Academic literature on the topic 'Cycloaddition [2+2+2]'

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Journal articles on the topic "Cycloaddition [2+2+2]"

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Grygorenko, Oleksandr O., Viktoriia S. Moskvina, Oleksandr V. Hryshchuk, and Andriy V. Tymtsunik. "Cycloadditions of Alkenylboronic Derivatives." Synthesis 52, no. 19 (2020): 2761–80. http://dx.doi.org/10.1055/s-0040-1707159.

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The literature on cycloaddition reactions of boron-containing alkenes is surveyed with 132 references. The data are categorized according to the reaction type ([2+1], [2+2], [3+2], [4+2], and [4+3] cycloadditions). The cyclopropanation and the Diels–Alder reactions of alkenylboronic derivatives have been studied more or less comprehensively, and for some substrates, they can be considered as convenient methods for the rapid regio- and stereoselective construction of even complex cyclic systems. Other types of the cycloadditions, as well as mechanistic aspects of the processes, have been addres
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Kotha, Sambasivarao, Kakali Lahiri, and Gaddamedi Sreevani. "Design and Synthesis of Aromatics through [2+2+2] Cyclotrimerization." Synlett 29, no. 18 (2018): 2342–61. http://dx.doi.org/10.1055/s-0037-1609584.

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The [2+2+2] cycloaddition reaction is a useful tool to realize unusual chemical transformations which are not achievable by traditional methods. Here, we report our work during the past two decades that involve utilization of transition-metal complexes in a [2+2+2] cyclotrimerization reaction. Several key “building blocks” were assembled by a [2+2+2] cycloaddition approach and they have been further expanded by other synthetic transformations to design unusual amino acids and peptides, diphenylalkanes, bis- and trisaryl benzene derivatives, annulated benzocycloalkanes, spirocycles, and spiroox
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Ahmad, Dalla Tiezza, and Orian. "In Silico Acetylene [2+2+2] Cycloadditions Catalyzed by Rh/Cr Indenyl Fragments." Catalysts 9, no. 8 (2019): 679. http://dx.doi.org/10.3390/catal9080679.

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Metal-catalyzed alkyne [2+2+2] cycloadditions provide a variety of substantial aromatic compounds of interest in the chemical and pharmaceutical industries. Herein, the mechanistic aspects of the acetylene [2+2+2] cycloaddition mediated by bimetallic half-sandwich catalysts [Cr(CO)3IndRh] (Ind = (C9H7)−, indenyl anion) are investigated. A detailed exploration of the potential energy surfaces (PESs) was carried out to identify the intermediates and transition states, using a relativistic density functional theory (DFT) approach. For comparison, monometallic parent systems, i.e., CpRh (Cp = (C5H
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Kanematsu, Ken, Noboru Sugimoto, Masayo Kawaoka, Sinkoo Yeo, and Motoo Shiro. "Competitive intramolecular [4+2] cycloaddition and [2+2] cycloaddition of sulfonylallene." Tetrahedron Letters 32, no. 10 (1991): 1351–54. http://dx.doi.org/10.1016/s0040-4039(00)79665-1.

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Tanaka, K., K. Masutomi, N. Sakiyama, and K. Noguchi. "Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition." Synfacts 9, no. 05 (2013): 0575. http://dx.doi.org/10.1055/s-0033-1338458.

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Rovis, T., and D. Dalton. "Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition." Synfacts 9, no. 09 (2013): 1030. http://dx.doi.org/10.1055/s-0033-1339688.

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Meyer, Vera J., Christoph Ascheberg, and Meike Niggemann. "Calcium-Catalyzed Formal [2+2+2] Cycloaddition." Chemistry - A European Journal 21, no. 17 (2015): 6371–74. http://dx.doi.org/10.1002/chem.201500181.

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Fleming, Steven A., and Susan C. Ward. "Stereocontrolled photochemical [2 + 2] cycloaddition." Tetrahedron Letters 33, no. 8 (1992): 1013–16. http://dx.doi.org/10.1016/s0040-4039(00)91847-1.

