and structural studies of 1,2,3,5 and 1,3,2,4 dithiadiazolylium salts and associated radical derivatives. Chapter one provides a brief history of sulphur nitrogen chemistry, in particular developments of 1,2,3,5 and 1,3,2,4 dithiadiazolyUum/ heterocyclic species. Also a quick outline of the pathways my research took are discussed. The following chapter is solely dedicated to the electrochemical investigations of (i) mono substituted aryl 1,2,3,4 and 1,3,2,4, (ii) di substituted aryl 1,2,3,4 and 1,3,2,4 and (iii) pyridyl 1,2,3,5 dithiadiazolylium sal
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12

Ndjeri-Ndjouhou, Marthe. "Synthèse et caractérisation de la birnessite électrodéposée : application à la dégradation du glyphosate." Thesis, Evry-Val d'Essonne, 2012. http://www.theses.fr/2012EVRY0001/document.

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Ce travail de thèse a eu pour thème central la birnessite, un oxyde de manganèse ubiquiste dans le milieu naturel et jouant un rôle fondamental dans la géochimie des sols. La première partie de cette thèse a été consacrée à l’électrodépôt et à la caractérisation de la birnessite par des méthodes électrochimiques couplées à la diffraction des rayons X. La caractérisation DRX in-situ au cours de l’électrodépôt a permis de mettre en évidence, lorsqu’on est en présence du cation électrolytique Na+, la formation d’un précurseur, la busérite, alors qu’en présence du cation électrolytique K+, la synt
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13

Öijerholm, Johan. "Ionic Transport in Metal Oxides Studied in situ by Impedance Spectroscopy and Cyclic Voltammetry." Doctoral thesis, KTH, Kemi, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4312.

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Ionic transport in metal oxides is crucial for the functioning of a broad range of different components, such as heat resistant alloys designed for high temperature applications and oxide electrolytes in solid oxide fuel cells. This thesis presents results from in situ electrochemical studies of properties related to ionic transport in metal oxides that are important for their applications as protective oxides and ionic conductors. Heat resistant alloys of alumina-former type are known to form an adherent, slowly growing and protective aluminium oxide (Al2O3) scale that protects metals from ch
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14

Chew, Mei. "Investigation of uranium redox chemistry and complexation across the pH range by cyclic voltammetry." Thesis, Loughborough University, 2013. https://dspace.lboro.ac.uk/2134/13475.

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The current option for the management of Intermediate-Level Waste (ILW) and High-Level Waste (HLW) in the UK is to store it in stainless steel containers and then placed in a deep underground Geological Disposal Facility (GDF). This may subsequently be backfilled with a cementitious material generating very high pH conditions. The eventual corrosion of the stainless steel canisters containing the waste used for disposal will lead to reducing conditions thereby promoting a low Eh environment. Electrochemical experiments are needed to determine which uranium species is/are present at a particula
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15

Öijerholm, Johan. "Ionic transport in metal oxides studied in situ by impedance spectroscopy and cyclic voltammetry /." Stockholm : Division of Corrosion Science, Department of Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4312.

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16

Chu, Suk-ling. "The first synthesis and structure of diazatetrathiafulvalenes and some spectroscopic and cyclic voltammetric measurements /." [Hong Kong : University of Hong Kong], 1993. http://sunzi.lib.hku.hk/hkuto/record.jsp?B13544548.

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17

朱淑玲 and Suk-ling Chu. "The first synthesis and structure of diazatetrathiafulvalenes and somespectroscopic and cyclic voltammetric measurements." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1993. http://hub.hku.hk/bib/B31211392.

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18

Long, Hunter Wayne. "Improving Fast-Scan Cyclic Voltammetry and Raman Spectroscopy Measurements of Dopamine and Serotonin Concentrations via the Elastic Net." Thesis, Virginia Tech, 2016. http://hdl.handle.net/10919/71679.

