Academic literature on the topic 'Cycloaddition reactions'

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Journal articles on the topic "Cycloaddition reactions"

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Grygorenko, Oleksandr O., Viktoriia S. Moskvina, Oleksandr V. Hryshchuk, and Andriy V. Tymtsunik. "Cycloadditions of Alkenylboronic Derivatives." Synthesis 52, no. 19 (2020): 2761–80. http://dx.doi.org/10.1055/s-0040-1707159.

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The literature on cycloaddition reactions of boron-containing alkenes is surveyed with 132 references. The data are categorized according to the reaction type ([2+1], [2+2], [3+2], [4+2], and [4+3] cycloadditions). The cyclopropanation and the Diels–Alder reactions of alkenylboronic derivatives have been studied more or less comprehensively, and for some substrates, they can be considered as convenient methods for the rapid regio- and stereoselective construction of even complex cyclic systems. Other types of the cycloadditions, as well as mechanistic aspects of the processes, have been addres
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Svete, Jurij, Uroš Grošelj, Franc Požgan, and Bogdan Štefane. "Copper-Catalyzed Azomethine Imine–Alkyne Cycloadditions (CuAIAC)." Synthesis 50, no. 23 (2018): 4501–24. http://dx.doi.org/10.1055/s-0037-1610284.

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Although the first example of copper-catalyzed azomethine imine–alkyne cycloaddition (CuAIAC) was published only a year after the seminal papers of Meldal and Sharpless on Cu-catalyzed azide–alkyne cycloaddition (CuAAC), the CuAIAC reaction has remained overlooked by the synthetic community for almost a decade. Since 2010, however, CuAIAC reaction started to emerge as a promising supplement to the well-known CuAAC reaction. The present review surveys primarily the literature on CuAIAC reaction since 2003. Beside this, azomethine imine–alkyne cycloadditions catalyzed by other metals, selected e
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Zhou, You-Yun, and Christopher Uyeda. "Catalytic reductive [4 + 1]-cycloadditions of vinylidenes and dienes." Science 363, no. 6429 (2019): 857–62. http://dx.doi.org/10.1126/science.aau0364.

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Cycloaddition reactions provide direct and convergent routes to cycloalkanes, making them valuable targets for the development of synthetic methods. Whereas six-membered rings are readily accessible from Diels-Alder reactions, cycloadditions that generate five-membered rings are comparatively limited in scope. Here, we report that dinickel complexes catalyze [4 + 1]-cycloaddition reactions of 1,3-dienes. The C1partner is a vinylidene equivalent generated from the reductive activation of a 1,1-dichloroalkene in the presence of stoichiometric zinc. Intermolecular and intramolecular variants of t
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Kotha, Sambasivarao, Kakali Lahiri, and Gaddamedi Sreevani. "Design and Synthesis of Aromatics through [2+2+2] Cyclotrimerization." Synlett 29, no. 18 (2018): 2342–61. http://dx.doi.org/10.1055/s-0037-1609584.

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The [2+2+2] cycloaddition reaction is a useful tool to realize unusual chemical transformations which are not achievable by traditional methods. Here, we report our work during the past two decades that involve utilization of transition-metal complexes in a [2+2+2] cyclotrimerization reaction. Several key “building blocks” were assembled by a [2+2+2] cycloaddition approach and they have been further expanded by other synthetic transformations to design unusual amino acids and peptides, diphenylalkanes, bis- and trisaryl benzene derivatives, annulated benzocycloalkanes, spirocycles, and spiroox
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Cordero, Franca Maria, Donatella Giomi, and Fabrizio Machetti. "Synthesis of 2-Azetidinones via Cycloaddition Approaches: An Update." Reactions 5, no. 3 (2024): 492–566. http://dx.doi.org/10.3390/reactions5030026.

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The present review is a comprehensive update of the synthesis of monocyclic β-lactams via cycloaddition reactions. According to the IUPAC definition of cycloaddition, both elementary and stepwise processes (formal cycloadditions) have been considered. The years 2019–2022 are covered by the cited literature. The focus of the review is on synthetic aspects with emphasis on the structural scope, reaction conditions, mechanistic aspects, and selectivity results. Selected significant data related to biological activities and synthetic applications are also highlighted.
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Kalluraya, Balakrishna, Kaushik B R, and H. M. Somashekarappa. "Effect of Gamma- Irradiation on Structure, Morphology and Thermal Properties of Novel Polyamide Based Thermoset Obtained by Double Cycloaddition." Journal of Modern Materials 7, no. 1 (2020): 17–25. http://dx.doi.org/10.21467/jmm.7.1.17-25.