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Treutwein, Jonas, and Gerhard Hilt. "Cobalt-Catalyzed [2+2] Cycloaddition." Angewandte Chemie International Edition 47, no. 36 (2008): 6811–13. http://dx.doi.org/10.1002/anie.200801778.

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Treutwein, Jonas, and Gerhard Hilt. "Cobalt-katalysierte [2+2]-Cycloaddition." Angewandte Chemie 120, no. 36 (2008): 6916–19. http://dx.doi.org/10.1002/ange.200801778.

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Dissertations / Theses on the topic "Cycloaddition [2+2+2]"

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Wan, Honghe. "Allenes and (2+2+1) cycloaddition reactions." Morgantown, W. Va. : [West Virginia University Libraries], 1998. http://etd.wvu.edu/templates/showETD.cfm?recnum=195.

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Thesis (M.S.)--West Virginia University, 1998.<br>Title from document title page. Document formatted into pages; contains xii, 99 p. : ill. Includes abstract. Includes bibliographical references (p. 93-99).
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Haraburda, Ewelina. "[2+2+2] cycloaddition reactions involving allenes catalysed by rhodium." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/328439.

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The development of new chemical processes for the formation of carbon-carbon bonds is an important topic in organic chemistry. In particular, the transition metal catalysed [2+2+2] cycloaddition reaction is a highly efficient synthetic tool that allows six-membered polysubstituted carbo- and heterocyclic derivatives to be obtained in an atom economy process. Allenes are versatile substrates for cycloaddition reactions that provide a good reactivity profile together with the ability to increase the stereochemical complexity of the cycloadducts obtained. This doctoral thesis, divided into seven
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Parera, Briansó Magda. "Transition metal-catalysed [2+2+2] cycloaddition reactions. Methodology and mechanism." Doctoral thesis, Universitat de Girona, 2014. http://hdl.handle.net/10803/145035.

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The transition-metal catalysed [2+2+2] cycloaddition reaction is a highly efficient synthetic tool that allows six-membered polysubstituted carbo- and heterocyclic derivatives to be obtained in an atom economy process. This doctoral thesis is based on methodological and mechanistic studies of the rhodium(I)-catalysed [2+2+2] cycloaddition reaction. In particular, the use of hemilabile S-stereogenic and P-stereogenic ligands for the rhodium-catalysed [2+2+2] cycloaddition is described. The activity of these new catalytic systems is evaluated in the cycloaddition of three alkynes and in the enan
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Fernández, Wang Martí. "New challenges in Rh(I)-catalysed [2+2+2] cycloaddition reactions." Doctoral thesis, Universitat de Girona, 2017. http://hdl.handle.net/10803/663661.

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This doctoral thesis studies the involvement of challenging unsaturated substrates in the transition-metal catalysed [2+2+2] cycloaddition reaction, as well as new catalytic systems for the reaction. First, Morita-Baylis-Hillman adducts are involved in the partial intramolecular rhodium(I)-catalysed [2+2+2] cycloaddition reaction. Next, linear chiral allene-yne/ene-allene substrates are synthesized and submitted to [2+2+2] cycloaddition reaction conditions. The process works with effective chirality induction of the chiral centres of the linear compounds to the cycloadducts. Following, the syn
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Dachs, Soler Anna. "Rhodium(I) catalyzed [2+2+2] cycloaddition reactions: experimental and theoretical studies." Doctoral thesis, Universitat de Girona, 2011. http://hdl.handle.net/10803/52981.

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The [2+2+2] cycloaddition reaction involves the formation of three carbon-carbon bonds in one single step using alkynes, alkenes, nitriles, carbonyls and other unsaturated reagents as reactants. This is one of the most elegant methods for the construction of polycyclic aromatic compounds and heteroaromatic, which have important academic and industrial uses. The thesis is divided into ten chapters including six related publications. The first study based on the Wilkinson’s catalyst, RhCl(PPh3)3, compares the reaction mechanism of the [2+2+2] cycloaddition process of acetylene with the cycloaddi
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Allart, Eric A. "Metal-promoted [3+2] and [4+2] cycloaddition reactions." Thesis, Loughborough University, 2008. https://dspace.lboro.ac.uk/2134/33615.