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Dopamine and serotonin are two neurotransmitters known to both play a very important role in the human brain. For example, the death of dopamine producing neurons in a region of the brain known as the substantia nigra are known to cause the motor symptoms of Parkinson's disease. Also, many antidepressants are believed to work by increasing the extracellular level of serotonin in the brain. For the first time, it is now possible to measure the release of these two chemicals at sub-second time resolution in a human brain using a technique known as fast-scan cyclic voltammetry, for example from p
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19

Hopwood, Sarah Elizabeth. "Control of serotonin release in the dorsal and median raphe nuclei." Thesis, Queen Mary, University of London, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369264.

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20

Osipovich, Nikolai P., Sergei K. Poznyak, Vladimir Lesnyak, and Nikolai Gaponik. "Cyclic voltammetry as a sensitive method for in situ probing of chemical transformations in quantum dots." Royal Society of Chemistry, 2016. https://tud.qucosa.de/id/qucosa%3A36419.

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The application of electrochemical methods for the characterization of colloidal quantum dots (QDs) attracts considerable attention as these methods may allow for monitoring of some crucial parameters, such as energetic levels of conduction and valence bands as well as surface traps and ligands under real conditions of colloidal solution. In the present work we extend the applications of cyclic voltammetry (CV) to in situ monitoring of degradation processes of water-soluble CdTe QDs. This degradation occurs under lowering of pH to the values around 5, i.e. under conditions relevant to bioimagi
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21

McGovern, William Robert. "Characterization of carbon-molecule-metal junctions by cyclic voltammetry, raman spectroscopy and X-Ray photoelectron spectroscopy." The Ohio State University, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=osu1114560996.

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22

Tammela, Petter. "Preparation and characterization of a metal hydride electrode." Thesis, Uppsala universitet, Oorganisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-180160.

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Metal hydrides are used as anode material in nickel metal hydride batteries and are of particular interest because of the potential to be a part of energy systems completely involving renewable sources (e.g. solar power, wind power etc.). Preparation and electrochemical characterization of metal hydride electrodes have not previously been performed at the Department of Chemistry – Ångström Laboratory. Two basic techniques that are desired to be used in the characterization are cyclic voltammetry and chronopotentiometry. This thesis work is aimed at preparation and electrochemical characterizat
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23

Yeary, Amber J. "Cetyltrimethylammonium Halide-Coated Electrodes for the Detection of Dopamine in the Presence of Interferents." Wright State University / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=wright1323471405.

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24

Ntshongontshi, Nomaphelo. "Cytochrome P450-3A4/copper-poly(propylene imine)- polypyrrole star co-polymer Nanobiosensor system for delavirdine – a non-nucleoside reverse transcriptase inhibitor HIV drug." University of the Western Cape, 2014. http://hdl.handle.net/11394/4446.

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>Magister Scientiae - MSc<br>HIV and AIDS are among the world's pandemics that pose serious concern to almost every individual in the world. With the current level of availability of anti-retroviral (ARV) drugs and the ease of accessibility of treatment in many countries such as South Africa, the disease can be controlled by suppressing the viral load of an infected individual. These anti HIV drugs such as delavirdine are metabolised by enzymes which are found in the liver microsomes, particularly those of the cytochrome P450 family. Due to the fact that the metabolic rate of a patient determi
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25

Waqar, Ammar Bin. "Exploration of Electrodeposition of Aluminum-Nickel Alloys and Multilayers in Organic Chloroaluminate Ionic Liquids." Scholar Commons, 2014. https://scholarcommons.usf.edu/etd/5397.

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Aluminum-nickel (Al-Ni) alloys and Al/Ni bilayers were successfully electrodeposited from AlCl3-EMIM-NiCl2 electrolyte at room temperature. Dissolution of NiCl2 was shown to be favorable in Lewis basic (with molar ratio of AlCl3 < 0.5) AlCl3-EMIM solution. The use of electrochemically active Cu working electrode as opposed to inert W induced additional Cu oxidation and dissolution in the cyclic voltammetry scan. The reduction potentials of Al and Ni were found to be ~ – 0.3 and 0.15 V vs. Al/Al3+ respectively. Increasing [NiCl2] in the electrolyte leads to an increase of Ni concentration in th
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26

Patel, Kishan. "Determination of the hydrogen peroxide concentration in rotenone induced dopaminergic cells using cyclic voltammetry and amplex red." Honors in the Major Thesis, University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETH/id/600.