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Cycloaddition reactions gained prominence in macromolecular chemistry for generating macromolecules because of high yields of these reactions, which is a key tool that drives polyaddition reactions. Cycloaddition reaction plays major role in extension of polymerisation or in other words high conversions of monomers to macromolecules of high molecular weights. Until the late 1990s, the major studies regarding cycloadditions in novel polymer synthesis were related to polyaddition reactions. Since then in the field of polymer synthesis the affirmative strengths of these cycloaddition reactions ha
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Mlostoń, Grzegorz, Yuriy Shermolovich, and Heinz Heimgartner. "Synthesis of Fluorinated and Fluoroalkylated Heterocycles Containing at Least One Sulfur Atom via Cycloaddition Reactions." Materials 15, no. 20 (2022): 7244. http://dx.doi.org/10.3390/ma15207244.

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Fluorinated heterocycles constitute an important group of organic compounds with a rapidly growing number of applications in such areas as medicinal chemistry, agrochemicals production, polymer chemistry, as well as chemistry of advanced materials. In the latter case, fluorinated thiophenes are considered as a lead class of compounds with numerous spectacular applications. On the other hand, cycloaddition reactions offer a superior methodology for stereo-chemically controlled synthesis of heterocycles with a diverse ring size and a variable number of heteroatoms. A comprehensive review of meth
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Li, Jin-Heng, De-Lie An, and Jing-Hao Qin. "Recent Advances in Cycloaddition Reactions with Alkynes to Construct Heterocycles." Synthesis 52, no. 24 (2020): 3818–36. http://dx.doi.org/10.1055/s-0040-1707355.

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Heterocyclic compounds, especially N-heterocycles and O-heterocycles, are prominent structural motifs present in numerous natural products and medically and/or economically important compounds. This review aims to describe the development of transition-metal-catalyzed cycloaddition reactions of functionalized m-atom partners with alkynes to access a wide range of five-, six-, and seven-membered heterocycles, that is functionalized N-heterocycles and O-heterocycles such as azepines, isoquinolines, isocoumarins, spiroheterocycles, indoles, furans, and pyrroles, in a selectively controlled manner
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Tietze, L. F., G. Kettschau, J. A. Gewert, and A. Schuffenhauer. "Hetero-Diels-Aider Reactions of 1-0xa-1,3-butadienes." Current Organic Chemistry 2, no. 1 (1998): 19–62. http://dx.doi.org/10.2174/1385272802666220126210654.

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Many biologically active and widely distributed natural products contain a dihydro- or a tetrahydropyran moiety. One of the best methods for the synthesis of these compounds is the hetero Diels-Aider reaction of 1-0Xia-1,3-butadienes which leads to substituted and annulated 3,4-dihydro-2H-pyrans usually in excellent yields and high selectivity. Further transformations of these substances e.g. by hydrogenation yield the tetrahydropyrans with the basic skeleton of the carbohydrates. In this article at first theoretical aspects of the cycloaddition are discussed which include ab initio calculatio
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Asmita, Mondal, Banerji Avijit, and Acharjee Nivedita. "Understanding [3 + 2] cycloaddition reactions from the molecular electron density perspective : A new theoretical outlook on organic reactions." Education in Chemical Science and Technology Vol. 3, Aug 2022 (2022): 131–50. https://doi.org/10.5281/zenodo.6822007.

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Department of Chemistry, Durgapur Government College, Durgapur-713 214, West Bengal, India Central Ayurveda Research Institute (CARI), Calcutta-700 091, West Bengal, India E-mail: ablabcu@yahoo.co.uk Cycloaddition reactions share the top shelf priority in the toolbox of organic chemists owing to their diverse pharmaceutical and industrial applications. The frontiers molecular orbital (FMO) theory has been used to study the reactivity of cycloaddition reactions since nearly the last five decades, though there have been criticisms, and even instances of failures. In 2016, an appealing alternativ
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Dissertations / Theses on the topic "Cycloaddition reactions"

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Boyd, Susan Mary. "Asymmetric cycloaddition reactions." Thesis, University of Oxford, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293374.

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Paramasivam, Indrani. "Alkyne cycloaddition reactions." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46486.

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Moore, Jane Elizabeth. "Cycloaddition reactions of alkynylboronates." Thesis, University of Sheffield, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420776.

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Ghose, S. "Cycloaddition reactions of nitroalkenes." Thesis, University of Liverpool, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.384381.

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Bragdon, Jason Paul. "Metal-Catalyzed Cycloaddition Reactions." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1244575259.