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Dicobalt complexes have been extensively used in synthetic chemistry to protect triple bonds, to form new carbon/carbon bonds using the Nicholas reaction and to form polycyclic molecules using the Pauson-Khand reaction. Using these dicobalt complexes, the formation of new carbon-heteroatom bonds was developed through [3+2] and [4+2] cycloaddition reactions via a stabilised dipole intermediate. Initial work carried out makes use of cyclopropanes substituted with a metal-alkyne complex towards the synthesis of tetrahydrofurans and pyrrolidines in good yields and with acceptable diastereoselectiv
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Garcia, Pierre. "Formation d'aminopyridines par cycloaddition [2+2+2] catalysée par des complexes du cobalt." Paris 6, 2013. http://www.theses.fr/2010PA066750.

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姚大源 and Tai-yuen Yue. "Cycloaddition reactions of 2-vinylchromones." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1992. http://hub.hku.hk/bib/B31210661.

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LLERENA, DOMINIQUE. "Reactions de cycloaddition (2+2+2) d'allenediynes catalysees par des complexes du cobalt (i)." Paris 6, 1995. http://www.theses.fr/1995PA066378.

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Des allenediynes diversement substitues, dont les syntheses originales sont decrites ont ete engages avec des quantites stoechiometriques de cpco(co)#2 dans des reactions de cycloaddition (2+2+2). Ces reactions ont permis la synthese de structures tricycliques analogues des cycles abc ou bcd de steroides. Par ailleurs, cette etude a permis de mettre en evidence une nouvelle catalyse de la ene-reaction par le cobalt mettant en jeu des composes allenynes
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Selva, Verónica. "Diastereoselective multicomponent [3+2] and [4+2] cycloadditions." Doctoral thesis, Universidad de Alicante, 2018. http://hdl.handle.net/10045/77573.

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En esta tesis doctoral se ha estudiado los iluros de azometino generados in situ en reacciones de cicloadición 1,3-dipolar y diferentes dipolarófilos para la síntesis multicomponente (libre de metales) de derivados de indolizidina a partir de pipecolinatos, aldehídos y dipolarofilos de forma térmica, y también a partir de ácido pipecólico de forma descarboxilada. También se ha estudiado la reacción de cicloadición 1,3-dipolar térmica multicomponente entre iluros de azometino no activados generados in situ a partir de aminas, aldehídos aromáticos y alquenos electrofílicos para generar derivados
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Books on the topic "Cycloaddition [2+2+2]"

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Davidson, Tony. Studies in the cobalt catalyzed [2+2+2+2] cycloaddition and deprotonation of dicobalt hexacarbonyl-acetylene complexes. National Library of Canada, 1990.

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Joseph Johannes Gerardus Steven van Es. 1, 3-cycloaddition reactions of diphenylphosphinoyl-activated azomethine ylides and 2-azaallyl anions: Synthetic applications and mechanistic aspects. Pasmans Offsetdrukkerij BV, 1992.

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Watanabe, Junʾichi. Hong 2/2. Cosmos, 1999.

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Domon, Fujuji. Uesugi 2/2. Gakuyo Shobo, 1992.

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Dmitriev, Oleg. 2-Obshchezhitie-2. Molodai︠a︡ gvardii︠a︡, 1988.

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Akagawa, Jirō. Wen 2/2. Zheng Wen, 2003.

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Denisov, Ėdison Vasilʹevich. Oktett für 2 Oboen, 2 Klarinetten, 2 Fagotte und 2 Hörner. H. Sikorski, 1991.

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Kagaku Busshitsu Hyōka Kenkyū Kikō and Shin Enerugī Sangyō Gijutsu Sōgō Kaihatsu Kikō (Japan), eds. 2-imidazorijinchion: 2-imidazolidinethione. Seihin Hyōka Gijutsu Kiban Kikō Kagaku Busshitsu Hyōka Kenkyū Kikō, 2009.