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Parkinson's disease (PD) is a neurodegenerative condition that affects millions of people worldwide. The exact etiology of PD is unknown. However, it is well established that environmental factors contribute to the onset of PD. In particular, chemicals such as the insecticide Rotenone have been shown to increase the death of dopaminergic (DA) neurons by increasing levels of reactive oxygen species (ROS). ROS such as hydrogen peroxide (H2O2) have been shown to be elevated above basal levels in PD patients. Currently, to measure H2O2 concentrations, a commercially available (Amplex® Red) fluores
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27

Potgieter, Dawid. "Using fast-scan cyclic voltammetry to investigate monoamine release in BAC transgenic rodent models of Parkinson's disease." Thesis, University of Oxford, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.665164.

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Parkinson's disease (PD) is the most common neurodegenerative movement disorder. Nigrostriatal dopamine (DA) neurons are particularly susceptible to degeneration in PD, and the concomitant loss of DA signalling in the striatum is believed to underlie the motor symptoms of PD. Transgenic rodent models expressing PD-related genes have previously revealed changes to DA synapse function as one of the earliest stages of PD progression, often preceding protein aggregation and cell death. However, such models often rely on foreign gene promoter elements that do not accurately replicate the genetic ex
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28

Kathiwala, Mehjabin Abdul Majid. "Measurement of stress and disease markers in biological fluids by fast scan cyclic voltammetry and HPLC-UV." [Gainesville, Fla.] : University of Florida, 2009. http://purl.fcla.edu/fcla/etd/UFE0024706.

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29

Rustin, Gavin James Mr. "The Analysis of the Decomposition of Hydrogen Peroxide Using a Schiff Base Copper Complex By Cyclic Voltammetry." Digital Commons @ East Tennessee State University, 2014. https://dc.etsu.edu/honors/224.

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Copper(II) complexes of Schiff bases can be used in the catalysis of hydrogen peroxide to create water and oxygen. The mechanism and the kinetics of this disproportionation reaction by a dimeric copper(II) complex [CuSALAD]2 are studied in this experiment, where SALAD refers to a Schiff Base ligand formed from salicyaldehyde and 1S,2S-D(+)-1-phenyl-2-amino-1,3-propanediol. By using cyclic voltammetry, the oxidation-reduction processes of a reaction may be monitored. The [CuSALAD]­2 is initially reacted with a base such as imidazole to form the catalytic species, and the ratio of the copper(
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30

Palmero, David A. "Comparison of cyclic voltammetry and HPLC for the determination of phenol in over-the counter sore throat sprays /." View abstract, 1999. http://library.ctstateu.edu/ccsu%5Ftheses/1540.html.

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Thesis (M.S.)--Central Connecticut State University, 1999.<br>Thesis advisor: James V. Arena, Ph. D. " ... in partial fulfillment of the requirements for the degree of Master of Science in Chemistry." Includes bibliographical references (leaf 48).
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Qian, Zepeng. "CYCLIC VOLTAMMETRIC DETERMINATION OF 17-α-ETHINYL ESTRADIOL ON DISPOSABLE SCREEN-PRINTED CARBON ELECTRODES". Miami University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=miami1565371346943373.

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32

Fattori, Alberto. "Electrochemical and spectroelectrochemical studies of dyes used in dye-sensitized solar cells." Thesis, University of Bath, 2010. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.538162.

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Electrochemical and spectroelectrochemical techniques were employed to investigate the redox characteristics of dyes for dye sensitized solar cells (DSCs) adsorbed at the surface of fluorine-doped tin oxide (FTO) and FTO TiO2 electrodes. In this work are studied Ru-based dyes such as cis-bis(isothiocyanato)-bis(2,2’-bipyridyl- 4,4’dicarboxylato)-ruthenium(II) (N719) and (cis-RuLL'(SCN)2 with L=4,4'- dicarboxylic acid-2,2'-bipyridine and L'=4,4'-dinonyl-2,2'-bipyridine) known as Z907, and indoline organic dyes coded as D102, D131, D149, and D205. The adsorption, diffusion and stability of adsor
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33

Siebritz, Robert Matthew. "The preparation of an immunosensor for the detection of microcystins and nodularins by immobilisation of a labelled antibody onto a polymer modified electrode." University of the Western Cape, 2011. http://hdl.handle.net/11394/5220.