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姚大源 and Tai-yuen Yue. "Cycloaddition reactions of 2-vinylchromones." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1992. http://hub.hku.hk/bib/B31210661.

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Leslie, Morag Garden. "Cycloaddition reactions of jojoba oil." Thesis, University of Edinburgh, 1990. http://hdl.handle.net/1842/12407.

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The cycloaddition reactions of nitrile oxides with jojoba oil have been investigated. The nitrile oxides were generated <i>in situ</i> by two principal routes: (i) by the base catalysed dehydration of nitromethyl compounds using tolylene-2,4-diisocyanate (the Mukaiyama method), and (ii) by thermolysis of nitro-acetate and -malonate esters (the Shimizu method). In order to faciliate the identification of modified jojoba products and establish optimum conditions for reaction with the unsaturation present in jojoba oil, the cycloaddition reactions of nitrile oxides with selected model alkenes wer
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Shengxian, Zhao. "Cycloaddition reactions of meso-tetraarylporphyrins." Doctoral thesis, Universidade de Aveiro, 2005. http://hdl.handle.net/10773/4871.

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Doutoramento em Química<br>O trabalho apresentado nesta dissertação descreve o comportamento de meso-tetra-arilporfirinas em reacções de ciclo-adição e suas possíveis aplicações na síntese de novas porfirinas com grupos policíclicos aromáticos (“π-extended porphyrins”). No capítulo 1 apresenta-se uma revisão das aplicações de porfirinas e compostos afins e também das reacções de ciclo-adição que envolvem ligações duplas (periféricas) do macrociclo. O capítulo 2 descreve o trabalho feito em reacções de cicloadição 1,3-dipolar de meso-tetra-arilporfirinas com iletos de azometino. Considerou-s
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Braunton, Alan James. "Tethered cycloaddition reactions for heterocycle synthesis." Thesis, Imperial College London, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.407915.

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Heaney, Mary Frances Teresa. "Cycloaddition reactions of oximes and imines." Thesis, Queen's University Belfast, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335415.

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Books on the topic "Cycloaddition reactions"

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Margetic, Davor. Microwave assisted cycloaddition reactions. Nova Science Publishers, 2012.

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Giuliano, Robert M., ed. Cycloaddition Reactions in Carbohydrate Chemistry. American Chemical Society, 1992. http://dx.doi.org/10.1021/bk-1992-0494.

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Carruthers, W. Cycloaddition reactions in organic synthesis. Pergamon, 1990.

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1954-, Giuliano Robert M., American Chemical Society. Division of Carbohydrate Chemistry., and American Chemical Society Meeting, eds. Cycloaddition reactions in carbohydrate chemistry. American Chemical Society, 1992.

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name, No. Cycloaddition reactions in organic synthesis. Wiley-VCH, 2002.

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1959-, Kobayashi S., and Jørgensen Karl Anker, eds. Cycloaddition reactions in organic synthesis. Wiley-VCH, 2002.

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Ma, Jihai. Mono(trimethylsilyl) bisketenes: Cycloaddition and electrophilic addition reactions. National Library of Canada = Bibliothèque nationale du Canada, 1997.

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Nishiwaki, Nagatoshi, ed. Methods and Applications of Cycloaddition Reactions in Organic Syntheses. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118778173.

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Montana, John Gary. The synthesis of novel prostaglandin analogues via cycloaddition reactions. University of East Anglia, 1989.

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Rigby, Samantha Jayne. Towards the recognition-mediated control and acceleration of cycloaddition reactions. University of Birmingham, 2000.

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Book chapters on the topic "Cycloaddition reactions"

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Szpilman, Alex M., and Erick M. Carreira. "Cycloaddition Reactions." In Silver in Organic Chemistry. John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470597521.ch2.

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Desimoni, Giovanni, and Giuseppe Faita. "Cycloaddition Reactions." In Quaternary Stereocenters. Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/3527606858.ch6.

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Dinda, Biswanath. "Cycloaddition Reactions." In Lecture Notes in Chemistry. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-45934-9_3.

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Li, Jie Jack. "Staudinger ketene cycloaddition." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_259.

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Li, Jie Jack. "Staudinger ketene cycloaddition." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_242.

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Dennis, N. "Addition Reactions: Cycloaddition." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470975800.ch12.

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Dennis, N. "Addition Reactions: Cycloaddition." In Organic Reaction Mechanisms · 2008. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470979525.ch12.

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Dennis, N. "Addition Reactions: Cycloaddition." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9781119972471.ch12.