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Claude, Mutafian, ed. Erkir 2: Yergir 2. H.H. Khatcherian, 2011.

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Yoshimura, Tatsuya. Shou ji 2/2. Zheng Wen, 2002.

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Book chapters on the topic "Cycloaddition [2+2+2]"

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Laue, Thomas, and Andreas Plagens. "[2+2] Cycloaddition." In Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, 1994. http://dx.doi.org/10.1007/978-3-322-94015-5_28.

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Laue, Thomas, and Andreas Plagens. "[2+2]Cycloaddition." In Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, 1998. http://dx.doi.org/10.1007/978-3-322-94077-3_29.

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Laue, Thomas, and Andreas Plagens. "[2+2]Cycloaddition." In Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, 1994. http://dx.doi.org/10.1007/978-3-322-94726-0_28.

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Hayashi, Yujiro, and Koichi Narasaka. "[2+2] Cycloaddition Reactions." In Comprehensive Asymmetric Catalysis I–III. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-642-58571-5_10.

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Halevi, E. Amitai. "Cycloadditions and Cycloreversions I. [2+2]-Cycloaddition." In Orbital Symmetry and Reaction Mechanism. Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-83568-1_6.

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Gandon, Vincent. "Cobalt-Mediated [2 + 2 + 2] Cycloaddition." In Transition-Metal-Mediated Aromatic Ring Construction. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch1.

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Kumar, Puneet, and Janis Louie. "Nickel-Mediated [2 + 2 + 2] Cycloaddition." In Transition-Metal-Mediated Aromatic Ring Construction. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch2.

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Yamamoto, Yoshihiko. "Ruthenium-Mediated [2 + 2 + 2] Cycloaddition." In Transition-Metal-Mediated Aromatic Ring Construction. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch3.

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Tanaka, Ken. "Rhodium-Mediated [2 + 2 + 2] Cycloaddition." In Transition-Metal-Mediated Aromatic Ring Construction. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch4.

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Takeuchi, Ryo. "Iridium-Mediated [2 + 2 + 2] Cycloaddition." In Transition-Metal-Mediated Aromatic Ring Construction. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch5.

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Conference papers on the topic "Cycloaddition [2+2+2]"

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Gómez- Campillos, Gonzalo, Cristina Aragoncillo, Pedro Almendros, and Benito Alcaide. "Pd−Catalyzed Domino Alkyne Dimerization/Double [2+2] Allenyne Cycloaddition." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00252.

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Förster, Nadja, Ann-Christin Pöppler, and Philipp Vana. "UV-induced [2+2]-cycloaddition for shell-formation of star polymers." In 6TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS (TOP) AND COMPOSITES. AIP, 2012. http://dx.doi.org/10.1063/1.4738496.

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Mancini, Pedro, Claudia Della Rosa, and Maria Kneeteman. "Behaviour of 2-nitroheterocycles in Cycloaddition Reactions." In The 9th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01477.

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Montero-Campillo, M., Jesús Rodríguez-Otero, and Enrique Cabaleiro-Lago. "Selectivity of the Ru(II)-Catalyzed [2+2+2] Cycloaddition of 1,6-Diynes and Tricarbonyl Compounds." In The 12th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01286.

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Rajzmann, Michel, Agnés Pommier, Jean-Marc Pons, Philippe Thomas, and André Baldy. "A semiempirical theoretical study of the [2+2] cycloaddition between ketene and formaldehyde." In The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47652.

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Yi, Jun, Junpeng Wang, and Zhou Lin. "MECHANISTIC STUDY OF PHOTOCHEMICAL [2+2] CYCLOADDITION BETWEEN 1,5-CYCLOOCTADIENE AND MALEIC ANHYDRIDE." In 2022 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2022. http://dx.doi.org/10.15278/isms.2022.rh11.