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Masters of Science<br>South African dams and reservoirs are increasingly showing the propensity to support sustained populations of Cyanobacteria (blue green algae). These photosynthetic bacteria occur throughout the world and can rapidly form blooms in eutrophic water systems. The occurrence of these photosynthetic bacteria, in our dwindling drinking water source dams, poses a serious, economic, as well as a health, threat to and arid country like South Africa due to is potential to produce of toxic metabolites like Microcystins and Nodularins (MCN). MCN's are cyclic peptides toxins, harmful
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34

Washington, Marlena Patrice. "Investigations of Opto-Electronically Interesting Materials Featuring Phosphorus-Carbon Double Bonds." Case Western Reserve University School of Graduate Studies / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=case1278691072.

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35

Farao, Al Cerillio. "Synthetic strategies for denatured cytochrome-c analogues towards analytical reporting of NOx species." University of the Western Cape, 2019. http://hdl.handle.net/11394/7012.

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Philosophiae Doctor - PhD<br>Nitric oxide (NO) plays a key role as biological messenger in the biological system, however detection and quantification thereof has always posed significant problems. NOx is a principal constituent of air pollutants. There are seven oxides of nitrogen of which N2O, NO and NO2 are most important. NO is a free radical and reacts extremely fast with oxygen, peroxides and superoxides. It’s these reactions which are responsible for NO’s fleeting existence. The specific detection and quantification of NO still remains challenging. Most techniques rely on the measureme
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36

Zosiwe, Mlandeli Siphelele Ernest. "Cytochrome P450 2E1/Nickel-Poly(propylene imine) dendrimeric nanobiosensor for pyrazinamide - A first line TB Drug." University of the Western Cape, 2015. http://hdl.handle.net/11394/4703.

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>Magister Scientiae - MSc<br>The tuberculosis (TB) disease to this day remains one of the world’s prominent killerdiseases. Pyrazinamide (PZA) is one of the most commonly prescribed anti- tuberculosis (anti-TB) drugs due to its ability to significantly shorten the TB treatment period from the former nine months to the current six months duration. However, excess PZA in the body causes hepatotoxicity and damages the liver. This hepatotoxicity, together with the resistance of the bacteria to treatment drugs, poor medication and inappropriate dosing, greatly contribute to the high incidents of TB
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37

Leve, Zandile Dennis. "Determination of paracetamol at the electrochemically reduced graphene oxide-metal nanocomposite modified pencil graphite (ERGO-MC-PGE) electrode using adsorptive stripping differential pulse voltammetry." University of Western Cape, 2020. http://hdl.handle.net/11394/7350.

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>Magister Scientiae - MSc<br>This project focuses on the development of simple, highly sensitive, accurate, and low cost electrochemical sensors based on the modification of pencil graphite electrodes by the electrochemical reduction of graphene oxide-metal salts as nanocomposites (ERGO-MC-PGE; MC = Sb or Au nanocomposite). The electrochemical sensors ERGO-Sb-PGE and ERGO-Au-PGE were used in the determination of paracetamol (PC) in pharmaceutical formulations using adsorptive stripping differential pulse voltammetry. The GO was prepared from graphite via a modified Hummers’ method and characte
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38

Huang, Long. "Copper Electrodeposition on Iridium, Ruthenium and Its Conductive Oxide Substrate." Thesis, University of North Texas, 2003. https://digital.library.unt.edu/ark:/67531/metadc4416/.

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The aim of this thesis was to investigate the physical and electrochemical properties of sub monolayer and monolayer of copper deposition on the polycrystalline iridium, ruthenium and its conductive oxide. The electrochemical methods cyclic voltammetry (CV) and chronocoulometry were used to study the under potential deposition. The electrochemical methods to oxidize the ruthenium metal are presented, and the electrochemical properties of the oxide ruthenium are studied. The full range of CV is presented in this thesis, and the distances between the stripping bulk peak and stripping UPD p
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Hlongwa, Ntuthuko Wonderboy. "Nanoparticles-infused lithium manganese phosphate coated with magnesium-gold composite thin film - a possible novel material for lithium ion battery olivine cathode." University of the Western Cape, 2014. http://hdl.handle.net/11394/4467.