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Dennis, N. "Addition Reactions: Cycloaddition." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2014. http://dx.doi.org/10.1002/9781118560273.ch12.

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Truscott, Fiona R., Giovanni Maestri, Raphael Rodriguez, and Max Malacria. "Catalytic Cycloaddition Reactions." In Modern Alkyne Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527677894.ch6.

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Conference papers on the topic "Cycloaddition reactions"

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Mangalagiu, Violeta, Dorina Amariucai-Mantu, Dumitrela Diaconu, Vasilichia Antoci, and Ionel Mangalagiu. "MICROWAVE AND ULTRASOUND ASSISTED SYNTHESIS AS ECOLOGICALLY FRIENDLY METHODS IN NITROGEN HETEROCYCLIC CHEMISTRY." In SGEM International Multidisciplinary Scientific GeoConference. STEF92 Technology, 2024. https://doi.org/10.5593/sgem2024v/6.2/s23.04.

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On the last few years, microwave and ultrasound irradiation has become a successful tool in modern medicinal and organic chemistry especially (but not only) because in many cases synthesis became ecologically friendly. As part of our ongoing efforts in the field of nitrogen heterocyclic derivatives, we present herein some core results obtained by our group in the field of N-alkylation and 3+2 cycloadditions reactions applied in the nitrogen heterocycles series, by using microwave and ultrasound irradiation. Comparative with conventional thermal heating, undeniable advantages of using microwave
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Ramasami, Ponnadurai, Lydia Rhyman, John Joule, and Luis Domingo. "Theoretical Studies on Cycloaddition Reactions." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-e022.

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Diaconu, Dumitrela, Violeta Mangalagiu, Dorina Amariucai-Mantu, Vasilichia Antoci, Ramona Danac, and Ionel Mangalagiu. "1,3-dipolar cycloaddition reactions of benzimidazolium-ylides to an activated symmetric alkyne." In Scientific seminar with international participation "New frontiers in natural product chemistry". Institute of Chemistry, Republic of Moldova, 2023. http://dx.doi.org/10.19261/nfnpc.2023.ab27.

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The cycloaddition reactions represent an important way to obtain cyclic structures and take place between two or more reactants containing double or triple bonds in the molecule. After Huisgen, the addition of 1,3-dipole to a dipolarophile, takes place through a concerted mechanism, when two  bonds are formed. [1,2] The purpose of this research is to study the Huisgen [3+2] dipolar cycloaddition reactions carried out in a conventional way (stirring at room temperature) and non-conventional way (ultrasonic irradiation), between benzimidazolium-ylides and an activated symmetric substituted alky
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Mancini, Pedro, Claudia Della Rosa, and Maria Kneeteman. "Behaviour of 2-nitroheterocycles in Cycloaddition Reactions." In The 9th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01477.

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Bastrakov, Maxim, Alexey Starosotnikov, Alexey Fedorenko, and Vladislav Nikol’skyа. "REACTIONS OF NITROPYRIDINES WITH NUCLEOPHILES: SUBSTITUTION, ADDITION, CYCLOADDITION." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m744.aks-2019/168-170.

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Cossío, Fernando, Aitor Lacambra, Ivan Rivilla, and Stéphane Quideau. "New Methods For Stereocontrolled Cycloaddition/Dearomatization Reactions Under Catalytic Conditions." In MOL2NET 2016, International Conference on Multidisciplinary Sciences, 2nd edition. MDPI, 2016. http://dx.doi.org/10.3390/mol2net-02-h006.

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Komarova, Ol’ga, Ruslan Baichurin, and Nataliya Aboskalova. "GEMINALLY ACTIVATED 4-PHENYL-1-NITRO-1,3-BUTADIENES IN CYCLOADDITION REACTIONS." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m791.aks-2019/352-355.

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Mancini, Pedro, Claudia Della Rosa, and Maria Kneeteman. "Comparison of the Reactivity Between Nitrothiophenes and Nitroselenophenes in Polar Cycloaddition Reactions." In The 12th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01250.

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Momo, Patrícia B., Ricardo B. Ayres, Timothy J. Brocksom, and Kleber T. de Oliveira. "1,3-Dipolar Cycloaddition Reactions of meso-Tetra(2’- thienyl)porphyrins with a Nitrile Oxide." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201391291318.

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Najera, Carmen, Tomas Abellan, Jesus Casas, Ana Costa, and José Sansano. "1,3-Dipolar Cycloaddition Reactions with Azomethine Ylides Catalysed by Ag(I). Synthesis of Substituted Prolines." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01810.

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