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Montero­Campillo, M., Enrique Cabaleiro­Lago, and Jesús Rodríguez­Otero. "On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes." In The 11th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2007. http://dx.doi.org/10.3390/ecsoc-11-01369.

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Sheradsky, Tuvia, and Elliad Silcoff. "The Synthesis of (2R,5R)-2-Amino-5-Hydroxyhexanoic Acid by Intermolecular Cycloaddition." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02026.

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Ramasami, Ponnadurai, Hanusha Bhakhoa, and Lydia Rhyman. "Copper(I) Catalyzed [3+2] Cycloaddition Reaction with Mechanistic Disparity: A DFT Study." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-e017.

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Barcellos, Júlio C. F., Ayres G.Dias, and Paulo R. R.Costa. "Synthesis of Azapterocarpan Analogues by Intramolecular 1,3-dipolar Cycloaddition." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0090-2.

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Reports on the topic "Cycloaddition [2+2+2]"

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Hunn, John D., Robert Noel Morris, Charles A. Baldwin, and Fred C. Montgomery. Safety Testing of AGR-2 UCO Compacts 5-2-2, 2-2-2, and 5-4-1. Office of Scientific and Technical Information (OSTI), 2016. http://dx.doi.org/10.2172/1328314.

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Hunn, John, Will Cureton, Darren Skitt, and Fred Montgomery. SAFETY TESTING OF AGR-5/6/7 COMPACTS 2-2-2 AND 2-2-4. Office of Scientific and Technical Information (OSTI), 2022. http://dx.doi.org/10.2172/1887660.

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Hunn, John D., Fred C. Montgomery, Tamara {Tammy} Jo Keever, Benjamin Roach, and Ralph Ilgner. Determination of Average Burnup in AGR-2 Compacts 3-3-1, 3-3-2, 2-2-2, and 6-4-2. Office of Scientific and Technical Information (OSTI), 2019. http://dx.doi.org/10.2172/1569364.

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Kettell, S. H. Measurement of the 2 sup 2 S sub 1/2 -2 sup 2 P sub 3/2 fine structure interval in muonium. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6849854.

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Montgomery, Fred C., John D. Hunn, Tamara J. Keever, et al. Measurement of Average Burnup in TRISO-Coated Particles from AGR-2 UCO Compacts 2-2-2 and 6-4-2. Office of Scientific and Technical Information (OSTI), 2018. http://dx.doi.org/10.2172/1476419.

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Amornrattanapong, Weeraphat. Malware Analysis Day 2 - Part 2. Office of Scientific and Technical Information (OSTI), 2019. http://dx.doi.org/10.2172/1574734.

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Armstrong, Beth, Lucy King, Robin Clifford, and Mark Jitlal. Food and You 2 - Wave 2. Food Standards Agency, 2021. http://dx.doi.org/10.46756/sci.fsa.dws750.

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Food and You 2 is a biannual survey which measures self-reported consumer knowledge, attitudes and behaviours related to food safety and other food issues amongst adults in England, Wales, and Northern Ireland. The survey is primarily carried out online using a methodology known as ‘push-to-web’. Fieldwork was conducted between 20 November 2020 and 21 January 2021. A total of 5,900 adults from 3,955 households across England, Wales and Northern Ireland completed the survey. Topics covered in the Food and You 2: Wave 2 Key Findings report include: Trust in FSA and the food supply chain Concerns
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Hunn, John D., Robert Noel Morris, Charles A. Baldwin, and Fred C. Montgomery. Safety testing of AGR-2 UO2 compacts 3-3-2 and 3-4-2. Office of Scientific and Technical Information (OSTI), 2015. http://dx.doi.org/10.2172/1222564.

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Hunn, John, Robert Morris, and Charles Baldwin. Safety Tests on Irradiated AGR-1 Compacts 3-3-2, 3-2-2, and 6-2-1. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1649218.

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Belshe, M., and R. Peon. Hypertext Transfer Protocol Version 2 (HTTP/2). Edited by M. Thomson. RFC Editor, 2015. http://dx.doi.org/10.17487/rfc7540.

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