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>Magister Scientiae - MSc<br>Architecturally enhanced electrode materials for lithium ion batteries (LIB) with permeable morphologies have received broad research interests over the past years for their promising properties. However, literature based on modified porous nanoparticles of lithium manganese phosphate (LiMnPO₄) is meagre. The goal of this project is to explore lithium manganese phosphate (LiMnPO₄) nanoparticles and enhance its energy and power density through surface treatment with transition metal nanoparticles. Nanostructured materials offer advantages of a large surface to volum
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40

Paschkewitz, Timothy Michael. "Ammonia Production at Ambient Temperature and Pressure: An Electrochemical and Biological Approach." Diss., University of Iowa, 2012. https://ir.uiowa.edu/etd/4893.

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The majority of power generated worldwide is from combustion of fossil fuels. The sustainability and environmental impacts of this non renewable process are severe. Alternative fuels and power generation systems are needed, however, to cope with increasing energy demands. Ammonia shows promise for use in power generation, however it is costly to produce and very few methods of using it as a fuel are developed. To address the need for alternative methods of ammonia synthesis, this research designed and tested a bioelectroch
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SWANSON, DALE DORSETT. "ELECTROCHEMICAL AND SPECTROSCOPIC STUDIES OF THIOETHER COORDINATION COMPLEXES (CYCLIC VOLTAMMETRY, OCTAHEDRAL LOW-SPIN METALS, BLUE COPPER PROTEINS, ELECTRON PARAMAGNETIC RESONANCE)." Diss., The University of Arizona, 1985. http://hdl.handle.net/10150/188102.

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The bis 1,4,7-trithiacyclononane (1,4,7-TTCN) complexes of iron, cobalt, nickel and copper are reported in this work. Their properties have been examined using computer-controlled electrochemical and spectroscopic techniques. These TTCN complexes form readily, are unusually symmetrical and support electron transfer reactions at the metal center. The cobalt(II) complex is octahedral, low spin and symmetrical. Four oxidation states of cobalt-TTCN complex are observed; two one-electron transfer processes are reversible. Copper (II) bis 1,4,7-TTCN is unusually symmetrical evidenced by both solid p
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42

Guan, Shaoliang. "Determination of the role of nanoparticle active sites in catalytic hydrogenation reactions by cyclic voltammetry and novel in-situ surface spectroscopy." Thesis, Cardiff University, 2014. http://orca.cf.ac.uk/73388/.

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Cyclic Voltammetry, Surface Enhanced Raman Spectroscopy and SHell-Isolated Nanoparticle-Enhanced Raman Spectroscopy (SHINERS) have been used to investigate two types of heterogeneously catalysed hydrogenation reactions – hydrogenation of selected alkynes and the Orito reaction. Using a spectro-electrochemical flowcell, which is designed and built in-house, the selectivity and reactivity of the reactions on platinum surfaces have been truly discovered. By studying hydrogenation of a range of alkyne molecules, including 2-butyne-1,4-diol, 2-pentyne, 4-octyne, propargyl alcohol and 2-methyl-3-but
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43

Pal, Chandana. "Thin films of non-peripherally substituted liquid crystalline phthalocyanines A." Thesis, Brunel University, 2014. http://bura.brunel.ac.uk/handle/2438/8997.

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Three non-peripherally substituted liquid crystalline bisphthalocyanine (Pc) compounds have been studied to examine the role of central metal ions lutetium (Lu), and gadolinium (Gd) and substituent chain lengths, i.e. octyl (C8H17) and hexyl (C6H13), in determining the physical properties. For the octyl substituted Pc molecules, the head-to-tail or Jaggregates within the as-deposited spun films produced a redshift of the optical absorption Q bands in relation to their 0.01 mgml-1 solutions. Annealing at 80˚C produced a well-ordered discotic liquid crystalline (LC) mesophase causing additional
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44

Amirat, S., R. Rehamnia, R. Bensalem, M. Bordes, and J. Creus. "Nucleation and Growth of the Zn-Fe Alloy from a Chloride Electrolyte." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35313.

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In this study, the kinetics of Zn-Fe codeposition was investigated in chloride acidic solution using cyclic voltammetry. Anomalous codeposition is detected and this mechanism depends on the Zn(II) / Fe(II) concentration ratio in the electrolytic bath. The study of early stages of electrodeposition showed that Zn- Fe follows a theoretical response to instantaneous nucleation evolves into a progressive nucleation according to the model of Scharifker and Hills. The morphology and structure of the coatings is discussed using characterization techniques. Dense, uniform, and singlephased Zn-Fe
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Abu, Eme A. "Spectroelectrochemical sensing of tris (2,2 bipyridyl) ruthenium (II) dichloride hexahydrate in low ionic strength samples and the spectroelectrochemical characterization of aeruginosin A." University of Cincinnati / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1337351210.

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Kalil, Haitham Fawzy Mohamed. "NANOMATERIALS-BASED SENSORS FOR PEROXYNITRITE DETECTION AND QUANTIFICATION." Cleveland State University / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=csu151336709631904.

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Kosillo, Polina. "Investigating circuits underlying acetylcholine-evoked striatal dopamine release in health and disease." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:1675813e-0b07-4ede-9094-cdc442679394.

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Dopamine (DA) is a key striatal neuromodulator central to normal functioning of the basal ganglia. Identifying and characterizing circuits governing striatal DA transmission is necessary for understanding DA involvement in adaptive behaviour and pathology. Properties of evoked striatal DA release can be examined using fast-scan cyclic voltammetry at carbon fibre microelectrodes, a technique enabling live monitoring of transmitter release events with sub-millisecond resolution. Experimental work presented in this thesis employed this approach to study regulation of striatal DA by acetylcholine
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Maoela, Manki Sarah. "Spectroelectrochemical determination of the antioxidant properties of carpobrotus mellei and carpobrotus quadrifidus natural products." Thesis, University of the Western Cape, 2009. http://hdl.handle.net/11394/3299.

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Philosophiae Doctor - PhD<br>South African Carpobrotus species have been found to contain hydrolysable tannins,various flavonoids e.g. rutin and hyperoside, phytosterols and aromatic acids which have a diverse range of pharmacological properties including antimicrobial and, antioxidant activities. The main aim of the thesis was to determine the natural products in C. mellei and C. quadrifidus using chromatographic techniques and electrochemical analysis. The antioxidant activity of both Carpobrotus species was determined by using a superoxide dismutase (SOD) biosensor. ESI-LC-MS was used to se
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Blavo, Selasi Ofoe. "Model Pt- and Pd-based Electrocatalysts for Low Temperature Fuel Cells Applications." Scholar Commons, 2013. http://scholarcommons.usf.edu/etd/4639.

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In the search for alternative energy technologies, low temperature fuel cells continue to feature as technologies with the most promise for mass commercialization. Among the low temperature fuel cells, alkaline and proton exchange membrane fuel cells are the most popular. Alkaline fuel cells have typically been used for water generation as well as auxiliary power for space shuttles. Their bulkiness however makes them undesirable for other applications, especially in automobiles, where there is a great demand for alternative technologies to internal combustion engines. Proton exchange membrane
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Woodvine, Helena Louise. "Development and characterisation of microelectrode and nanoelectrode systems." Thesis, University of Edinburgh, 2012. http://hdl.handle.net/1842/9570.

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Micro- and nano-electrodes have distinct advantages over large electrodes, including their decreased iR drop and enhanced mass transport due to radial diffusion characteristics which leads to the ready establishment of a steady state (or near steady-state) signal without convection. This enhanced mass transport also leads to increased current densities and signal to noise ratios. However, there is a need for fabrication techniques which reproducibly give micro- and nano-electrodes of controlled size and shape. The optimisation of systematic arrays on the nano-scale, open up possibilities for d
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